三元体系CaCl₂?SrCl₂?H₂O的相平衡及其在钙锶分离中的应用          下载免费PDF全文

韩海军  吉祥  陈烽雄  李家乐  黄军榜 《盐湖研究》2022,30(4)

采用等温溶解平衡法研究了三元体系CaCl₂?SrCl₂?H₂O温度从323.15 K到353.15 K范围内的相平衡。基于该三元体系多温下的相平衡数据,设计开展了实验室模拟南翼山油田卤水中氯化钙和氯化锶在温度323.15 K下的分离实验。实验室模拟钙锶分离实验结果表明,在323.15 K下时分离一次固相产品中的钙锶摩尔比可以从25.46:1降至1.73:1,SrCl₂的回收率为52.47 %,所得一次固相产品在323.15 K下溶解并再次蒸发。钙和锶的摩尔比从1.73:1降至1.1:1,SrCl₂的回收率为78.67 %。  相似文献   

Preliminary Photometric Evidence of Starspot Umbrae and Penumbrae on Late-Type Active Stars     

Sergio Messina  Edward F. Guinan 《Astrophysics and Space Science》2006,304(1-4):191-193

We constrain the properties of the spotted regions on the photosphere of the active late-type star DX Leonis by comparing the observed amplitudes of light and color variations with synthetic amplitudes obtained by means of Dorren's spot model and computed for a grid of values of spot temperatures, areas and latitudes.  相似文献   

Experimental determination of the surface photometric contribution in the spectral reflectance deconvolution processes for a simulated martian crater-like regolithic target     

Aurélien M. Cord  Patrick C. Pinet  Yves Daydou  Serge D. Chevrel 《Icarus》2005,175(1):78-91

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Scattering properties of planetary regolith analogs     

Jennifer L. Piatek  Bruce W. Hapke  William D. Smythe 《Icarus》2004,171(2):531-545

The physics of scattering of electromagnetic waves by media in which the particles are in contact, such as planetary regoliths, has been thought to be relatively well understood when the particles are larger than the wavelength. However, this is not true when the particles are comparable with or smaller than the wavelength. We have measured the scattering parameters of planetary regolith analogs consisting of suites of well-sorted abrasives whose particles ranged from larger to smaller than the wavelength. We measured the variation of reflectance as the phase angle varied from 0.05° to 140°. The following parameters of the media were then deduced: the single scattering albedo, single scattering phase function, transport mean free path, and scattering, absorption, and extinction coefficients. A scattering model based on the equation of radiative transfer was empirically able to describe quantitatively the variation of intensity with angle for each sample. Thus, such models can be used to characterize scattering from regoliths even when the particles are smaller than the wavelength. The scattering parameters were remarkably insensitive to particle size. These results are contrary to theoretical predictions, but are consistent with earlier measurements of alumina abrasives that were restricted to small phase angles. They imply that a basic assumption made by virtually all regolith scattering models, that the regolith particles are the fundamental scattering units of the medium, is incorrect. Our understanding of scattering by regoliths appears to be incomplete, even when the particles are larger than the wavelength.  相似文献   

Ground-based photometric observations of Jupiter's inner satellites Thebe, Amalthea, and Metis at small phase angles     

I. Kulyk  K. Jockers 《Icarus》2004,170(1):24-34

We present the results of photometric measurements of the inner jovian satellites Thebe, Amalthea and Metis based on extensive optical observations taken from October 1999 to January 2002. The observations were made in the phase angle range from 8.1° to 0.3°. The Two-Channel Focal Reducer of the Max-Planck Institute for Aeronomy attached to the 2-m RCC telescope at Terskol Observatory (Pik Terskol, Northern Caucasus) was used in coronagraph mode. The observations were performed at a wavelength of 0.887 μm. Mean observational uncertainties corresponding to 1σ rms errors were 3% for the leading and trailing sides of Amalthea, 7 and 9% for the leading and trailing sides of Thebe and 9% for the leading side of Metis after taking into account the longitude brightness variations. Photometric data calibrated on an absolute scale were used to evaluate the near-opposition behavior of satellite brightness. All three satellites exhibit significant opposition brightening, but the strength of this effect, measured as the ratios of intensities at α₁=1.6° and α₂=6.7° does not vary significantly among these satellites. In order to measure the opposition surge parameters the empirical law proposed by Karkoschka and Hapke's model were used. The parameters of the satellite opposition effects are presented and discussed. The values of geometric albedos calculated with best-fit Hapke parameters are 0.096, 0.157, and 0.24 for Thebe, Amalthea, and Metis respectively. We found that the average leading/trailing ratios of surface reflectance at the measured phase angles are 1.53±0.05, 1.25±0.04, 1.04±0.08 for Amalthea, Thebe, and Metis.  相似文献   

Polarization and brightness opposition effects for the E-type Asteroid 64 Angelina     

Vera K. Rosenbush  Nikolai N. Kiselev  Klaus Jockers  Yuriy S. Efimov 《Icarus》2005,178(1):222-234

We present new polarimetric and photometric observations of the high-albedo Asteroid 64 Angelina in the UBVRI wavebands at phase angles ranging from 0.43° to 13.02° during oppositions in 1995, 1999, and 2000/2001. The polarization opposition effect has been observed in the form of a sharp peak of negative polarization with amplitude of about −0.4% centered at αmin≈1.8°, which is superimposed on the regular negative polarization branch. The amplitude of the polarization opposition effect appears to be apparition-dependent. Our photometric data confirm the early detected by Harris et al. [1989. Phase relations of high-albedo asteroids: The unusual opposition brightening of 44 Nysa and 64 Angelina. Icarus 81, 365-374] of a very strong and unusually narrow opposition spike, i.e., brightness opposition effect, for Angelina. Thus, 64 Angelina is the first asteroid for which both the polarization opposition effect and the brightness opposition effect have been detected. We observed that the polarization opposition effect as well as the regular negative polarization branch depends on the wavelength of scattered light, but in different manners. In addition, the colors B-V and V-R show little phase-angle dependence, while the color U-B increases with increasing phase angle, thus indicating that the amplitude of the brightness opposition effect is larger in the U band and almost the same in the B, V, and R bands. It appears that all colors indices begin to increase with decreasing phase angle to zero. The composite lightcurve computed with a period of 8.752 h has amplitude of 0.13 magnitude.  相似文献   

The ammonia-water system at high pressures: Implications for the methane of Titan     

O. Grasset  J. Pargamin 《Planetary and Space Science》2005,53(4):371-384

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Are the circular, dark features on Comet Borrelly's surface albedo variations or pits?     

Robert M Nelson  Laurence A Soderblom 《Icarus》2004,167(1):37-44

The highest resolution images of Comet 19P/Borrelly show many dark features which, upon casual inspection, appear to be low albedo markings, but which may also be shadows or other photometric variations caused by a depression in the local topography. In order to distinguish between these two possible interpretations we conducted a photometric analysis of three of the most prominent of these features using six of the highest quality images from the September 22, 2001 Deep Space 1 (DS1) flyby. We find that: 1. The radiance in the darkest parts of each feature increases as phase angle decreases, similarly to the radiance behavior of the higher albedo surrounding terrain. The dark features could be either fully illuminated low albedo spots or, alternatively, they could be depressions. No part of any of the three regions was in full shadow. 2. One of the regions has a radiance profile consistent with a rimmed depression, the second, with a simple depression with no rim, and the third with a low albedo spot. 3. The regolith particles are backscattering and carbon black is one of the few candidate regolith materials that might explain this low albedo. We conclude that Borrelly's surface is geologically complex to the limit of resolution of the images with a combination complex topography, pits, troughs, peaks and ridges, and some very dark albedo markings, perhaps a factor of two to three darker than the average 3-4% albedo of the surrounding terrains. Our technique utilizing measured radiance profiles through the dark regions is able to discriminate between rimmed depressions, rimless depressions and simple albedo changes not associated with topography.  相似文献   

Tracing exhumation record in high-pressure micaschists: A new tectonometamorphic model of the evolution of the eastern part of the Fore Sudetic Block,Kamieniec Metamorphic Belt,NE Bohemian Massif,SW Poland     

Jacek Szczepański  Marcin Goleń 《Chemie der Erde / Geochemistry》2022,82(1):125859

The Kamieniec Metamorphic Belt comprises a volcano-sedimentary succession exposed within a collision zone between the Saxothuringian and Brunovistulian crustal domains of the European Variscides. The studied rocks recorded two metamorphic episodes. The first episode, M₁, occurred at conditions of c. 485 ± 25 °C and 18 ± 1.8 kbar related to burial within a subduction zone. The subsequent episode, M₂, was linked to the final phases of exhumation to mid-crustal level, associated with pressure and temperature (P–T) conditions ranging from c. 520 ± 26 °C and 6 ± 0.6 kbar through 555 ± 28 °C and 7 kbar ± 0.7 to ~590 ± 30 °C and 3–4 ± 0.4 kbar. The documented deformation record is ascribed to three events, D₁ to D₃, interpreted as related to the burial and subsequent exhumation of the Kamieniec Metamorphic Belt. The D₁ event must have witnessed the subduction of the Kamieniec Metamorphic Belt rock succession whereas the D₂ event was associated with the exhumation and folding of the Kamieniec Metamorphic Belt in an E-W-directed shortening regime. A subsequent folding related to the D₂ event was initiated at HP conditions, however, the planar fabric produced during a late stage of the D₂ event, defined by a low-pressure mineral assemblage M₂, indicates that the D₂ final stage was synchronous with the onset of the M₂ episode. Consequently, the entire D₂ event seems to have been associated with the exhumation of the Kamieniec Metamorphic Belt to mid crustal level. The third deformation event D₃, synchronous with the M₂ episode, marked the last stage of the exhumation, and was linked to emplacement of granitoid veins and lenses. The latter resulted in heating and rheological weakening of the entire rock succession and in the formation of non-coaxial shear zones.  相似文献   

http://www.sciencedirect.com/science/article/pii/S1674987114001601   总被引：3，自引：2，他引：1  

Tim E.Johnson  Chris Clark  Richard J.M.Taylor  M.Santosh  Alan S.Collins 《地学前缘(英文版)》2015,6(3):373-387

Data from a migmatised metapelite raft enclosed within charnockite provide quantitative constraints on the pressure-temperature-time[P-T-t) evolution of the Nagercoil Block at the southernmost tip of peninsular India.An inferred peak metamorphic assemblage of garnet,K-feldspar.sillimanite,plagioclase,magnetite,ilmenite,spinel and melt is consistent with peak metamorphic pressures of 6-8 kbar and temperatures in excess of 900℃.Subsequent growth of cordierite and biotite record high-temperature retrograde decompression to around 5 kbar and 800 C.SHRIMP U-Pb dating of magmatic zircon cores suggests that the sedimentary protoliths were in part derived from felsic igneous rocks with Palaeoproterozoic crystallisation ages.New growth of metamorphic zircon on the rims of detrital grains constrains the onset of melt crystallisation,and the minimum age of the metamorphic peak,to around560 Ma.The data suggest two stages of monazite growth.The first generation of REE-enriched monazite grew during partial melting along the prograde path at around 570 Ma via the incongruent breakdown of apatite.Relatively REE-depleted rims,which have a pronounced negative europium anomaly,grew during melt crystallisation along the retrograde path at around 535 Ma.Our data show the rocks remained at suprasolidus temperatures for at least 35 million years and probably much longer,supporting a long-lived high-grade metamorphic history.The metamorphic conditions,timing and duration of the implied clockwise P-T-t path are similar to that previously established for other regions in peninsular India during the Ediacaran to Cambrian assembly of that part of the Gondwanan supercontinent.  相似文献