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91.
The South Karaku
oil field is located in southeast Turkey, and produces, from the Late Cretaceous Mardin Group, carbonate reservoirs consisting of the Karababa, Derdere, Sabunsuyu and Areban Formations. The Karababa Formation is divided into three members, of which the productive Karababa-C member, discussed here, is composed of shallow marine bioclastic mudstone to wackestone. It is affected by early to late diagenetic processes that caused modification of the original pore system by cementation, dissolution and fracturing. Two petrophysical-petrologic facies can be discriminated by principal component analysis, and linear, multiple and stepwise multiple regression analysis of petrophysical data. These correspond to vuggy-moldic porosity and microporosity dominated reservoirs. 相似文献
92.
93.
S. G. Eeckhout E. De Grave R. Vochten N. M. Blaton 《Physics and Chemistry of Minerals》1999,26(6):506-512
Mössbauer spectra (MS) of anapaite (Ca2 Fe2+(PO4)2?·?4H2O) and of a sample after being immersed in a 4% H2O2 solution at room temperature (RT) over 12 days (hereafter an4ox) were collected at temperatures in the range 4.2 to 420?K and 11 to 300?K respectively. All MS consist of symmetrical doublets, hence magnetic ordering was not observed. The temperature dependencies of the Fe2+ centre shifts of anapaite and an4ox were analysed with the Debye model for the lattice vibrations. The characteristic Mössbauer temperatures were found as 370?K?±?25?K and 340?K?±?25?K, and the intrinsic isomer shifts as 1.427?±?0.005?mm/s and 1.418?±?0.005?mm/s respectively. From the external-field (60?kOe) MS recorded at 4.2 and 189?K for the non-treated sample, the principal component V zz of the electric field gradient (EFG) is determined to be positive and the asymmetry parameter η?≈?0.2 and 0.4 respectively. The temperature variations of the quadrupole splittings, ΔE Q(T), cannot be interpreted on the basis of the thermal population of the 5 D electronic levels resulting from the tetragonal compression of the O6 co-ordination. The low-temperature linear behaviour of ΔE Q(T) is attributed to a strong orbit-lattice coupling. A field of 60 kOe applied to anapaite at 4.2?K produces magnetic hyperfine splitting with effective hyperfine fields of ?136, ?254 and ?171?kOe along the principal axes Ox, Oy and Oz of the EFG tensor respectively. Additional oxidation treatments in solutions with various H2O2 concentrations up to 20% and subsequent Mössbauer experiments at room temperature, have revealed that the anapaite structure is not sensitive to oxidation since eventually only a small amount of Fe2+ (~6.5%) is converted into Fe3+. 相似文献
94.
S. Rossano E. Balan G. Morin J.-P. Bauer G. Calas C. Brouder 《Physics and Chemistry of Minerals》1999,26(6):530-538
Tektite glasses are investigated using 57Fe Mössbauer spectroscopy. Room temperature spectra analysis is performed using two complementary analytical methods based on two-dimensional distributions of both isomer shift and quadrupole splitting. No a priori correlation between the two hyperfine parameters is considered. The first method, based on a shape independent distribution, provides the justification for the Gaussian distribution shape used in the second method. No ferric iron contribution is evidenced by Mössbauer spectra analysis in these samples, although several criteria are used. Ferrous iron sites are shown to be continuously distributed between four- and five-fold co-ordinated sites. 相似文献
95.
伽玛能谱参数与金矿找矿 总被引:1,自引:0,他引:1
γ能谱测量方法是一种简便、有效、快速的间接找金的方法,不同类型的金矿其伽玛能谱特征并不相同。与深成脉岩活动有关的脉状金矿,具有明显的伽玛能谱K/U参数异常;与中浅成中酸性侵入发杂岩体有关的金矿,具有K/U,K/Th参数正异常;而与浅成-超玫成偏碱性杂岩体有关的隐爆角砾岩型金矿,则具有一致的U,Th,K及F参数正异常。本介绍了在山东东部乳山地区及临沂西部地区,利用没的伽玛能谱参数进行不同类型的金矿 相似文献
96.
The geochemical signatures of fifty-four rock samples and three supplementary drill stem test(DST) oils from the Yacheng-Sanya formations in the central Qiongdongnan Basin(CQB) were analysed. Reconstruction of the early Oligocene-early Miocene(36–16 Ma) palaeovegetation and source analyses of organic matter(OM) were conducted using aliphatic biomarkers in ancient sediments and DST oils. Both the interpreted aquatic and terrigenous OM contributed to the CQB source rocks(SRs) but had varying relat... 相似文献
97.
98.
The accurate and precise determination of Li isotopic composition by MC‐ICP‐MS suffers from the poor performance of traditional column chromatography. Previously established chromatographic processes cannot completely remove Na in complex geological samples, which is currently interpreted to be a result of Na breakthrough. In this study, Na breakthrough during single‐column purification was found to differ between simply artificial Na‐containing sample solutions, where a little Na residue was found, and silicate rocks, where a large amount of breakthrough occurred. A revised two‐step column purification for Li using 0.5 and 0.3 mol l?1 HCl as eluents was designed to remove the Na. This modified method achieves high‐efficiency Li purification from Na and consequently avoiding high Na/Li ratio interference for subsequent MC‐ICP‐MS analyses. The proposed method was validated by the analysis of a series of reference materials, including Li2CO3 (IRMM‐016, ‐0.10‰), basalt (BCR‐2: 2.68‰; BHVO‐2: 4.39‰), andesite (AGV‐2: 6.46‰; RGM‐2: 2.59‰), granodiorite (GSP‐2: ?0.87‰) and seawater (CASS‐5, 30.88‰). This work reports early Na appearance prior to the elution curves in chromatography and emphasises its influence for subsequent Li isotope measurement. Based on the findings, the established two‐step method would be more secure than single‐column chemistry for Li purification. 相似文献
99.
针对准噶尔盆地玛湖凹陷西斜坡风南地区三叠系百口泉组扇三角洲砂岩物性空间变化大、优质储集层(孔隙度大于7.4%,渗透率大于0.05×10-3μm2)预测难的问题,在沉积岩石学、地震沉积学以及地震反演和解释理论指导下,综合利用测井、岩心和三维地震等资料开展了高精度层序地层划分、沉积微相描述和优质储集层地震反演研究。建立了风南井区四级层序地层格架,明确了扇三角洲多期水进水退的充填过程,指出SSQ3和SSQ5是优质储集层的发育层系;识别出扇三角洲平原分流河道、河道间和扇三角洲前缘水下分流水道、河口坝、席状砂等沉积微相,指出扇三角洲平原是优质储集层发育相带;通过应用高分辨层序地层纵向边界和沉积相横向边界约束,进行分层相控叠后地震波阻抗反演,提升储集层预测精度,在SSQ3和SSQ5预测5个优质储集层发育区,提出3口井的井位建议,钻探均获工业油流。 相似文献
100.
根据陡坡段桥梁基桩承载特性,提出了一种可考虑桩土非线性作用的基桩内力与位移分析有限杆单元方法。首先,基于单元划分结果,结合桩侧摩阻力和坡体侧向推力的分布规律,得到了相应的等效结点荷载向量表示方法;其次,在线弹性地基反力法的基础上,引入p-y曲线开展了桩周土抗力非线性分析,并结合桩身P-?效应(P为桩顶轴向荷载,?为桩顶水平位移)计算方法给出了单元刚度矩阵修正方法,进而提出了适用于基桩内力位移非线性分析的有限杆单元法并编制了MATLAB计算程序;最后,结合某工程实例,将计算结果与工程实测值及已有理论值进行对比。结果表明:考虑桩土非线性作用的计算方法是合理的;当桩身具有自由段时,P-?效应对基桩内力位移的影响较大,在实际工程设计中不可忽视。 相似文献