Solubility of FeO in (Mg,Fe)SiO₃ perovskite and the post-perovskite phase transition     

Shigehiko Tateno  Kei Hirose  Nagayoshi Sata  Yasuo Ohishi 《Physics of the Earth and Planetary Interiors》2007,160(3-4):319-325

Phase relations in Mg_0.5Fe_0.5SiO₃ and Mg_0.25Fe_0.75SiO₃ were investigated in a pressure range from 72 to 123 GPa on the basis of synchrotron X-ray diffraction measurements in situ at high-pressure and -temperature in a laser-heated diamond-anvil cell (LHDAC). Results demonstrate that Mg_0.5Fe_0.5SiO₃ perovskite is formed as a single phase at 85–108 GPa and 1800–2330 K, indicating a high solubility of FeO in (Mg,Fe)SiO₃ perovskite at high pressures. Post-perovskite appears coexisting with perovskite in Mg_0.5Fe_0.5SiO₃ above 106 GPa at 1410 K, the condition very close to the post-perovskite phase transition boundary in pure MgSiO₃. The coexistence of perovskite and post-perovskite was observed to 123 GPa. In addition, post-perovskite was formed coexisting with perovskite also in Mg_0.25Fe_0.75SiO₃ bulk composition at 106–123 GPa. In contrast to earlier experimental and theoretical studies, these results show that incorporation of FeO stabilizes perovskite at higher pressures. This could be due to a larger ionic radius of Fe²⁺ ion, which is incompatible with a small Mg²⁺ site in the post-perovskite phase.  相似文献   

The Role of Pressure in Producing Compositional Diversity in Intraplate Basaltic Magmas   总被引：3，自引：0，他引：3  

Whitaker  M. L.; Nekvasil  H.; Lindsley  D. H.; Difrancesco  N. J. 《Journal of Petrology》2007,48(2):365-393

Basaltic magmas found in intraplate suites appear to followmore than one differentiation trend. Many ocean island suitesfollow the ocean island tholeiitic trend, with the basalts differentiatingfrom olivine tholeiite through basaltic andesite, andesite,and dacite to sodic rhyolite. Many continental intraplate magmaticregimes, such as those of the Snake River Plain and the plutonicsequences associated with massif anorthosites, follow the potassicsilica-saturated alkalic trend, in which basalt differentiatesfrom olivine tholeiite through ferrobasalt (jotunite or ferrodiorite),Fe-rich intermediate rocks (trachybasalt or monzonite), andtrachyte (syenite) to potassic rhyolites and granites. Crystallizationexperiments on an olivine tholeiite from the Snake River Plainshow that the basaltic portions of the ocean island tholeiitictrend and the potassic silica-saturated alkalic trend (whichleads to strong alkali, P, Ti, and Fe enrichment and silicadepletion) can arise from the same ‘dry’ tholeiiticparental magma. These compositional differences are inducedby changes in phase equilibria as a function of pressure, withthe ocean island tholeiitic series arising from crystal–liquiddifferentiation at low pressure and the potassic silica-saturatedalkalic series arising via differentiation at elevated pressures. KEY WORDS: tholeiite differentiation; experimental petrology; phase equilibria; ferrodiorite; ferrobasalt  相似文献   

LiMn_2O_4的溶胶─凝胶─酯化法合成及性能Ⅱ　立方尖晶石的形成及其形貌     

尉继英  孙长敏  高海春 《盐湖研究》1998,(1)

以溶胶-凝胶-酯化法在220℃即可得到纯相的LixMn2O4（0.762＜x＜1.139）尖晶石粉体材料。它在880℃时发生立方相向四方相的转变：900℃－1000℃间,四方相渐变为正交相LiMnO2,过程中有Li2MnO3生成。应用SEM、TEM观测了材料的粘度及形貌,其粒度10－40nm,粒子间极易团聚成为1-206μm的团块。以BET法测其比表面为3.6m2／g。  相似文献   

干涉雷达在DEM测量中的精度影响及处理方法   总被引：1，自引：0，他引：1  

郭泾平  彭军  向茂生 《测绘学院学报》1998,(3)

干涉合成孔径雷达 (INSAR)为数字高程模型 (DEM)测量提供了一种新的手段。它具有同时获取三维信息、测量范围广、空间和高程分辨率高等优点。文中首先扼要介绍了干涉雷达的原理 ,然后重点讨论几个影响测量精度的因素及其处理方法 ,如相关、运动补偿、配准、相位展开等。  相似文献   

淮河流域洪涝变化吸引子维数研究   总被引：15，自引：1，他引：14  

周寅康  包浩生 《地理科学》1998,18(4):362-367

淮河流域洪涝序列的功率谱表现出了较好的混沌谱特征,这是序列呈分形结构的内在原因。洪涝序列及其不同平滑序列的关联维数表明,序列平滑程度越大,关联维数越小,关联维数反映了序列所在系统的层次,是系统结构复杂性的重要量度,是 系统建模所需独立变量的控制参数。要恰当地描述淮河流域洪涝发生系数,需构造至少５个状态变量的动力学系统。  相似文献   

1997年9月三水3.7和4.4级地震特征初析     

王正尚  康英 《华南地震》1998,18(1):125-129

对１９９７年９月２３日和２６日两次三水有感地震的特征进行了初步分析,认为这两次地震具有震前和震后地震活动水平低、面波发育和低震级高烈度等特性;震区的主压应力为北北西方向,两震的受力方向基本一致,但断层面解明显不同。  相似文献   

Petrogenesis of impure dolomitic marble from the Dabie Mountains, central China   总被引：2，自引：0，他引：2  

S. Omori  J. G. Liou  R. Y. Zhang  & Y. Ogasawara 《Island Arc》1998,7(1-2):98-114

Petrogeneses of impure dolomitic marble and enclosed eclogite from the Xinyan area, Dabie ultrahigh-pressure (UHP) metamorphic terrane, central China were investigated with a special focus on fluid characteristics. Identified carbonate-bearing UHP assemblages are Dol + Coe ± Arg (or Mgs) ± Ap, Dol + Omp ± Coe ± Ap ± Arg (or Mgs), Phen + Omp + Coe + Dol ± Arg and Dol + Coe + Phen + Rt ± Omp ± Arg ± Ap. Retrograde assemblages are characterized by symplectitic replacement of Tr–Ab and Di–Ab after omphacite, and Phl–Pl symplectite after phengite. The P–T conditions of UHP metamorphism were estimated to be P > 2.7 GPa and T > 670 °C by the occurrence of coesite inclusions in garnet in enclosed eclogite and garnet–clinopyroxene geothermometer. The P–T conditions of initial amphibolitization were estimated to be 620 < T < 670 °C and 1.1 < P < 1.3 GPa by calcite–dolomite solvus thermometer and mineral parageneses. Phase relations in P–T– X CO ₂ space in the systems NaAl–CMSCH and KCMASCH were calculated in order to constrain fluid compositions. Compositions and parageneses of UHP-stage minerals suggest the presence of fluid in UHP and exhumation stages. Occurrence of retrograde low-variance assemblages indicates that fluid composition during amphibolitization was buffered. A metastable persistence of magnesite and very restricted occurrence of calcite, magnesite and dolomite suggest a low fluid content in the post-amphibolitization stage.  相似文献   

察尔汗盐湖盐田渗漏及其工程地质条件分析     

王石军 《化工矿产地质》1998,20(4):301-307

１９８１年以来对察尔汗盐湖三次渗漏试验结果表明,盐田渗漏是盐田土层与外界条件综合作用的结果,在盐田建设和生产管理过程中,应结合不同地点的土层特性、工程地质条件和其它有关条件,采取不同的处理措施。  相似文献   

大气动力学方程组的定性理论及其应用   总被引：9，自引：2，他引：7  

李建平  丑纪范 《大气科学》1998,22(4):443-453

基于完整的湿大气动力学方程组,利用无穷维动力系统的新理论和新方法,系统讨论了强迫耗散的非线性大气系统的定性理论及其应用。将完整的强迫耗散非线性湿大气动力学方程组化为Hilbert空间中一个等价的算子方程,研究了算子的性质及其物理意义,在此基础上得到湿大气系统全局吸引子的存在性定理,揭示出系统向外源的非线性适应特征,并把结果推广到有地形动力作用和非定常外源强迫的情形。同时探讨了大气方程组惯性流形的存在,大气多平衡态产生的根源以及强迫、耗散和非线性对系统解的渐近行为的影响。在理论结果的基础上,提出强迫耗散的非线性动力系统中存在三类时间边界层、方程组简化准则、分解算法的算子约束原则以及支撑吸引子基底的少数自由度的构造方法,探讨了理论在非线性发展方程差分格式的设计和计算稳定性分析、多平衡态的数值分析、数值模式延伸预报的改进、短期气候预测以及一类中尺度系统分析与预测中的应用,指出描述长期过程动力学模式的必备条件,给出初值与模式相协调的合理解释。最后,对今后的研究方向作了展望。  相似文献   

Constraining peak P–T conditions in UHP eclogites: calculated phase equilibria in kyanite‐ and phengite‐bearing eclogite of the Tromsø Nappe,Norway     

M. JANÁK  E. J. K. RAVNA  K. KULLERUD 《Journal of Metamorphic Geology》2012,30(4):377-396

Kyanite‐ and phengite‐bearing eclogites have better potential to constrain the peak metamorphic P–T conditions from phase equilibria between garnet + omphacite + kyanite + phengite + quartz/coesite than common, mostly bimineralic (garnet + omphacite) eclogites, as exemplified by this study. Textural relationships, conventional geothermobarometry and thermodynamic modelling have been used to constrain the metamorphic evolution of the Tromsdalstind eclogite from the Tromsø Nappe, one of the biggest exposures of eclogite in the Scandinavian Caledonides. The phase relationships demonstrate that the rock progressively dehydrated, resulting in breakdown of amphibole and zoisite at increasing pressure. The peak‐pressure mineral assemblage was garnet + omphacite + kyanite + phengite + coesite, inferred from polycrystalline quartz included in radially fractured omphacite. This omphacite, with up to 37 mol.% of jadeite and 3% of the Ca‐Eskola component, contains oriented rods of silica composition. Garnet shows higher grossular (X_Grs = 0.25–0.29), but lower pyrope‐content (X_Prp = 0. 37–0.39) in the core than the rim, while phengite contains up to 3.5 Si pfu. The compositional isopleths for garnet core, phengite and omphacite constrain the P–T conditions to 3.2–3.5 GPa and 720–800 °C, in good agreement with the results obtained from conventional geothermobarometry (3.2–3.5 GPa & 730–780 °C). Peak‐pressure assemblage is variably overprinted by symplectites of diopside + plagioclase after omphacite, biotite and plagioclase after phengite, and sapphirine + spinel + corundum + plagioclase after kyanite. Exhumation from ultrahigh‐pressure (UHP) conditions to 1.3–1.5 GPa at 740–770 °C is constrained by the garnet rim (X_Ca^Grt = 0.18–0.21) and symplectite clinopyroxene (X_Na^Cpx = 0.13–0.21), and to 0.5–0.7 GPa at 700–800 °C by sapphirine (X_Mg = 0.86–0.87) and spinel (X_Mg = 0.60–0.62) compositional isopleths. UHP metamorphism in the Tromsø Nappe is more widespread than previously known. Available data suggest that UHP eclogites were uplifted to lower crustal levels rapidly, within a short time interval (452–449 Ma) prior to the Scandian collision between Laurentia and Baltica. The Tromsø Nappe as the highest tectonic unit of the North Norwegian Caledonides is considered to be of Laurentian origin and UHP metamorphism could have resulted from subduction along the Laurentian continental margin. An alternative is that the Tromsø Nappe belonged to a continental margin of Baltica, which had already been subducted before the terminal Scandian collision, and was emplaced as an out‐of‐sequence thrust during the Scandian lateral transport of nappes.  相似文献