Episodic shear zone associated fluid flow in the Curnamona Province, South Australia     

Chris Clark  Andreas Schmidt Mumm  Martin Hand  Kevin Faure 《Journal of Geochemical Exploration》2006,89(1-3):69

Two distinct generations of fluid flow associated with shear zone activity have been identified in Willyama Supergroup rocks of the southern Curnamona Province in northeastern South Australia. Fluids in the first event are inferred to have been sourced from the devolatilisation of Willyama Supergroup metasedimentary rocks during prograde metamorphism associated with the (1.61–1.58 Ga) Mesoproterozoic Olarian Orogeny. The second episode of fluid flow occurred during the (c. 500 Ma) Cambrian Delamerian Orogeny and resulted in localised rehydration of the Willyama Supergroup. Fluids were isotopically light and most likely sourced from prograde Delamerian metamorphism and dehydration of fault rocks and entrained meteoric waters that originally were involved in (c. 700 Ma) Neoproterozoic Adelaidean rifting. A key outcome of this study is the identification of this previously unrecognised fluid flow system that was active during the Delamerian Orogeny.  相似文献   

Fluid flow evolution in petroleum reservoirs with a complex diagenetic history: An example from Veracruz, Mexico   总被引：4，自引：0，他引：4  

H. Ferket  R. Swennen  S. Ortuo Arzate  F. Roure 《Journal of Geochemical Exploration》2006,89(1-3):108

This paper discusses the fluid flow evolution in the Veracruz petroleum province of eastern Mexico based on results of an integrated diagenetic, sedimentological and structural analysis. The area progressively changed from passive foreland towards an active fold-and-thrust belt into a passive belt with infill of the foreland basin and finally underwent transpressional deformation. This varied kinematic evolution resulted in numerous fluid flow events, among which were four different petroleum migration pulses.  相似文献   

Sulfur isotopic compositions of the Huize super-large Pb–Zn deposit, Yunnan Province, China: Implications for the source of sulfur in the ore-forming fluids     

X.B. Li  Z.L. Huang  W.B. Li  Z.L. Zhang  Z.F. Yan   《Journal of Geochemical Exploration》2006,89(1-3):227

The Huize Pb–Zn deposit of Yunnan Province, China, is located in the center of the Sichuan–Yunnan–Guizhou Pb–Zn–Ag district. Four primary orebodies (orebody No. 1, No. 6, No. 8 and No. 10), with Pb + Zn reserves from 0.5 Mt to 1 Mt, have been found at depth in this deposit. This paper provides new data on the sulfur isotopic compositions of the four orebodies. The data show that the principal sulfide minerals (galena, sphalerite and pyrite) in the four orebodies are enriched in heavy sulfur, the δ³⁴S values between 10.9‰ and 17.7‰ and where δ³⁴S_pyrite > δ³⁴S_sphalerite > δ³⁴S_galena. The δ³⁴S values of sulfide are close to that of the sulfates from the carbonate strata within the region. The similarity in sulfur isotope composition between sulfides and sulfates indicates the sulfur in the ore-forming fluids was likely derived by thermochemical sulfate reduction of sulfates contained within carbonate units.  相似文献   

Contrasting fluid inclusion characteristics of staniferous and non-staniferous pegmatites of Southeast Bastar, Central India     

Dipak C. Pal  M.K. Panigrahi  B. Mishra 《Journal of Asian Earth Sciences》2006,28(4-6):306-319

Tin and rare metal-bearing granitic pegmatites in the Bastar–Malkangiri pegmatite belt of Central India are hosted by metabasic and metasedimentary country rocks. Fluid inclusion studies were conducted in spatially associated two-mica granite and the staniferous and non-staniferous pegmatites to characterize the physicochemical environment of mineralization, to distinguish different pegmatites in terms of their fluid characteristics and to envisage a possible genetic link between the pegmatites and spatially associated granite. Three different types of primary inclusions were identified. The type-I, aqueous bi-phase (L+V) inclusions are the most abundant and ubiquitous. Type-II polyphase (L+V+S) inclusions are rare. Type-III, monophase (L) and metastable aqueous inclusions, though less abundant than type-I inclusions, are ubiquitous. The fluid evolution trends indicate that mixing of two different fluids of contrasting salinities, one of high salinity (20–30 wt% NaCl equivalent) and another of low salinity (0–10 wt% NaCl equivalent), was responsible for precipitation of the bulk of the cassiterite. This mixing is the single most important characteristic that distinguishes the staniferous pegmatites from their non-staniferous counterparts. The non-staniferous pegmatites, on the other hand, are typified by the presence either of a high saline or a low saline fluid that evolved through simple cooling. The minimum pressure–temperature of entrapment, estimated from the intersections of the halide liquidus with the corresponding inclusion isochores of type-II inclusions, range between 2.1–2.2 kb and 300–325 °C. The similar P–T range of fluid entrapment of the staniferous and non-staniferous pegmatites indicates that they were possibly emplaced within a similar physical environment. Type-I inclusions from granite recorded only the high salinity fluid, the salinity of which compares well with that of the highly saline fluid component of type-I inclusions in the pegmatites. This is a possible indication of a genetic link between the pegmatites and spatially associated granite.  相似文献   

Geochemical constraints on the origin of the Kicking Horse and Monarch Mississippi Valley-type lead-zinc ore deposits, southeast British Columbia, Canada   总被引：1，自引：0，他引：1  

Veerle Vandeginste  Rudy Swennen  Sarah A. Gleeson  Rob M. Ellam  Kirk Osadetz  François Roure 《Mineralium Deposita》2007,42(8):913-935

Two Mississippi Valley-type (MVT) ore deposits, Kicking Horse and Monarch, have been studied with the aim of comparing the ores at the two localities and to characterize the origin of the mineralizing fluids and the ore formation process(es). Both deposits are hosted by the Middle Cambrian Cathedral Formation carbonate host rocks, Kicking Horse on the north and Monarch on the south flank of the Kicking Horse valley near Field (SE British Columbia). The ore bodies are situated at the transition of (western) basinal to (eastern) shallow-water strata of the paleo-Pacific passive margin succession in the Cordilleran Foreland Province of the Western Canada Sedimentary Basin. Both deposits are related spatially to normal faults. In both localities, the ore minerals are dominated by pyrite, sphalerite, and galena. Dolomite, minor quartz, and calcite are also present in close association with the ores. The salinity (21–30 wt% NaCl eq.) and homogenization temperatures (63–182°C) measured in fluid inclusions in carbonate, quartz, and sphalerite lie within the typical range of MVT fluid conditions. The good stoichiometry (50–53 mol% CaCO₃), low δ¹⁸O values (−21 to −14‰ Vienna Peedee belemnite) and relatively high homogenization temperatures (>95°C) of the dolomite suggest the dolomites were formed under burial diagenesis. The ore-forming fluids probably interacted with siliciclastic units, based on elevated Li contents and ⁸⁷Sr/⁸⁶Sr ratios, which are highest in the dolomite type after the main ore stage. We propose that the ores formed from the mixing of a downward-infiltrating, sulfur-bearing halite-dissolution fluid with an upward-migrating, metal-rich evaporated seawater fluid, which had already undergone minor mixing with a dilute fluid.  相似文献   

胶东牟平邓格庄金矿床流体包裹体研究   总被引：5，自引：15，他引：5  

胡芳芳范宏瑞  杨奎锋沈昆翟明国  金成伟 《岩石学报》2007,23(9):2155-2164

邓格庄金矿是胶东牟平-乳山金成矿带内第二大石英脉型金矿,金主要产于黄铁矿和多金属硫化物石英腑/细脉中。流体包裹体研究表明,邓格庄金矿不同蚀变带岩石和各成矿阶段金矿石中的流体包裹体主要有三种类型:H_2O-CO_2包裹体、CO_2-H_2O±CH_4包裹体和 H_2O 溶液包裹体。早期乳白色石英中主要赋存原生的 H_2O-CO_2包裹体和次生的 CO_2-H_2O±CH_4包裹体;成矿期黄铁矿石英脉和多金属硫化物石英脉中的 CO_2-H_3O±CH_4包裹体主要为原生,随机分布,气液比变化较大,有时出现不同相比例的包裹体共存现象,而 H_2O 溶液包裹体明显沿愈合裂隙分布;在成矿晚期的石英和方解石中主要发育原生 H_2O 溶液包裹体。显微测温结果显示,成矿前(第1阶段)H_2O-CO_2包裹体的完全均一温度(T_(h,TOT),至液相)为254℃至365℃,成矿期(第Ⅱ和Ⅲ阶段)CO_2-H_2O±CH_4包裹体的完全均一温度(T_(h,TOT),至液相)为195～317℃,成矿后(第Ⅳ阶段)H_2O 溶液包裹体的均一温度(T_(h,TOT);至液相)为156～219℃。成矿的初始流体富 CO_2,主成矿期有 CH_4流体加入,成矿晚期则演化为低温的水溶液流体。水/岩反应及流体不混溶可能是邓格庄金矿金沉淀的主要原因。  相似文献   

胶东蓬莱金矿区流体包裹体和氢氧同位素地球化学研究   总被引：5，自引：2，他引：5  

侯明兰蒋少涌  沈昆连国建  刘其臣肖风利 《岩石学报》2007,23(9):2241-2256

蓬莱地区金矿床以石英脉型为主,其次是蚀变岩型;成矿条件与著名的玲珑金矿床相似。金主要产于黄铁矿和多金属硫化物石英脉中。流体包裹体研究表明,金矿床中主要存在两种类型的流体包裹体:CO_2-H_2O 包裹体和中低盐度的NaCl-H_2O 溶液包裹体。CO_2-H_2O 包裹体气相以 CO_2为主,可含少量 CH_4、H_4S、CO。其中,黄铁绢英岩的石英中含有丰富的CO_2-H_2O 包裹体,而黄铁矿石英脉和多金属硫化物石英脉中富 CO_2与富 H_2O 的 CO_2-H_2O 包裹体共存。显微测温结果显示,黄铁绢英岩中的 CO_2-H_2O 包裹体的均一温度范围为230℃～300℃;而黄铁矿和多金属硫化物石英包裹体的均一温度为220℃～390℃,鉴于这些包裹体是从不混溶的 CO_2-H_2O 流体中捕获的,因此它们的温度下限220℃～250℃左右,应该看作是它们的形成温度。成矿早期流体为富含挥发份(流体密度0.92～0.985g/cm~3)、中低盐度(4.15%～5.23%NaCl eqv)的流体;到主成矿期逐渐演化为温度升高,盐度变化范围大(1.02%～15.5%NaCl eqv),水溶液以 NaCl 为主,气体仍以 CO_2为主,但可含少量的 CH_2、H_2S、CO 及有机质等的流体(流体密度0.32～0.99g/cm~3);成矿期后的流体盐度、温度及 CO_2含量降至最低。本区矿床中石英的δ~(18)O 值变化在13.8‰～18.3‰,成矿流体的δ~(18)O 值在4.9‰～10.9‰之间,流体包裹体中δD变化范围很小,从-78‰变化到-101‰,主要集中在-78‰～-88‰之间。由此表明成矿流体以岩浆水为主,伴有大气降水的参与。在主成矿期成矿流体表现出明显的多期、多来源特征。温度降低和流体不混溶是导致金等成矿元素沉淀和富集的重要机制。  相似文献   

三塘湖盆地流体包裹体研究及其应用     

曹青  柳益群 《岩石学报》2007,23(9):2309-2314

通过镜下观察,并对流体包裹体岩相学特征、不同包裹体组合特征和显微测温等方面进行分析,可以确定不同产状内包裹体形成的先后关系,同时依据烃类包裹体特征可以分析储层的烃类组成、烃类充注史、古流体压力和古流体势。根据三塘湖盆地包裹体岩相学特征、组合类型以及与烃类包裹体伴生盐水包裹体的均一温度,不同微裂隙内的包裹体按照其产状可分为两类:网状微裂隙内捕获的包裹体和单向微裂隙内捕获的包裹体。根据不同产状内的包裹体特征,分析得出它们是由不同流体来源在不同时期捕获的。根据古地温演化趋势图,通过测温数据推算三塘湖盆地条湖凹陷内大量烃类包裹体被捕获的时间在晚侏罗世,马朗凹陷内大量烃类包裹体被捕获的时间在晚白垩世。在计算包裹体流体势基础上做出古流体势图,显示各凹陷的北部较利于油气聚集,预测位于油气运聚路线上的马中构造带是有利油气聚集区。  相似文献   

滇东北铅锌(银)成矿规律   总被引：2，自引：0，他引：2  

李才先 《云南地质》2005,24(3):275-281

滇东北铅锌(银)矿由峨眉山玄武岩喷发提供成矿热液,通过EW向构造导矿,NE—SW向构造控矿,在特定的岩性(碳酸盐岩)条件下形成,同一矿床又分脉状矿体(主要)、似层状矿体(次要),成因类型应为碳酸盐型中温热液矿床。  相似文献   

江苏句容-黄桥地区有机包裹体形成期次和捕获温度、压力的PVTsim模拟计算   总被引：8，自引：0，他引：8  

刘德汉 宫色刘东鹰  曾庆辉肖贤明 田辉申家贵  李贤庆 《岩石学报》2005,21(5):1435-1448

据流体包裹体显微镜观测和石油包裹体群的气体色谱和全烃色谱、色谱-质谱分析结果，句容和黄桥地区三叠系和下二叠系地层中的石油包裹体明显不同，句容地区三叠系灰岩储层中的石油包裹体的个体较大，在透光下为黄色一棕黄色，荧光显微镜下发亮黄色荧光，包裹体中气态烃的C1／C2-5，比值较低，液态烃中三环萜炕、五环三萜烷和规则甾烷系列的生物标志物化合物含量比较丰富，而句容和黄桥地区下二叠系石油包裹体比较细小，发黄色-黄绿色荧光，包裹体中气态烃的C1／C2-5。比值较高，液态烃中均难检测到甾萜烷系列的生物标志物。由流体包裹体均一温度等观测资料与捕获温度、捕获压力的PVTsim的模拟计算结果：句容地区三叠系储层的石油包裹体捕获温度Tr=107．9℃，捕获压力Pr=289bar，约相当于白垩纪晚期（90～83Ma）充注成藏。句容地区下二叠深灰色灰岩中分布的油包裹体的捕获温度Tr=123℃，捕获压力Pr=305．95bar，反映白垩系晚期还有一期温度比较高的含烃流体充注的现象。黄桥地区在含CO2气藏的下二叠系存在有交切关系的，黄色和黄绿色两种荧光性质不同的石油包裹体，前者模拟计算的捕获温度Tr=97．3℃，捕获压力Pr=184．75bar，后者模拟计算的捕获温度Tr=145．5℃，捕获压力Pr=220．05bar，分别相当于白垩纪晚期（95～90Ma）和白垩纪末期（65～60Ma）有合烃流体运聚现象。但是，由于在白垩纪末-第三纪的抬升作用阶段，油气大量散失，因此在喜山期大量无机CO2充注成藏时期，储层中已不合烃类流体。  相似文献