Determination of cadmium(II), copper(II), manganese(II) and nickel(II) species in Antarctic seawater with complexing resins   总被引：1，自引：0，他引：1  

Raffaela Biesuz  Giancarla Alberti  Girolamo D'Agostino  Emanuele Magi  Maria Pesavento 《Marine Chemistry》2006,101(3-4):180-189

The strong species of cadmium(II), copper(II), manganese(II) and nickel(II) in an Antarctic seawater sample are investigated by a method based on the sorption of metal ions on complexing resins. The resins compete with the ligands present in the sample to combine with the metal ions. Two resins with different adsorbing strengths were used. Very stable metal complexes were investigated with the strong sorbent Chelex 100 and weaker species with the less strong resin, Amberlite CG-50. Strong species were detected for three of the considered metal ions, but not for Mn(II). Cu(II) is completely linked to species with a side reaction coefficient as high as log α_M(I) = 11.6 at pH = 7.3. The ligand concentration was found to be similar to that of the metal ion, and the conditional stability constant was around 10²⁰ M^− 1. In the considered sample, only a fraction of the metal ions Cd(II) and Ni(II) is bound to the strong ligands, with side reaction coefficients equal to log α_M(I) = 5.5 and 6.5 at pH = 7.3 for Cd(II) and Ni(II), respectively. These findings were confirmed by the test with the weaker sorbent Amberlite CG-50. It can be calculated from the sorption equilibria that neither Mn(II) nor Ni(II) is adsorbed on Amberlite CG-50 under the considered conditions and, in fact, only a negligible fraction of Mn(II) and Ni(II) was adsorbed. A noticeable fraction of Cd(II) was adsorbed on Amberlite CG-50, meaning that cadmium(II) is partially linked to weak ligands, possibly chloride, while no copper(II) was adsorbed on this resin, confirming that copper(II) is only combined in strong species. These results are similar, but not identical, to those obtained for other seawater samples examined in previous investigations.  相似文献   

Modelling linear wave transformation induced by dissipative structures—Random waves     

R. Silva  M.A. Losada  P. Salles 《Ocean Engineering》2006,33(16):2174-2194

The relevant theory is presented and numerical results are compared with the analytical solution for the interaction of non-breaking waves with an array of vertical porous circular cylinders on a horizontal bed. The extension to the cases of unidirectional and multidirectional waves is obtained by means of a transfer function. The influence of the mechanical properties of porous structures and wave irregularity on wave transformation is analysed. Results for unidirectional and multidirectional wave spectra are compared to those obtained for regular waves. The model presented reproduces well the analytical results and provides a tool for analysing several engineering problems.  相似文献   

山东全新世滨海软土与工程地质灾害的研究   总被引：2，自引：0，他引：2  

吴建政 《海洋地质与第四纪地质》1995,15(3):43-54

山东全新世滨海软土分布在海湾、泻湖、河口区，厚度１－１０ｍ。海湾、泻湖软土为淤泥、淤泥质土，陆源物质供应丰富的浅水区，软土颗粒偏粗，强度相对较高，触变性对建筑物危害性大，陆源物质供应少的深水区，软土颗粒偏细，低强度、高压缩性、沉降变形大和蠕变性是危及建筑物稳定的主要因素。海湾、泻湖软土位于地下水位下，具低透水性，掩埋后短期不易排水固结，软土下为强度较高的冲积物，对一般建筑物，利用强夯、粉喷搅拌桩、  相似文献   

柴达木盆地新构造运动主要特征与成因机制   总被引：10，自引：0，他引：10  

杨明慧 《海洋地质与第四纪地质》1997,17(3):71-78

研究表明，在壳幔结构、地球物理背景、沉积物结构、多层关地幔和构造样式等方面，达木盆地与中国东部新生代裂谷类伸展盆地具有可比性，应该归属 展性盆 。盆地伸展和收缩作用相间进行，伸展起因于地幔底辟；而收缩受两人因素影响；（１）盆地伸展作用受相邻造山带反作用诱导的挤压应力；（２）板块碰撞传递的远程板内应力。在此基础邮新的构造期达木盆地演化的“双层模式”，即地幔上隆－地壳伸展；被动挤压＋板内应力－地壳收缩  相似文献   

波浪底摩擦力对重砂富集的影响——以鲁南近岸区为例     

金秉福 《海洋科学》1997,21(5):49-52

根据浅水波浪的底摩擦效应，对鲁南灵山湾和臼－岚山镇近岸区进行了波浪的海底摩擦力计算。波浪的海底摩擦力等值图与已知滨海锆石砂矿资料对比表明，底摩擦力大于０．１８Ｎ／ｍ＾２的动力分选区有利于重矿物砂富集。据此，进一步预测了鲁南近岸带的砂矿富集区。  相似文献   

Applying an alternative method of echo-integration     

Aksland  Magnar 《ICES Journal of Marine Science》2006,63(8):1438-1452

  相似文献   

Time changes in fishing power in the Danish cod fisheries of the Baltic Sea     

Marchal  Paul; Nielsen  J. Rasmus; Hovgard  Holger; Lassen  Hans 《ICES Journal of Marine Science》2001,58(1):298-310

  相似文献   

山东沿海旅游业可持续发展对策研究   总被引：4，自引：1，他引：4  

盛红  董玉明 《海岸工程》2001,20(4):63-68

滨海旅游是旅游活动的重要组成部分 ,在我国具有广阔的发展潜力。在讨论了山东沿海旅游业发展中存在的问题的基础上 ,指出发展滨海旅游与滨海和海洋环境之间的相关关系 ,探讨了使山东沿海旅游业可持续发展的主要对策  相似文献   

对虾体内氯霉素含量测定方法的研究   总被引：1，自引：0，他引：1  

李兰生  王勇强 《中国海洋大学学报(自然科学版)》1995,(3)

应用ＨＰＬＣ技术建立常用药物氯霉素的虾体动力学研究方法。该方法的特点是：与微生物法、比色法、气相色谱法、荧光法及免疫法比较．测试准确、快速且灵敏度高。应用该方法可以从虾体内的血液、肌肉、肝胰脏、肠胃中分离出被虾吸收的氯霉素，并定量测定。在１—５０μｇ／ｍｌ范围内线性关系相关系数为０．９９９５。  相似文献   

山东省淡水枝角类的初步调查   总被引：4，自引：0，他引：4  

毛乾盛 《海洋湖沼通报》1993,(2):78-83

山东省淡水水域广阔,不仅河流多,而且湖泊、水库、坑塘星罗棋市,资源丰富。其中的淡水枝角类是水体食物链之重要环节,对渔业主产和环境保护工作具有相当重要的现实的意义。因此,必须对其更好地调查研究如培育利用。笔者多年来,就山东省若干地区的淡水枝角类进行采集、分类等研究工作。本文报道其初步结果——隶属7科,24属,71种。  相似文献