A stochastic model of surface contaminant releases to support assessment of site contamination at a former industrial site     

R. Mackay  J.A. Morakinyo 《Stochastic Environmental Research and Risk Assessment (SERRA)》2006,20(3):213-222

An industrial site is usually contaminated by accidental (and occasionally intentional) releases of pollutants to the environment from various operations carried out on that site. Consequently, the pattern of contamination created during the life of the site depends in part, at least, on the pattern of operations. Thus, the assessment of the pattern of contamination over the site should be improved: if it is possible to identify the pattern of operations on the site, the duration of the different activities and the perceived likelihood of releases from the different operations. A stochastic model has been developed that can be used to simulate alternative realizations of contaminant releases (duration, extent and timing). The model employs release zones associated with particular activities or groups of activities on the site and the areas of each of the zones may be independent or overlapping. The period of activity in each zone is obtained from the site records, while the likelihood and extent of contamination in each zone is inferred from an analysis of the contamination data obtained by point sampling. The form of the model, the method of inference of the model parameter values from the site data and the application of the model to the study site are presented. The release model has been developed as part of a suite of stochastic models for site ground contamination analysis. The stochastic soil and transport models and the application of the integrated modelling system are described in separate papers.  相似文献   

Mineralogy and heavy metal content in sediments from Rio Gato,Carelmapu and Cucao,Southern Chile     

I. González  M. M. Jordán  T. Sanfeliu  M. Quiroz  C. de la Fuente 《Environmental Geology》2007,52(7):1243-1251

In southern Chile, with a mild and rainy climate, high levels of heavy metals have been detected in many gold placer deposits. Many of the contaminants pose risks to human life, and consequently damage the trofic chain in this environment. The study zones selected correspond to the handicraft gold-bearing sands of Rio Gato (Los Muermos), Carelmapu and Cucao. These are all located in the X Region of “Los Lagos” in Chile. The type of methodology used in the characterization of the associated mineralization consists of testing each representative sample with a grain size distribution, statistical parameter analysis and a mineralogical analysis, using a binocular magnifying glass, a petrographic microscope, XRD and SEM/EDX. The chemical composition was defined by means of X ray fluorescence and micro-chemical analysis. The results of the study about sediments in southern Chile are presented. The major concentrations of heavy minerals are generally located in areas of dynamic river energy. In the samples, more than 70% of the heavy minerals were distributed among grain sizes corresponding to thin sand with good grain selection (meshes of 0.25–0.06 mm). The main mineral phases present in the analysed samples were gold, zircon, olivine, ilmenite, hornblende, hypersthene, hematite, garnet, chromite, chlorite, augite, amphibolitic-epidote, etc. The main heavy metals found as a result of the study were mercury, lead, cadmium, chrome, tellurium, indium, zinc, cobalt, copper, platinum, gold, etc., and as well some less common elements like cerium, praseodymium, gadolinium, neodymium, samarium and lanthanum. This research work is only a starting point for carrying out a risk probability mapping of heavy metals and the mineralogy of the Cucao, Carelmapu and Rio Gato gold-bearing sands.  相似文献   

Gravitational model of the Taiwan lithosphere (along the profile Taiwan Strait-Taiwan Island-West Philippine basin)     

G. Z. Gil’manova  V. Ya. Podgornyi 《Russian Journal of Pacific Geology》2007,1(3):230-239

Based on two-dimensional gravity modeling, the density section of the lithosphere beneath Taiwan and the surrounding areas is constructed. According to the density parameters, the lithosphere of this region comprises both the continental and oceanic types. The continental lithosphere is lighter than the oceanic one and demonstrates insignificant density differentiation through the entire section. The oceanic lithosphere is more contrasting with respect of both the crust and mantle density. The complicated Taiwan density structure corresponding to Taiwan Island is defined to be superimposed on the transition zone between the continental and oceanic lithospheric blocks. This structure with contrasting density boundaries is characterized by the elevated and high density values of its constituting heterogeneities. The formation of the Taiwan density structure is related to geodynamic processes in the Taiwan area marking the collision zone between the Eurasian and Philippine Sea plates.  相似文献   

苏鲁超高压变质带的深部构造特征——宽频地震层析结果     

姜枚  王亚军刘因钱辉  李庆庆 《岩石学报》2007,23(12):3302-3308

为了探测苏鲁超高压变质带的岩石圈结构实施了山东日照到滨洲剖面的宽频带地震探测,于2003～2005年使用REFTER130-01型和CMG-6TD型三分量地震仪(频宽50～60s).以10～25km间距布设了25个台站观测近三年时间.由远震地震层析反演结果得到了华北板块、超高压变质带、扬子板块清晰的P波速度图像.华北板块具有简单的低速体形态,越过郯庐断裂向超高压变质带扩张,并平稳地由郯庐断裂向北延伸直到黄河以北的古城镇.Moho面和岩石圈深度分别为30～35km,75～80km;扬子板块为高速体,界于两者之间的苏鲁超高压变质带地壳的平均速度大于两侧板块,剖面上从日照到五莲-烟台断裂范围内除地壳为高速体外,30～60km深度范围内有一个高速体和一个低速体拼会在一起,构成了超高压变质带岩石圈最突出的构造特征.此高速体应为榴辉橄榄岩等超基性岩组成,它可能属于折返回来又被移动的超高压变质岩组合体,并与华北板块基底直接接触,超高压变质带的下界面深度为60km.下界面平直,可能意味着正在消退的造山带的山根,或是造山带的下一层Moho面?郯庐断裂带地壳出露的共四条带,比较陡的产状向深部延伸,并逐步向南倾,TLF2～TLF4在岩石圈底界处合并.  相似文献   

Magmatic History of Somma-Vesuvius on the Basis of New Geochemical and Isotopic Data from a Deep Borehole (Camaldoli della Torre)   总被引：3，自引：0，他引：3  

Di Renzo  V.; Di Vito  M. A.; Arienzo  I.; Carandente  A.; Civetta  L.; D'antonio  M.; Giordano  F.; Orsi  G.; Tonarini  S. 《Journal of Petrology》2007,48(4):753-784

A continuous-coring borehole recently drilled at Camaldoli dellaTorre on the southern slopes of Somma–Vesuvius providesconstraints on the volcanic and magmatic history of the Vesuvianvolcanic area since c. 126 ka BP. The cored sequence includesvolcanic units, defined on stratigraphical, sedimentological,petrological and geochemical grounds, emitted from both localand distal vents. Some of these units are of known age, suchas one Phlegraean pre-Campanian Ignimbrite, Campanian Ignimbrite(39 ka), Neapolitan Yellow Tuff (14· 9 ka) and VesuvianPlinian deposits, which helps to constrain the relative ageof the other units. The main rock types encountered are shoshonite,phonotephrite, latite, trachyte and phonolite. The sequenceincludes, from the base upwards: a thick succession of pyroclasticunits emplaced between 126 and 39 ka, most of them attributedto eruptions that occurred in the Phlegraean area; the CampanianIgnimbrite; the products of a local tuff cone formed between39 ka and the deposition of the products of the earliest activityof the Mt. Somma volcano; the products of the Somma–Vesuviusvolcano, which include from the base upwards a thick sequenceof lavas, pyroclastic rocks and the products of a local spattercone dated between 3· 7 ka and AD 79. The data obtainedfrom the study of the borehole show that, before the CampanianIgnimbrite eruption, low-energy explosive volcanism took placein the Vesuvian area, whereas mostly high-energy explosive eruptionscharacterized the Campi Flegrei activity. In the Vesuvian area,Campanian Ignimbrite deposition was followed by the eruptionof a local tuff cone and a long repose time, which predatedthe formation of the Mt. Somma edifice. Since 18· 3 ka(Pomici di Base eruption) the activity of Somma–Vesuviusbecame mostly explosive with rare lava effusions. The shallowestcored deposits belong to the Camaldoli della Torre cone, formedbetween the Pomici di Avellino and Pomici di Pompei eruptions(3· 7 ka–AD 79). New geochemical and Sr–Nd–Pb–B-isotopicdata on samples from the drilled core, together with those availablefrom the literature, allow us to further distinguish the volcanicrocks as a function of both their provenance (i.e. Phlegraeanor Vesuvian areas) and age, and to identify different magmaticprocesses acting through time in the Vesuvian mantle source(s)and during magma ascent towards the surface. Isotopically distinctmagmas, rising from a mantle source variably contaminated byslab-derived components, stagnated at mid-crustal depths (8–10km below sea level) where magmas differentiated and were probablycontaminated. Contamination occurred either with Hercynian continentalcrust, mostly during the oldest stages of Vesuvian activity(from 39 to 16 ka), or with Mesozoic limestone, mostly duringrecent Vesuvian activity. Energy constrained assimilation andfractional crystallization (EC-AFC) modelling results show thatcontamination with Hercynian crust probably occurred duringdifferentiation from shoshonite to latite. Contamination withlimestone, which is not well constrained with the availabledata, might have occurred only during the transition from shoshoniteto tephrite. From the ‘deep’ reservoir, magmas rosetowards a series of shallow reservoirs, in which they differentiatedfurther, mixed, and fed volcanic activity. KEY WORDS: Somma–Vesuvius; crustal contamination; source heterogeneity; radiogenic and stable isotopes; magmatic system  相似文献   

Early-indicator signals of groundwater contamination: the case of seawater encroachment   总被引：4，自引：0，他引：4  

A. J. Melloul  L. C. Goldenberg 《Environmental Geology》1998,33(4):279-288

 An early indication of groundwater contamination occurs when pollutant concentrations start to fluctuate and exceed background values of ambient fresh groundwater. An analysis of a characteristic situation of this type uses data from Israel's coastal phreatic granular aquifer. The pollutant is generally seawater, and the contamination process involves replacement of freshwater by encroaching sea- or other saltwater, a process augmented by human activity. The contamination process involves three stages: (1) groundwater composition remains relatively stable with small salinity content; (2) small salinity changes are perceptible with reversible fluctuations; and (3) salinity concentration increases at a sharply higher rate. The second stage is a useful early-indicator signal of contamination. Early-indicator signals of groundwater pollutant concentrations involve "minor" fluctuations in water chemistry at the advent of the contamination process. The intensity and magnitude of such a salinization/pollution process at any given location depends upon lithologic matrix, aquifer heterogeneity, and resultant flow domain characteristics, as well as contaminant properties. If such "signs" are detected at a sufficiently early stage, appropriate management steps may be taken to rectify further seawater and/or saltwater encroachment. Received: 23 July 1996 · Accepted: 25 June 1997  相似文献   

环境磁学在城市环境污染监测中的应用和进展   总被引：15，自引：4，他引：15       下载免费PDF全文

张春霞  黄宝春 《地球物理学进展》2005,20(3):705-711

环境磁学是一门介于地球科学、环境科学和磁学之间的边缘科学，已广泛应用于很多领域.本文在简述了环境磁学参数和不同环境中磁性矿物变迁和演化过程的基础上,介绍了环境磁学在城市环境污染的不同方面所取得的进展,探讨了环境磁学在土壤污染和大气等城市环境污染研究中的不足,提出了环境磁学在城市环境污染研究领域的发展趋势.  相似文献   

纵向弥散作用与渗透介质非均质性定量关系的模拟研究          下载免费PDF全文

张嘉  王明玉 《地学前缘》2010,17(6):152-158

在地下水污染模拟预报中,弥散参数是很难确定的一个模型参数。因实验室小尺度弥散规律一般不能用于大尺度弥散过程,而野外示踪试验却耗资大、周期长,限制了其实用性。文中利用随机数值模拟手段、基于随机理论的蒙特卡罗方法及序贯高斯模拟技术来生成渗透系数随机场,并研究渗透系数对数场的方差、相关长度以及变异函数类型在不同尺度上对纵向弥散度的影响,进而建立纵向弥散度与随机分布渗透系数场的方差和相关长度的统计定量关系,并与Gelhar理论计算结果进行比较。数值模拟结果表明,经过一定迁移距离后纵向弥散度与随机分布渗透系数对数场的方差和相关长度具有良好的线性统计关系,与Gelhar理论公式表达的关系类型类似。但对于较大的方差,纵向弥散度模拟结果明显大于Gelhar理论计算值,而对于较大相关长度在迁移距离不很大时,纵向弥散度模拟结果明显小于Gelhar理论计算值。本研究可为野外大尺度地下水污染预报模型中水动力弥散参数的确定提供方法借鉴。  相似文献   

Techniques and methods of arsenic contaminated groundwater exploration in the Hetao plain of Inner Mongolia,China          下载免费PDF全文

Toshiaki ITO  Fumio KANAI  Kazuro BANDO  Research group for arsenic contamination of groundwater in Inner Mongoli  Asia Arsenic Network  Research Group for Applied Geology 《中国地质》2010,37(3):730-740

1990年报道了在中国内蒙古河套平原由于饮用污染的地下水而患砷中毒的病例.估计目前内蒙受到砷中毒影响的居民已超过41万人.从1997年至2004年,在长达8年的时间里,我们进行了水文地质调查、地质调查和医学调查,并装置了管道输送的供水系统.这些调查揭示了河套平原地下水受砷污染的机理:由于被吸收的砷释放进入地下水,蓄水层中不断加强的还原环境造成铁氢氧化物的溶解.为了防止砷中毒病人数量的进一步增加,停止饮用污染过的水和供应安全的饮用水是重要的.我们需要根据当地的地质和水文地质条件来了解砷污染的机理.  相似文献   

http://www.sciencedirect.com/science/article/pii/S1674987110000071   总被引：2，自引：1，他引：1  

Tingdong Li 《地学前缘(英文版)》2010,1(1):45-56

<正>The lithospheric structure of China and its adjacent area is very complex and is marked by several prominent characteristics.Firstly,China's continental crust is thick in the west but thins to the east,and thick in the south but thins to the north.Secondly,the continental crust of the Qinghai—Tibet Plateau has an average thickness of 60—65 km with a maximum thickness of 80 km,whereas in eastern China the average thickness is 30—35 km,with a minimum thickness of only 5 km in the center of the South China Sea.The average thickness of continental crust in China is 47.6 km,which greatly exceeds the global average thickness of 39.2 km.Thirdly,as with the crust,the lithosphere of China and its adjacent areas shows a general pattern of thicker in the west and south,and thinner in the east and north.The lithosphere of the Qinghai—Tibet Plateau and northwestern China has an average thickness of 165 km, with a maximum thickness of 180—200 km in the central and eastern parts of the Tarim Basin,Pamir, and Changdu areas.In contrast,the vast areas to the east of the Da Hinggan Ling—Taihang—Wuling Mountains,including the marginal seas,are characterized by lithospheric thicknesses of only 50—85 km.Fourthly,in western China the lithosphere and asthenosphere behave as a "layered structure", reflecting their dynamic background of plate collision and convergence.The lithosphere and asthenosphere in eastern China display a "block mosaic structure",where the lithosphere is thin and the asthenosphere is very thick,a pattern reflecting the consequences of crustal extension and an upsurge of asthenospheric materials.The latter is responsible for a huge low velocity anomaly at a depth of 85—250 km beneath East Asia and the western Pacific Ocean.Finally,in China there is an age structure of "older in the upper layers and younger in the lower layers" between both the upper and lower crusts and between the crust and the lithospheric mantle.  相似文献