Spatial and seasonal variations in depth profile of trace metals in saltmarsh sediments from Sapelo Island, Georgia, USA   总被引：1，自引：0，他引：1  

Alakendra N. Roychoudhury   《Estuarine, Coastal and Shelf Science》2007,72(4):675-689

This study was undertaken to elucidate the impact of early diagenetic processes on the accumulation of trace metals in Sapelo Island saltmarsh sediments as a function of time, space and sediment properties. Samples were collected from three sites in summer (May 1997) and winter (January 1998) along a transect from an unvegetated Creek Bank through a vegetated Tidal Levee to the vegetated midmarsh with evident lateral heterogeneity caused by hydrologic regime, macrophytes and microbial and macrofaunal activities. A suite of trace metals (As, Ba, Cr, Co, Cu, Cd, Mo, Ni, Pb, Th, Ti, U, V, Zn and Zr) was analyzed to obtain their depth-distribution at the three sites. Spatially marked differences were observed, that were primarily related to hydraulic flushing of trace metals away from the sites in high-energy regimes, rapid downward mixing and reworking of sediment via bioturbation, and below-ground degradation and production of Spartina biomass. Although sulfate reduction and the formation of acid volatile sulfide and pyrite were dominant processes throughout the marsh, the trace metal scavenging role of sulfides was not apparent. However, possible sulfurization of organic matter, leading to enhanced trapping of trace metals with organic carbon, may have played an important role in sequestration of trace metals.No similarity was observed visually between the depth trends of trace metals and sediment properties (grain size, iron-oxyhydroxide content, acid volatile sulfides and pyrite content) that are known to play a major role in trace metal partitioning. Only organic carbon content closely followed the trace metal profiles at all the three sites. Minor variation in depth-integrated sediment trace metal content was observed seasonally at each of the three sites. Furthermore, the depth trend of profiles of individual trace metals also did not vary significantly over the seasons either.  相似文献   

Facies reconstruction from resistivity-at-the-bit images recorded in a submarine felsic volcanic succession     

Juliane Arnold  Anne Bartetzko  Holger Paulick  Gerardo Iturrino 《Marine Geophysical Researches》2007,28(4):331-341

  相似文献   

南海高钙沉积物中18种常微量元素的ICP-AES测定方法研究     

王湘芹  陈志华  任红  孙琼 《海洋科学进展》2007,25(2):220-225

在利用ICP-AES分析南海高钙沉积物中的常微量元素时,钙、镁常常干扰其它元素测试。通过采用优化仪器工作参数、扣除背景值、谱线干扰校正和基体匹配的步骤,消除了元素干扰和钙、镁基体效应,提高了方法的灵敏度和准确度。通过对南海沉积物样品的大量实验和国家一级标准样验证,建立了适宜高钙海洋沉积物元素含量的ICP-AES测试方法。该方法检出限为1.55~271μg/L,相对标准偏差RSD<4.54%(n=6)。  相似文献   

马里亚纳海槽扩张轴(中心)玄武岩铂族元素特征   总被引：2，自引：0，他引：2  

曹志敏  安伟  周美夫  郑建斌  漆亮 《海洋学报》2006,28(5):69-75

马里亚纳海槽扩张轴中心玄武岩铂族元素(PGE)总量变化范围为0.418×10-9~1.022×10-9,其原始地幔标准化配分模式呈正倾斜型,表现出PPGE(包括Pt,Pd,Rh)和金的相对富集.与其他幔源岩石相比,该区玄武岩PGE总量较低,(Pd/Ir)N,(Pd/Pt)N,(Pd/Ru)N变化较大,表现出铂、铱的相对亏损和明显的铂负异常(Pt/Pt*=0.01~0.15).PGE的分布特征一方面反映了该区地幔熔融度不高,另一方面,大离子亲石元素LILE(铷、锶、钾等)、铅和轻稀土LREE略富集,暗示扩张中心之下的软流圈地幔源受到了岛弧地幔的混染.上述特征反映了马里亚纳海槽玄武岩是MORB型与岛弧型地幔源不同程度混合后部分融熔的产物.  相似文献   

连云港近岸海域物理自净能力研究及水质预测——Ⅲ.西大堤建成后对物质输运的影响     

赵可胜  娄安刚  王学昌 《中国海洋大学学报(自然科学版)》1994,(Z1)

在连云港近岸海域计算潮流场基础上建立拉格朗日余流模型,并对连云港市两大堤建成前后的拉格朗日余流变化进行了分析,且选择有代表性的排污口进行了数值跟踪。  相似文献   

鲁苏榴辉岩的地球化学     

韩宗珠 《中国海洋大学学报(自然科学版)》1994,(1)

以微量元素、稀土元素、Ｓｒ和Ｎｄ同位素变异特征为依据，确定鲁苏榴辉岩为多成因、多来源和多阶段，指出主要是在印支期扬子陆块与华北陆块碰撞造山作用过程中，挤入的上地幔碎片以及不同原岩类型的壳内高压变质岩碎块。燕山晚期的区域构造热事件使得某些榴辉岩的同位素体系再平衡。  相似文献   

Geochemical and hydrodynamic constraints on the distribution of trace metal concentrations in the lagoon of Nouméa, New Caledonia   总被引：1，自引：0，他引：1  

Christophe Migon  Sylvain Ouillon  Xavier Mari  Emmanuel Nicolas 《Estuarine, Coastal and Shelf Science》2007,74(4):756

Seawater samples were collected in the lagoon of Nouméa (southwest New Caledonia) along two transects from eutrophic coastal bays to the oligotrophic barrier reef. Land-based emissions to the lagoon were measured with dissolved and particulate concentrations of chromium (Cr) and nickel (Ni), used as tracers of both terrigenous and industrial (Ni ore treatment) activities, as well as dissolved and particulate concentrations of zinc (Zn), used as a tracer of urban effluents. The spatial variability of metal concentrations was related to geochemical and hydrodynamic conditions, i.e., respectively: (1) natural and anthropogenic emission sources, and chemical processes occurring in the water column; and (2) water residence times. The parameter used to describe the residence time of water masses was the local e-flushing time, i.e. the time required for a tracer mass contained within a given station to be reduced by a factor 1/e. High metal concentrations were found in coastal areas (up to 9000 ng dissolved Ni L⁻¹), and steeply decreased with distance from the coast (down to 101 ng dissolved Ni L⁻¹ near the barrier reef) to reach levels similar to those found in remote Pacific waters, suggesting a rapid renewal of waters close to the barrier. Distributions of metals in the lagoon are controlled upstream by land-based emission sources and later chemical processes. Then hydrodynamics constrain metal distributions, as shown by the observed relationship between local e-flushing times and the spatial variability of metal concentrations. In addition, a change in the direction of prevailing winds yielded a decrease of dissolved metal concentrations at the same site by a factor of 2.5 (Cr and Ni) and 2.9 (Zn). It is suggested that the residence time is a key parameter in the control of elemental concentrations in the lagoon waters, as much as land-based emission sources.  相似文献   

复合加载模式作用下地基承载性能数值分析   总被引：11，自引：3，他引：11  

栾茂田  赵少飞  袁凡凡  吕爱钟  武科 《海洋工程》2006,24(1):34-40

确定竖向荷载(V)、水平荷载(H)和力矩(M)共同作用下建筑物地基的破坏模式及在荷载空间(H,V,M)中的破坏包络面是地基设计中的关键问题。为提高Swipe试验方法计算精度,提出了改进方案,进而利用有限元方法分析了复合加载模式作用下均质粘性土地基上条形基础的破坏包络面。计算表明,基于改进Swipe试验方法的数值模拟结果明显好于常规Swipe试验方法。针对海洋工程中实际复合加载模式的特点,探讨了竖向荷载分量V对地基破坏模式和H-M荷载平面上的破坏包络线的影响,结果表明竖向荷载分量显著地改变了地基的破坏模式及包络线的形状。  相似文献   

Geochemistry of trace elements and Sr-Nd isotopes of foraminifera shell from the Okinawa Trough   总被引：1，自引：0，他引：1  

Meng Xianwei  Du Dewen  Cheng Zhenbo 《海洋学报(英文版)》2001,20(1):95-103

ＩＮＴＲＯＤＵＣＴＩＯＮＰｒｏｖｅｎａｎｃｅｏｆｍａｒｉｎｅｓｅｄｉｍｅｎｔｓｈａｓａｌｗａｙｓｂｅｅｎａｆｏｃｕｓｅｄｐｒｏｂｌｅｍｉｎｍａｒｉｎｅｓｅｄｉｍｅｎｔｇｅ ｏｌｏｇｙ.Ｒｅｃｏｇｎｉｔｉｏｎｏｆｅｎｄｍｅｍｂｅｒｓａｎｄｅｓｔｉｍａｔｉｏｎｏｆｔｈｅｉｒｒｅｌａｔｉｖｅｐｒｏｐｏｒｔｉｏｎｓｆｒｏｍｍｉｘｅｄｓｅｄｉｍｅｎｔｓｈａｖｅｂｅｅｎａｋｅｙｃｏｎｔｅｎｔｉｎｔｈｅｓｔｕｄｙｏｆｐｒｏｖｅｎａｎｃｅ .Ｆｏｒｔｈｉｓａｉｍ ,ｉｔｉｓｎｅｃｅｓｓａｒｙｔｏｓｅｌｅｃｔｅｎｄｍｅ…  相似文献   

Binogeochemical process of major elements in sinking particulate of Nansha coral reef lagoons,South     

Song Jinming 《海洋学报(英文版)》1997,16(4):557-562

Ｂｉｎｏｇｅｏｃｈｅｍｉｃａｌ　ｐｒｏｃｅｓｓ　ｏｆ　ｍａｊｏｒ　ｅｌｅｍｅｎｔｓ　ｉｎ　ｓｉｎｉｎｇ　ｐａｒｔｉｃｕｌａｔｅ　ｏｆ　Ｎａｎｓｈａ　ｃｏｒａｌ　ｒｅｅｆ　ｌａｇｏｏｎｓ，Ｓｏｕｔｈ　TXＢｉｎｏｇｅｏｃｈｅｍｉｃａｌｐｒｏｃｅｓｓｏｆｍ...  相似文献