Investigation of datolite (CaB[SiO₄/(OH)]) from basalts in the Northern Apennines ophiolites (Italy): Genetic implications     

F. Zaccarini  S. Morales-Ruano  M. Scacchetti  K. Heide 《Chemie der Erde / Geochemistry》2008,68(3):265-277

Datolite, ideally CaB[(OH/SiO₄)], from hydrothermal veins crosscutting pillow basalt in 10 different localities of the Northern Apennine ophiolites was investigated with regard to mineral chemistry and fluid inclusion microthermometry. Bulk analyses of datolite crystals show REE contents below chondritic, except for La and Ce. With respect to host rock, datolite is occasionally enriched in La, Rb, Cs, Be, and shows relatively high contents of chalcophile elements (Cu, Zn, Pb, Ni) when occurring in contact with sulfide-mineralized basalt. Volatiles escaped during the decomposition in the temperature range 600 and 700 °C. The main component is water. The temperature maximum of water release is different and frequently with a shoulder or a second maximum. Together with water, sulfur species as H₂S and SO₂ and traces of boron species escaped. The CO₂ release by the decomposition especially of datolite from Castellaro and Cinghi has a maximum in the range of 500-580 °C and is different from the decomposition of calcite. Together with CO₂ a boron species escaped. Chlorine does not detect. Two-phase (L+V) fluid inclusions texturally identifiable as primary and secondary were observed, yielding average homogenization-temperatures of 236 and 173 °C, respectively. Fluid inclusion cooling data yield calculated salinity in the range of 10-16 wt% NaCl equivalents, thus relatively higher compared with seawater. The results are compatible with those reported for fluids formed under diagenetic conditions, but differ from those observed in seafloor hydrothermal systems and/or emanating from magmas. Distribution of trace elements between datolite and host basalt indicates enrichment with respect to the host rock limited to a few elements such as La, Rb, Cs, Be, Ni, Cu, Zn and Pb. The lithophile elements can be hosted in the datolite lattice, whereas the chalcophile metals and Ni are probably carried in sub-microscopic inclusions.  相似文献   

The Othris Ophiolite, Greece: A snapshot of subduction initiation at a mid-ocean ridge     

Matthias G. Barth  Paul R.D. Mason  Gareth R. Davies  Martyn R. Drury 《Lithos》2008,100(1-4):234-254

The mantle section of the Tethyan-type Othris Ophiolite, Greece, records tectono-magmatic processes characteristic of both mid-ocean ridges and supra-subduction zones. The Othris Ophiolite is a remnant of the Jurassic Neotethys Ocean, which existed between Eurasia and Gondwanaland. Othris peridotites range from fertile plagioclase lherzolites to depleted harzburgites. Abundances of Al₂O₃ and CaO show well-defined inverse linear correlations with MgO, suggesting that the Othris peridotites formed as residua from variable degrees of partial melting.

Peridotites from the Fournos Kaïtsa and western Katáchloron sub-massifs are similar to abyssal peridotites and can be explained by a multistage model with some melting in the garnet stability field followed by moderate degrees of anhydrous near-fractional melting in the spinel stability field. In contrast, the peridotites from the Metalleio, Eretria, and eastern Katáchloron sub-massifs, and the Vourinos ophiolite are highly depleted and have extremely low concentrations of Al₂O₃ and heavy rare earth elements. These peridotites have enriched light REE contents compared to the middle REE. These residua are best modelled by hydrous melting due to a flux of slab-derived fluid to the mantle wedge during melting.

The occurrence of both styles of melting regimes within close spatial and temporal association in the same ophiolite is explained by intra-oceanic thrusting and forced subduction initiation at (or near) a mid-ocean ridge. Thus, the Othris Ophiolite, and probably Tethyan-type ophiolites in general, represent a transient phase of plate tectonic reorganisation rather than quasi-steady state plate tectonics.  相似文献   

青岛榴辉岩相蛇绿混杂岩的岩石学证据及退变质P-T轨迹   总被引：2，自引：2，他引：2  

李曙光  孙卫东  葛宁洁  王楠  刘德良  陈移之  张志敏 《岩石学报》1992,(4)

青岛榴辉岩相蛇绿混杂岩发育在胶南隆起北缘地缝合线附近,构造侵位于胶南群云母斜长片麻岩中。它主要由斜方辉橄岩、玄武质和玄武安山质火山岩及少量杂砂岩和硅质岩组成。它与一般仰冲蛇绿岩的主要区别是:玄武质和玄武安山质岩石普遍遭受了榴辉岩相变质作用并发生强烈的糜棱岩化和退变质作用。强烈的退变质作用使大部分榴辉岩变为含石榴石石英斜长角闪岩,但仍保留有少量榴辉岩透镜体。它们可能是俯冲陆壳前缘岛弧地壳或岛弧型蛇绿岩残片的推覆体。它的退变质P-T轨迹表明,在其上升过程中热传导速率较高,这可能与该岩石强烈糜棱岩化和含水有关。  相似文献   

贺根山蛇绿岩带航磁异常特征及成矿潜力分析     

段明  张锋  谢瑜  曾威  魏佳林  刘晓雪  冯晓曦  王继春 《地质论评》2016,62(S1):87-88

铬铁矿贺根山蛇绿岩带地处西伯利亚板块和华北板块的汇聚部位,该带出露中国北方最大的超基性岩体群,大小有超过超过30个超基性岩块,其中自西向东分布的朝根山,贺根山,崇根山,乌兹尼黑为最大的蛇绿岩块。与超基性岩关系最密切的矿产莫过于铬铁矿,数年来很多学者针对贺根山蛇绿岩的含矿性做了大量工作(白文吉等1993,1995; Miao Laicheng et al.,2008;段明,2009,2015;黄竺,2015;王成,2016),该带分布的铬铁矿床（点）众多,有代表性矿床(点)为赫根敖拉、733和3756,然而能达到工业开采的矿床只有3756。近些年在该地区的找矿勘查工作未取得突破,笔者认为很多原因在于该区覆盖面积太大,找矿靶区定位不准以及对隐伏的矿体勘查力度不够。2013-2015年天津地质调查中心在2009~2011年度新飞的航磁资料基础之上对该区进行了航磁异常查证与评价研究工作,对该区的成矿潜力与找矿方向提出了心得认识。  相似文献   

Significance of gabbronorite occurrence in the crustal section of the Semail ophiolite     

Boudier  Françoise  Godard  Marguerite  Armbruster  Catherine 《Marine Geophysical Researches》2000,21(3-4):307-326

The eastern end of the Haylayn massif exposes a complex paleoridge structure interpreted as the tip of a northwestward propagating segment (Nicolas et al., this issue). The area, revisited from a petrostructural and geochemical viewpoint, offers the most documented exposures of the association of olivine gabbros and gabbronorites in Oman (Juteau et al., 1988). Gabbronorites were injected while the main gabbro unit was deforming in the magmatic state. Both units do not differ chemically, except for the SiO₂ enrichment of the orthopyroxene-rich gabbros relative to olivine-gabbro. In addition, they display the same trace element signature, which implies the same parent magma for both units. The extension of the stability field of orthopyroxene is assigned to increase of oxygen fugacity due to hydration. The source of hydration is the ridge axis hydrothermal circulation, suggesting hydrothermal/magma interaction at temperatures above the gabbro solidus. The distribution of gabbronorites at the scale of the entire ophiolite suggests a relation with ridge tectonics where high-T conditions of hydrothermal-magmatic interaction are met. Such conditions are met when propagating segments rotate the structures of the dying magma chamber.  相似文献   

Compressional origin of the Aegean Orogeny,Greece     

《地学前缘(英文版)》2022,13(2):101049

The Aegean Sea area is thought to be an actively extending back-arc region, north of the present day Hellenic volcanic arc and north-dipping subduction zone in the Eastern Mediterranean. The area shows extensive normal faulting, ductile ‘extensional’ shear zones and extensional S-C fabrics throughout the islands that have previously been related to regional Aegean extension associated with slab rollback on the Hellenic Subduction Zone. In this paper, we question this interpretation, and suggest the Cenozoic geodynamic evolution of the Aegean region is associated with a Late Cretaceous–Eocene NE-dipping subduction zone that was responsible for continent-continent collision between Eurasia and Adria-Apulia/Cyclades. Exhumation of eclogite and blueschist facies rocks in the Cyclades and kyanite-sillimanite grade gneisses in the Naxos core complex have pressures that are far greater than could be accounted for purely by lithospheric extension and isostatic uplift. We identify four stages of crustal shortening that affected the region prior to regional lithospheric extension, herein called the Aegean Orogeny. This orogeny followed a classic Wilson cycle from early ophiolite obduction (ca. 74 Ma) onto a previously passive continental margin, to attempted crustal subduction with HP eclogite and blueschist facies metamorphism (ca. 54–45 ?Ma), through crustal thickening and regional kyanite – sillimanite grade Barrovian-type metamorphism (ca. 22–14 ?Ma), to orogenic collapse (<14 ?Ma). At least three periods of ‘extensional’ fabrics relate to: (1) Exhumation of blueschists and eclogite facies rocks showing tight-isoclinal folds and top-NE, base-SW fabrics, recording return flow along a subduction channel in a compressional tectonic setting (ca. 50–35 ?Ma). (2) Extensional fabrics within the core complexes formed by exhumation of kyanite- and sillimanite gneisses showing thrust-related fabrics at the base and ‘extensional’ fabrics along the top (ca. 18.5–14 ?Ma). (3) Regional ductile-brittle ‘extensional’ fabrics and low-angle normal faulting related to the North Cycladic Detachment (NCD) and the South(West) Cycladic Detachment (WCD) during regional extension along the flanks of a major NW–SE anticlinal fold along the middle of the Cyclades. Major low-angle normal faults and ductile shear zones show symmetry about the area, with the NE chain of islands (Andros, Tinos, Mykonos, Ikaria) exposing the NE-dipping NCD with consistent top-NE ductile fabrics along 200 ?km of strike. In contrast, from the Greek mainland (Attica) along the SE chain of islands (Kea, Kythnos, Serifos) a SW-dipping low-angle normal fault and ductile shear zone, the WCD is inferred for at least 100 ?km along strike. Islands in the middle of the Cyclades show deeper structural levels including kyanite- and sillimanite-grade metamorphic core complexes (Naxos, Paros) as well as Variscan basement rocks (Naxos, Ios). The overall structure is an ~100 ?km wavelength NW–SE trending dome with low-angle extensional faults along each flank, dipping away from the anticline axis to the NE and SW. Many individual islands show post-extensional large-scale folding of the low-angle normal faults around the domes (Naxos, Paros, Ios, Sifnos) indicating a post-Miocene late phase of E–W shortening.  相似文献   

准噶尔北部蛇绿岩形成时限新证据及其东、西准噶尔蛇绿岩的对比研究   总被引：30，自引：13，他引：17  

张元元  郭召杰 《岩石学报》2010,26(2):422-430

准噶尔北部出露有塔尔巴哈台库吉拜蛇绿岩、洪古勒楞-和布克赛尔蛇绿岩及扎河坝-阿尔曼太蛇绿岩。洪古勒楞蛇绿岩中的堆晶辉长岩样品进行SHRIMP U-Pb定年,结果为472±8.4Ma(MSWD=1.4),限定洪古勒楞-和布克赛尔蛇绿岩形成于早奥陶世。对扎河坝蛇绿岩中斜长花岗岩采用SHRIMP U-Pb方法测定年龄为495.9±5.5Ma(MSWD=2.7),证实扎河坝蛇绿岩形成于晚寒武世-早奥陶世。塔尔巴哈台蛇绿岩、和布克赛尔-洪古勒楞蛇绿岩以及扎河坝-阿尔曼太蛇绿岩均在早奥陶世已经形成,大部分以断层侵位的形式侵位于泥盆纪-石炭系火山-沉积地层中。准噶尔北部东西三段蛇绿岩在形成时代、区域地质以及地球物理特征等方面具有可对比性,认为它们构成一条贯穿东、西准噶尔的蛇绿岩带,这为新疆北部及邻区古生代构造格局的重建以及区域构造的对比连接提供了重要信息。  相似文献   

新疆萨尔托海铬铁矿中的Fe-Ni-As-S矿物研究   总被引：2，自引：1，他引：1  

谭娟娟  朱永峰 《岩石学报》2010,26(8):2264-2274

新疆萨尔托海铬铁矿是一个典型的与蛇绿岩有关的高铝型豆荚状铬铁矿,其中矿石铬尖晶石发生了明显的热液蚀变,发育了富Cr的蚀变环边,形成高铁铬铁矿,Cr#在蚀变后升高,发生了Cr元素的次生富集。在矿石颗粒间隙中的Fe-Ni-As-S矿物组合主要为镍黄铁矿-赫硫镍矿-针镍矿-砷镍矿。围岩纯橄岩普遍发育强烈的蛇纹石化,其中的Fe-Ni-As-S矿物组合为赫硫镍矿-镍黄铁矿-砷镍矿,还有少量的针镍矿和铜矿物。通过对硫化物的成分对比分析,认为矿石中的镍黄铁矿和赫硫镍矿都属于岩浆演化的产物(600℃),与赫硫镍矿和针镍矿一样,均从贫S的母岩浆中通过岩浆熔离过程形成。围岩和矿石中的含砷矿物以及围岩中的镍黄铁矿都是晚期热液活动的结果,其中砷镍矿具有特殊的蠕虫状-乳滴状结构,与围岩中的赫硫镍矿和镍黄铁矿共生。围岩和矿石中Fe-Ni-As-S矿物组合的形态和成分差异,说明金属矿物的整体演化从岩浆期到热液期经历了从贫S到富As的环境变化,最终形成了现在所观察到的复杂Fe-Ni-As-S矿物组合。  相似文献   

西准噶尔石炭纪洋中脊俯冲岩浆活动:以玛里雅蛇绿岩为例   总被引：4，自引：2，他引：2  

张继恩  肖文交  韩春明  郭谦谦  毛启贵  敖松坚 《岩石学报》2010,26(11):3272-3282

玛里雅蛇绿岩位于新疆准噶尔西缘达拉布特断裂东侧的弧前增生楔内,形成于石炭纪,出露岩石类型齐全,其中硅质岩与火山岩相间出露,多表现为非构造接触。地球化学特征表明,它们大致可以分为四个系列:(1)A系列为岛弧英安岩,Th强烈富集,可能有洋壳沉积物参与,高场强元素Nb亏损,与洋壳的俯冲有关;(2)M系列与典型洋中脊玄武岩的稀土元素配分模式一致,不过Ba强烈富集,可能受到俯冲流体的影响;(3)E系列位于地幔序列N-MORB和E-MORB之间,表明它可能是地幔岩浆的混合产物,未受到地幔岩浆源区之外物质的影响;(4)O系列与典型的洋岛玄武岩基本一致,只是Ta、La和Th含量略偏低,但都处于地幔序列范围内,可能与其他岩浆源有轻微的混合。这种岩浆特征与智利洋中脊俯冲环境下所产生的岩浆特征一致;由于西准噶尔晚古生代仍然发生俯冲消减,因此推测玛里雅蛇绿岩可能形成于洋中脊俯冲环境。  相似文献   

对新疆北部蛇绿岩及相关问题的思考和认识   总被引：21，自引：9，他引：12  

王宗秀  周高志李涛 《岩石学报》2003,19(4):683-691

蛇绿岩是作为大陆古板块划分及洋壳存在的重要佐证,同时也是许多地质问题争论的焦点之一。关于新疆北部地区大地构造单元的划分,尽管从不同理论、不同专业角度进行了许多研究和论述,但也因对区内蛇绿岩的认识不同而仍存在诸多争议。本文针对以区内蛇绿岩形成时代来确定洋盆出现所存在的一些可变因素的阐述,提出在新疆北部地区于震旦纪-石炭纪期间可能只存在一个水域相通的统一大洋～准噶尔-天山洋的认识。并以此为基点,对新疆北部地区的构造单元进行了初步划分,划分出两个被动陆缘带和三个弧盆带,同时将其构造演化概括为陆壳拉张(Z—C)、洋盆形成(O-S)及洋盆消减(D—C)三个阶段。  相似文献