Origin and evolution of Pliocene–Pleistocene granites from the Larderello geothermal field (Tuscan Magmatic Province, Italy)     

A. Dini  G. Gianelli  M. Puxeddu  G. Ruggieri   《Lithos》2005,81(1-4):1-31

Extensive, mainly acidic peraluminous magmatism affected the Tuscan Archipelago and the Tuscan mainland since late Miocene, building up the Tuscan Magmatic Province (TMP) as the Northern Apennine fold belt was progressively thinned, heated and intruded by mafic magmas. Between 3.8 and 1.3 Ma an intrusive complex was built on Larderello area (Tuscan mainland) by emplacement of multiple intrusions of isotopically and geochemically distinct granite magmas. Geochemical and isotopic investigations were carried out on granites cored during drilling exploration activity on the Larderello geothermal field. With respect to the other TMP granites the Larderello intrusives can be classified as two-mica granites due to the ubiquitous presence of small to moderate amounts of F-rich magmatic muscovite. They closely resemble the almost pure crustal TMP acidic rocks and do not show any of the typical petrographic features commonly observed in the TMP hybrid granites (enclaves, patchy zoning of plagioclase, amphibole clots). On the basis of major and trace elements, as well as REE patterns, two groups of granites were proposed: LAR-1 granites (3.8–2.3 Ma) originated by biotite-muscovite breakdown, and LAR-2 granites (2.3–1.3 Ma) generated by muscovite breakdown. At least three main crustal sources (at 14–23 km depth), characterized by distinct ε_Nd(t) and ⁸⁷Sr/⁸⁶Sr values, were involved at different times, and the magmas produced were randomly emplaced at shallow levels (3–6 km depth) throughout the entire field. The partial melting of a biotite-muscovite-rich source with low ε_Nd(t) value (about −10.5) produced the oldest intrusions (about 3.8–2.5 Ma). Afterwards (2.5–2.3 Ma), new magmas were generated by another biotite-rich source having a distinctly higher ε_Nd(t) value (−7.9). Finally, a muscovite-rich source with high ε_Nd(t) (about −8.9) gave origin to the younger group of granites (2.3–1.0 Ma). The significant Sr isotope disequilibrium recorded by granites belonging to the same intrusion is interpreted, as due to the short residence time of magmas in the source region followed by their rapid transfer to the emplacement level. Partial melting was probably triggered by multiple, small-sized mafic intrusions, distributed over the last 3.8 Ma that allowed temporary overstepping of biotite- and muscovite-dehydration melting reactions into an already pre-heated crust. Dilution in time of the magmatic activity probably prevented melt mingling and homogenization at depth, as well as the formation of a single, homogeneous, hybrid pluton at the emplacement level. Moreover the high concentrations of fluxing elements (B, F, Li) estimated for the LAR granites modified melt properties by reducing solidus temperatures, decreasing viscosity and increasing H₂O solubility in granite melts. The consequences were a more efficient, fast, magma extraction and transfer from the source, and a prolonged time of crystallization at the emplacement level. These key factors explain the long-lived hydrothermal activity recorded in this area by both fossil (Plio-Quaternary ore deposits) and active (Larderello geothermal field) systems.  相似文献   

High-T phase transition of synthetic ANaB(LiMg)CMg5Si8O22(OH)2 amphibole: an X-ray synchrotron powder diffraction and FTIR spectroscopic study     

Gianluca Iezzi  Mario Tribaudino  Giancarlo Della Ventura  Fabrizio Nestola  Fabio Bellatreccia 《Physics and Chemistry of Minerals》2005,32(7):515-523

The synthetic amphibole Na_0.95(Li_0.95Mg_1.05)Mg₅Si₈O₂₂(OH)₂ was studied in situ at high-T, using IR OH-stretching spectroscopy and synchrotron X-ray powder diffraction. At room-T the sample has P2₁ /m symmetry, as shown by the FTIR spectrum. It shows in the OH region two well-defined and intense absorptions at 3,748 and 3,712 cm⁻¹, respectively, and two minor bands at 3,667 and 3,687 cm⁻¹. The main bands are assigned to the two independent O–H groups in the primitive structure. The two minor bands evidencing the presence of small amount of vacant A-site (^A□_0.05). With increasing T, these bands shift continuously and merge into a unique absorption at high temperature. A change as a function of increasing T is revealed by the evolution of the refined unit-cell parameters, whose trend shows a transition to C2/m at about 320–330°C. The spontaneous scalar strain, fitted with a tricritical 2–6 Landau potential, gives a T _c of 325(10)°C (β parameter = 0.27). Comparison with the second-order P2₁ /m ⇔ C2/m phase transition at 255°C for synthetic amphibole ^ANa_0.8^B(Na_0.8Mg_1.2)^CMg₅Si₈O₂₂(OH)₂ indicates that the substitution of Na with Li at the B-sites strongly affects the thermodynamic character and the T _c of the phase transition. The comparison of LNMSH amphiboles with cummingtonitic ones shows that the high-T thermodynamic behaviour is affected by A-site occupancy.  相似文献   

Hydrochemical characteristics and salinity of groundwater in the Ejina Basin, Northwestern China   总被引：8，自引：0，他引：8  

X. Wen  Y. Wu  J. Su  Y. Zhang  F. Liu 《Environmental Geology》2005,48(6):665-675

A hydrochemical investigation was conducted in the Ejina Basin to identify the hydrochemical characteristics and the salinity of groundwater. The results indicate that groundwater in the area is brackish and are significantly zonation in salinity and water types from the recharge area to the discharge area. The ionic ration plot and saturation index (SI) calculation suggest that the silicate rock weathering and evaporation deposition are the dominant processes that determine the major ionic composition in the study area. Most of the stable isotope δ¹⁸O and δD compositions in the groundwater is a meteoric water feature, indicating that the groundwater mainly sources from meteoric water and most groundwater undergoes a long history of evaporation. Based on radioactive isotope tritium (³H) analysis, the groundwater ages were approximately estimated in different aquifers. The groundwater age ranges from less than 5 years, between 5 years and 50 years, and more than 50 years. Within 1 km of the river water influence zone, the groundwater recharges from recent Heihe river water and the groundwater age is about less than 5 years in shallow aquifer. From 1 km to 10 km of the river water influence zone, the groundwater sources from the mixture waters and the groundwater age is between 5 years and 50 years in shallow aquifer. The groundwater age is more than 50 years in deep confined aquifer.  相似文献   

On the Kimmeridgian (Jurassic) succession of the Normandy coast, northern France     

R.W. Gallois 《Proceedings of the Geologists' Association. Geologists' Association》2005,116(1):33-43

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Environmental significance of C/C and O/O ratios of modern land-snail shells from the southern great plains of North America     

Meena Balakrishnan  James L. Theler  Don G. Wyckoff 《Quaternary Research》2005,63(1):15-30

¹³C/¹²C and ¹⁸O/¹⁶O ratios of aragonite shells of modern land snails from the southern Great Plains of North America were measured for samples from twelve localities in a narrow east-west corridor that extended from the Flint Hills in North Central Oklahoma to the foothills of the Sangre de Cristo Mountains in Northern New Mexico, USA. Across the study area, shell δ¹⁸O values (PDB scale) ranged from −4.1‰ to 1.2‰, while δ¹³C values ranged from −13.2‰ to 0.0‰. δ¹⁸O values of the shell aragonite were predicted with a published, steady state, evaporative flux balance model. The predicted values differed (with one exception) by less than 1‰ from locality averages of measured δ¹⁸O values. This similarity suggests that relative humidity at the time of snail activity is an important control on the δ¹⁸O values of the aragonite and emphasizes the seasonal nature of the climatic information preserved in the shells. Correlated δ¹³C values of coexisting Vallonia and Gastrocopta suggest similar feeding habits and imply that these genera can provide information on variations in southern Great Plains plant ecology. Although there is considerable scatter, multispecies, transect average δ¹³C values of the modern aragonite shells are related to variations in the type of photosynthesis (i.e., C₃, C₄) in the local plant communities. The results of this study emphasize the desirability of obtaining isotope ratios representing averages of many shells in a locale to reduce possible biases associated with local variations among individuals, species, etc., and thus better represent the “neighborhood” scale temporal and/or spatial environmental variations of interest in studies of modern and ancient systems.  相似文献   

The Blake Event recorded near the Eemian type locality – A diachronic onset of the Eemian in Europe     

《Quaternary Geochronology》2015

Multidisciplinary analysis including paleomagnetic, sedimentologic, sea-level change, luminescence dating and palynologic research was performed on a 25 m long orientated core taken at Rutten, close to Eemian key localities in the Netherlands. The main goal of our research was to test a possible delayed onset of temperate conditions in this region compared to Southern Europe, occurring within the Last Interglacial. The sediments revealed the presence of the paleomagnetic Blake Event in ca. 10 m of lower-deltaic floodbasin sediments that contain a pollen record covering the Eemian. The position of the Blake Event in relation to the pollen stratigraphy concurs with the earlier studied Neumark Nord 2 site. Paleomagnetic correlation to core MD95-2042 off SW Iberia indicates ca. 5 kyr diachroneity between the pollen-based onset of temperate interglacial conditions between northern and southern Europe. The onset of the Eemian in north-western and central Europe (ca. 121.0 ka) post-dates the Marine Isotope Stage 6/5e transition by ca. 10 kyr. In addition, the Rutten data provide evidence for a relatively long duration of the Blake Event of at least 8 kyr. The late onset of the temperate conditions that define the base of the Eemian, imply that NW Europe with the Eemian type area is not the most suited region to define the beginning of the Last Interglacial and Late Pleistocene for global chronostratigraphic use.  相似文献   

Vegetation history of the penultimate glacial period (Marine isotope stage 6) at Ioannina,north‐west Greece     

K. H. Roucoux  P. C. Tzedakis  I. T. Lawson  V. Margari 《第四纪科学杂志》2011,26(6):616-626

The vegetational history of the penultimate glacial period, Marine Isotope Stage (MIS) 6 (c. 185–135 ka), has remained relatively unexplored. Here we present a new record from the Ioannina basin, north‐west Greece, which constitutes the highest‐resolution terrestrial pollen record for this interval produced to date. It shows that the vegetation history of MIS 6 in this region can be divided into two parts: an early period (185–155 ka) with pronounced oscillations in tree population extent, and a later period (155–135 ka) with much smaller tree populations and subdued oscillations. This pattern is analogous to the MIS 3/MIS 2 division during the last glacial in the same sequence, although the early part of MIS 6 had larger Pinus populations and fewer temperate trees relative to the equivalent interval in MIS 3. This implies cooler and wetter conditions, which is somewhat counterintuitive given the high summer insolation during MIS 6e, but is in line with other palaeoclimatic evidence from the Mediterranean. Comparison with North Atlantic records suggests that despite the absence of pronounced iceberg discharges during MIS 6, North Atlantic millennial‐scale variability had a significant downstream impact on tree populations in north‐west Greece. Copyright © 2011 John Wiley & Sons, Ltd.  相似文献   

Last interglacial vegetation and climate history from the Portuguese coast          下载免费PDF全文

T. A. MINCKLEY  J. A. HAWS  M. M. BENEDETTI  S. C. BREWER  S. L. FORMAN 《第四纪科学杂志》2015,30(1):59-69

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Remote estimation of terrestrial evapotranspiration by Landsat 5 TM and the SEBAL model in cold and high‐altitude regions: a case study of the upper reach of the Shule River Basin,China          下载免费PDF全文

Yaping Chang  Yongjian Ding  Qiudong Zhao  Shiqiang Zhang 《水文研究》2017,31(3):514-524

Evapotranspiration (ET) is an important expenditure in water and energy balances, especially on cold and high‐altitude land surfaces. Daily ET of the upper reach of the Shule River Basin was estimated using Landsat 5 TM data and the Surface Energy Balance Algorithm for Land (SEBAL) model. Based on observations made at the Suli station, the algorithms of land surface temperature and soil heat flux in SEBAL were modified. Land surface temperature was retrieved and compared with ground truth via three methods: the radiative transfer equation method, the mono‐window algorithm, and the single‐channel method. We selected the best of these methods, mono‐window algorithm, for estimating ET. The average error of daily ET estimated by the modified SEBAL model and measured by the eddy covariance system was 16.4%, with a root‐mean‐square error of 0.52 mm d^?1. The estimated ET means were 3.09, 2.48, and 1.48 mm d^?1 on June 9 (DOY 160), June 25 (DOY 176), and July 27 (DOY 208) of the year 2010, respectively. The average estimated ET on the glacier surface of all days was more than 3 mm d^?1, a measurement that is difficult to capture in‐situ and has rarely been reported. This study will improve the understanding of water balance in cold, high‐altitude regions. Copyright © 2016 John Wiley & Sons, Ltd.  相似文献   

运用ENVI实现SPOT-5卫星影像的RVI提取     

尹芬  丁美青 《测绘与空间地理信息》2016,(1)

运用ENVI软件处理长沙地区的SPOT-5影像,将全色影像和多波段影像进行融合,分析融合后的影像,再选择感兴趣区域进行影像裁剪;采用ENVI的波段运算(Band3/Band2)提取该地区比值植被指数并进行分析。结果表明:比值植被指数对植被覆盖率较高的区域有非常高的敏感度;在植被覆盖率小于50%的时候,其敏感度明显降低,在绿色植被覆盖区域的比值植被指数远大于1,在裸露地表、建筑物、水体等没有植被覆盖区域的比值植被指数则在1附近,而比值植被指数大于2的则出现在高覆盖健康绿色植被上。  相似文献