The role of discontinuous magma inputs in felsic magma and ore generation     

J.L. Vigneresse   《Ore Geology Reviews》2007,30(3-4):181-216

For a long time, granites have been considered as passive bodies ascending under intrinsic negative density and viscosity contrasts with their host rocks. Chemical variations within a granitic body resulted from in situ differentiation and crystal fractionation. Since the mid 1980s, this global view has been significantly modified by (i) shifting melting from water-saturated conditions to fluid-absent reactions, (ii) increasing the role played by the mantle during granite generation, (iii) reassessing the rheology of partially molten rocks, (iv) demonstrating stepwise segregation and ascent of magmas by analogue and numerical models, (v) combining structural, geophysical and geochemical studies to reveal the internal structures in granitic plutons. It results that a granitic body is built up by a discontinuous accumulation of successive magma intrusions. The discontinuous nature of magma emplacement has also significant consequences for its ability to generate ore. The processes that lead to ore deposits are examined, with a brief review of the magmatic and fluid phases that concentrate ore forming elements. Examples are taken from crustal-derived granites and porphyry-type deposits. Those are considered as the two end-members of magmatic and hydrothermal ore deposits. The source characteristics of the magma, the emplacement mechanisms and magma mixing processes are the frame that controls the potential to carry base metals with the magma. The distribution of elements is controlled by diffusion, partition between minerals and melt, solubility and redox conditions. Variations of those parameters are examined by considering their activation energy which controls the exponential dependence with temperature. A characteristic length depending on the activation energy, temperature variation and time is estimated for a characteristic time lag of 30 ka. The intrusion of a magma into a magma chamber of similar composition, hence temperature, has few effects on diffusion, partition coefficient and redox conditions, because of a too low temperature contrast. The intrusion of a mafic magma into a felsic one induces a variation of 300 °C in both magmas. The characteristic length of diffusion may vary by up to two orders of magnitude, whereas the variation of partition coefficients is only one order of magnitude. The redox conditions are about 2.5 log unit in the mafic magma, but they can vary by 7 log units in the felsic magma. Hence, a strong decrease in δD values is observed in porphyry-type deposits. The effect is a removal of the elements with higher activation energy (W, Sn, Zr) from the mafic to the felsic magma. Deformation during the late stages of emplacement also controls ore formation.  相似文献   

Characteristics of fluid inclusions and metallogenic mechanism of the Longshang skarn type tin polymetallic deposit in eastern Hunan Province,ChinaSCIEI北大核心CSCD     

王旭东  袁顺达  吴胜华  徐丽燕  赵盼捞 《岩石学报》2023,(6):1743-1756

矽卡岩型锡矿是全球重要的锡金属来源,但是锡石沉淀成矿机制仍存在较大的争议。垄上矽卡岩型锡矿床位于湘东锡田锡多金属矿田中部,是南岭钨锡成矿带内矽卡岩型锡矿的典型代表。本文在野外考察、矿石矿相学、流体包裹体岩相学研究的基础上,采用流体包裹体组合法对垄上矽卡岩矿床不同矿化阶段代表矿物中的流体包裹体进行了详细研究。结果显示,垄上矽卡岩型多金属矿床成矿阶段可划分为矽卡岩阶段、退化蚀变阶段、云英岩-氧化物阶段、石英硫化物阶段以及萤石碳酸盐化等5个阶段,其中,锡石主要形成于云英岩-氧化物阶段。与锡石密切共生的石英中发育流体包裹体类型主要为富液相、富气相两相水溶液包裹体,含液相CO_(2)三相水溶液包裹体和纯CO_(2)型包裹体。流体温度和盐度具有较大的变化范围(200-400℃和2%-9%NaCleqv),指示流体在降温过程中经历了显著的不混溶。与硫化物共生的石英中主要为富液相两相水溶液包裹体,温度和盐度主要集中在190-261℃和3%-7%NaCleqv,指示流体冷却过程同时经历了流体混合。本次研究提出锡田矽卡岩型矿床中流体不混溶是导致云英岩-氧化物阶段锡石沉淀成矿的主要机制,而流体冷却和混合是导致硫化物沉淀的主要原因。  相似文献   

铟矿床时空分布、成矿背景及其成矿过程   总被引：10，自引：8，他引：2  

徐净  李晓峰 《岩石学报》2018,34(12):3611-3626

铟是一种稀散金属元素,特殊的地球化学性质导致其难以形成独立的矿床,均以伴生矿产的形式产出于富锡岩浆热液与陆相火山-次火山热液系统,以及相对贫锡的海底(火山)热液系统。研究表明,铟矿床广泛分布于活动的大洋或大陆板块边缘,成因上主要与板块俯冲以及碰撞作用密切相关,少量与火山岩以及喷流沉积岩相关的块状硫化物矿床形成的有利构造背景则是弧后环境和裂谷环境。在不同地质历史时期,铟的巨量堆积作用主要有新第三纪、白垩纪、泥盆纪三个时期,对应的矿化类型分别以浅成低温热液-锡多金属脉型、矽卡岩型以及块状硫化物(VMS)型矿床为主,其中与铟成矿作用相关的岩浆岩多为A型或S型花岗岩。铟独立矿物目前报道约15种,主要包括自然铟、硫铟铜矿、铟石、樱井矿、羟铟石等,其中以硫铟铜矿最为广泛。绝大多数铟主要以类质同象的形式赋存于闪锌矿中,其次为黝锡矿、锌黄锡矿、黄铜矿、锡石、黝铜矿、砷黝铜矿等。富铟闪锌矿通常形成于高温热液体系,常显示阶段性富集特征,最普遍的置换机制为(Ag,Cu)~++In~(3+)2Zn~(2+)。文章指出为完善铟金属成矿理论,需进一步加强铟的成矿物质来源、铟沉淀的物理化学条件及其与主矿种成生关系的研究。  相似文献   

Indoor experiment and numerical simulation study of ammonia-nitrogen migration rules in soil column          下载免费PDF全文

ZHAN Jiang  LI Wu-jin  LI Zhi-ping  ZHAO Gui-zhang 《地下水科学与工程》2018,6(3):205-219

The riverbank soil is a natural purifying agent for the polluted river water(Riverbank filtration, RBF). This is of great importance to groundwater safety along the riverbank. This paper examines the migration and transformation rules of ammonia-nitrogen in three typical types of sand soil using the indoor leaching experiment of soil column, and then makes comparison with the indoor experiment results in combination with the numerical simulation method. The experiment process shows that the change in ammonia-nitrogen concentration goes through three stages including "removal-water saturation-saturation". As the contents of clay particles in soil sample increase, the removal of ammonia-nitrogen from soil sample will take more time and gain higher ratio. During the removal period, the removal ratio of Column 1, Column 2 and Column 3 averages 68.8%(1-12 d), 74.6%(1-22 d) and 91.1%(1-26 d). The ammonia-nitrogen removal ratio shows no noticeable change as the depth of soil columns varies. But it is found that the ammonia-nitrogen removal ratio is the least of the whole experiment when the soil columns are at the depth of 15 cm. It can be preliminary inferred that the natural purifying performance of soil along the river for ammonia-nitrogen in river water mainly depends on the proportion of fine particles in soil. HYDRUS-1D model is used to simulate this experiment process, analyze the change of the bottom observation holes by time and depth in three columns(the tenth day), and make comparison with the experiment result. The coefficients of determination for fitting curves of Column 1, Column 2 and Column 3 are 0.953, 0.909, 0.882 and 0.955, 0.740, 0.980 separately. Besides, this paper examines the contribution of absorption, mineralization and nitrification in the simulation process. In the early removal stage, mineralization plays a dominant role and the maximum contribution rate of mineralization is 99%. As time goes by, absorption starts to function and gradually assumes a dominant position. In the middle and late removal stage, nitrification in Column 1 and Column 2 makes more contribution than mineralization. So the experiment result of the ammonia-nitrogen concentration is 0.6% and 2.4% lower than that in effluent and the maximum contribution ratio of nitrification is -4.53% and -5.10% respectively when only the function of absorption is considered. The mineralization in Column 1 and Column 2 in the middle and late removal stage still plays a more important role than nitrification. So the experiment result is 1.4% higher than that in effluent and the maximum contribution ratio of nitrification is -2.51% when only the function of absorption is considered. Therefore, absorption, mineralization and nitrification make different contributions during different part of the stage. This means that the natural purifying performance of soil along the river for ammonia-nitrogen in river water not only depends on the proportion of fine particles in soil, but depends on the mineralization and nitrification environment. This can offer some insights into the protection and recovery of groundwater along the riverbank.  相似文献   

河北省丁庄湾地区钼多金属矿找矿潜力分析     

王瑞军  张春雷  孙永彬  王诜  王永军 《地质论评》2021,67(Z1):67z1169-67z1170

正丁庄湾地区位于河北省赤城县北西侧,北临沽源县。前人在丁庄湾地区及周边区域已经完成1∶20万区域地球化学勘查,圈出综合异常多处,划分钼银多金属成矿远景区(汪冰,2011;王瑞军等,2014)。通过对远景区开展1∶1万土壤化探测量和岩石地球化学剖面查证,发现原生晕异常,经槽探揭露,发现一定规模钼矿化带,伴生银异常,显示丁庄湾地区具有较大的钼多金属矿成矿潜力。  相似文献   

基于Aster和Landsat8数据在青海赛什腾地区蚀变信息提取研究     

王曦  程三友  林海星  陈静  肖良 《地质论评》2021,67(6):67120017-67120017

青海赛什腾地区位于无人区,穿越条件极差,传统地质找矿勘探工作难以开展,因其植被稀少,有利于多光谱遥感数据提取矿化蚀变信息。本文以Landsat8和Aster数据为数据源,利用成像光谱法以及主成分分析法对赛什腾地区进行矿化蚀变信息的提取,成像光谱法包括最小噪声变换（MNF）,像元纯净指数（PPI）,N维可视化端元识别（N-Dimensional Visualization）以及光谱角匹配（SAM）,最终获得了赛什腾地区矿物信息分布图。利用主成分分析法对Landsat8和Aster数据分别提取黄铁矿、褐铁矿等铁染蚀变矿物和绢云母等羟基蚀变矿物,通过对Aster和Landsat8两种数据提取的蚀变信息进行空间叠加分析,定量地分析对比两种数据的蚀变信息提取效果,具有提高提取蚀变信息准确性的优势。通过样品实测光谱及镜下鉴定特征验证了研究区铁染以及羟基蚀变存在的真实性,并将矿化蚀变信息分布图与野外调查已知矿（化）点坐标进行叠加验证,结果显示矿（化）点坐标基本落在提取的矿化蚀变范围内,说明基于这两种遥感数据的处理方法以及提取结果是可靠的,为圈定找矿靶区以及扩大找矿范围提供了重要的指导意义。  相似文献   

南秦岭桂林沟斑岩型钼矿Re-Os同位素年代学及其构造意义研究     

张红  陈丹玲  翟明国  张复新  宫相宽  孙卫东 《岩石学报》2015,31(7):2023-2037

陕西省镇安县桂林沟斑岩型钼矿床位于南秦岭多金属成矿带内,其成矿围岩主要为细粒花岗岩、钾长花岗岩和蚀变的粗粒花岗岩。本文通过对桂林沟斑岩型钼矿床中辉钼矿Re-Os同位素定年以及围岩中锆石U-Pb年代学研究,旨在探讨成矿成岩的关系及其构造意义。结果表明,6件辉钼矿的Re-Os同位素年龄在195.9~198.5Ma之间,加权平均年龄为197.2±1.3Ma,表明桂林沟钼矿形成于早侏罗世。围岩细粒花岗岩、钾长花岗岩和粗粒花岗岩的锆石U-Pb年龄分别为199±1.4Ma、201±3.1Ma和198±11Ma,这说明其成岩和成矿年龄基本一致。值得注意的的是,桂林沟钼矿床的形成年龄不同于前人已报导的秦岭钼矿的三个主要成矿期,即238~213Ma、145~126Ma和116~110Ma,其稍晚于第一成矿期。200~190Ma可能代表了秦岭成矿带一期尚未认识的重要成矿事件,对于南秦岭找矿具有重要意义。该期钼矿形成于秦岭印支期碰撞之后,是在造山带垮塌引起的岩浆-热液事件过程中形成的。  相似文献   

内蒙狼山成矿带东升庙多金属硫化物矿床硫的来源及矿化过程     

高兆富  朱祥坤  张衎  罗照华  包创  唐超 《岩石学报》2015,31(12):3725-3731

东升庙多金属硫化物矿床是狼山成矿带最大和最典型的铅锌多金属硫化物矿床,目前该矿床硫的来源及成矿过程仍存在争议。本文对矿区常见硫化物矿石和最重要的赋矿围岩——绢云石墨片岩中的硫化物分别进行硫同位素分析。结果显示东升庙矿床的硫化物普遍富集硫的重同位素,且矿石与围岩中的硫化物的硫同位素分布范围均较为集中。绢云石墨片岩中的黄铁矿的δ~(34)S值在+19.4‰~+23.4‰之间,具有和当时海水硫酸盐相似的硫同位素组成,指示围岩中的不规则黄铁矿是孔隙水(海水)中的硫酸盐被完全还原后形成的。矿石硫化物的δ~(34)S值在+28.3‰~+31.3‰之间,相比围岩中的黄铁矿明显富集硫的重同位素,指示两者具有不同的硫源。矿石中的硫可能源自基底地层中蒸发岩的溶解,由此形成的硫酸盐占主导的热液流体可萃取大量铅、锌等金属,当遇到狼山群地层中富含有机质的沉积岩时发生热化学还原反应,从而造成硫化物的大量卸载,形成金属硫化物矿床。  相似文献   

山西灵丘梨园金矿床流体包裹体特征     

朱晓强  庞振山  甄世民  贾宏翔  石光耀 《地质论评》2016,62(S1):149-150

梨园金矿床位于山西省灵丘县,矿床大地构造位置处于华北板块的燕山断块,在区域上位于呈NNE向展布的太行山—岩浆—多金属成矿带上。矿区出露的地层较为简单,主要新太古界阜平群的黑云斜长片麻岩和斜长角闪岩。矿区构造发育,特别是断裂构造最为明显,主要为NNE向、近EW向、NW向及NE向,其中NNE向断裂是主要的控矿构造,梨园金矿产于NNE向断裂F3及其派生断裂带和角砾岩带中。矿区内出露的岩浆岩有伟晶状钾长花岗岩、石英斑岩、闪长岩和辉绿岩。  相似文献   

湘东茶陵地区老山坳剪切带特征及其与湘东钨矿的关系   总被引：3，自引：2，他引：1  

宋超  卫巍  侯泉林  刘庆  张宏远  伍式崇  朱浩峰  李晖 《岩石学报》2016,32(5):1571-1580

湘东茶陵地区老山坳剪切带及其与湘东钨矿的关系是长期以来备受关注且颇具争议的问题。其争议主要表现为:(1)老山坳剪切带(断层)的性质(逆断层、正断层,还是走滑断层)及其发育机理;(2)老山坳剪切带对湘东钨矿的成矿是促进作用还是破坏作用。本文对老山坳剪切带以及湘东钨矿进行了系统地观察和测量,采用宏观、微观构造研究和矿脉统计相结合的方法进行了综合分析。结果表明,老山坳剪切带的活动主要分为两期:早期主要表现为向SE方向的伸展拆离作用,且可能与晚侏罗世八团岩体侵位密切相关,形成了透入性的强烈脆、韧性变形,特别是在糜棱岩中,由于高压流体的作用造成了一系列同期节理(R和R’节理)发育,为石英脉型钨锡矿床的形成提供了条件;后期,大致在晚白垩世及之后老山坳剪切带表现为向NW方向的逆冲作用,致使上盘(主动盘)的钨锡矿脉被推至浅部。因此,我们认为晚侏罗世八团岩体的侵位作用与老山坳剪切带的伸展拆离作用共同控制了湘东钨矿的形成。韧性剪切带中,由于高压流体作用引起局部应变速率增加,同时降低岩石强度而发生脆性破裂(如T节理,R和R’节理),而且按照破裂准则发生和扩展,该过程为成矿元素析出成矿提供了条件,这可能是剪切带成矿的重要方式之一。  相似文献