Fluid and source magma evolution of the Questa porphyry Mo deposit,New Mexico,USA   总被引：14，自引：1，他引：13  

Leonhard M. Klemm  Thomas Pettke  Christoph A. Heinrich 《Mineralium Deposita》2008,43(5):533-552

Combined fluid inclusion microthermometry and microanalysis by laser ablation inductively coupled plasma mass spectrometry (LA-ICPMS) are used to constrain the hydrothermal processes forming a typical Climax-type porphyry Mo deposit. Molybdenum mineralisation at Questa occurred in two superimposed hydrothermal stages, a magmatic-hydrothermal breccia and later stockwork veining. In both stages, texturally earliest fluids were single-phase, of low salinity (~7 wt.% NaCl_equiv.) and intermediate-density. Upon decompression to ~300 bar, they boiled off a vapour phase, leaving behind a residual brine (up to 45 wt.% NaCl_equiv) at temperatures of ~420°C. The highest average Mo concentrations in this hot brine were ~500 μg/g, exceeding the Mo content of the intermediate-density input fluid by about an order of magnitude and reflecting pre-concentration of Mo by fluid phase separation prior to MoS₂ deposition from the brine. Molybdenum concentrations in brine inclusions, then, decrease down to 5 μg/g, recording Mo precipitation in response to cooling of the saline liquid to ~360°C. Molybdenite precipitation from a dense, residual and probably sulphide-depleted brine is proposed to explain the tabular shape of the ore body and the absence of Cu-Fe sulphides in contrast to the more common Cu-Mo deposits related to porphyry stocks. Cesium and Rb concentrations in the single-phase fluids of the breccia range from 2 to 8 and from 40 to 65 μg/g, respectively. In the stockwork veins, Cs and Rb concentrations are significantly higher (45–90 and 110–230 μg/g, respectively). Because Cs and Rb are incompatible and hydrothermally non-reactive elements, the systematic increase in their concentration requires two distinct pulses of fluid exsolution from a progressively more fractionated magma. By contrast, major element and ore metal concentrations of these two fluid pulses remain essentially constant. Mass balance calculations using fluid chemical data from LA-ICPMS suggest that at least 25 km³ of melt and 7 Gt of deep input fluid were necessary to provide the amount of Mo contained in the stockwork vein stage alone. While the absolute amounts of fluid and melt are uncertain, the well-constrained element ratios in the fluids together with empirical fluid/melt partition coefficients derived from the inclusion analyses suggest a high water content of the source melt of ~10%. In line with other circumstantial evidence, these results suggest that initial fluid exsolution may have occurred at a confining pressure exceeding 5 kbar. The source of the molybdenum-mineralising fluids probably was a particularly large magma chamber that crystallised and fractionated in the lower crust or at mid-crustal level, well below the shallow intrusions immediately underlying Questa and other porphyry molybdenum deposits. Electronic supplementary material  The online version of this article (doi:) contains supplementary material, which is available to authorized users.  相似文献   

Age and depositional environment of the Draa Sfar massive sulfide deposit, Morocco     

C. Moreno  R. Sáez  F. González  G. Almodóvar  M. Toscano  G. Playford  A. Alansari  S. Rziki  A. Bajddi 《Mineralium Deposita》2008,43(8):891-911

The Draa Sfar mineralization consists of two main stratabound orebodies, Sidi M’Barek and Tazacourt, located north and south of the Tensift River (“Oued Tessift”), respectively. Each orebody is comprised by at least two massive sulfide lenses. The hosting rocks are predominantly black shales, although minor rhyolitic rocks are also present in the footwall to the southern orebody. Shales, rhyolitic volcanic rocks, and massive sulfides are all included into the Sarhlef Series, which is recognized as one of the main stratigraphic units of the Moroccan Variscan Meseta. Hydrothermal activity related with an anomalous thermal gradient, together with a high sedimentation rate in a tectonically driven pull-apart marine basin, favored the accumulation of organic-rich mud in the deepest parts of the basin and the sedimentary environment suitable for massive sulfide deposition and preservation. This took place by replacement of the hosting unlithified wet mud below the sediment–water interface. Geochemical data suggest a sedimentary environment characterized by oxic water column and anoxic sediment pile with the redox boundary below the sediment–water interface. The low oxygen availability within the sediment pile inhibited oxidation and pyritization of pyrrhotite. Biostratigraphic analysis, based on the palynological content of the hosting black shales, restricts the age of the sulfides to the Asbian substage (mid-Mississippian). This age is consistent with earlier geochronological constraints.  相似文献   

Anhydrite pseudomorphs and the origin of stratiform Cu–Co ores in the Katangan Copperbelt (Democratic Republic of Congo)   总被引：1，自引：1，他引：0  

Ph. Muchez  P. Vanderhaeghen  H. El Desouky  J. Schneider  A. Boyce  S. Dewaele  J. Cailteux 《Mineralium Deposita》2008,43(5):575-589

The stratiform Cu–Co ore mineralisation in the Katangan Copperbelt consists of dispersed sulphides and sulphides in nodules and lenses, which are often pseudomorphs after evaporites. Two types of pseudomorphs can be distinguished in the nodules and lenses. In type 1 examples, dolomite precipitated first and was subsequently replaced by Cu–Co sulphides and authigenic quartz, whereas in type 2 examples, authigenic quartz and Cu–Co sulphides precipitated prior to dolomite and are coarse-grained. The sulphur isotopic composition of the copper–cobalt sulphides in the type 1 pseudomorphs is between −10.3 and 3.1‰ relative to the Vienna Canyon Diablo Troilite, indicating that the sulphide component was derived from bacterial sulphate reduction (BSR). The generation of during this process caused the precipitation and replacement of anhydrite by dolomite. A second product of BSR is the generation of H₂S, resulting in the precipitation of Cu–Co sulphides from the mineralising fluids. Initial sulphide precipitation occurred along the rim of the pseudomorphs and continued towards the core. Precipitation of authigenic quartz was most likely induced by a pH decrease during sulphide precipitation. Fluid inclusion data from quartz indicate the presence of a high-salinity (8–18 eq. wt.% NaCl) fluid, possibly derived from evaporated seawater which migrated through the deep subsurface. ⁸⁷Sr/⁸⁶Sr ratios of dolomite in type 1 nodules range between 0.71012 and 0.73576, significantly more radiogenic than the strontium isotopic composition of Neoproterozoic marine carbonates (⁸⁷Sr/⁸⁶Sr = 0.7056–0.7087). This suggests intense interaction with siliciclastic sedimentary rocks and/or the granitic basement. The low carbon isotopic composition of the dolomite in the pseudomorphs (−7.02 and −9.93‰ relative to the Vienna Pee Dee Belemnite, V-PDB) compared to the host rock dolomite (−4.90 and +1.31‰ V-PDB) resulted from the oxidation of organic matter during BSR.  相似文献   

Mineralogy and composition of Kuroko deposits from northeastern Honshu and their possible modern analogues from the Izu-Ogasawara (Bonin) Arc south of Japan: Implications for mode of formation     

G.P. Glasby  K. Iizasa  M. Hannington  H. Kubota  K. Notsu 《Ore Geology Reviews》2008,34(4):547-560

The Kuroko deposits of NE Honshu are a key type deposit for the study of volcanogenic massive sulfide deposits. However, these deposits have not been studied in detail since the early 1980's and knowledge of their mode of formation is now dated. In this study, we present the analysis of 12 samples of the Kuroko deposits, 12 samples of submarine hydrothermal minerals from the Sunrise deposit and 6 samples from Suiyo Seamount, both of which are located on the Izu-Ogasawara (Bonin) Arc, for 27 elements. For the Kuroko deposit, Cd>Sb>Ag>Pb>Hg>As>Zn>Cu are highly enriched, Au>Te>Bi>Ba>Mo are moderately enriched, In>Tl are somewhat enriched and Fe is not significantly enriched relative to the average continental crust. Within each of these deposits, a similar pattern of element associations is apparent: Zn–Pb with As, Sb, Cd, Ag, Hg, Tl and Au; Fe–Cu–Ba with As, Sb, Ag, Tl, Mo, Te and Au; Si–Ba with Ag and Au; CaSO₄. The enrichment of the chalcophilic elements in these deposits is consistent with hydrothermal leaching of these elements from the host rocks which are dominantly rhyolite–dacite in the case of the Kuroko deposits, rhyolite in the case of the Sunrise deposit and dacite–rhyolite in the case of the Suiyo Seamount deposit. However, this pattern of element enrichment is also similar to that observed in fumarolic gas condensates from andesitic volcanoes. This suggests that there may be a significant magmatic contribution to the composition of the hydrothermal fluids responsible for the formation of the Kuroko deposits, although it is not yet possible to quantify the relative contributions of these two sources of elements.The compositional data show that Sunrise and Suiyo Seamount deposits are much closer compositionally to the Kuroko deposits from NE Honshu than are the submarine hydrothermal deposits from the JADE site in the Okinawa Trough which contain, on average, significantly higher concentrations of Pb, Zn, Sb, As and Ag than each of these deposits. In spite of the greater similarity in tectonic setting of the Hokuroku Basin in which the Kuroko deposits formed to the Okinawa Trough (intracontinental rifted back-arc basin) compared to Myojin Knoll and Suiyo Seamount (active arc volcanoes), it appears that submarine hydrothermal deposits from Myojin Knoll and Suiyo Seamount are closer analogues of the Kuroko deposit than are those from the Okinawa Trough. The present data are consistent with the magmatic hydrothermal model for the formation of Kuroko-type deposits as formulated by Urabe and Marumo [Urabe, T., Marumo, K., 1991. A new model for Kuroko-type deposits of Japan. Episodes 14, 246–251].  相似文献   

河南省栾川县罗村钼矿成矿特征及找矿   总被引：2，自引：1，他引：1  

李新 《地质与勘探》2008,44(6):21-26

通过对河南省栾川县罗村钼矿区域地质背景、矿床地质特征与南泥湖、三道庄及东沟超大型钼矿的综合对比、分析、研究,总结归纳了矿区NWW构造形迹、小岩体与钼矿成矿关系、围岩对成矿的控制作用、围岩蚀变与成矿的关系、地球化学异常与钼矿床的关系等成矿特征.根据罗村钼矿的成矿特征,初步指出今后的找矿方向.  相似文献   

西天山特克斯达坂库勒萨依序列埃达克岩的确立及钼找矿意义   总被引：9，自引：6，他引：3  

李永军  辜平阳  庞振甲  栾新东  佟丽莉 《岩石学报》2008,24(12):2713-2719

库勒萨依序列斑岩体δ平均3.05,属于钙碱性系列岛弧浅成岩。 SiO₂含量为57.06％~70.74％,高Al₂O₃、Na₂O、Sr和相对富集LREE,低MgO、Y、Yb,强烈亏损HREE。Na₂O/K₂O＞1,Sr/Y平均57.67,正Eu异常,因而具有典型O型埃达克岩特征。库勒萨依序列斑岩体与Mo异常套合好,已发现钼矿体,找矿前景良好。该埃达克岩的确立,对深化西天山区域成矿规律和指导今后找矿具有借鉴和指导意义。  相似文献   

松花江哈尔滨段河床冲积物与沙尘天气关系的讨论          下载免费PDF全文

何葵 康春国  张丽娟 《中国地质》2008,35(1):150-156

笔者重点分析了哈尔滨河床冲积物的粒度组成,结合沙尘沉降物的粒度组成,论述了裸露河床冲积物对沙尘天气的影响。河床冲积物及沙尘沉降物粒度分析结果显示,裸露河床冲积物粒径大于63μm的颗粒占84%以上,而小于63μm粒径的颗粒很少,小于10μm的颗粒微乎其微;沙尘沉降物中小于63μm的粉粘颗粒含量在90%以上。对河床冲积物而言,无论是砂级别的粗颗粒物质还是粉粘级别的细颗粒物质都与沙尘沉降物的粒度无相关性,对沙尘暴物质组成没有影响或影响很小。受砂级别的粗颗粒物质扬起高度和搬运距离的限制,沙尘暴发生时,裸露河床中的冲积物颗粒不会被远距离搬运而影响到整个哈尔滨地区,真正影响整个哈尔滨地区的沙尘物质是小于63μm的粉砂级别的颗粒,特别是小于10μm的粉尘。笔者认为对哈尔滨沙尘天气产生重大影响的是含有大量细颗粒物质的城市地表土和建筑土等,这些地域是防止沙尘天气的重点治理区域。  相似文献   

南极冰退与深圳湾北岸海平面变化的地质记录     

郑洪汉  黄宝林 《热带海洋学报》1996,(4)

南极冰层的冰量为２４．５×１０６ｋｍ３，占地球总冰量的９０％以上，南极冰川进退控制着全球海平面变化和气候波动。酉部南极乔治王岛第四纪冰碛与湖积剖面记录了近１２０００ａ来南极曾于距今１１０００ａ，９０００ａ和６１００ａ出现过３次快速的冰消过程，近６０００ａ来是一小幅度冷暖交替的气候波动过程。深圳湾北岸潮间带堆积是在近６０００ａ以来发育的，堆积物的环境记录表明，海平面呈周期性升降变化，波动周期平均为６７０ａ，低海面时期发生于距今５５００—４９００ａ，３９００—３６００ａ，２４００—２２００ａ和１３００—１２００ａ。相邻低海面间则是海面上升时期，每一升降周期的海平面变化幅度为８０ｃｍ左右，近１００ａ的现代增温，海平面处于上升阶段，上升速率为２—３ｍｍ·ａ（－１）。  相似文献   

安徽宣城地区中晚更新世风成堆积与环境变迁   总被引：25，自引：7，他引：25  

杨达源  房迎三 《海洋地质与第四纪地质》1991,11(2):97-104

通过对宣城向阳中晚更新世沉积剖面的综合研究,认为该剖面与中国北方同时代的黄土—古土壤剖面相比较,虽然长江下游以南地区中晚更新世多个冰期中风成堆积的单层厚度与累积厚度,亦即风成物质的沉积通量与沉积速率均比北方黄土区要小,但它们所反映的气候与环境的变化具有明显的可比性。  相似文献   

南海深海盆地沉积柱样中的浊流沉积     

陈峰  蔡锋 《台湾海峡》1992,11(4):339-344

本文根据南海深海盆地三个沉积柱样的粒度结构、地球化学、微体古生物等特征分析,深讨了南海深海盆地细粒沉积物的浊积现象。结果表明,位于南海北部陆架斜坡上KL37孔的浊流沉积现象并不明显;位于陆架斜坡和深海盆地交界处的KL29孔存在着大量的浊积层,属于浊流沉积和半远洋沉积环境;位于南海盆地中部的KL91孔虽然已属于远洋性沉积环境,但除出现火山灰沉积外,浊流沉积作用仍然是相当活跃的。  相似文献