Results of a single group participating in an international experiment are analyzed. The experiment served to verify computational predictions of the ground-motion variations due to near-surface geological effects at a site established for that purpose by the California Department of Conservation. Based on an acceleration record at a rock location, and geotechnical model of medium, records at the other locations of a nearby sedimentary deposit were predicted. A 2-D finite-difference sensitivity analysis suggested that the lateral wave-propagation effects are negligibly small, and locally 1-D computations are sufficient for the present site. Those computations are compared with observations not available to the authors during the blind prediction. Peak accelerations, peak velocities and RMS accelerations were predicted with errors less than 159%, 114% and 62%, respectively. Maxima of the response spectra were fitted within a factor of 2. The predicted and observed Husid's plots (i.e., the normalized cumulative plots of the acceleration squared) have the correlation coefficients 0.98. The detected misfits do not show any simple relation to the instrument location, component, frequency, or time. 相似文献
A critical evaluation of literature values for the solubility products, K
spNBS
= [Fe2+][HS–] Fe2+
HS– (H
NBS+
)–1, of various iron sulphide phases results in consensus values for the pKs of 2.95 ± 0.1 for amorphous ferrous sulphide, 3.6 ± 0.2 for mackinawite, 4.4 ± 0.1 for greigite, 5.1 ± 0.1 for pyrrhotite, 5.25 ± 0.2 for troilite and 16.4 ± 1.2 for pyrite.Where the analogous ion activity products have been measured in anoxic freshwaters in which there is evidence for the presence of solid phase FeS, the values lie within the range of 2.6–3.22, indicating that amorphous iron sulphide is the controlling phase. The single value for a groundwater of 2.65 (2.98 considering carbonate complexation) agrees. In seawater four values range between 3.85 to 4.2, indicating that mackinawite or greigite may be the controlling phase. The single low value of 2.94 is in a situation where particularly high fluxes of Fe (II) and S (–II) may result in the preferential precipitation of amorphous iron sulphide. Formation of framboidal pyrite in these sulphidic environments may occur in micro-niches and does not appear to influence bulk concentrations. Calculations show that the formation of Fe2S2 species probably accounts for very little of the iron or sulphide in most natural waters. Previously reported stability constants for the formation of Fe (HS)2 and (Fe (HS)3)– are shown to be suspect, and these species are also thought to be negligible in natural waters. In completely anoxic pore waters polysulphides also have a negligible effect on speciation, but in tidal sediments they may reach appreciable concentrations and lead to the direct formation of pyrite. Concentrations of iron and sulphide in pore waters can be controlled by the more soluble iron sulphide phase. The change in the IAP with depth within the sediment may reflect ageing of the solid phase or a greater flux of Fe (II) and S (–II) nearer the sediment surface. This possible kinetic influence on the value of IAPs has implications for their use in geochemical studies involving phase formation. 相似文献
Coastlines epitomize deterministic fractals and fractal (Hausdorff-Besicovitch) dimensions; a divider [compass] method can be used to calculate fractal dimensions for these features. Noise models are used to develop another notion of fractals, a stochastic one. Spectral and variogram methods are used to estimate fractal dimensions for stochastic fractals. When estimating fractal dimension, the objective of the analysis must be consistent with the method chosen for fractal dimension calculation. Spectal and variogram methods yield fractal dimensions which indicate the similarity of the feature under study to noise (e.g., Brownian noise). A divider measurement method yields a fractal dimension which is a measure of complexity of shape. 相似文献
The true potential energy curves for the electronic ground states of astrophysically important AlH and CaH molecules are constructed by the Rydberg-Klein-Rees method. Empirical potential functions, of three-parameters by Lippincott, of five-parameters by Hulburt and Hirsch-felder and, of electronegativity by Szöke and Baitz, are examined for the adequacy to represent the true curve. From the best-fitting function, the dissociation energiesD00 of AlH and CaH molecules are estimated to be 2.99 ± 0.08 and 2.72 ± 0.06 eV respectively. The force constants indicate that these values are of correct magnitude. 相似文献
A temporal seismic network recorded local seismicity along a 130 km long segment of the transpressional dextral strike-slip Liquiñe-Ofqui fault zone (LOFZ) in southern Chile. Seventy five shallow crustal events with magnitudes up to Mw 3.8 and depths shallower than 25 km were observed in an 11-month period mainly occurring in different clusters. Those clusters are spatially related to the LOFZ, to the volcanoes Chaitén, Michinmahuida and Corcovado, and to active faulting on secondary faults. Further activity along the LOFZ is indicated by individual events located in direct vicinity of the surface expression of the LOFZ. Focal mechanisms were calculated using deviatoric moment tensor inversion of body wave amplitude spectra which mostly yield strike-slip mechanisms indicating a NE–SW direction of the P-axis for the LOFZ at this latitude. The seismic activity reveals the present-day activity of the fault zone. The recent Mw 6.2 event near Puerto Aysén, Southern Chile at 45.4°S on April 21, 2007 shows that the LOFZ is also capable of producing large magnitude earthquakes and therefore imposing significant seismic hazard to this region. 相似文献
We designed a new seismic source model for Italy to be used as an input for country-wide probabilistic seismic hazard assessment (PSHA) in the frame of the compilation of a new national reference map.
We started off by reviewing existing models available for Italy and for other European countries, then discussed the main open issues in the current practice of seismogenic zoning.
The new model, termed ZS9, is largely based on data collected in the past 10 years, including historical earthquakes and instrumental seismicity, active faults and their seismogenic potential, and seismotectonic evidence from recent earthquakes. This information allowed us to propose new interpretations for poorly understood areas where the new data are in conflict with assumptions made in designing the previous and widely used model ZS4.
ZS9 is made out of 36 zones where earthquakes with Mw > = 5 are expected. It also assumes that earthquakes with Mw up to 5 may occur anywhere outside the seismogenic zones, although the associated probability is rather low. Special care was taken to ensure that each zone sampled a large enough number of earthquakes so that we could compute reliable earthquake production rates.
Although it was drawn following criteria that are standard practice in PSHA, ZS9 is also innovative in that every zone is characterised also by its mean seismogenic depth (the depth of the crustal volume that will presumably release future earthquakes) and predominant focal mechanism (their most likely rupture mechanism). These properties were determined using instrumental data, and only in a limited number of cases we resorted to geologic constraints and expert judgment to cope with lack of data or conflicting indications. These attributes allow ZS9 to be used with more accurate regionalized depth-dependent attenuation relations, and are ultimately expected to increase significantly the reliability of seismic hazard estimates. 相似文献
Two different models of the structure of the Icelandic crust have been presented. One is the thin-crust model with a 10–15 km thick crust beneath the axial rift zones, with an intermediate layer of partially molten basalt at the base of the crust and on the top of an up-domed asthenosphere. The thick-crust model assumes a 40 km thick and relatively cold crust beneath central Iceland. The most important and crucial parameter to distinguish between these different models is the temperature distribution with depth. Three methods are used to estimate the temperature distribution with depth. First, the surface temperature gradient measured in shallow wells drilled outside geothermal areas. Second, the thickness of the seismogenic zone which is associated with a 750 °C isothermal surface. Third, the depth to a layer with high electrical conductivity which is associated with partially molten basalt with temperature around 1100 °C at the base of the crust. Combination of these data shows that the temperature gradient can be assumed to be nearly linear from the surface down to the base of the crust. These results are strongly in favour of the thin-crust model. The scattered deep seismic reflectors interpreted as Moho in the thick-crust model could be caused by phase transitions or reflections from melt pockets in the mantle. 相似文献