Temporal and spatial variability of dissolved organic carbon concentration in the Xijiang River, South China     

Zhen Tao  Quanzhou Gao  Wenping Guo  Zhengang Wang  Yongling Zhang  Chenji Xie  Xiakun Huang  Hongwei Zhong 《山地科学学报》2011,8(5):694-703

A whole year analysis of riverine dissolved organic carbon (DOC) concentrations in the Xijiang River (XJR), South China, showed that the mean riverine DOC concentration (1.24 mg L-1) in the XJR was notably lower than the averaged value (5.75 mg L-1) of the global riverine DOC concentration in several major rivers. There is an inconspicuous monthly fluctuation of the DOC signal in the XJR, but on a semi-yearly time scale, however, the riverine DOC concentration had significant difference between hydrological...  相似文献   

Rio Tinto estuary (Spain): 5000 years of pollution   总被引：6，自引：0，他引：6  

R.A. Davis Jr.  A. T. Welty  J. Borrego  J. A. Morales  J. G. Pendon  J. G. Ryan 《Environmental Geology》2000,39(10):1107-1116

 Mining of massive sulfide deposits in southwestern Spain extending back to the Copper and Bronze Ages has resulted in the pollution of the Rio Tinto fluvial-estuarine complex, the site of Columbus' departure for the New World in 1492. Additional sources of potential pollution include the large industrial complex at Huelva near the lower portion of the estuary. Extensive analysis of surface sediment samples and cores has established that there are no geographic trends in the distribution of the pollutants, which include Cu, Fe, Pb, Zn, Ti, Ba, Cr, V and Co. These data have, however, demonstrated that tidal flux within the estuary carries phosphorus and perhaps other elements from the industrial complex at Huelva to the tidal limit of the system, several kilometers upstream from the discharge site. Radiometric analysis of short cores shows that sedimentation rates over at least the past couple of centuries have been about 0.3 cm/year. These data and that from a single deep core demonstrate that the estuary was polluted from mining activity long before the large-scale operations began in the late nineteenth century. Received: 3 May 1999 · Accepted: 18 October 1999  相似文献   

辽北太古宙块状硫化物矿床     

方如恒 《国土资源》1992,(1)

辽北太古宙由花岗岩-绿岩带组成。绿岩生成于岛弧构造环境,时间在3.0—2.8Ga,火山岩属拉斑玄武质及钙碱性火山岩。花岗岩在绿岩之后侵入,具多旋回特点。块状硫化物矿床与长英质火山岩有关,具有2—3含矿层位,透镜状矿体数目较多,未发现管状细脉带。矿石中Cu>Zn>>Pb,具有明显贫铅的特点,Cu×100/Cu+Zn为88—25。矿床类型属活火山型火山热液矿床。成矿温度为350—250℃,压力为9.5—4.0MPa,fo_2为10~(-30)-10~(-44)Pa,fs_2为2.57×10~(-9)-8.13×10~(-14)Pa,pH值为4.5—5。共生有阿尔戈马型铁矿与火山成因金矿。块状硫化物矿床遭受变质、变形、伟晶岩的改造,并在主褶皱幕期迭生与基性岩有关的热液多金属矿化。  相似文献   

Facies analyses and volcanic setting of the giant Neves Corvo massive sulfide deposit,Iberian Pyrite Belt,Portugal     

Carlos J. P. Rosa  Jocelyn McPhie  Jorge M. R. S. Relvas  Zélia Pereira  Tomás Oliveira  Nelson Pacheco 《Mineralium Deposita》2008,43(4):449-466

In the Iberian Pyrite Belt, volcanic rocks are relatively scarce, accounting for approximately only 25% of the geologic record, with the remaining 75% consisting of sedimentary units. This association is very clear in the host succession to the Neves Corvo massive sulfide deposit in Portugal. The Neves Corvo host succession comprises the products of explosive and effusive rhyolitic eruptions intercalated with mudstone that records a submarine below-wave-base environment and provides precise biostratigraphic age constraints. The first and second volcanic events involved eruptions at local intrabasinal vents. The first event generated thick beds of fiamme breccia that are late Famennian in age. The fiamme were originally pumice clasts produced by explosive eruptions and were subsequently compacted. The second event was the late Strunian (latest Famennian) effusion of rhyolitic lava that was pervasively quench-fragmented. The third and final event is younger than the massive sulfide deposits poorly represented in the mine area and minor compared with the two other events. The integration of biostratigraphic data with the volcanic facies architecture indicates that the Neves Corvo ore deposits are similar in age to the late Strunian rhyolitic lava. Although regionally the Iberian Pyrite Belt is essentially a sedimentary succession, ore formation at Neves Corvo can be closely linked to discrete volcanic events that produced a relatively narrow range of volcanic facies.  相似文献   

Lacustrine massive mudrock in the Eocene Jiyang Depression,Bohai Bay Basin,China: Nature,origin and significance     

《Marine and Petroleum Geology》2016

Massive mudrock refers to mudrock with internally homogeneous characteristics and an absence of laminae. Previous studies were primarily conducted in the marine environment, while notably few studies have investigated lacustrine massive mudrock. Based on core observation in the lacustrine environment of the Jiyang Depression, Bohai Bay Basin, China, massive mudrock is a common deep water fine-grained sedimentary rock. There are two types of massive mudrock. Both types are sharply delineated at the bottom and top contacts, abundant in angular terrigenous debris, and associated with oxygen-rich (higher than 2 ml O₂/L H₂O) but lower water salinities in comparison to adjacent black shales. In addition, type 1 is laterally isolated and contains abundant sand injections and contorted layers formed in the depositional process, but type 2 exactly distributes in the distal part of deep water gravity-driven sandstone units, and shows scoured bases, high-angle mineral crytsals, and fining-upward trend. It is suggested that type 1 is a muddy mass transport deposit (MMTD) formed by slide, slump, and/or debris flow, and type 2 is a turbiditic mudrock deposited by settling from dilute turbidity currents. A warm and humid climate and high subsidence rate are two main triggering events. Because of its mass movement nature, MMTD preserves the mineralogic composition and organic matter characteristics of the source sediment. By contrast, dilute turbidity currents are able to greatly entrain biochemically-formed micrite and planktonic organisms from the water column, and deposit them in the turbiditic mudrock. Because of their different ability to deposit organic matter, MMTD have poor or fair source rock potential, but the turbiditic mudrock is able to be a potentially effective source rock. The minerals in the massive mudrock are disorganized and chaotic, which cause fractures to develop in various directions, thereby, enhancing the vertical migration of oil and gas molecules to horizontal wellbore in shale reservoir exploitation.  相似文献   

Hydrodynamics of Supernova Evolution in the Winds of Massive Stars     

Vikram V. Dwarkadas 《Astrophysics and Space Science》2007,307(1-3):153-158

Core-Collapse supernovae arise from stars greater than 8 M_⊙. These stars lose a considerable amount of mass during their lifetime, which accumulates around the star forming wind-blown bubbles. Upon the death of the star in a spectacular explosion, the resulting SN shock wave will interact with this modified medium. We study the evolution of the shock wave, and investigate the properties of this interaction. We concentrate on the evolution of the SN shock wave in the medium around a 35 solar mass star. We discuss the hydrodynamics of the resulting interaction, the formation and growth of instabilities, and deviations from sphericity.  相似文献   

辽宁红透山块状硫化物矿床蚀变带元素迁移特征及定量计算   总被引：2，自引：1，他引：1  

郑远川  顾连兴  汤晓茜  吴昌志  李春海  刘四海 《矿床地质》2010,29(5):785-809

辽宁红透山块状硫化物矿床（MSD）位于华北地台东北部的浑北花岗岩-绿岩地体内,矿区岩石在30～28 亿年期间受到了600～650℃的高级角闪岩相变质。研究结果表明,广泛分布于红透山层状矿体下盘数百米处的和直接产于矿体下盘的堇青-直闪片麻岩,分别代表了变质后的MSD成矿系统以绿泥石化为特征的半整合和筒状不整合海底热液蚀变带。微量元素特征显示,层状堇青-直闪片麻岩的原岩并非同一种岩石,而是由5种不同岩性的岩石组成,筒状堇青-直闪片麻岩的原岩主要由流纹质岩石组成,而在堇青-直闪片麻岩走向上与之过渡的角闪片麻岩和黑云片麻岩则代表了不同岩性蚀变岩的未蚀变原岩。质量变化计算表明,相对于未蚀变原岩而言,两种蚀变岩的成分发生了显著变化,其中层状堇青-直闪片麻岩的Fe、Mg发生了富集,Na、K、Ca、Cu、Pb和Zn等元素被迁出,而筒状堇青-直闪片麻岩的Fe、Mg、Si、Na、Pb、Cu和Zn等元素则发生了富集,K被迁出。重稀土元素（HREE）和高场强元素(Zr、Ti、Nb、Hf和Ta)在海底热液蚀变过程中保持惰性,而Rb、Sr、Ba和轻稀土元素（LREE,尤其是Eu）则被强烈的迁出。这些元素变化特征表明海底热液蚀变以绿泥石化和硅化为特征,同时海底水-岩反应体系具有高水/岩比值。层状堇青-直闪片麻岩可作为红透山矿区成矿潜力评价的重要依据,而含硫化物石英脉的筒状堇青-直闪片麻岩不但本身可成为工业矿体,还可作为上覆层状矿体的近矿找矿标志。  相似文献   

The use of electron backscatter diffraction and orientation contrast imaging as tools for sulphide textural studies: example from the Greens Creek deposit (Alaska)     

Katja?Freitag  Alan?P.?BoyleEmail author  Eric?Nelson  Murray?Hitzman  James?Churchill  Magda?Lopez-Pedrosa 《Mineralium Deposita》2004,39(1):103-113

The Greens Creek polymetallic massive sulphide deposit is hosted in a typical polyphase deformed lower greenschist facies orogenic setting. The structure of the host rocks is well constrained, exhibiting a series of three superimposed ductile deformations followed by two brittle episodes. The ore is found both in fold hinges where early-formed depositional features are preserved and in fold limbs where primary features are typically strongly modified or obliterated. Samples from both settings have been investigated using electron backscatter diffraction (EBSD) coupled with forescatter orientation contrast (OC) imaging in order to observe the effects of deformation and lower greenschist facies metamorphism on pyrite. Results suggest that colloform pyrite may preserve information relevant to palaeoenvironment, that apparently simple textures are generally more complex, and that pyrite can deform plastically by dislocation glide and creep processes at lower temperatures and/or strain rates than generally accepted. This analysis indicates that EBSD and OC imaging provide powerful tools for observing textural relationships in pyrite that are not shown by more traditional methods. They should become routine tools for pyrite texture analysis.Editorial handling: D. Lentz  相似文献   

Zn–Pb–Cu volcanic-hosted massive sulphide deposits: criteria for distinguishing brine pool-type from black smoker-type sulphide deposition     

M. Solomon  F. Tornos  R. R. Large  J. N. P. Badham  R. A. Both  Khin Zaw 《Ore Geology Reviews》2004,25(3-4):259-283

Eight Zn–Pb–Cu massive sulphide deposits that appear to have formed on the sea floor (seven in Spain, one in Tasmania) are believed to have been precipitated in brine pools, based on the salinities and temperatures of fluid inclusions in underlying stockworks. Comparing the geological features of these deposits with those of the Zn–Pb–Cu massive sulphide ores of the Hokuroku Basin, Japan, which have formed as mounds from buoyant fluids of low salinity, shows that brine pool deposits have: (1) potentially very large size and tonnage, and high aspect ratio, (2) higher Zn/Cu and Fe/Cu values, (3) no evidence of chimneys, (4) relatively abundant framboidal pyrite and primary mineral banding, (5) reduced mineral assemblages (pyrite-arsenopyrite/pyrrhotite), and minor or rare barite in the massive sulphide, (6) associated stratiform and/or vein carbonates, (7) relatively unimportant zone refining, (8) lack of vertical variation in sphalerite and sulphur isotopic compositions, and (9) evidence of local bacterial sulphate reduction. Application of these criteria to the Rosebery deposit in Tasmania, for which there are no fluid inclusion data, leads to the conclusion that the southern section was deposited as separate lenses in a brine-filled basin or basins. Other potential candidates include Brunswick no. 12 and Heath Steele (Canada), Woodlawn and Captains Flat (New South Wales), Hercules and Que River (Tasmania), and Tharsis and the orebodies at Aljustrel (Spain and Portugal). Recently published fluid inclusion data for Gacun (China) and Mount Chalmers (Queensland) suggest that not all ores deposited from highly saline fluids have reduced mineral assemblages.  相似文献   

安徽新桥块状硫化物矿床地球化学特征   总被引：6，自引：0，他引：6  

李红阳  李英杰  侯增谦  杨竹森  蒙义峰  曾普胜  徐文艺 《地质科学》2005,40(3):337-345

新桥块状硫化物矿床发育双层结构,地球化学特征也呈现出明显的“二元性”和垂向变化。下部网脉状蚀变矿化岩石SiO₂、Al₂O₃、K₂O和Na₂O等含量较高,上部层状块状矿石和含矿岩石Fe₂O₃、FeO、CaO、MgO及SiO₂等明显富集。稀土含量相对较低,上部层状块状矿层平均值为10.73×10^-6,下部通道相蚀变矿化岩石平均值为126.1×10^-6。重晶石δ³⁴S值为+16.2‰,硬石膏δ³⁴S值为+11.2‰,黄铁矿δ³⁴S值为+1.5‰～+4.7‰。含矿硅质岩δ¹⁸O为+12.0‰～+13.9‰,下部通道相含黄铁矿石英脉δ¹⁸O值为+13.3‰～+18.6‰。自下部网脉状矿化到上部层状块状矿层,从粗晶细晶到变胶状胶状黄铁矿,δ³⁴S、δ¹⁸O和δ30Si值逐渐降低,²⁰⁶Pb/²⁰⁴Pb、²⁰⁷Pb/²⁰⁴Pb和²⁰⁸Pb/²⁰⁴Pb平均值逐渐增高。  相似文献