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51.
沉积盆地有机质自由基热演化特征及其作为古温标的探索 总被引:1,自引:0,他引:1
恢复沉积盆地热历史的方法主要有古地温指标法和动力学模拟法两类.古温标法中最常用的为有机质成熟度和矿物裂变径迹,动力学模拟法中最常用的是盆地的拉张模型和挤压模型.本文针对Ⅰ型有机质自由基浓度作为沉积盆地古温标进行了探索研究.分析了自然演化系列Ⅰ型有机质的自由基的热演化特征;根据自然演化系列的Ⅰ型有机质自由基浓度及时间-温度指数(TTI)数据,对热模拟实验下的Ⅰ型有机质自由基浓度及时间-温度指数(TTI)值进行校正,由校正后的数据初步建立了Ⅰ型有机质的自由基浓度(Ng)与时间-温度指数(TTI)的定量模型. 相似文献
52.
本文对冀北—辽西地区早白垩世沉积盆地富有机质沉积岩进行了初步有机地球化学分析研究。结果显示,冀北—辽西沉积盆沉积有机质特征在时间和空间上存在很大差异,代表白垩系早期沉积的滦平盆地大北沟组有机质丰度低,这不仅显示其所代表的沉积相带不利于有机质的聚集,也反映了当时生物不够繁盛;大店子组时期沉积相带发生了变化,有机质类型随着发生了变化,丰度有所增高,但总体上显示环境条件不利于生物的发育和繁盛。到了桥头组和义县组沉积岩有机质丰度大幅升高,表明生物界非常繁盛,古气候环境有利于有机质的大量生成和堆积,总体上反映了温湿的气候条件;但同时也存在较为频繁或交替性寒冷气候波动,具体的古气候环境状态尚需进一步深入研究。 相似文献
53.
藏南白垩系黑-红层沉积岩有机质组成分布特征 总被引:1,自引:0,他引:1
对藏南江孜县床得剖面白垩系黑层和红层沉积岩进行的有机地球化学研究表明,黑层有机碳含量高于红层5~10倍,红层和黑层饱和烃主峰碳数分别为nC25和nC23;黑层和红层沉积有机质的母质来源都以水生植物和菌藻类等低等生物为主,陆源有机质的输入非常有限;但饱和烃的分布和主峰碳数的差异可能反映了有机母源物质在种群方面的差异,而这种差异可能主要是水体温度存在差异造成的,即红层发育时期水体温度可能高于黑层沉积时期.而在高温度条件下,水生生物和陆生植物的生长发育受到限制,造成原始有机质产率和有机质沉积保存量低可能是红层沉积岩形成的主要原因. 相似文献
54.
Kyu Han Kim Keisuke Nagao Hirochika Sumino Tsuyoshi Tanaka Takamasa Hayashi Toshio Nakamura Jong Ik Lee 《Chemical Geology》2008,253(3-4):180-195
We report analyses of noble gases and Nd–Sr isotopes in mineral separates and whole rocks of late Pleistocene (< 0.2 Ma) monzonites from Ulleungdo, South Korea, a volcanic island within the back arc basin of the Japan island arc. A Rb–Sr mineral isochron age for the monzonites is 0.12 ± 0.01 Ma. K–Ar biotite ages from the same samples gave relatively concordant ages of 0.19 ± 0.01and 0.22 ± 0.01 Ma. 40Ar/39Ar yields a similar age of 0.29 ± 0.09 Ma. Geochemical characteristics of the felsic plutonic rocks, which are silica oversaturated alkali felsic rocks (av., 12.5 wt% in K2O + Na2O), are similar to those of 30 alkali volcanics from Ulleungdo in terms of concentrations of major, trace and REE elements. The initial Nd–Sr isotopic ratios of the monzonites (87Sr/86Sr = 0.70454–0.71264, 143Nd/144Nd = 0.512528–0.512577) are comparable with those of the alkali volcanics (87Sr/86Sr = 0.70466–0.70892, 143Nd/144Nd = 0.512521–0.512615) erupted in Stage 3 of Ulleungdo volcanism (0.24–0.47 Ma). The high initial 87Sr/86Sr values of the monzonites imply that seawater and crustally contaminated pre-existing trachytes may have been melted or assimilated during differentiation of the alkali basaltic magma.A mantle helium component (3He/4He ratio of up to 6.5 RA) associated with excess argon was found in the monzonites. Feldspar and biotite have preferentially lost helium during slow cooling at depth and/or during their transportation to the surface in a hot host magma. The source magma noble gas isotopic features are well preserved in fluid inclusions in hornblende, and indicate that the magma may be directly derived from subcontinental lithospheric mantle metasomatized by an ancient subduction process, or may have formed as a mixture of MORB-like mantle and crustal components. The radiometric ages, geochemical and Nd–Sr isotopic signatures of the Ulleungdo monzonites as well as the presence of mantle-derived helium and argon, suggests that these felsic plutonic rocks evolved from alkali basaltic magma that formed by partial melting of subcontinental lithospheric mantle beneath the back arc basin located along the active continental margin of the southeastern part of the Eurasian plate. 相似文献
55.
Hong-Fu Zhang Steven L. Goldstein Xin-Hua Zhou Min Sun Jian-Ping Zheng Yue Cai 《Contributions to Mineralogy and Petrology》2008,155(3):271-293
The ages of subcontinental lithospheric mantle beneath the North China and South China cratons are less well-constrained than
the overlying crust. We report Re–Os isotope systematics of mantle xenoliths entrained in Paleozoic kimberlites and Mesozoic
basalts from eastern China. Peridotite xenoliths from the Fuxian and Mengyin Paleozoic diamondiferous kimberlites in the North
China Craton give Archean Re depletion ages of 2.6–3.2 Ga and melt depletion ages of 2.9–3.4 Ga. No obvious differences in
Re and Os abundances, Os isotopic ratios and model ages are observed between spinel-facies and garnet-facies peridotites from
both kimberlite localities. The Re–Os isotopic data, together with the PGE concentrations, demonstrate that beneath the Archean
continental crust of the eastern North China Craton, Archean lithospheric mantle of spinel- to diamond-facies existed without
apparent compositional stratification during the Paleozoic. The Mesozoic and Cenozoic basalt-borne peridotite and pyroxenite
xenoliths, on the other hand, show geochemical features indicating metasomatic enrichment, along with a large range of the
Re–Os isotopic model ages from Proterozoic to Phanerozoic. These features indicate that lithospheric transformation or refertilization
through melt-peridotite interaction could be the primary mechanism for compositional changes during the Phanerozoic, rather
than delamination or thermal-mechanical erosion, despite the potential of these latter processes to play an important role
for the loss of garnet-facies mantle. A fresh garnet lherzolite xenolith from the Yangtze Block has a Re depletion age of
∼1.04 Ga, much younger than overlying Archean crustal rocks but the same Re depletion ages as spinel lherzolite xenoliths
from adjacent Mesozoic basalts, indicating Neoproterozoic resetting of the Re–Os system in the South China Craton. 相似文献
56.
Vittorio Zanon Fátima Viveiros Catarina Silva Ana Rita Hipólito Teresa Ferreira 《Natural Hazards》2008,45(1):19-31
A detailed study was carried out on a piece of land that had been struck by lightning during the violent rainstorm that raged
over the Island of S?o Miguel (Azores Archipelago) in late October 2006. Temperature and gas measurements (CO2, CO, H2S and CH4) were performed in four study trenches, dug in an area of ∼3 m2, where an underground fire had been initiated by the impact with a lightning stroke, followed by the emission of a column
of gases and smoke. The soil under study was originally a well-pedogenized about 80 cm thick bed, made of volcanic clayey
to silty tephra fallouts and contained 5.5–9.7% of organic matter. The underground fire was monitored for one week and revealed a peak release of
404 ppm CO and 3.4% CO2 originating from a horizon located about 45 cm under the soil surface. Measurements of temperature, performed one week after
the impact, indicated a maximum value of 326°C inside the soil, while 516.5°C were measured on the surface of a lava block
interred about 20 cm under the surface. Subsequently, a stratigraphic and sedimentologic study proved the role of the grain-size
of the soil and of the organic matter content of the different horizons of the impact area, in determining the ratio between
anoxic/oxidised combustion conditions and in the progress of the process itself. It was also noticed that combustion was not
total all over in the soil bed and that the process had slightly migrated toward SW during the observation period. The combustion
process went on for about ten days, in spite of several other violent rainstorms, until it was artificially extinguished through
the excavations made to obtain study trenches. This particular circumstance evidenced the potential natural hazard represented
by this kind of atmospheric event, especially in a land where the volcanic nature of the soil may easily mislead inexperienced
observers and, consequently, delay proper action. 相似文献
57.
In situ strength measurements on natural upper-mantle minerals 总被引:1,自引:0,他引:1
Junji Yamamoto Jun-ichi Ando Hiroyuki Kagi Toru Inoue Akihiro Yamada Daisuke Yamazaki Tetsuo Irifune 《Physics and Chemistry of Minerals》2008,35(5):249-257
Using in situ strength measurements at pressures up to 10 GPa and at room temperature, 400, 600, and 700°C, we examined rheological
properties of olivine, orthopyroxene, and chromian-spinel contained in a mantle-derived xenolith. Mineral strengths were estimated
using widths of X-ray diffraction peaks as a function of pressure, temperature, and time. Differential stresses of all minerals
increase with increasing pressure, but they decrease with increasing temperature because of elastic strain on compression
and stress relaxation during heating. During compression at room temperature, all minerals deform plastically at differential
stress of 4–6 GPa. During subsequent heating, thermally induced yielding is observed in olivine at 600°C. Neither orthopyroxene
nor spinel shows complete stress relaxation, but both retain some stress even at 700°C. The strength of the minerals decreases
in the order of chromian-spinel ≈ orthopyroxene > olivine for these conditions. This order of strength is consistent with
the residual pressure of fluid inclusions in mantle xenoliths. 相似文献
58.
青藏高原东南木里地区二叠纪苦橄岩的Os-Sr-Nd同位素地球化学研究 总被引:3,自引:2,他引:1
本文报道了在青藏高原东南木里地区发现的二叠纪苦橄岩和与其共生玄武岩的主微量元素地球化学特征以及Os-Sr-Nd同位素组成。苦橄岩和与其共生玄武岩受地壳混染作用影响较小。根据苦橄岩的Ti/Y比值和初始的Os同位素组成,将木里苦橄岩分为两类:高Ti/Y型苦橄岩和低Ti/Y型苦橄岩,其中高Ti/Y型苦橄岩具有高的γ_(Os)= 5.3~ 10.7和ε_(Nd)= 5.9~ 6.4,与全球典型洋岛玄武岩的Os和Nd同位素组成接近,代表了地幔柱源区的同位素特征;而低Ti/Y型苦橄岩具有低的γ_(Os)=-4.1~ 1.2和ε_(Nd)= 3.2~ 5.0,可能表明受到了SCLM(大陆岩石圈地幔)源区物质的混染。与其共生的玄武岩具有低的γ_(Os)=-3.5~-1.6和ε_(Nd)=-0.6~ 0.7,表明其来自于不同于低Ti/Y型苦橄岩也有异于高Ti/Y型苦橄岩的地幔源区,但是也可能受到了SCLM物质的混染。基于Nd-Os同位素的地幔柱与SCLM的二端元混合模型显示:低Ti/Y型苦橄岩可能是SCLM物质组分与地幔柱起源的苦橄质原始岩浆混合形成的;与苦橄岩共生的玄武岩可能是由地幔柱来源的玄武质岩浆与SCLM小比例熔融的熔体混合形成的。 相似文献
59.
地幔岩中流体包裹体研究 总被引:5,自引:2,他引:3
地幔岩石中的流体包裹体代表地幔流体的样品。地幔流体包裹体可以存在从地幔来的金刚石,地幔捕虏体和岩浆碳酸岩中。研究这些岩石和矿物中的流体包裹体可以得出其所代表的地幔流体的温度、压力、成分和同位素。我们目前见到的这三类地幔岩石的包裹体主要可在橄榄石、辉石、金刚石、方解石和磷灰石中见到。这些包裹体可以粗略地分为CO2包襄体和硅酸盐熔融体包裹体。又可细分为四类包裹体:(1)富碳酸盐的硅酸盐熔融包裹体。这种包裹体在金刚石、地幔岩捕虏体和岩浆碳酸盐岩中见到,它又可分为结晶质熔融包裹体和玻璃包裹体。(2)CO2包裹体。这种包裹体大多见于地幔捕虏体中,在金刚石和岩浆碳酸岩中也可见到。(3)含硫化物的包裹体。这种包裹体见于地幔捕虏体中,与纯CO2包裹体和含CO2的熔融包裹体共存。(4)高密度的流体包裹体。这种包裹体见于金刚石中,是一种高盐度、高密度的含K、Cl和H2O的流体包裹体,又可分为高卤水包裹体和含卤水的富硅的碳酸盐岩浆包裹体。从对金刚石、地幔捕虏体和岩浆碳酸盐岩中流体包裹体的研究表明,地幔流体存在不均匀性和不混溶性。 相似文献
60.
Re-Os同位素对峨眉山大火成岩省成因制约的探讨 总被引:6,自引:3,他引:3
峨眉山大火成岩省(ELIP)主要由玄武岩、玄武质火山碎屑岩及少量的苦橄岩(包括越南的科马提岩)、长英质岩石以及层状岩体和岩墙组成,其物质来源直接关系到其成因是否与地幔柱活动有关。Re-Os同位素体系是地核、地幔和地壳物质的最佳示踪剂。前人对ELIP内的Re-Os同位素研究表明,低Ti玄武岩的Os含量为0.006×10^-9-0.40010^-9,^187Os/^188Os初始值为0.1371~1.403,并提出其与地幔柱活动有关;而高Ti玄武岩的Os含量为0.00410^-9~0.56010^-9,^187Os/^188Os初始值为0.1271~5.19,认为起源于大陆岩石圈地幔或地幔柱上升过程中受到大量岩石圈地幔“混染”(xu JF et al.,2007);科马提岩的0s含量为1.2410^-9~7.0010^-9,^187Os/^188Os初始值为0.1251~0.1261,苦橄岩的Os含量为0.3210^-9~2.32910^-9,^187Os/^188Os初始值为0.1233~0.1266,指示苦橄岩和科马提岩均来自亏损地幔源区(Hanski et al.,2004;陈雷等,2007)。本文利用Os含量最低、^187Os/^188Os最高的高Ti玄武岩作为地壳端员,用铁质陨石、原始上地幔(PUM)和亏损地幔(DMM)作为地核和各种地幔端员,分别做二元混合计算,结果显示绝大多数玄武岩和所有苦橄岩及科马提岩均落在地壳和DMM混合曲线附近,并且邻区特提斯洋地幔岩与DMM具有相近的Os含量和^187Os/^188Os组成,据此推测峨眉山火成岩的形成与特提斯洋的活动有关,主要受控于地壳和亏损地幔的相互作用。 相似文献