Experimental calibration of sapphirine–spinel Fe–Mg exchange thermometer: Implication for constraints on P–T condition of Howard Hills, Napier Complex, East Antarctica     

Kei Sato  Tomoharu Miyamoto  Toshisuke Kawasaki 《Gondwana Research》2006,9(4):398-408

The Fe²⁺–Mg distribution coefficients between sapphirine and spinel:were experimentally determined at pressures of 9–13 kbar and temperatures of 950–1150 °C using a natural ultrahigh-temperature (UHT) granulite with paragenesis of these minerals from the Napier Complex in East Antarctica [X_Mg = Mg / (Fe + Mg); X_Fe = Fe / (Fe + Mg)]. A new sapphirine–spinel geothermometer has been obtained as:

We applied the exchange thermometer to UHT or high-grade metamorphic rocks that were reported from various complexes in the world. If the K_D values of 2.63–4.34 obtained from low-Cr mineral pairs such as X_Cr^Spr < 0.016 and X_Cr^Spl < 0.047 were substituted into the equation, their temperature conditions would be estimated as 806–1050 °C at 11 kbar. The X_Cr means Cr / (Al + Cr(+ Fe³⁺)). These temperatures are reasonable retrograde or near peak metamorphic condition.  相似文献   

辽宁后仙峪硼矿床中电气石的矿物学特征及其成岩成矿意义   总被引：1，自引：0，他引：1       下载免费PDF全文

薛建玲  许虹 高一鸣黄静宜 《中国地质》2006,33(6):1386-1392

笔者对辽宁后仙峪硼矿床中电气石的矿物学特征和化学成分特征进行了分析．探讨了电气石化学成分对成岩成矿的指示意义。本区电气石属于镁电气石-铁电气石系列。其Mg／Fe与硼酸盐矿体有着密切的时空关系。不同产状中电气石的颜色、粒度、形态和环带特征都有明显的差别。靠近硼酸盐矿体的电气石环带各环圈都较为富Mg。从中心到边缘Mg总体有降低的趋势；远离硼酸盐矿体的各环圈都较富Fe。从中心到边缘Fe总体上有降低的趋势。电气石含量上盘总体上较下盘高，电英岩主要出现在硼酸盐矿体附近．Mg／Fe在远离硼酸盐矿体的电气石中与Na2O呈明显的正相关关系。电气石的上述化学成分特征反映了成岩成矿过程中流体演化的特点．早期的电气石是沉积物中富B部分经交代作用而成。在蒸发盆地的演化过程中，流体中Mg、Na、K成分增加，造成Mg／Fe的分带现象。电气石的所有矿物和化学特征表明电气石的形成方式包括沉积变质成因和热液交代两种．电气石的形成与硼酸盐的沉积过程密切相关．  相似文献   

Constraints on paleowater dissolved loads and on catchment weathering over the past 16 ka from Sr/Sr ratios and Ca/Mg/Sr chemistry of freshwater ostracode tests in sediments of Lake Constance, Central Europe     

Bernd Kober  Antje Schwalb  Georg Schettler  Martin Wessels   《Chemical Geology》2007,240(3-4):361-376

Sr isotope and Ca/Mg/Sr chemical compositions of freshwater ostracode tests separated from a sediment core represent the last 16 ka of sedimentation in Lake Constance, Central Europe. The chemical evolution of the paleowater's dissolved load of Lake Constance was estimated by correcting the ostracode data for Ca/Mg/Sr fractionation due to biogenic calcification. Since the Late Pleistocene deglaciation, the Ca/Sr molar ratios of paleowaters increased systematically from about 100 (a near marine signature) to about 200. Ca/Mg molar ratios varied in the range of 1–25. The ⁸⁷Sr/⁸⁶Sr ratios indicate Late Pleistocene paleowater compositions of 0.7086–0.7091, significantly more radiogenic than present day waters (0.7085). Sr isotopes and Ca/Mg/Sr chemical data together show that weathering of Mesozoic evaporites consistently dominated the dissolved Sr load (80–90%). Carbonate and silicate weathering were less important (1–10%). Trends of Sr dissolved loads were therefore not related to Mg which was mainly mobilized by carbonate weathering. Biotite weathering was an important source of radiogenic Sr in the paleowaters. The short-term release (duration about 600–800 years) of radiogenic Sr during glacier retreat started 15.2 ka ago and was due to enhanced biotite weathering at the glacier base. Long-term release of radiogenic Sr was due to biotite weathering in glacial soils and silicate rocks, and has gradually declined since the Late Pleistocene/Holocene transition.  相似文献   

Mg Isotope Interlaboratory Comparison of Reference Materials from Earth‐Surface Low‐Temperature Environments          下载免费PDF全文

Netta Shalev  Juraj Farkaš  Jan Fietzke  Martin Novák  Jan A. Schuessler  Philip A.E. Pogge von Strandmann  Philip B. Törber 《Geostandards and Geoanalytical Research》2018,42(2):205-221

To enable quality control of measurement procedures for determinations of Mg isotope amount ratios, expressed as δ²⁶Mg and δ²⁵Mg values, in Earth‐surface studies, the δ²⁶Mg and δ²⁵Mg values of eight reference materials (RMs) were determined by interlaboratory comparison between five laboratories and considering published data, if available. These matrix RMs, including river water SLRS‐5, spring water NIST SRM 1640a, Dead Sea brine DSW‐1, dolomites JDo‐1 and BCS‐CRM 512, limestone BCS‐CRM 513, soil NIST SRM 2709a and vegetation NIST SRM 1515, are representative of a wide range of Earth‐surface materials from low‐temperature environments. The interlaboratory variability, 2s (twice the standard deviation), of all eight RMs ranges from 0.05 to 0.17‰ in δ²⁶Mg. Thus, it is suggested that all these materials are suitable for validation of δ²⁶Mg and δ²⁵Mg determinations in Earth‐surface geochemical studies.  相似文献   

鲕粒原生矿物识别及对海水化学成分变化的指示意义   总被引：1，自引：0，他引：1  

李飞  武思琴  刘柯 《沉积学报》2015,33(3):500-511

鲕粒是碳酸盐沉积过程中一类非常特殊的颗粒类型, 为研究当时的沉积背景、水动力条件、气候环境, 甚至储层特征提供了重要线索。然而, 鲕粒的矿物组成及控制因素问题, 长期受到忽视。组成鲕粒的原生矿物类型在地质历史时期呈周期性变化, 在显生宙表现为三个以文石和高镁方解石占主导的时期以及两个以低镁方解石占主导的时期, 这也被称作“文石海”和“方解石海”时期。原生矿物的组成, 制约着鲕粒的纹层结构、保存程度以及成岩特征, 还蕴含着海水化学成分变化的线索。鲕粒原生矿物识别主要依据:①原生纹层结构;②保存程度;③微量元素浓度, 尤其是Sr-Mg的浓度。文石质鲕粒受文石不稳定性的影响, 原生结构保存程度较差;一般保存有典型的文石残余纹层结构(例如砖砌结构、溶解变形结构以及偏心结构等);在封闭成岩环境下原生矿物为文石质的鲕粒Sr浓度往往大于2 000 ppm;纹层结构主要为切线状(占主导)和放射状。方解石质鲕粒包括低镁方解石和高镁方解石两种类型:低镁方解石为稳定矿物, 原生结构一般保存良好。尽管高镁方解石也为亚稳定矿物, 但成岩转换后的保存程度好于文石。两者Sr含量一般均低于1 000 ppm, Mg含量一般在0~20 mol % MgCO₃(两者以4 mol % MgCO₃为界)。高镁方解石受成岩作用影响, 在纹层中往往保留有微粒白云石包裹体;海相地层中保存的方解石质鲕粒为放射状或同心-放射状结构。另外还存在一类由两种矿物共同构成的双矿物鲕粒, 可以通过分析两类纹层在结构和保存特征上的差异进行区分。鲕粒原生矿物成分随时间的波动变化受到海水化学条件, 尤其是Mg/Ca比值, 大气二氧化碳分压以及碳酸盐饱和度的控制。Mg/Ca比值的波动决定着鲕粒原生矿物类型的长期变化规律。一些突发性事件可能会扰动(区域)短时间尺度下鲕粒原生矿物的组成, 造成鲕粒原生矿物的转换。通过研究碳酸盐鲕粒原生矿物特征以及控制因素进而了解海水的化学特征, 是独立于古生物学和地球化学分析之外的一种较为可靠的沉积学方法。  相似文献   

Titanium‐in‐biotite thermometry in porphyry copper systems: Challenges to application of the thermometer     

Mohsen Rezaei  Alireza Zarasvandi 《Resource Geology》2020,70(2):157-168

Empirical geothermometer dealing with Ti solubility in the Fe‐Mg biotites was originally proposed for biotites in graphitic, peraluminous metapelites containing ilmenite or rutile that equilibrated roughly at 4–6 kbar. Given that biotites are abundant in the porphyry copper systems, this geothermometer has frequently been used for the determination of magmatic–hydrothermal temperatures in the porphyry copper systems. Common associations of porphyry copper deposits (PCDs), that is, low Al content of biotite, biotite chloritization (causes the biotite to become more magnesian and to lose Ti), and biotite formation by amphibole replacement, as well as disequilibrium, local equilibrium, or re‐equilibration of biotites, especially through potassic alteration, may provide significant uncertainty in the temperatures estimated a by Ti‐in‐biotite geothermometer. In addition, besides the calibration range of thermometer for pressure (400–600 MPa), the temperatures of major sulfide precipitation in PCDs (>~400°C) does not fit with the temperature range of thermometer calibration (480–800°C). Worth noting, as confirmed by fluid inclusion data in the Sarkuh PCD, regardless of presence of mineralogical requirements, obtained temperatures of sulfide mineralization using Ti in biotite thermometer could be overestimated. This may be due to the difference between general conditions of sulfide mineralization and calibration range of Ti in the biotite thermometer for pressure and temperature, as well as the metaluminous nature of biotites in PCDs.  相似文献   

三叠纪西秦岭西北部洋俯冲的记录:来自镁安山岩/高镁安山岩的证据          下载免费PDF全文

李康宁  刘伯崇  狄永军 《中国地质》2020,47(3):709-724

三叠纪以来,西秦岭地区构造-岩浆活动极为强烈,中酸性侵入岩呈北西向弧状分布,前人做了大量卓有成效的工作,但对出露较少的火山岩鲜有研究。本次工作选取青海省同仁县麦秀和甘肃省夏河县甘加、德乌鲁3个地区的安山岩,从岩石学、岩石地球化学、年代学等进行分析。结果显示安山岩均属于钙碱性系列,具有富钾火山岩的特征。其中,麦秀安山岩中既有高镁安山岩,也有镁安山岩,而甘加与德乌鲁安山岩属于镁安山岩,为洋壳俯冲作用形成的两种典型火山岩类型。西秦岭地区安山岩形成时间东早西晚,由西向东安山岩基性程度降低,K_2O、Na_2O、∑REE等含量增高,MF、FL、DI、La/Sm等值变大,SI、Mg~#等值降低,并且呈明显的线性特征,构成同仁—合作镁安山岩(镁闪长岩)岩浆弧组合,和北部隆务峡蛇绿岩带一起,组成岩性分布极性,从而判断出西秦岭西北部在三叠纪存在隆务峡蛇绿岩代表的洋壳板块向南俯冲作用。  相似文献   

Geochemical evolution of groundwater in the carbonate aquifers of Sierra de Segura (Betic Cordillera, southern Spain)   总被引：1，自引：0，他引：1  

F. Moral  J.J. Cruz-Sanjulin  M. Olías 《Journal of Hydrology》2008,360(1-4):281-296

Sierra de Segura (Betic Cordillera), with a total area of over 3000 km², is the source of the two principal rivers in southern Spain, the Guadalquivir and the Segura. Due to the orographic effect of these mountains, precipitations are considerably more abundant than in nearby lowland areas, where the climate is semi-arid. Sierra de Segura is constituted of Mesozoic and Cenozoic sedimentary rocks, among which there are thick limestone–dolomitic formations which have given rise to extensive outcrops of permeable materials. In geomorphological terms, there is a large plateau intensively karstified that constitutes the main recharge area. Discharge takes place via a large number of springs, of which the 50 most important add up to a mean spring flow of about 13,500 l/s. The active geochemical processes in aquifers of Sierra de Segura, with their corresponding time sequence, are: dissolution of CO₂, dissolution of calcite, incongruent dissolution of dolomite, dedolomitization, exsolution of CO₂, and precipitation of calcite. More evolved water has higher temperature, magnesium content and Mg/Ca ratio; therefore, these parameters can be utilised as indicators of the degree of hydrochemical evolution. In addition, a good correlation between water temperature and magnesium concentration (or Mg/Ca ratio) indicates that an increase in temperature accelerates the kinetics of the dissolution of dolomite. Finally, the distribution of the temperatures in the vadose zone, determined by atmospheric thermal gradient, implies an apparent stratification of the predominant hydrochemical processes and of the groundwater physical and chemical characteristics.  相似文献   

重庆地区石笋记录中Mg /Ca比值及古气候意义   总被引：6，自引：3，他引：3  

李清  王建力  李红春  叶明阳  王勇  李廷勇  何潇 《中国岩溶》2008,27(2):145-150

在重庆梁天湾洞石笋LT14 31. 9～ 15. 02ka. B. P.古气候重建成果已发表的此基础上,本文选取Mg / Ca比值这一新的替代指标,探讨其在重庆地区独特的水热组合模式下的古气候指示意义,从而进一步探讨了该时段的气候变化。研究结果发现,重庆地区Mg /Ca 比值与碳同位素的正相关关系较好( R2= 0. 60) ,可能与碳酸钙溶液在到达洞顶之前提前沉淀或滴率减小机制有关,它间接响应了降水的变化。运用Mg / Ca 值变化对古气候的重建结果与以前的研究基本相符,说明Mg /Ca 比值可以作为古降水的指标,但需同碳氧稳定同位素结合起来讨论,以便相互验证,提高古环境解译的准确性。   相似文献   

Quantifying the carbon source of pedogenic calcite veins in weathered limestone: implications for the terrestrial carbon cycle     

Lin Zou  Lin Dong  Meng Ning  Kangjun Huang  Yongbo Peng  Shujian Qin  Honglin Yuan  Bing Shen 《Acta Geochimica》2019,(4):481-496

The continent is the second largest carbon sink on Earth’s surface.With the diversification of vascular land plants in the late Paleozoic,terrestrial organic carbon burial is represented by massive coal formation,while the development of soil profiles would account for both organic and inorganic carbon burial.As compared with soil organic carbon,inorganic carbon burial,collectively known as the soil carbonate,would have a greater impact on the long-term carbon cycle.Soil carbonate would have multiple carbon sources,including dissolution of host calcareous rocks,dissolved inorganic carbon from freshwater,and oxidation of organic matter,but the host calcareous rock dissolution would not cause atmospheric CO2drawdown.Thus,to evaluate the potential effect of soil carbonate formation on the atmospheric p CO2level,different carbon sources of soil carbonate should be quantitatively differentiated.In this study,we analyzed the carbon and magnesium isotopes of pedogenic calcite veins developed in a heavily weathered outcrop,consisting of limestone of the early Paleogene Guanzhuang Group in North China.Based on the C and Mg isotope data,we developed a numerical model to quantify the carbon source of calcite veins.The modeling results indicate that4–37 wt%of carbon in these calcite veins was derived from atmospheric CO2.The low contribution from atmospheric CO2might be attributed to the host limestone that might have diluted the atmospheric CO2sink.Nevertheless,taking this value into consideration,it is estimated that soil carbonate formation would lower 1 ppm atmospheric CO2within 2000 years,i.e.,soil carbonate alone would sequester all atmospheric CO2within 1 million years.Finally,our study suggests the C–Mg isotope system might be a better tool in quantifying the carbon source of soil carbonate.  相似文献