内蒙古赛乌素金矿稳定同位素组成特征及成因意义     

赵百胜  刘家军  王建平  翟裕生 《地质找矿论丛》2007,22(3):195-200

内蒙古赛乌素金矿是产于中-新元古代白云鄂博群变质碎屑岩中的石英脉型金矿,矿床稳定同位素地球化学特征表明,成矿热液来源复杂,可能有岩浆水和大气降水的混合作用;成矿早期的硫来自花岗岩浆,成矿晚期的硫有一部分可能来自地层,铅同位素特征表明铅来自地幔,因此推断成矿物质主要来自于岩浆活动.  相似文献   

Evaluation of Simultaneous Analyte Leaching/Vapour Phase Introduction for Direct Osmium Isotope Ratio Measurements in Solid Samples by Double-Focusing Sector Field ICP-MS     

Ilia Rodushkin  Emma Engström  Douglas C. Baxter 《Geostandards and Geoanalytical Research》2007,31(1):27-38

The analytical performance of a method for Os isotope ratio measurement by double‐focusing, sector field ICP‐MS (ICP‐SFMS) was evaluated. The method is based on several optimised, concurrent processes: Os extraction from samples in hot concentrated nitric acid; separation of Os from the digest solution by the formation of volatile osmium tetroxide accelerated by continuous hydrogen peroxide addition; transport of analyte vapour by an oxygen flow into the ICP; and isotopic determination by ICP‐SFMS. Due to the very efficient utilisation of analyte (approaching 0.5‰), Os isotope ratio measurement could be performed at low pg levels. Combined with an ability to process sample sizes up to 2 g (up to 50 g if the organic matrix of biological or botanical samples is eliminated by ashing), materials with Os concentrations in the low, or even sub pg g^?1 range could be determined by this method. Given that two complete digestion/distillation systems were available for interchangeable use, throughputs of up to fifteen samples per 8 hour shift could be achieved. The method precision, evaluated as the long‐term reproducibility of ¹⁸⁷ Os/¹⁸⁸Os ratio measurements in a commercial Os reference sample containing 0.5 ng Os, was 0.16% relative standard deviation (RSD, 1s). The method has been applied to perform replicate ¹⁸⁷ Os/¹⁸⁸ Os ratio measurements on a suite of fifty reference materials of various origins and matrix compositions, with Os concentrations varying from < 0.1 pg g^?1 to > 100 ng g^?1, yielding an average precision of 3% RSD. Though none of the materials tested are certified for Os content or Os isotope composition, comparison of the obtained data with published Os isotope information for similar sample types revealed close agreement between the two. The method can also be used for the simultaneous, semi‐quantitative determination of Os concentrations.  相似文献   

Determination of Bromine and Iodine in Twenty-three Geochemical Reference Materials by ICP-MS   总被引：1，自引：0，他引：1  

Jian Y. Chai  Yasuyuki Muramatsu 《Geostandards and Geoanalytical Research》2007,31(2):143-150

Trace amounts (from nanogram to microgram levels) of bromine and iodine were determined by inductively coupled plasma-mass spectrometry (ICP-MS) in twenty-three geochemical reference materials issued by the GSJ, USGS, IAEA etc. The pyrohydrolysis technique was used to separate bromine and iodine from samples analysed in the form of powder. The accuracy and precision of the experimental values were assessed by the comparative analysis of well established reference materials such as USGS AGV-1, BCR-1 and IGGE GBW07312. The measured values agreed well with reported values within a 10% error range. We also report reliable new data for these elements in these geochemical reference materials.  相似文献   

新疆粘土矿物材料在环境污染治理中的应用和展望   总被引：3，自引：0，他引：3  

聂俊杰  汪立今 《岩石矿物学杂志》2007,26(6):602-606

对粘土矿物在当前环境污染治理中的基本应用做了介绍,并系统阐述了主要粘土矿物的结构特征、基本性能和主要应用。对粘土矿物材料在环境污染治理中的应用领域提出了一些思考,这对当前粘土矿物材料在环境污染治理中的应用具有一定的指导意义。  相似文献   

应变组合的地质意义及其分解实例     

魏宽义  张复新 《地球科学与环境学报》1998,20(3)

以分析递进变形序列为主线,论述了主有限应变和增量应变的内部旋转所组合的应变扇形区的空间展布。结合发育于剪切带中的一个微细粒浸染型金矿的找矿实际,指出该理论的野外应用方法。  相似文献   

General absorbing boundary conditions for dynamic analysis of fluid-saturated porous media     

T. Akiyoshi  X. Sun  K. Fuchida 《Soil Dynamics and Earthquake Engineering》1998,17(6):397-406

General absorbing boundary conditions based on Biot's two-phase mixture theory and paraxial approximation is presented for the dynamic analysis of fluid-saturated porous media with isotropic, transverse isotropic, and anisotropic properties. For the last two cases, the equivalent Lame's constants, under conditions of uniqueness, are introduced to facilitate the analytical solutions. The numerical results show that the proposed absorbing boundary can greatly suppress spuriously reflected waves and efficiently model the far field of the system with sufficient accuracy.  相似文献   

Preparation of Two New GSJ Geochemical Reference Materials: Basalt JB-1b and Coal Fly Ash JCFA-1   总被引：1，自引：0，他引：1  

Shigeru Terashima  Masahiro Taniguchi  Masumi Mikoshiba  Noboru Imai 《Geostandards and Geoanalytical Research》1998,22(1):113-117

  相似文献   

Determination of the Platinum-Group Elements and Gold in Twenty Rock Reference Materials by Inductively Coupled Plasma-Mass Spectrometry (ICP-MS) after Pre-Concentration by Nickel Sulfide Fire Assay     

Hans-Gerrit Plessen  Jörg Erzinger 《Geostandards and Geoanalytical Research》1998,22(2):187-194

The platinum-group elements (PGE) and gold have been determined in twenty international rock reference materials by inductively coupled plasma-mass spectrometry (ICP-MS) after pre-concentration by a nickel sulfide fire assay. It was possible to achieve determination limits for a 50 g sample that ranged from 1 pg g^-1 (Rh) to 23 pg g^-1 (Au). Compared to published certified and recommended values for rock reference materials, the trueness of the method was found to be good. However, in some cases we observed large deviations for all elements in the sub 10 ng g^-1 range within individual reference sample splits. Our results show that the PGE and Au are inhomogeneously distributed in the reference materials analysed here, where they are present in low concentrations, using 50 g test portions.  相似文献   

A note on permeability changes in geologic material due to stress   总被引：6，自引：0，他引：6  

W. F. Brace 《Pure and Applied Geophysics》1978,116(4-5):627-633

Summary Stress produces framatic changes in fluid permeability of geologic materials. An increase of nearly threefold occurred in granite at high stress, an increase of 20 percent in sandstone, and a hundredfold decrease in compacted sand. Permeability of sand and sandstone did not follow the effective stress law. Flow along joints was very sensitive to effected stress changes, a fourfold change being caused by as little as 1.0 MPa.  相似文献   

Multiscale approach to geo‐composite cellular structures subjected to rock impacts     

François Nicot  Philippe Gotteland  David Bertrand  Stéphane Lambert 《国际地质力学数值与分析法杂志》2007,31(13):1477-1515

Geo‐composite cellular structures are an efficient technological solution for various applications in civil engineering. This type of structure is particularly well adapted to resisting rockfalls and can act as a defensive structure. However, the design of such structures is for the most part empirically based; this lack of research‐based design stagnates optimization and advanced development. In this paper, the mechanical behaviour of a geo‐composite cellular structure is investigated using a multi‐scale approach, from the individual cell made up of an assembly of rocky particles contained in a wire netting cage to the entire structure composed of a regular array of cells. Based on discrete modelling of both the cell and structure scales, a computational tool has been developed for design purposes. Copyright © 2007 John Wiley & Sons, Ltd.  相似文献