Determination of cadmium(II), copper(II), manganese(II) and nickel(II) species in Antarctic seawater with complexing resins   总被引：1，自引：0，他引：1  

Raffaela Biesuz  Giancarla Alberti  Girolamo D'Agostino  Emanuele Magi  Maria Pesavento 《Marine Chemistry》2006,101(3-4):180-189

The strong species of cadmium(II), copper(II), manganese(II) and nickel(II) in an Antarctic seawater sample are investigated by a method based on the sorption of metal ions on complexing resins. The resins compete with the ligands present in the sample to combine with the metal ions. Two resins with different adsorbing strengths were used. Very stable metal complexes were investigated with the strong sorbent Chelex 100 and weaker species with the less strong resin, Amberlite CG-50. Strong species were detected for three of the considered metal ions, but not for Mn(II). Cu(II) is completely linked to species with a side reaction coefficient as high as log α_M(I) = 11.6 at pH = 7.3. The ligand concentration was found to be similar to that of the metal ion, and the conditional stability constant was around 10²⁰ M^− 1. In the considered sample, only a fraction of the metal ions Cd(II) and Ni(II) is bound to the strong ligands, with side reaction coefficients equal to log α_M(I) = 5.5 and 6.5 at pH = 7.3 for Cd(II) and Ni(II), respectively. These findings were confirmed by the test with the weaker sorbent Amberlite CG-50. It can be calculated from the sorption equilibria that neither Mn(II) nor Ni(II) is adsorbed on Amberlite CG-50 under the considered conditions and, in fact, only a negligible fraction of Mn(II) and Ni(II) was adsorbed. A noticeable fraction of Cd(II) was adsorbed on Amberlite CG-50, meaning that cadmium(II) is partially linked to weak ligands, possibly chloride, while no copper(II) was adsorbed on this resin, confirming that copper(II) is only combined in strong species. These results are similar, but not identical, to those obtained for other seawater samples examined in previous investigations.  相似文献   

Modelling linear wave transformation induced by dissipative structures—Random waves     

R. Silva  M.A. Losada  P. Salles 《Ocean Engineering》2006,33(16):2174-2194

The relevant theory is presented and numerical results are compared with the analytical solution for the interaction of non-breaking waves with an array of vertical porous circular cylinders on a horizontal bed. The extension to the cases of unidirectional and multidirectional waves is obtained by means of a transfer function. The influence of the mechanical properties of porous structures and wave irregularity on wave transformation is analysed. Results for unidirectional and multidirectional wave spectra are compared to those obtained for regular waves. The model presented reproduces well the analytical results and provides a tool for analysing several engineering problems.  相似文献   

一种污水排海的近远区计算与控制方法──以大亚湾水容量计算及污水排海为例     

韩保新  彭海君  曾小清  胡康萍  吕先林 《热带海洋学报》1996,(4)

针对点容量计算中混合区限制的要求，采用了动量积分法、经验公式法和有限差分法，分别对污水排放后可能引起的近区、过渡区和远区的污水浓度变化进行了模拟预测，并就一定的限制性条件对容量点近区、高浓度混合区及容量点远区影响范围进行了分析。在大亚湾水容量计算及污水排海规划中的应用表明，该法具有计算机时较省、精度相对较高等优点。  相似文献   

柴达木盆地新构造运动主要特征与成因机制   总被引：10，自引：0，他引：10  

杨明慧 《海洋地质与第四纪地质》1997,17(3):71-78

研究表明，在壳幔结构、地球物理背景、沉积物结构、多层关地幔和构造样式等方面，达木盆地与中国东部新生代裂谷类伸展盆地具有可比性，应该归属 展性盆 。盆地伸展和收缩作用相间进行，伸展起因于地幔底辟；而收缩受两人因素影响；（１）盆地伸展作用受相邻造山带反作用诱导的挤压应力；（２）板块碰撞传递的远程板内应力。在此基础邮新的构造期达木盆地演化的“双层模式”，即地幔上隆－地壳伸展；被动挤压＋板内应力－地壳收缩  相似文献   

MM5数值预报产品在舟山海域风力分区预报中的释用   总被引：1，自引：0，他引：1  

黄辉  陈淑琴 《海洋预报》2006,23(2):67-71

本文阐述了舟山海域地理气候特征及开展舟山海域风力分区预报的重要性,详细介绍了利用海岛测风站资料研究的MM5数值预报产品在舟山海域风力分区预报中的释用技术,实践证明该释用技术能为风力分区预报提供重要的技术支撑,并为研究同类数值预报产品释用技术提供重要的参考依据。  相似文献   

我国海啸灾害及预警现状与建议   总被引：8，自引：1，他引：8  

叶琳  于福江  吴玮 《海洋预报》2005,22(Z1):147-157

本文给出了海啸定义及其它有关概念与术语,简要给出了我国及全球的海啸灾害.全面介绍了我国海啸监测能力、预警现状、研究成果以及有关国际合作的情况,重点介绍了我国自主研制的海啸数值模式,利用该模式我们模拟了2004年12月26日发生在印度洋大海啸以及假想的发生在我国南海的海啸对周边国家的影响.对海啸预警中存在的问题及未来急需开展的工作,作者也将一一给予阐述.  相似文献   

山东省近50年海洋气象灾害特征分析   总被引：3，自引：0，他引：3  

刘敦训 《海洋预报》2006,23(1):59-64

本文通过大量的文献和资料查阅,系统的统计分析了近50a山东省沿海及责任海区海雾、风暴潮、风暴海浪、海冰等几种主要海洋气象灾害的海洋、气象及分布特征和灾害情况,进一步分析了它们的变化规律和产生原因,为海洋气象业务、服务、科研提供有益的参考。  相似文献   

Applying an alternative method of echo-integration     

Aksland  Magnar 《ICES Journal of Marine Science》2006,63(8):1438-1452

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Time changes in fishing power in the Danish cod fisheries of the Baltic Sea     

Marchal  Paul; Nielsen  J. Rasmus; Hovgard  Holger; Lassen  Hans 《ICES Journal of Marine Science》2001,58(1):298-310

  相似文献   

南黄海辐射沙洲附近海域悬浮体的研究   总被引：4，自引：0，他引：4  

宋召军  黄海军  杜廷芹  刘芳  倪金龙 《海洋地质与第四纪地质》2006,26(6):19-25

对2003年春季(3—4月)和秋季(9月)南黄海辐射沙洲附近海域的悬浮体样品进行了空间分布特征、有机无机组成、粒度特征及其季节变化分析。结果表明:(1)2003年春季研究区内悬浮体浓度要普遍高于秋季的悬浮体浓度。悬浮体浓度最高值区位于长江口-老黄河口之间的近岸区。陆源物质为主的无机组分是悬浮体的主体成分,特别是在近岸浅水区和接近海底的底层水中尤为突出;(2)研究区海水中的悬浮体主要来源于辐射沙脊区(老黄河-长江复合三角洲)沉积物再悬浮;(3)悬浮体分布是风浪、潮流及沿岸流等多种因素综合作用的结果,而风浪和潮流是影响本区悬浮体分布的主要因素,巨大的风浪和强大的潮流造成辐射沙洲海底的沉积物再悬浮、搬运和再沉积,并在苏北沿岸流的作用下向沙洲外缘输运。  相似文献