小秦岭金矿含金石英脉中黄铁矿晶体的表面微形貌研究   总被引：1，自引：0，他引：1  

张良钜 《岩石矿物学杂志》2004,23(2):167-172

利用微分干涉显微镜、扫描电镜、透射电镜等对小秦岭金矿含金石英脉中黄铁矿晶体的表面微形貌进行了研究。黄铁矿晶体的{210}面上发育自由生长层，表明{210}面是F面，其生长机理受二维成核层生长所制约。除简单的五角十二面体外，其他形态黄铁矿晶体的{210}面上也发育有自由生长层。{210}面上的正条纹有些是由{100}面上生长层的边缘台阶在{210}面上叠堆形成，另一些正条纹则是{210}面上生长层边缘台阶堆叠的产物。透射电镜和电子衍射花样研究表明，负条纹黄铁矿晶体是由30～50nm大小的核团经自动定向附生作用形成，每个核团不是单晶体，而是由许多早先在溶液中形成的小微晶聚合而成。这些特征表明负条纹黄铁矿晶体是在溶液过饱和度极高和温度梯度小的理想环境中形成，它的形成与杂质无关。PBC理论和唐纳-哈克定律能较好地解释自然界中黄铁矿晶体{100}面上普遍发育自由生长层、而{210}面上自由生长层极为罕见的原因。除日本释迦内矿区黑矿之上的浮岩凝灰岩中产生出负条纹黄铁矿晶体外，在石英脉型金矿床中也有负条纹黄铁矿晶体产出。  相似文献   

北大别漫水河混合岩化片麻岩中锆石微区微量元素特征及其地质意义   总被引：1，自引：1，他引：1  

吴元保陈道公  郑永飞夏群科 涂湘林 《岩石学报》2004,20(5):1141-1150

本文通过对北大别漫水河片麻岩的锆石进行阴极发光(CL)显微图像观察及激光剥蚀等离子体质谱(LA-ICP-MS)微区微量元素分析，试图对重结晶和深熔成因变质锆石的微量元素特征进行制约。CL图像显示该片麻岩锆石存在复杂的内部结构，有原岩岩浆锆石、重结晶变质锆石和深熔锆石。不同锆石区域的Hf、P、Ti、Nb、Ta和Ce等元素含量及Nb/Ta比值相似。但重结晶和深熔锆石的Th/U比值明显低于原岩锆石(分别为0.33～1.12、0.03～0.60和0.92～1.99).重结晶锆石区域低Th/U比值是由于重结晶过程中Th比U更易排出锆石晶格，而深熔锆石区域低Th/U比值是其结晶的熔体中低Th和高U含量的原因。不同锆石区域的稀土元素含量也不相同。原岩锆石稀土总量高(621.9～1331.6ppm)，变化较大，而深熔锆石和重结晶锆石稀土总量低(分别为236.8～642.5ppm；98.5～435，6ppm)。不同锆石区域的稀土元素配分模式相似。但重结晶锆石的稀土元素含量比原岩锆石低3～4倍，可能是重结晶过程中稀土元素被逐出锆石晶格所致。深熔锆石的稀土元素含量受深熔熔体与残留体之间平衡与否的制约，如果熔体与残留体之间达到了平衡，则深熔锆石与原岩锆石有相似的稀土元素含量；反之，深熔锆石的稀土元素含量就会低于原岩锆石。漫水河片麻岩深熔锆石的稀土含量比原岩锆石低1～4倍，反映了深熔熔体与残留体之间没有达到平衡。结合已有的花岗岩与混合岩化岩石的年龄和同位素特征，说明北大别混合岩化片麻岩可能与同时代花岗岩的形成有成因关系。  相似文献   

Paleozoic serpentinite-enclosed chromitites from Tehuitzingo (Acatlán Complex, southern Mexico): a petrological and mineralogical study     

J. A. Proenza  F. Ortega-Gutirrez  A. Camprubí  J. Tritlla  M. Elías-Herrera  M. Reyes-Salas 《Journal of South American Earth Sciences》2004,16(8):129

The serpentinites and associated chromitite bodies in Tehuitzingo (Acatlán Complex, southern Mexico) are in close relationship with eclogitic rocks enclosed within a metasedimentary sequence, suggesting that the serpentinites, chromitites and eclogitic rocks underwent a common metamorphic history.Primary chromites from the chromitite bodies at Tehuitzingo are of refractory-grade (Al-rich) and have a chemical composition similar to that expected to be found in an ophiolitic environment. The chromite grains in chromitites and serpentinites are systematically altered to ‘ferritchromite’. The alteration trend is usually characterized by a decrease in the Al, Mg and Cr contents coupled by an increase in Fe³⁺ and Fe²⁺.The Tehutizingo chromitites have low Platinum Group Elements (PGE) contents, ranging from 102 to 303 ppb. The chondrite-normalized PGE patterns are characterized by an enrichment in the Ir-subgroup elements (IPGE=Os, Ir, Ru) relative to the Pd-subgroup elements (PPGE=Rh, Pt, Pd). In addition, all chromitite samples display a negative slope from Ru to Pd [(Os+Ir+Ru)/(Pt+Pd)=4.78−14.13]. These patterns, coupled with absolute PGE abundances, are typical of ophiolitic chromitites elsewhere. Moreover, all the analyzed samples exhibit chondrite-normalized PGE patterns similar to those found for non-metamorphosed ophiolitic chromitites. Thus, the PGE distribution patterns found in the Tehuitzingo chromitites have not been significantly affected by any subsequent Paleozoic high-pressure (eclogite facies) metamorphic event.The chondrite-normalized PGE patterns of the enclosing serpentinites also indicate that the PGE distribution in the residual mantle peridotites exposed in Tehuitzingo was unaffected by high-pressure metamorphism, or subsequent hydrothermal alteration since the serpentinites show a similar pattern to that of partially serpentinized peridotites present in mantle sequences of non-metamorphosed ophiolites.Our main conclusion is that the chromitites and serpentinites from Tehuizingo experienced no significant redistribution (or concentration) of PGE during the serpentinization process or the high-pressure metamorphic path, or during subsequent alteration processes. If any PGE mobilization occurred, it was restricted to individual chromitite bodies without changing the bulk-rock PGE composition.Our data suggest that the Tehuitzingo serpentinites and associated chromitites are a fragment of oceanic lithosphere formed in an arc/back-arc environment, and represent an ophiolitic mantle sequence from a supra-subduction zone, the chemical composition of which remained essentially unchanged during the alteration and metamorphic events that affected the Acatlán Complex.  相似文献   

Improved Platinum-Group Element Extraction by NiS Fire Assay from Chromitite Ore Samples Using a Flux Containing Sodium Metaphosphate   总被引：1，自引：0，他引：1  

L. Paul Bédard  Sarah-Jane Barnes 《Geostandards and Geoanalytical Research》2004,28(2):311-316

Many chromite-rich rocks contain relatively high concentrations of the platinum-group elements (PGE). In many cases, the phases carrying PGE occur as either platinum-group minerals (PGM) or as base metal sulfides in solid solution in sulfides. In some cases, such as the UG-2 unit of the Bushveld Complex, the PGM are occluded inside chromite grains. Chromites are notably difficult to dissolve in most fluxes and if the chromite contains some PGM the possibility exists that not all the PGE will be recovered during fusion. In this work, shortcomings in published methods of analysis based on the nickel sulfide fire assay procedure were investigated and a new procedure developed based on the addition of sodium metaphosphate to the fusion mixture. Optimum composition of the fusion mixture was found to be 10 g sodium metaphosphate and 9 g silica to 10 g sample, 15 g sodium carbonate, 30 g lithium tetraborate, 7.5 g nickel and 4.5 g sulfur to achieve complete dissolution of chromite grains. The new flux mixture was evaluated by the analysis of reference material CHR-Pt+ (which is known to contain PGM inside chromite grains) and no undissolved chromite grains were found in the glassy slag. Analysis of the nickel sulfide beads from this fire assay using neutron activation analysis showed similar results for Rh and Ru when compared with published conventional true (or accepted) values, while Au, Ir, Os, Pd and Pt values determined here were 10 to 30% higher than the corresponding published conventional true values. It was concluded that the addition of sodium metaphosphate improved chromite dissolution in the flux and appears to improve PGE recovery.  相似文献   

Fold-Thrust-Belt Structure of the Proterozoic Eastern Ghats Mobile Belt: A Proposed Correlation Between India and Antarctica in Gondwana     

T.K. Biswal  S. Sinha 《Gondwana Research》2004,7(1):43-56

The Proterozoic Eastern Ghats Mobile Belt along the east coast of India shares a thrusted lower contact with the surrounding cratons. The thrust, known as the Terrane Boundary shear zone, is associated with two large lateral ramps resulting in a curved outline on the northwestern corner of the mobile belt. The Eastern Ghats Mobile Belt is divided into two lithotectonic units, the Lathore Group and the Turekela Group, based on their lithological assemblages and deformational history. On the basis of published data from a Deep Seismic Sounding (DSS) profile of the Eastern Ghats crust, the Terrane Boundary Shear Zone is considered to be listric in nature and acts as the sole thrust between craton and mobile belt. The Lathore and Turekela Groups are nappes. With this structural configuration the NW part is described as a fold thrust belt. However, the thrusting postdates folding and granulite metamorphism that occurred in the Eastern Ghats, as in the Caledonide type of fold thrust belt of NW Scotland. The Terrane Boundary Shear Zone is interpreted to be contiguous with the Rayner-Napier boundary of the Enderby Land in a Gondwana assembly.  相似文献   

巧用CASIO fx-4800P计算器测设线路复合曲线     

李铭石  周照群  张进民 《现代测绘》2004,27(3):38-40

应用地面点与线路中线相对关系的统一数学模型，使用CASIO fx-4800P程序型计算器编制的适合野外测设线路各种复合曲线(包括直线、缓和曲线、圆曲线的任意组合)的实用程序。  相似文献   

Continuous Multi‐probe Measurements in Fastflowing Waters Using a Hydrographic Slot     

Bernhard Karrasch  Michael Herzog 《洁净——土壤、空气、水》2005,33(2):165-169

Taking continuous spatiotemporal in situ measurements with multi‐probes in fast‐flowing waters/rivers can be problematic because the sensors may be damaged by high shear forces and flotsam. To protect the multi‐probe and to enable easy access for the maintenance and calibration of the sensors, a special multi‐probe holder fixed in a hydrographic slot was developed. The validation of the probe system revealed a “memory effect” at short time scales (< 10 s) within sharp gradients caused by the overflow container of the multi‐probe rack keeping the sensors submerged in the sample water. Continuously recorded data (conductivity, temperature, pH, oxygen concentration and saturation, as well as in vivo fluorescence of chlorophyll‐a) from a research cruise on board the RV ALBIS along the river Elbe (river km 309) and entering the river Saale are presented. This river stretch upstream of the city of Magdeburg to the mouth of the Saale tributary was found to have a complex physicochemical character, which is attributable to the long mixing process of water from the river Saale and the river Elbe.  相似文献   

Hydrothermal Quartz Vein Formation, Revealed by Coupled SEM-CL Imaging and Fluid Inclusion Microthermometry: Shuteen Complex, South Gobi, Mongolia     

Bayaraa Batkhishig    Greg Bignall  Noriyoshi Tsuchiya 《Resource Geology》2005,55(1):1-8

Abstract. Scanning electron microscopy-cathodoluminescence (SEM-CL) imaging of vein quartz in the Cu-mineralised, Shuteen Complex (South Gobi, Mongolia) has revealed a complex history of crystal growth, dissolution and microfracture healing, associated with several hydrothermal events that could not be detected using other observational techniques (e.g. transmitted/reflected light microscopy, back-scattered electron imaging, or secondary electron imaging).
The quartz initially grew as CL-bright/grey crystals in a 345±30C liquid reservoir, as inferred by the analysis of primary liquid fluid inclusions (average Th of 343C; 6.6∼7.7 wt% NaCl_eq). Quartz precipitation occurred at the edge of the crystals as reservoir fluids cooled to 260±25C, as indicated by micron-scale CL-dark/CL-bright quartz growth bands containing abundant fluid inclusions (with an average T_h values of 261C). Pressure fluctuations were the likely cause of dissolution, as SEM-CL imaging reveals the quartz have corroded or rounded crystal edges, and precipitation of later quartz into open space. SEM-CL imaging shows the quartz contains healed microfractures that trapped low salinity fluids (3.9 wt% NaC1_eq) with Th values of 173±15C.
SEM-CL imaging provides a means of deciphering the thermal and chemical evolution of the fossil Shuteen hydrothermal system, and the nature of hydrothermal quartz vein-forming processes, by facilitating the correlation of distinct fluid inclusion populations and their relative chronology, with specific hydrothermal events.  相似文献   

玄武岩浆起源和演化的一些基本概念以及对中国东部中-新生代基性火山岩成因的新思路   总被引：44，自引：3，他引：44  

牛耀龄 《高校地质学报》2005,11(1):9-46

以全球大地构造为背景讨论了玄武岩浆起源和演化的一些基本概念.这些概念的正确理解有助于合理解释各种环境中火成岩的形成机制,也有助于依据野外岩石组合来判别古构造环境.在此基础上结合已有资料和观察,对中国东部中生代岩石圈减薄及中-新生代基性火山岩成因提出了一些新解释.这些解释与地质观察相吻合,且符合基本的物理学原理.虽然中国东部基性火山活动可称为"板内"火山活动,但它实际上是板块构造的特殊产物.中国东部中生代岩石圈减薄是其下部被改造为软流层的缘故.这种改造是加水"软化"所致.水则源于中国东部地幔过渡带(410～660 km)内古太平洋(或其前身)俯冲板块脱水作用.其将岩石圈底部改造为软流层的过程,实际上就是岩石圈减薄的过程.因为软流层是地幔对流的重要部分,而大陆岩石圈则不直接参与地幔对流.中生代玄武岩具有εNd＜0的特征,说明其源于新近改造而成的软流层,亦即原古老岩石圈之底部.中国大陆北北东-南南西向的海拔梯度突变界线与东-西部重力异常,陆壳厚度变化,以及地幔地震波速变化梯度吻合.因此可将北北东-南南西向梯度线称为"东-西梯度界".该界东-西海拔高差(西部高原与东部丘陵平原),陆壳厚度差异(西部厚而东部薄)和100～150 km的深度范围地幔地震波速差异(西部快而东部慢),均受控于上地幔重力均衡原理.这表明西部高原岩石圈厚度＞150～200 km,而东部丘陵平原岩石圈厚度＜80km."遥远"的西太平洋俯冲带具有自然的地幔楔吸引作用.此吸引作用可引起中国东部"新生"软流层东流.软流层东流必将引起西部高原底部软流层的东向补给(流动).这一过程必然导致东移软流层的减压,即从西部的深源(岩石圈深度＞150～200 km处)到东部的浅源(岩石圈深度～80km处).东移软流层的减压分熔可合理解释具有软流圈地球化学特征(εNd＞0)的新生代中国东部基性火山活动及玄武岩的成因.这些对中国东部中-新生代地质过程的解释,将为更加细致的,以岩石学和地球化学为主的讨论所验证.  相似文献   

Thermal evolution of an extensional detachment as constrained by organic metamorphic data and thermal modeling: Graz Paleozoic Nappe Complex (Eastern Alps)   总被引：1，自引：0，他引：1  

Gerd Rantitsch  Reinhard F. Sachsenhofer  Christian Hasenhüttl  Barbara Russegger  Thomas Rainer 《Tectonophysics》2005,411(1-4):57-72

Following Early Cretaceous nappe stacking, the Eastern Alps were affected by late-orogenic extension during the Late Cretaceous. In the eastern segment of this range, a Late Cretaceous detachment separates a very low- to low-grade metamorphic cover (Graz Paleozoic Nappe Complex, GPNC) above a low- to high-grade metamorphic basement. Synchronously, the Kainach Gosau Basin (KGB) collapsed and subsided on top of the section.Metamorphism of organic material within this section has been investigated using vitrinite reflectance data and Raman spectra of extracted carbonaceous material. In the southern part of the GPNC, vitrinite reflectance indicates a decrease in organic maturity towards the stratigraphic youngest unit. The remaining part of the GPNC is characterized by an aureole of elevated vitrinite reflectance values and Raman R2 ratios that parallels the margins of the GPNC. Vitrinite reflectance in the KGB shows a steep coalification gradient and increases significantly towards the western basin margin. The observed stratigraphic trend in the southern GPNC is a result of deep Paleozoic to Early Cretaceous burial. This maturity pattern was overprinted along the margins by advective heat and convective fluids during Late Cretaceous to Paleogene exhumation of basement rocks.During shearing, the fault zone was heated up to ca. 500 °C. This overprint is explained by a two-dimensional thermal model with a ramp-flat fault geometry and a slip rate of 1 to 1.5 cm/year during 5 Ma fault movement. The collapse basin above the detachment subsided in a thermal regime which was characterized by relaxing isotherms.  相似文献