海南蓬莱蓝宝石的光致发光谱学特征及意义     

杨琴  杨勇  田永红 《矿物学报》2009,29(4)

从光致发光光谱角度探讨了海南蓬莱蓝宝石的呈色机理.结果发现:与蓝宝石吸收光谱的500～700 nm吸收宽带相比,在500～720 nm发光波段内存在566.8 nm锐峰、600 nm左右肩峰和Cr~(3+)的694.2 nm特征峰.600 nm肩峰与其吸收峰镜像对称,566.8 nm处锐峰的产生原因复杂.600 nm肩峰可能与Fe~(2+)-Fe~(2+)离子对的电子跃迁有关;566.8 nm锐峰因532 nm激光激发Fe~(2+)-Ti~(4+)或Fe~(2+)-Fe~(3+)间的电荷迁移带,通过晶格造成Si~(4+)、Mg~(2+)等微量杂质离子敏化而产生.光致发光谱中呈现更多谱峰,能呈现离子跃迁时不同离子间发生的相互作用,为500～700 nm吸收宽带由不同致色机制的叠加给出了直接证明,是一种能全面地研究宝石矿物中致色元素能级结构的有效方法.  相似文献   

Penglai Zircon Megacrysts: A Potential New Working Reference Material for Microbeam Determination of Hf–O Isotopes and U–Pb Age     

Xian-Hua Li  Weng-Guo Long  Qiu-Li Li  Yu Liu  Yong-Fei Zheng  Yue-Heng Yang  Kevin R. Chamberlain  De-Fang Wan  Cun-Hua Guo  Xuan-Ce Wang  Hua Tao 《Geostandards and Geoanalytical Research》2010,34(2):117-134

We introduce a potential new working reference material – natural zircon megacrysts from an Early Pliocene alkaline basalt (from Penglai, northern Hainan Island, southern China) – for the microbeam determination of O and Hf isotopes, and U–Pb age dating. The Penglai zircon megacrysts were found to be fairly homogeneous in Hf and O isotopes based on large numbers of measurements by LA-multiple collector (MC)-ICP-MS and SIMS, respectively. Precise determinations of O isotopes by isotope ratio mass spectrometry (IRMS) and Hf isotopes by solution MC-ICP-MS were in good agreement with the statistical mean of microbeam measurements. The mean δ¹⁸O value of 5.31 ± 0.10‰ (2s) by IRMS and the mean ¹⁷⁶Hf/¹⁷⁷Hf value of 0.282906 ± 0.0000010 (2s) by solution MC-ICP-MS are the best reference values for the Penglai zircons. SIMS and isotope dilution-TIMS measurements yielded consistent ²⁰⁶Pb/²³⁸U ages within analytical uncertainties, and the preferred ²⁰⁶Pb/²³⁸U age was found to be 4.4 ± 0.1 Ma (95% confidence interval). The young age and variably high common Pb content make the Penglai zircons unsuitable as a primary U–Pb age reference material for calibration of unknown samples by microbeam analysis; however, they can be used as a secondary working reference material for quality control of U–Pb age determination for young (particularly < 10 Ma) zircon samples.  相似文献   

山东蓬莱石家金矿原生晕地球化学特征及深部找矿预测     

张英帅  顾雪祥  章永梅  王佳琳  冯李强  葛战林  何宇 《现代地质》2021,35(1):258-269

为预测和评价山东蓬莱石家金矿床的深部找矿远景,延长矿山服务年限,着重论述了该矿床的原生晕地球化学特征,对矿床的深部找矿潜力进行了探讨。原生晕元素组合特征分析表明,石家金矿床的矿体及近矿晕元素组合为Au、Ag、Cu、Pb、Zn、S、Te,前缘晕为Hg、As、Sb、Ba,尾晕为Mo、W、Sn。元素异常形态特征显示,326号矿脉南段以前缘晕和近矿晕为主,北段以前缘晕和尾晕为主,近矿晕元素异常较弱,矿体总体具有向南侧伏的特点。原生晕轴向分带序列在36线和84线均呈现反分带和前缘晕、尾晕共存的特点,结合地球化学参数在垂向上呈振荡波动变化的特征,说明矿体由多期次成矿作用叠加形成,同时预示矿体向深部还有一定延伸或有盲矿体存在。综合分析认为,326号矿脉南段为成矿的有利部位,深部仍有较大的找矿空间;矿体北段深部矿化减弱,但出现了前缘晕、尾晕元素的共存,预示深部可能还有盲矿体存在。  相似文献   

Temperature and salinity effects in modeling the trajectory of the 2011 Penglai 19-3 oil spill     

Yebao Wang  Xiangyang Zheng  Xiang Yu 《Marine Georesources & Geotechnology》2017,35(7):946-953

In this paper, two hydrodynamic models were developed using Delft3D and were then applied to the 2011 Penglai 19-3 accident in the Chinese Bohai Sea. One model includes constant temperature and salinity, while the other model utilizes variable temperature and salinity. The two models both simulate currents fields in the Bohai Sea and utilize wind data from the National Meteorological Service of Germany (DWD) to calculate the drift of spilled oil. The hydrodynamic simulation results are consistent with the results of previous studies. We subsequently predict the surface oil trajectories of the Penglai 19-3 oil spill based on the two models, respectively. Comparing the oil-spill simulation results with remote sensing information, we show that the model with variable temperature and salinity exhibits a better fit with the actual observations. Temperature and salinity were two important factors that influenced the movement of spilled oil on the sea surface. According to the result of the variable thermohaline model, most of the oil particles spread northwest and a small portion spreads southeast to the Chinese Bohai Strait. We conclude that density currents should be considered in future oil-spill studies to generate more realistic results.  相似文献   

A Potential (U‐Th)/He Zircon Reference Material from Penglai Zircon Megacrysts          下载免费PDF全文

Youjuan Li  Dewen Zheng  Ying Wu  Ying Wang  Huaiyu He  Jianzhang Pang  Yizhou Wang  Jingxing Yu 《Geostandards and Geoanalytical Research》2017,41(3):359-365

In this study (U‐Th)/He dating of the Penglai zircons, which occur as abundant megacrysts in Neogene alkaline basalts in northern Hainan Province, south‐eastern China, was undertaken. A weighted mean age of 4.06 ± 0.35 Ma (2s) with a mean square weighted deviation (MSWD) of 1.79 was obtained from eighteen fragments of four zircon megacrysts using single‐crystal laser fusion He determinations and the U‐Th isotope dilution (ID) method. The (U‐Th)/He ages are consistent, homogeneous and systematically slightly younger than the preferred ²⁰⁶Pb/²³⁸U age of 4.4 ± 0.1 Ma (95% confidence interval) determined by ID‐TIMS and subsequently published U‐Pb results. The U‐Pb isotopic system in zircon has a high closure temperature of ~ 900 °C, and the preferred U‐Pb age may record both the time since eruption and the zircon residence time in the magma chamber. In contrast, the closure temperature of the zircon (U‐Th)/He system is ~ 190 °C and the zircon megacrysts were brought quickly to the surface by the host basaltic magma. Thus, the (U‐Th)/He age represents the timing of the eruption. Based on the unlimited quantity, large grain size, mostly weak broad zoning, rapid cooling and homogenous (U‐Th)/He ages, we consider the Penglai zircons suitable for use as a reference material in (U‐Th)/He isotope geochronology.  相似文献   

海南岛陆缘扩张带形成及新生代岩石圈动力学机制:来自幔源包体的地球化学证据     

蒋英  梁细荣  梁新权  付建刚  王策  周云  温淑女 《大地构造与成矿学》2017,41(1):157-182

海南岛陆缘扩张带蓬莱地区新生代玄武岩中捕获大量尖晶石二辉橄榄岩和方辉橄榄岩幔源包体。激光剥蚀等离子体质谱(LA-ICP-MS)分析结果表明,蓬莱地幔橄榄岩含有三种不同地球化学特征的单斜辉石(Cpx):(1)a类单斜辉石Mg~#=92.3~93.4,来自富集Cpx的二辉橄榄岩,具有极低的LREE和不相容元素含量,HREE平坦,Th、U、La、Sr正异常,经历了7%~10%的尖晶石相部分熔融,仅受到极低程度强不相容元素(Th、U、La、Sr)初期富集交代作用;(2)b类单斜辉石Mg~#=89.9~90.3,来自较富集Cpx的二辉橄榄岩,具有中等的LREE和LILE含量,HREE平坦,微量元素蛛网图上显示Th、U正异常,Rb、Ba、Nb、Ta、Sr、Ti负异常,经历4%~5%的尖晶石相部分熔融,可能受到了含LREE和Th、U等不相容元素的硅酸盐熔体交代;(3)c类单斜辉石Mg~#=91.4~92.8,来自贫Cpx的二辉橄榄岩和方辉橄榄岩,具有富集的LREE和LILE含量,HREE弱分异,微量元素蛛网图上显示Th、U正异常及强烈的Nb、Ta、Ti负异常,经历了8%~20%的尖晶石相部分熔融,其交代熔体可能是来自源区有石榴子石残留的碳酸盐熔体。全岩主、微量元素及模拟计算结果表明,这些幔源包体的主量元素主要受部分熔融程度影响,并且方辉橄榄岩经历的部分熔融程度大于二辉橄榄岩。地幔橄榄岩的Sr-Nd同位素组成表明该区具有MORB-OIB型亏损地幔特征。此外,蓬莱部分地幔橄榄岩包体显示正斜率的HREE分异特征((Gd/Yb)_N=0.4~0.7),暗示该区地幔经历了源自石榴子石稳定区的变压熔融,总体熔融程度为18%以上,指示了较高的地幔潜能温度。综合前人对海南岛新生代玄武岩最新研究成果,我们认为海南地幔柱可能为该区软流圈地幔置换古老岩石圈地幔提供了热源,导致了区域岩石圈地幔的破坏,从而引起包括地幔柱本身、软流圈和富集岩石圈的熔融。岩石圈地幔性质的改变和不均一性可能是海南岛陆缘扩张带新生代岩石圈减薄的主要动力学机制。  相似文献   

山东蓬莱史家沟西山火山碎屑岩风化壳元素地球化学特征     

王集宁  蒙永辉  颜堂  姚英强  刘瑞峰  邹连庆  商婷婷  付娟 《地球学报》2018,39(4):498-512

以山东蓬莱城西史家沟的西山火山碎屑岩风化壳为研究对象,系统采集样品,并测试了微量元素、主量元素、稀土元素以及黏土矿物等指标,揭示了西山火山碎屑岩风化壳的元素地球化学特征,讨论了风化壳的形成年代及其气候条件。史家沟火山碎屑岩风化壳源自基性-超基性玻屑凝灰岩母岩,CIA平均值为92.3,总体上处于为强度风化水平,K、Na、Ca和Mg等元素淋失殆尽,出现了脱硅富铝铁现象,为轻稀土富集型风化壳。西山火山碎屑岩风化壳可分为两个喷发旋回,大致以200 cm为界限,在此以下第一旋回,以上为第二旋回。第一旋回的CIA介于94.0~97.2之间,V、Rb、Sb、Mo、Li和Ga等微量元素出现淋失,在213 cm处并出现了?REE、?LREE和?HREE的峰值、Ce的负异常,蒙脱石化彻底,风化壳呈现灰白色。第二旋回的CIA在86.3~89.2之间,风化程度较第一旋回稍低,微量元素和稀土元素垂直变化较小,蒙脱石化并不完全彻底,仍残留长石、赤铁矿和石英等原生矿物,因而仍然呈现红色或淡红色。西山火山碎屑岩风化壳形成于中新世末到上新世,为温暖湿润的亚热带环境;中新世后的气候趋冷造成了两个旋回风化程度和元素地球化学特征的差异。  相似文献   

蓬莱北部地区典型矿床三维地质模型构建与成矿预测研究          下载免费PDF全文

赵辉绩  韩艳超  吴宁宁  张迪 《山东国土资源》2022,38(8)

蓬莱北部地区位于胶东金矿集中区栖霞—大柳行金矿带北端,发育有一系列含金石英脉型及破碎带蚀变岩型金矿床。以区内的徐家集矿田及龙山店矿田中的典型金矿为研究对象,采用Creatar XModeling软件引入三维地质建模,依据区域地质剖面、重磁联合剖面、CSAMT剖面及勘探工程数据构建矿田尺度岩体、断裂构造、蚀变带模型,并建立典型矿床三维地质模型,实现矿体空间可视化,为典型矿床深部找矿提供依据。  相似文献   

山东蓬莱西石硼金矿地质特征及找矿方向          下载免费PDF全文

董小涛  孔晓敏  穆锡川  陈汉  马顺溪 《山东国土资源》2016,32(8)

西石硼金矿位于栖霞-蓬莱金成矿带,成因类型为岩浆期后热液型金矿床。矿体受NNE—NE向断裂严格控制,赋矿围岩为郭家岭二长花岗岩,矿体呈脉状、透镜状产出。矿石为黄铁绢英岩化花岗质碎裂岩夹石英脉,矿石矿物主要为黄铁矿、银金矿、自然金等。通过对该矿床地质特征、控矿因素的研究,在分析找矿标志的基础上,提出应加大深部找矿的建议。  相似文献   

山东蓬莱新生代玄武岩的构造背景及宝石找矿前景     

闫积惠 《地质论评》1999,45(7):560-564

山东蓬莱位于胶东地体北缘中部。板块动力作用形成了前古生代近EW向构造和中生代NE—NNE向走滑断层,侏罗纪以来地幔柱构造作用逐渐加强,地壳伸展减薄,幔源物质上涌,导致新生代碱性玄武岩喷发。碱性玄武岩中普通辉石、镁铝榴石等可作为低档宝石原料。玄武岩的构造背景、喷发形式、火山机构、岩性特征等与昌乐赋蓝宝石的碧玄岩极为相似,经过有针对性的详细调查研究,寻找红、蓝宝石是有希望的。  相似文献