Initial Characterisation of SK01 Sanidine: A Candidate 40Ar/39Ar Reference Material     

Youjuan Li  Brian R. Jicha  Wanfeng Zhang  Wen Chen  Brad S. Singer  Dewen Zheng  Huaiyu He 《Geostandards and Geoanalytical Research》2023,47(3):657-668

The precision and accuracy of ⁴⁰Ar/³⁹Ar dates are ultimately linked to co-irradiated reference materials of known age. Here we provide new data from the SK01 sanidine, which was analysed in three different laboratories to evaluate it as a ⁴⁰Ar/³⁹Ar reference material. Aliquots of 5 mg, incrementally heated in two laboratories, yielded indistinguishable results with a weighted mean age of 27.58 ± 0.06 Ma (95% confidence level). Single-crystal step heating and single-crystal total fusion analyses of SK01 sanidine were undertaken in the third laboratory to further test the intracrystalline homogeneity. For the seven step-heating analyses, six crystals yielded nearly concordant age spectra with ⁴⁰Ar/³⁹Ar ages ranging from 26.853 ± 0.094 Ma to 26.963 ± 0.067 Ma, whereas one crystal gave an older age of 27.774 ± 0.071 Ma with a slightly discordant age spectrum. Twenty-three single-crystal total fusion analyses yielded ⁴⁰Ar/³⁹Ar ages ranging from 27.070 ± 0.108 Ma to 27.736 ± 0.062 Ma with a dispersion of ~ 3.8%. The older ages from single-crystal total fusion dates are interpreted to reflect an inherited or excess argon component in some crystals. This is an initial characterisation of the SK01 sanidine, and additional work needs to be conducted to further evaluate the age dispersion so that it can be utilised as a ⁴⁰Ar/³⁹Ar reference material.  相似文献   

Geochronology and geochemistry of lithium-rich tuffs in the Sichuan basin,western Yangtze: Implication for the magmatic origin and final closure of eastern Paleo-Tethys     

《地学前缘(英文版)》2023,14(1):101480

The felsic volcanogenic tuffs named “green-bean rocks” (GBRs), characterized by a green or yellowish green color, are widely distributed in the western Yangtze platform and have a high lithium content (286–957 ppm). This paper studies the ages, origin and tectonic setting of the GBRs in the Sichuan basin on the western margin of the Yangtze platform through the whole-rock geochemistry and zircon trace elements by using U–Pb dating and Hf–O isotopes. The GBR samples from the Quxian and Beibei sections yielded zircon U–Pb ages of 245.5 ± 1.8 Ma and 244.8 ± 2.2 Ma. These samples can be used as the isochronous stratigraphic marker of the Early–Middle Triassic boundary (EMTB) for regional correlation. The whole-rock and zircon geochemistry, and zircon Hf–O isotopes exhibited S-type geochemical affinities with high positive δ¹⁸O values (9.28‰–11.98‰), low negative ε_Hf(t) values (?13.87 to ? 6.79), and T_DM² ages of 2150–1703 Ma, indicating that the lithium-rich GBRs were generated by the remelting of the pre-existing ancient Paleoproterozoic layer without mantle source contamination in the arc-related/orogenic tectonic setting. The results of this study demonstrate that the lithium-rich GBRs in the western Yangtze platform were derived from arc volcanic eruptions along the Sanjiang orogen, triggered by the closure of the eastern Paleo-Tethys Ocean and the syn-collision between the continental Indochina and Yangtze blocks at ca. 247 Ma. This was marked by a major shift from I-type magmas with intermediate ε_Hf(t) values to S-type magmas with low negative ε_Hf(t) values. Collectively, our results provide new insights into the origin of the GBRs and decodes the closure of the eastern Paleo-Tethys.  相似文献   

江西德兴斑岩铜矿石英闪长玢岩成因及成矿学意义     

鲍波  姜军胜  于玉帅  秦拯纬  郑忠超  柳潇  陕亮  董宜勇  李福林 《岩石矿物学杂志》2023,42(4):483-501

为探究石英闪长玢岩成因及幔源基性岩浆对斑岩铜矿的贡献,本文选取德兴矿床石英闪长玢岩开展了锆石U-Pb定年、Hf同位素和全岩地球化学研究。获得石英闪长玢岩LA-ICP-MS锆石U-Pb年龄为169 Ma,与成矿花岗闪长斑岩侵位时间一致,岩体为中侏罗世岩浆活动的产物。石英闪长玢岩具有低的SiO₂(58.41%~63.12%)和K₂O(1.68%~2.94%)含量及A/CNK值(0.85~1.04),富集大离子亲石元素和轻稀土元素,亏损高场强元素Nb、Ta、Ti和重稀土元素,属于钙碱性到高钾钙碱性系列岩石。具有相对亏损的锆石Hf同位素组成,εHf(t)=2.20~7.93(最大值7.93),指示其源区为岩石圈地幔。锆石稀土元素配分模式图显示出明显的正Ce异常,岩浆氧逸度(lg f_O2)为-20.05~-6.66,达到磁铁矿-赤铁矿氧逸度等级,指示石英闪长玢岩结晶自高氧逸度岩浆。全岩地球化学特征显示,德兴石英闪长玢岩与成矿花岗闪长斑岩及其暗色包体符合岩浆混合的演化趋势,说明成矿花岗闪长斑岩可能是中侏罗世幔源基性岩浆和地壳酸性岩浆大规模混合作用的产物,并且石英闪长玢岩代表了岩浆混合过程中的幔源基性端员。结合前人研究成果,认为在中侏罗世伸展构造背景下,软流圈物质上涌导致新元古代受交代的岩石圈地幔部分熔融形成幔源基性岩浆,基性岩浆的底侵作用诱发下地壳物质熔融并与之发生一定程度的岩浆混合作用,形成了花岗闪长斑岩的母岩浆。高氧逸度幔源岩浆的加入可抑制斑岩体系硫化物的过早饱和,同时为德兴矿床注入了成矿所需的部分挥发分和金属元素。  相似文献   

Coherent Chemical Variation Trends of the 55-25 Ma Magmatic Rocks in SE Tibet:N-S Direction Lithospheric Stretching of Eurasia during Early Stage of India-Eurasia Collision     

YANG Tiannan  DONG Mengmeng  XUE Chuandong  XIN Di  LIANG Mingjuan 《《地质学报》英文版》2023,97(5):1283-1305

The progressive indentation of India into Eurasia generated an E–W-trending orthogonal collision belt and a N–S-trending oblique collision belt. Compiling available data reveals that ～70% of the Cenozoic igneous rocks in eastern and southeastern Tibet are concentrated within an ENE-trending, ～550-km long and ～250-km wide magmatic zone(CMZ) that once separated the orthogonal and oblique collision belts. The Latitude 26°N Line is now its southern boundary. The onset timing of magmatism of the CMZ ...  相似文献   

Study on Yanshanian metallogenic granitoids magmatism in Baoshan deposit,southern Hunan ProvinceSCIEI北大核心CSCD     

曹亮  许国锋  刘磊  邵拥军 《岩石学报》2023,(3):886-909

本文对湘南宝山花岗闪长斑岩进行了系统的锆石和磷灰石U-Pb定年、岩石地球化学以及锆石Hf同位素研究,并探讨了宝山花岗闪长斑岩的岩石成因和构造意义。锆石和磷灰石的LA-ICP-MS U-Pb定年显示,宝山花岗闪长斑岩的成岩年龄为160Ma。综合元素和同位素地球化学证据,宝山花岗闪长斑岩的成因可能为新生地壳与古老地壳的混合熔融,同时宝山花岗闪长斑岩中发现的890±20Ma的继承锆石,验证了新元古代新生地壳的参与。磷灰石的主微量元素研究显示花岗闪长斑岩具有较高的氧逸度和Cl含量,Sr/Th比值具有较大变化,而La/Sm比值变化不大等特征,表明形成花岗闪长斑岩岩浆的母岩受到俯冲板片脱水形成的流体交代作用影响。在上述过程中,富含Cl和H2O的流体从板片中释放出来,引发地幔楔熔融,并对矿床中成矿金属元素进行提取。由于古太平洋板块俯冲引发的伸展-减薄运动,在地幔上涌过程中,新元古代新生地壳发生部分熔融,这些高温岩浆底侵老地壳源区,诱发老地壳部分熔融,进而发生了强烈的壳-壳混合作用,产生花岗闪长质岩浆。  相似文献   

Tectono-magmatic evolution from accretion to collision in the southern margin of the Central Asian Orogenic BeltSCIEI北大核心CSCD     

李舢  王涛  肖文交  侯泉林 《岩石学报》2023,(5):1261-1275

造山带演化及增生到碰撞的转变是板块构造与大陆动力学研究中的前沿科学问题。中亚造山带被认为是古亚洲洋长期俯冲-增生演化形成的显生宙最大的增生造山带,以发育巨量的面状展布的俯冲-增生相关的弧岩浆岩为特征。并且,由于中亚增生型造山带在潘吉亚最后聚合过程中发生弧弧(陆)碰撞,因此缺乏大规模且跨构造单元的碰撞相关的构造和变质等物质标志。显然,能否识别出大洋闭合期间碰撞作用的岩浆标志成为确定增生造山带增生过程终止的关键之一。本文系统研究确定:中亚造山带东南缘二叠纪到三叠纪钙碱性-碱钙性岩浆在空间分布上显示出由北西向南东迁移演化的特征;在岩浆性质上具有从二叠纪新生地壳来源的弧岩浆向早-中三叠世碰撞挤压背景下古老陆壳组分逐渐增多的高Sr/Y岩浆以及晚三叠世后造山伸展相关的A型花岗岩演化的特征。这些特征提供了俯冲-增生向碰撞造山演变的关键岩浆岩证据。结合区域资料,厘定出增生造山带最后碰撞相关的标志性岩浆为沿缝合带呈零星线性展布的增厚下地壳源区的高Sr/Y花岗岩类,构建了中亚造山带南缘从双向俯冲-增生到增生楔-增生楔碰撞及后造山伸展的三阶段构造-岩浆演化模型。系统对比研究,揭示出增生-碰撞相关的岩浆记录沿横向展布在中亚造山带南缘甘肃北山到吉林中部一带,表明碰撞挤压相关的岩浆作用在中亚造山带南缘具有一定的普适性。中亚造山带南缘从增生到碰撞的岩浆演化记录的厘定,证实显生宙最大的巨型增生造山带演化末期经历了碰撞造山作用,对进一步深入探索增生造山演化末期碰撞相关的标志性岩浆具有重要意义。  相似文献   

里下河地区极端降水时空变化及未来趋势分析     

鞠艳  杨星  王轶虹  王冬梅  齐斐  王志寰 《水文》2023,43(4)

随着全球变暖,极端天气事件逐渐增加,影响着社会经济发展,揭示区域极端降水时空变化对防洪减灾具有重要意义。基于1960—2019年的逐日降水,通过MK趋势检验、小波分析、重标极差以及克里金插值方法,从强度、频率和持续性三方面分析里下河地区的极端降水指数,并进一步探究其未来趋势变化。结果表明：（1）里下河地区多年平均降水为1017.25 mm,呈不显著增加趋势;空间分布差异明显,总体呈自西北向东南逐渐增加的分布。（2）研究区内各站点极端降水指数变化不同,总体而言,极端降水强度、频率均呈现增加趋势,持续性呈减少趋势。（3）极端降水指数变化过程中存在3类尺度的周期性变化,在整个时间尺度上存在3个偏多中心和2个偏少中心。（4）除R10mm和R20mm未来变化趋势与过去趋势相反且呈弱持续性,其他极端降水指数未来变化趋势与过去相一致,且过去总体趋势对未来趋势的影响时间长度在9~16年左右。研究结果为里下河地区科学合理应对气象灾害、合理配置水资源提供依据。  相似文献   

江西印支期蔡江岩体中暗色微粒包体的发现及其地质意义     

刘运超  姜耀辉  青龙  杜佛光 《高校地质学报》2022,28(4):473-483

文章报道了江西蔡江花岗质岩体中发现暗色微粒包体,以及这些包体的地质、岩相学、LA-ICP-MS锆石U-Pb年代学和元素地球化学特征。包体多呈椭圆状,显示淬冷边和反向脉,具有典型的岩浆结构并含有针状磷灰石,有的包体含有长石捕虏晶。包体具有相对较低的SiO₂（低至57.05 wt%）和较高的MgO+Fe₂O₃（高达14.21 wt%）含量。LA-ICP-MS锆石U-Pb定年数据表明,包体形成于晚三叠世（224 Ma）,与寄主花岗岩（230~228 Ma）在误差范围内基本一致。上述特征表明,包体是离散的幔源偏基性岩浆团或者是幔源与寄主岩浆混合的产物。原始包体岩浆属于超钾质岩浆,可能是通过岩石圈地幔中交代成因的金云母辉石岩脉发生部分熔融而形成的。暗色微粒包体的发现为幔源岩浆底侵提供了直接证据,从而为蔡江花岗质岩石形成于较高温度提供佐证。该研究对于进一步探讨华南印支期花岗岩形成的热源机制具有意义。  相似文献   

遥感在大兴安岭森林覆盖区地质矿产调查中的应用——以黑龙江洛古河1:5万区域地质矿产调查工作为例     

周传芳  陈卓  孙彦峰  梁中恺  杨长保  姜平  冯嘉  杜海双 《地质与资源》2022,31(5):632-641

大兴安岭地区森林覆盖严重, 气候严寒, 交通极为不便, 野外有效工作时间短, 给区域地质矿产调查工作增加了难度, 急需遥感手段提高成果质量和效率. 在黑龙江大兴安岭洛古河等4幅1:5万区域地质矿产调查工作中, 利用SPOT7、Landsat7/8、ASTER等多种遥感数据开展地质矿产解译, 进行遥感影像分区, 建立地层、构造和侵入岩解译标志, 提取羟基和铁染蚀变异常, 结合水系沉积物测量成果划分了成矿有利区, 有效降低了地质矿产调查强度, 提高了调查效率, 增强了调查质量. 表明遥感技术在大兴安岭高植被覆盖区地质矿产调查过程中能够取得较好效果.  相似文献   

Testing a new combined (U,Th)–He and U/Th dating approach on Plio-Pleistocene calcite speleothems     

《Quaternary Geochronology》2022

The geochronology of cave deposits in the Cradle of Humankind UNESCO World Heritage Site in South Africa provides a timeframe essential for the interpretation of its fossils. The uranium-lead (U–Pb) and uranium-thorium disequilibrium (U/Th) dating of speleothems, mostly flowstones that underlie and blanket the fossil-bearing sediments, have been effective in this sense, but U–Pb is limited by the requirement of ∼1 ppm U concentrations and low common Pb contents, and U/Th has a c. 500 ka limit of applicability. Here we report age results for calcite-aragonite speleothems obtained using a new combined uranium-thorium-helium ((U,Th)–He) and U/Th dating routine. We reproduced within analytical uncertainty, the published U–Pb or U/Th ages for (a) flowstone in three drill core samples in the range 2000–3000 ka, (b) a flowstone hand sample taken at surface with an age of 1800 ka, and (c) five underground flowstone samples in the range 100–800 ka. Calcite retentivity for He under cave conditions is thus demonstrated. In the few cases where helium loss was observed in speleothems, only some of the subsamples were affected, and to varying degrees, suggesting loss by lattice damage not related to diagenetic processes, rather than volume diffusion. In the 100 to 800 ka range, the combined U/Th disequilibrium and (U,Th)–He method also yielded reliable values for initial (²³⁰Th/²³⁸U) and (²³⁴U/²³⁸U) activity ratios. Importantly, most subsamples had high initial (²³⁰Th/²³⁸U) values, ranging from 1.0 to 19.7, although having low Th/U ratios. This is probably due to incorporation of Fe–Mn oxides-hydroxides dust, on which ²³⁰Th was previously adsorbed. Such samples are mostly not dateable by U/Th without the additional input from the He analysis. If not detected and corrected for, such high initial (²³⁰Th/²³⁸U) values can lead to inaccurate U/Th and U–Pb ages. Our study shows that the incorporation of He analysis in U/Th dating has broad potential application, with four methods for calculating the ages, in carbonates from different environments where U-Pb or U/Th dating would not work.  相似文献