Distribution,sources and potential toxicological significance of polycyclic aromatic hydrocarbons (PAHs) in surface soils of the Yellow River Delta,China   总被引：1，自引：0，他引：1  

Hongming Yuan  Tiegang Li  Xigui Ding  Guangming Zhao  Siyuan Ye 《Marine pollution bulletin》2014

PAH concentrations of 61 surface soil samples collected from the Yellow River Delta (YRD), China were measured to determine occurrence levels, sources, and potential toxicological significance of PAHs. The total concentrations of ∑PAHs ranged from 27 to 753 ng/g d.w., with a mean of 118 ± 132 ng/g. The highest concentrations was found in the mid-southern part of the YRD (753 ng/g), which was associated with the oil exploration. The ratios indicated that the PAHs throughout the YRD were mostly of pyrogenic origin; while various sites in mid-southern part in the region were derived mainly from the petrogenic sources. Multivariate statistical analyses supported that the PAHs in surface soils of the YRD were principally from the coal and biomass combustion, petroleum spills, and/or vehicular emissions. The toxic assessment suggested that the PAHs in soils were at low potential of ecotoxicological contamination level for the YRD.  相似文献   

δ15N variation in Ulva lactuca as a proxy for anthropogenic nitrogen inputs in coastal areas of Gulf of Gaeta (Mediterranean Sea)     

《Marine pollution bulletin》2014,85(1-2):76-82

We tested the capacity of Ulva lactuca to mark N sources across large marine areas by measuring variation in its δ¹⁵N at several sites in the Gulf of Gaeta. Comparisons were made with the macroalga Cystoseira amentacea. Variation of δ¹⁵N values was assessed also in the coastal waters off the Circeo Natural Park, where U. lactuca and C. amentacea were harvested, as these waters are barely influenced by human activities and were used as reference site. A small fragment from each frond was preserved before deployment in order to characterize the initial isotopic values. After 48 h of submersion, U. lactuca was more responsive than C. amentacea to environmental variation and δ¹⁵N enrichment in the Gulf of Gaeta was observed. The spatial distribution of δ¹⁵N enrichment indicated that different macro-areas in the Gulf were affected by N inputs from different origins. Comparison of the δ¹⁵N values of fragments taken from the same transplanted frond avoided bias arising from natural isotopic variability.  相似文献   

Enzymatic methods for the determination of pollution in seawater using salt resistant alkaline phosphatase from eggs of the sea urchin Strongylocentrotus intermedius     

《Marine pollution bulletin》2014,80(1-2):188-195

A new salt resistant alkaline phosphatase from eggs of the sea urchin Strongylocentrotus intermedius (StAP) has been shown to have a unique property to hydrolyze substrate in seawater without loss of enzymatic activity. The enzyme has pH optimum at 8.0–8.5. Model experiments showed various concentrations of copper, zinc, cadmium and lead added to seawater or a standard buffer mixture to inhibit completely the enzyme activity at the concentrations of 15–150 μg/l. StAP sensitivity to the presence in seawater of metals, pesticides, detergents and oil products appears to be considerably less. Samples of seawater taken from aquatic areas of the Troitsy Bay of the Peter the Great Bay, Japan Sea have been shown to inhibit the enzyme activity; the same was shown for the samples of fresh waters. The phosphatase inhibition assay developed proved to be highly sensitive, technically easy-to use allowing to test a great number of samples.  相似文献   

Deep-sea faunal communities associated with a lost intermodal shipping container in the Monterey Bay National Marine Sanctuary,CA     

Josi R. Taylor  Andrew P. DeVogelaere  Erica J. Burton  Oren Frey  Lonny Lundsten  Linda A. Kuhnz  P.J. Whaling  Christopher Lovera  Kurt R. Buck  James P. Barry 《Marine pollution bulletin》2014

Carrying assorted cargo and covered with paints of varying toxicity, lost intermodal containers may take centuries to degrade on the deep seafloor. In June 2004, scientists from Monterey Bay Aquarium Research Institute (MBARI) discovered a recently lost container during a Remotely Operated Vehicle (ROV) dive on a sediment-covered seabed at 1281 m depth in Monterey Bay National Marine Sanctuary (MBNMS). The site was revisited by ROV in March 2011. Analyses of sediment samples and high-definition video indicate that faunal assemblages on the container’s exterior and the seabed within 10 m of the container differed significantly from those up to 500 m. The container surface provides hard substratum for colonization by taxa typically found in rocky habitats. However, some key taxa that dominate rocky areas were absent or rare on the container, perhaps related to its potential toxicity or limited time for colonization and growth. Ecological effects appear to be restricted to the container surface and the benthos within ∼10 m.  相似文献   

Use of Mosses as Biomonitors of Major,Minor and Trace Element Deposition Around the Largest Thermal Power Plant in Serbia          下载免费PDF全文

Mirjana Ćujić  Snežana Dragović  Marko Sabovljević  Latinka Slavković‐Beškoski  Milan Kilibarda  Jelena Savović  Antonije Onjia 《洁净——土壤、空气、水》2014,42(1):5-11

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Vertical Distribution and Mobility of Heavy Metals in Agricultural Soils along Jishui River Affected by Mining in Jiangxi Province,China   总被引：1，自引：0，他引：1       下载免费PDF全文

Guannan Liu  Wei Xue  Li Tao  Xinhui Liu  Jing Hou  Meaghan Wilton  Ding Gao  Anjian Wang  Ruiping Li 《洁净——土壤、空气、水》2014,42(10):1450-1456

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Atmospheric Nitrogen and Phosphorus Deposition at Three Sites in Nanjing,China, and Possible Links to Nitrogen Deposition Sources   总被引：1，自引：0，他引：1       下载免费PDF全文

Liying Sun  Yinglie Liu  Jinyang Wang  Mohammad Aslam K. Khalil  Jianwen Zou  Zhengqin Xiong 《洁净——土壤、空气、水》2014,42(11):1650-1659

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Organoclays as Sorbent Material for Phenolic Compounds: A Review          下载免费PDF全文

Muhammad Nafees  Amir Waseem 《洁净——土壤、空气、水》2014,42(11):1500-1508

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Hydrochemical variation in the springs water between Jerusalem–Ramallah Mountains and Jericho Fault,Palestine     

Saed Khayat  Peter Möller  Stefan Geyer  Amer Marei  Christian Siebert  Fayez Abu Hilo 《Environmental Geology》2009,57(8):1739-1751

The spatial and temporal changes of the composition of the groundwater from the springs along the Wadi Qilt stream running from the Jerusalem–Ramallah Mountains towards the Jericho Plain is studied during the hydrological year 2006/2007. The residence time and the intensity of recharge play an important role in controlling the chemical composition of spring water which mainly depends on distance from the main recharge area. A very important factor is the oxidation of organics derived from sewage and garbage resulting in variable dissolved CO₂ and associated HCO₃ ⁻ concentration. High CO₂ yields lower pH values and thus under-saturation with respect to calcite and dolomite. Low CO₂ concentrations result in over-saturation. Only at the beginning and at the end of the rainy season calcite saturation is achieved. The degradation of dissolved organic matter is a major source for increasing water hardness. Besides dissolution of carbonates dissolved species such as nitrate, chloride, and sulfate are leached from soil and aquifer rocks together with only small amounts of Mg. Mg not only originates from carbonates but also from Mg–Cl waters are leached from aquifer rocks. Leaching of Mg–Cl brines is particularly high at the beginning of the winter season and lowest at its end. Two zones of recharge are distinguishable. Zone 1 represented by Ein Fara and Ein Qilt is fed directly through the infiltration of meteoric water and surface runoff from the mountains along the eastern mountain slopes with little groundwater residence time and high flow rate. The second zone is near the western border of Jericho at the foothills, which is mainly fed by the under-groundwater flow from the eastern slopes with low surface infiltration rate. This zone shows higher groundwater residence time and slower flow rate than zone 1. Groundwater residence time and the flow rate within the aquifer systems are controlled by the geological structure of the aquifer, the amount of active recharge to the aquifer, and the recharge mechanism. The results of this study may be useful in increasing the efficiency of freshwater exploitation in the region. Some precautions, however, should be taken in future plans of artificial recharge of the aquifers or surface-water harvesting in the Wadi. Because of evaporation and associated groundwater deterioration, the runoff water should be artificially infiltrated in zones of Wadis with high storage capacity of aquifers. Natural infiltration along the Wadis lead to evaporation losses and less quality of groundwater.  相似文献   

Magnetic Susceptibility and Heavy Metals Distribution from Risk‐cultivated Soil around the Iron–Steel Plant,China     

Pingguo Yang  Miao Yang  Hongbo Shao 《洁净——土壤、空气、水》2012,40(6):615-618

Magnetic susceptibility is a non‐conventional way that can be used for evaluating proxy soil heavy metals pollution. The paper monitors available heavy metals (Cu, Fe, Zn, and Mn) present in cultivated soils around iron–steel plant by soil magnetic susceptibility. Our study was located in an area with high pollution with small grid density of 250 m in China. Results showed that low field magnetic susceptibility was significantly correlated with available Cu, Zn, and Mn. No clear association exists between magnetic susceptibility and available Fe, soil organic matter, pH. Frequency dependent susceptibility >5% suggests the possible presence of super‐paramagnetic particles, fly ashes produced during coal combustion.  相似文献