Identification of Pb sources in Yellow Sea sediments using stable Pb isotope ratios   总被引：1，自引：0，他引：1  

Man-Sik Choi  Hi-Il Yi  Shou Ye Yang  Chang-Bok Lee  Hyun-Ju Cha 《Marine Chemistry》2007

Rapid economic developments in East Asian countries have inevitably resulted in environmental degradation in the surrounding seas, and concern for both the environment and protection from pollutants is increasing. Identification of sources of contaminants is essential to environmental pollution management. In this study, the provenance of anthropogenic lead (Pb), a major pollutant of Yellow Sea sediments, was determined for river mouth sediments, including those of the Changjiang, Huanghe, Han, and Geum Rivers, and for age-determined shelf core sediments through the measurement of Pb isotope ratios in the HCl-leached fraction using multi-collector inductively coupled plasma-mass spectrometry (MC ICP/MS). Anthropogenic Pb has accumulated in shelf core sediments since 1910, and its isotope ratios were estimated as 0.863–0.866 and 2.119–2.125 for ²⁰⁷Pb/²⁰⁶Pb and ²⁰⁸Pb/²⁰⁶Pb, respectively, from the mixing relationships of the two endmembers. River mouth sediments exhibited enough distinction in anthropogenic Pb isotope ratios to be discriminated: 0.874 (2.144) in the Huanghe, 0.856 (2.129) in the Han, 0.857 (2.122) in the Geum, and 0.854 (2.101) in the Changjiang for ²⁰⁷Pb/²⁰⁶Pb (²⁰⁸Pb/²⁰⁶Pb), respectively. Although isotope ratios of geogenic Pb in sediments dating before 1910 showed narrow ranges (0.842–0.845 and 2.088–2.100 for ²⁰⁷Pb/²⁰⁶Pb and ²⁰⁸Pb/²⁰⁶Pb, respectively), distinct isotope ratios in each core permitted source identification of sediments in the Yellow Sea based on geographic locations and the geogenic Pb of each river. By comparing the isotope ratios of the estimated anthropogenic Pb to source-related materials, the provenances of anthropogenic Pb in Chinese river sediments were presumed to be Chinese coal or ore, which is also a major source of atmospheric particulate Pb. The anthropogenic Pb in the shelf core sediments in the northern Yellow Sea originated from northern Chinese cities such as Beijing and Tianjin through atmospheric pathways. Pb isotope ratios indicated that Pb in Korean river sediments was characteristic of local Korean ores.  相似文献   

渐新世/中新世分界的地层学事件   总被引：5，自引：1，他引：5  

李前裕  郑范  刘传联 《海洋地质与第四纪地质》2007,27(5):57-64

介绍渐新世/中新世分界面(即古近纪/新近纪分界面)附近的浮游有孔虫和钙质超微化石事件及其新年龄。2004年国际地层年代表确定该分界面位于第58长偏心率周期弱振幅处,古地磁事件C6Cn.2n底面,经天文调谐后的年龄为23.03 Ma。发生在该界面附近的生物地层学事件主要是浮游有孔虫Paragloborotalia kugleri的始现面(22.96 Ma)和钙质超微化石Sphenolithus delphix的末现面(23.11 Ma)。在南海北部东沙群岛附近的大洋钻探ODP1148站,渐新世/中新世界面以崩塌沉积物为特征,有明显沉积间断,标志南海当时有较大范围的构造运动。  相似文献   

冲绳海槽天然气水合物BSR的地震研究   总被引：8，自引：0，他引：8       下载免费PDF全文

唐勇  金翔龙  方银霞  孙鹏  李新 《海洋学报》2003,25(4):59-66

根据多道地震反射资料分析,在冲绳海槽南部和中部发现了拟海底反射层(BSR)现象。通过对海底异常反射层的振幅特征、速度异常和AVO属性分析,说明该BSR可能反映了天然气水合物的存在,并发现冲绳海槽断层与天然气水合物的形成有密切关系。  相似文献   

The pelagic foodweb in the upwelling ecosystem of Galicia (NW Spain) during spring: natural abundance of stable carbon and nitrogen isotopes   总被引：6，自引：1，他引：6  

Bode  Antonio; Carrera  Pablo; Lens  Santiago 《ICES Journal of Marine Science》2003,60(1):11-22

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蒸发皿中水面蒸发氢氧同位素分馏的实验研究   总被引：3，自引：0，他引：3       下载免费PDF全文

包为民  胡海英  王涛  瞿思敏 《水科学进展》2008,19(6):780-785

气象要素与蒸发密切相关,通过室内外不同气象条件下的器皿水蒸发实验,获得了水面蒸发氢氧稳定同位素分馏因子与气象要素的关系。实验结果表明,随着蒸发的进行,剩余水体中逐渐富集重同位素;自由水体蒸发同位素分馏在垂线上有分层现象,表层水体同位素值比垂线平均的同位素值略富集;不同温度条件下的室内蒸发实验中,温度越高,液-气间分馏系数越小,相应于同一剩余水体体积比,剩余水体稳定同位素值则越低。室外器皿水自由蒸发实验中得出的蒸发线方程斜率较大地偏离了当地降水线,表明实验期间水体蒸发分馏作用较明显。该研究为进一步揭示水体蒸发分馏规律提供了可靠的实验依据。  相似文献   

Bottom Simulating Reflector and Gas Seepage in Okinawa Trough： Evidence of Gas Hydrate in an Active Back-Arc Basin     

栾锡武  Kelin  Wang  Roy  Hyndman  Eleanor  Willoughby 《中国地质大学学报(英文版)》2008,19(2):152-161

To look for gas hydrate, 22 multi-channel and 3 single-channel seismic lines on the East China Sea (ECS) shelf slope and at the bottom of the Okinawa Trough were examined. It was found that there was indeed bottom simulating reflector (BSR) occurrence, but it is very rare. Besides several BSRs, a gas seepage was also found. As shown by the data, both the BSR and gas seepage are all related with local geological structures, such as mud diapir, anticline, and fault-controlled graben-like structure. However, similar structural "anomalies" are quite common in the tectonically very active Okinawa Trough region, but very few of them have developed BSR or gas seepage. The article points out that the main reason is probably the low concentration of organic carbon of the sediment in this area. It was speculated that the rare occurrence of gas hydrates in this region is governed by structure-controlled fluid flow. Numerous faults and fractures form a network of high-permeability channels in the sediment and highly fractured igneous basement to allow fluid circulation and ventilation. Fluid flow in this tectonic environment is driven primarily by thermal buoyancy and takes place on a wide range of spatial scales. The fluid flow may play two roles to facilitate hydrate formation:to help gather enough methane into a small area and to modulate the thermal regime.  相似文献   

Main Controlling Factors on Hydrocarbon Accumulation and Distribution in Marine Sedimentary Sequences in South China     

蔡立国  周雁  白振瑞 《中国地质大学学报(英文版)》2008,19(6):645-655

Multiple source rock assemblages were deposited in the sedimentary provinces in South China in geologic history,and some of them were destructed by and some survived against multiple tectonic movements.Therefore,multiple sources,mixed sources,and uneven distribution of sources occurred in the marine sedimentary basins in South China during the late stage of hydrocarbon pooling.Epidiagenesis of the marine carbonate reservoirs and its modification to reservoir poroperm characteristics determined the formation and the scale of natural gas pools.The exploration practices show that the large to medium gas fields mainly occur in areas with high-quality reservoirs.Detailed study of the paleo-oil accumulations and typical oil and gas reservoirs reveals that the basins experienced multiphase superimposition and modification,leading to the distribution of the Paleozoic paleo-oil accumulations and bitumen in the peripheral areas.The phenomenon that oil and gas production concentrates in the Sichuan basin indicates that the overall sealing conditions of a basin determine the oil/gas potentials and the scale of oil and gas production.This is a critical factor controlling the accumulation and distribution of gas in the marine sequences in South China.The early oil and gas pools in the Yangtze platform left billions of bitumen in the peripheral areas due to the destruction of seals.Since the Himalayan,"late-generation and late-accumulation" gas pools represented by the gas pools in the Sichuan (四川) basin were formed in the marine sedimentary sequences in South China as a result of the change of the sealing conditions.Current gas discoveries appear to be "paleo-generation and paleo-accumulation" gas pools but actually are "late-generation and late-accumulation" gas pools.These patterns of hydrocarbon pooling clearly depict themselves in western Sichuan basin and Weiyuan (威远)gas field.It is revealed that the gas pools in the Sichuan basin were mainly formed as a result of hydrocarbon phase change (thermal cracking of oil to gas),miscible migration,and dynamic equilibration since the Himalayan.A large number of gas pools were formed in the Himalayan and the gas pools in the marine sequences are characterized by late pooling; this kind of gas fields/pools are controlled by:(1) effectiveness of modification and superimposition of the marine basins,(2) effectiveness of the source rocks,(3) effectiveness of the overall preservation conditions,and (4) effectiveness of plays.  相似文献   

Formation Models and Distribution of Oil and Gas Pools in Tarim Basin,China     

龙胜祥 《中国地质大学学报(英文版)》2008,19(6):665-674

This article reports the main formation models and distribution of the oil and gas pools in Tarim basin,China,including (I) occurrence of the found oil and gas pools,(2) main formation models of oil and gas pools,and (3) distribution law of oil/gas pools.Petroleum is distributed widely in the strata of Tarim basin from the Sinian at the bottom to the Neogene at the top.However,the found oil and gas fields are mainly distributed in Shaya (沙雅) uplift,Tazhong (塔中) uplift,and Kuche (库车)depression.This article presents 4 main formation models,namely,early formation and long-term preservation,early formation and late reformation,middle-late multiphase-multisource formation,late single-stage formation.Tarim basin is very rich in petroleum resources.Long-term inherited intrabasinal paleohighs and slope zones are the most favorable areas for accumulation of hydrocarbons,but the types of oil and gas pools are different from area to area.The control of unconformities and faults on hydrocarbon accumulating is prominent in Tarim basin.Preservation conditions are of utmost importance.Formation of some oil and gas pools is the result of reforming and re-accumulating of early accumulated hydrocarbons.  相似文献   

关注苏皖南部地区海相油气资源          下载免费PDF全文

范小林 《江苏地质》2008,32(1):16-18

据苏皖南部地区地表露头及部分井下所发现的海相油气显示表明,这里存在海相油气资源勘探远景,关注这一地区的海相油气资源,如何开展和寻找这类油气资源,将有利于该地区区域性经济建设的可持续发展。  相似文献   

岩石圈深部温压条件下萜烷演化的实验研究     

王传远  杜建国  段毅  周晓成  陈志 《矿物岩石》2008,28(2):76-80

在密闭体系中700℃、压力高达3 GPa条件下进行褐煤加水的模拟实验,分析实验产物中的萜烷的变化规律,进而对高压高温下有机质演化进行研究.实验结果表明,相同压力条件下,温度升高有利于有机质的成熟演化;压力增加会抑制或延迟油气的生成和有机质成熟;五环三萜烷ββ生物构型转化为αβ地质构型所需能量比烯烃双键加氢饱和更高.高温超高压条件下,研究样品中C24四环萜烷存在4种同分异构体,含量由高到低依次包括10β(H)-降A-羽扇烷、10p(H)-降A-奥利烷、C24-17,21-断藿烷和10β(H)-降A-乌散烷.高碳数烷烃在地幔高压力条件下仍可以存在,这为认识超压盆地的油气资源与深层油气成藏及保存提供了新的思路.  相似文献