基于自动观测站的鲁中地区土壤水分变化规律及精细化预报模型的研究     

环海军  杨再强  刘岩  夏福华 《气象科学》2016,36(6):834-842

为了建立鲁中地区土壤水分精细化预报模型,利用2010—2013年农田土壤水分自动站逐日资料进行土壤水分年、月变化特征研究,并结合附近自动气象站资料,以土壤水分平衡方程、农田蒸散模型为基础,采用逐步回归和曲线估计等方法建立4—6月无降水条件下平原水浇田与山旱田土壤水分1 d、7 d降幅的经验预报模型。结果表明:鲁中地区0~100 cm土壤水分贮存量年变化趋势和0~50 cm基本一致,年最高出现在8月,最低出现在6月,年降幅最大出现在3—6月,易出现干旱。对预报模型进行回代和预报检验结果显示,回代平均相对误差为0.07%,7 d模型和1 d模型滚动预报第7天0~50 cm土壤水分贮存量,绝对误差分别为-0.15和-2.17 mm,平均相对误差分别为-0.07%和-1.56%,模型具有较强的理论基础和实用性,预报精度较高,为鲁中地区土壤墒情监测和精细化预报提供支持。  相似文献   

Preservation of coal-waste geochemical markers in vegetation and soil on self-heating coal-waste dumps in Silesia,Poland     

《Chemie der Erde / Geochemistry》2016,76(2):211-226

Occurrence and distributions of geochemical markers on vegetation and in soils covering two self-heating coal waste dumps were investigated with gas chromatography-mass spectrometry (GC–MS) and compared with those of bitumen expelled on the coal waste dump surface. Presence of biomarkers, alkyl aromatic hydrocarbons, polycyclic aromatic hydrocarbons (PAHs), and such polar compounds as phenols indicate that components of self-heating coal wastes indeed migrate to soils and plants surface and their characteristic fingerprints can be applied in passive monitoring to investigate migration of contaminants from self-heating coal wastes. Moreover, results allow to discriminate between the Upper- and Lower Silesian coal basins, notwithstanding value shifts caused by heating. Mechanisms enabling the migration of geochemical compounds into soils include mixing with weathered coal-waste material, transport in gases emitted due to self-heating and, indirectly, by deposition of biomass containing geochemical substances. Transport in gases involves mostly lighter compounds such as phenols, methylnaphthalenes, methylbiphenyls, etc. Distributions and values of geochemical ratios are related to differences in their boiling temperatures in the case of lighter compounds but preserve geochemical features in the case of heavier compounds such as pentacyclic trierpanes.  相似文献   

Petrogenesis and geodynamic evolution of the Kajan Neogene subvolcanic rocks,Nain, Central Iran     

《Chemie der Erde / Geochemistry》2016,76(4):567-578

Kajan subvolcanic rocks in the Urumieh–Dokhtar magmatic arc (UDMA), Central Iran, form a Late Miocene-Pliocene shallow-level intrusion. These subvolcanics correspond to a variety of intermediate and felsic rocks, comprising quartz diorite, quartz monzodiorite, tonalite and granite. These lithologies are medium-K calc-alkaline, with SiO₂ (wt.%) varying from 52% (wt.%) to 75 (wt.%). The major element chemical data also show that MgO, CaO, TiO₂, P₂O₅, MnO, Al₂O₃ and Fe₂O₃ define linear trends with negative slopes against SiO₂, whilst Na₂O and K₂O are positively correlated with silica. Contents of incompatible trace elements (e.g. Ba, Rb, Nb, La and Zr) become higher with increasing SiO₂, whereas Sr shows an opposite behaviour. Chondrite-normalized multi-element patterns show enrichment in LILE relative to HFSE and troughs in Nb, P and Ti. These observations are typical of subduction related magmas that formed in an active continental margin. The Kajan rocks show a strong affinity with calc-alkaline arc magmas, confirmed by REE fractionation (La_N/Yb_N = 4.5–6.4) with moderate HREE fractionation (Sm_N/Yb_N = 1.08–1.57). The negative Eu anomaly (Eu/Eu* <1), the low to moderate Sr content (< 400 ppm) and the Dy/Yb values reflect plagioclase and hornblende (+- clinopyroxene) fractionation from a calc-alkaline melt Whole–rock Sr and Nd isotope analyses show that the ⁸⁷Sr/⁸⁶Sr initial ratios vary from 0.704432 to 0.705989, and the ¹⁴³Nd/¹⁴⁴Nd initial ratios go from 0.512722 to 0.512813. All the studied samples have similar Sr-Nd isotopes, indicating an origin from a similar source, with granite samples that has more radiogenic Sr and low radiogenic Nd isotopes, suggesting a minor interaction with upper crust during magma ascent. The Kajan subvolcanic rocks plot within the depleted mantle quadrant of the conventional Sr-Nd isotope diagram, a compositional region corresponding to mantle-derived igneous rocks.  相似文献   

Multiple statistical approaches for the discrimination of mangrove species of Rhizophoraceae using transformed field and laboratory hyperspectral data   总被引：1，自引：0，他引：1  

Kumar Arun Prasad 《国际地球制图》2016,31(8):891-912

This study aims at discriminating eight mangrove species of Rhizophoraceae family of Indian east coast using field and laboratory spectra in spectral range (350–2500 nm). Parametric and non-parametric statistical analyses were applied on spectral data in four spectral modes: (i) reflectance (ii) continuum removed, (iii) additive inverse and (iv) continuum removed additive inverse. We introduced continuum removal of inverse spectra to utilize the advantage of continuum removal in reflectance region. Non-parametric test gave better separability than parametric test. Principal component analysis and stepwise discriminant analysis were applied for feature reduction and to identify optimal wavelengths for species discrimination. To quantify the separability, Jeffries–Matusita distance measure was derived. Green (550 nm), red edge (680–720 nm) and water absorption region (1470 and 1850 nm) were found to be optimal wavelengths for species discrimination. The continuum removal of additive inverse spectra gave better separability than the continuum removed spectra.  相似文献   

Quantification of LST and CO2 levels using Landsat-8 thermal bands on urban environment     

Venkatesh Reddy Chejarla  Pramod Kumar Maheshuni 《国际地球制图》2016,31(8):913-926

Land surface temperature (LST) is an important aspect in global to regional change studies, for control of climate change and balancing of high temperature. Urbanization is one of the influencing factors increasing land surface and atmospheric temperature, by the emission of greenhouse gases (e.g. CO₂, NO and methane). In the present study, LST was derived from Landsat-8 of multitemporal data sets to analyse the spatial structure of the urban thermal environment in relation to the urban surface characteristics and land use–land cover (LULC). LST is influenced by the greenhouse gases i.e. CO₂ plays an important role in increasing the earth’s surface temperature. In order to provide the evidence of influence of CO₂ on LST, the relationship between LST, air temperature and CO₂ was analysed. Landsat-8 satellite has two thermal bands, 10 and 11. These bands were used to accurately to calculate the temperature over the study area. Results showed that the strength of correlation between ground monitoring data and satellite data was high. Based on correlation values of each month April (R² = 0.994), May (R² = 0.297) and June (R² = 0.934), observed results show that band 10 was significantly correlating with air temperature. Relationship between LST and CO₂ levels were obtained from linear regression analysis. band 11 was correlating significantly with CO₂ values in each of the months April (R² = 0.217), May (R² = 0.914) and June, (R² = 0.934), because band 11 is closer to the 15-micron band of CO₂. From the results, it was observed that band 10 can be used for calculating air temperature and band 11 can be used for estimation of greenhouse gases.  相似文献   

Application of Zn isotopes in environmental impact assessment of Zn–Pb metallurgical industries: A mini review     

《Applied Geochemistry》2016

Zn and Pb smelters are the major contributors to Zn and Pb emissions among all anthropogenic sources, thus, it is essential to understand Zn isotopic variations within the context of metallurgical industries, as well as its fractionation in different environments impacted by smelting activities. This mini review outlines the current state of knowledge on Zn isotopic fractionation during the high-temperature roasting process in Zn and Pb refineries; δ⁶⁶Zn values variations in air emissions, slags and effluents from the smelters in comparison to the geogenic Zn isotopic signature of ores formation and weathering. In order to assess the environmental impact of these smelters, the available and measured δ⁶⁶Zn values are compiled for smelter impacted natural water bodies (groundwater, stream and river water), sediments (lake and reservoir) and soils (peat bog soil, inland soil). Finally, the discussion is extended to the fractionation induced during numerous physicochemical reactions and transformations, i.e. adsorption, precipitation as well as both inorganic and organic surface complexation.  相似文献   

Late Oligocene–Early Miocene palaeoecology based on pollen data from the Kalkım-Gönen Basin (Northwest Turkey)     

Sariye Duygu Üçbaş Durak  Mehmet Serkan Akkiraz 《Geodinamica Acta》2016,28(4):295-310

Radiometric and palynological data of the Upper Oligocene–Lower Miocene Soma Formation from the Kalk?m-Gönen Basin yield new results related to age and palynological contents. In this study, Upper Oligocene strata from the Dani?ment and Linfa areas and Lower Miocene strata from the Bengiler area were sampled palynologically and for radiometric dating. The Dani?ment assemblage, which is older than the Linfa assemblages, mainly contains coniferous and evergreen to deciduous mixed mesophytic forest elements. Relatively high quantities of the altitudinal plants Picea and Abies, indicate a cooler palaeoclimate. The Linfa associations mainly include coniferous and riparian elements. Pollen of the riparian plant Alnus and Taxodiaceae indicative for the swamp forest community was predominant, probably as a result of a high lake level. There is a hiatus during the Oligocene–Miocene transition, probably showing a non-depositional phase and sea-level fall indicating the Mi-1 glaciation event. Higher in the sequence, the Aquitanian Bengiler sediments include high amounts of coniferous forest elements as well as components indicative for the evergreen and deciduous mesophytic forest and also riparian forest and swamp forest. Due to presence of thermophilous taxa Reveesia, Mastixiaceae and Arecaceae, a warm and humid palaeoclimate is inferred according to quantitative analyses using the Coexistence Approach.  相似文献   

A note on “Origin of components in Chilean thermal waters” by     

《Journal of South American Earth Sciences》2016

Risacher et al. (2011) have presented voluminous data on thermal waters of Chile that is quite appreciable; however, their work still falls short on several counts. The most notable shortcoming of the work is the presentation and treatment of data. The interpretations are based on questionable premises (viz., extent of seawater intrusion) and considerations (viz., using average chemical composition of rock types for geochemical modeling, considering volcanic rocks as the only rock type in contact with the geothermal fluids) and assumptions not always substantiated by facts (with proper references) could have been corroborated. Use of Cl/Br ratio for discrimination purpose is unconvincing, considering the uncertainty in the measurement of low (<1 mg/L) Br concentration.  相似文献   

Geochemistry of Paraná-Etendeka basalts from Misiones,Argentina: Some new insights into the petrogenesis of high-Ti continental flood basalts     

《Journal of South American Earth Sciences》2016

The Early Cretaceous (∼135–131 Ma) Paraná-Etendeka continental flood basalts, preserved in bulk in the Paraná basin of southern Brazil and vicinity, have been divided into low-Ti and high-Ti types that govern the southern and northern halves of the basin, respectively. We have examined a new sample set from the southern margin of the northern high-Ti segment of Paraná basalts in Misiones, northeastern Argentina. These basalts are strongly to moderately enriched in TiO₂ (2–4 wt.%), have relatively high Ti/Y (300–500), low MgO (3.5–6.5 wt.%), and high Fe (FeO(tot) 12–14 wt.%) and belong to the Pitanga and Paranapanema magma types of Peate et al. (1992). Nd and Sr isotope compositions are quite unvarying with ε_Nd (at 133 Ma) values of −4.6 to −3.6 and initial ⁸⁷Sr/⁸⁶Sr of 0.7054–0.7059 and show no variation with fractionation. Compared to high-Ti lavas in the central and northern parts of the Paraná high-Ti basalt segment, the lavas from Misiones are similar to those in the northeastern magin of the basin but less radiogenic in initial Nd isotope composition than those in the central part. This variation probably reflects mixed EM1-EM2 source components in the sublithospheric mantle. A polybaric melt model of a sublithospheric mantle source at the garnet lherzolite-spinel lherzolite transition is compatible with the observed Ti budget of the Pitanga and Paranapanema lavas, regardless of the Nd isotope composition of their purported source.  相似文献   

江南造山带新元古代中期(830～750Ma)岩浆活动及对构造演化的制约     

邓奇  王剑  汪正江  崔晓庄  施美凤  杜秋定  马龙  廖世勇  任光明 《大地构造与成矿学》2016,(4):768-786

连接扬子地块和华夏地块的江南造山带是华南前寒武纪最重要的构造单元,其形成和演化长期以来备受关注。在江南造山带的范围内广泛发育了新元古代岩浆岩,它们是探讨江南造山带构造演化的重要对象,但其成因和形成的构造背景却备受争论。本文系统收集和分析了江南造山带830~820 Ma花岗岩、800~780 Ma酸性岩和800~750 Ma基性岩的地球化学数据。研究表明,不同时间段的岩石成因类型存在系统差异,830~820 Ma的花岗岩主要为S型花岗岩,800~780 Ma的酸性岩主要为A型酸性岩,而800~750 Ma的基性岩以拉斑系列和碱性系列为主,并在构造判别图中显示了板内玄武岩(WPB)和洋中脊玄武岩(MORB)的特征。综合同位素年代学、岩石地球化学和沉积学等学科领域的研究成果我们认为:扬子北缘和西缘应先于东南缘在1000~900 Ma期间发生碰撞,而此时的东南缘仍为活动大陆边缘;直到~830 Ma,扬子地块与华夏地块沿江南造山带发生拼贴,但只是陆-弧-(微)陆之间的"软碰撞",而无山脉隆升和高级变质作用,各个块体之间处于"联而不合"的状态,大洋岩石圈拆沉之后的软流圈上涌和由拆沉所引起的拉张作用导致了上覆岩石圈和陆壳发生部分熔融,产生了江南造山带830~820 Ma的S型花岗岩;随着全球Rodinia超大陆的裂解,~820 Ma,华南裂谷盆地开启,并在随后的裂解过程中发育了大量与伸展有关的800~780 Ma A型酸性岩和基性岩脉/墙,而其明显高于同时代MORB源区的地幔潜能温度显示,导致Rodina超大陆裂解的地幔柱可能对该时期岩浆岩的地幔源区有一定影响;随着拉张作用的不断加强,出现了760~750 Ma碱性系列和具MORB特征的基性岩,此时的软流圈地幔既提供热量又有物质供应。  相似文献