Determining Pressure with Daughter Minerals in Fluid Inclusion by Raman Spectroscopy: Sphalerite as an Example     

YANG Yuping  ZHENG Haifei  ZHANG Lifei 《《地质学报》英文版》2009,83(3):628-632

Abstract: Raman frequency of some materials, including minerals, molecules and ions, shifts systematically with changing pressure and temperature. This property is often used as a pressure gauge in high pressure experiments with the hydrothermal diamond anvil cell (HDAC). Since the system of fluid inclusion is similar to that of HDAC, it can also be used to determine the internal pressure of fluid inclusions. Sphalerite is a common daughter mineral. In this study, the frequency shift of the 350 cm?1 peak of sphalerite has been studied from 296 to 523 K and from 0.07 to 2.00 GPa using the HDAC. The global slope of the isotherms (?n350/?p)T is 0.0048 in the studied pressure range. No significant variation of the slopes with temperature has been observed. The correlation between the frequency shift of the 350 cm?1 peak of sphalerite and pressure and temperature is constrained as P=208.33(?np)350+3.13T?943.75. This relationship may be used to estimate the internal pressure of the sphalerite-bearing fluid inclusions.  相似文献   

甘东南流动台阵微震监测结果   总被引：7，自引：1，他引：6  

高见  张元生  郭飚  刘旭宙 《地震工程学报》2013,35(1):177-182

利用高密度宽频带流动台阵资料,应用网格搜索地震定位方法对甘东南2009年11月-2011年11月期间的微震进行了重新定位.在研究区内有3个以上台站记录到的微震共3 014个,比常规台网记录多1 693个.重新定位结果显示:在各断裂带附近地震分布更加密集,沿断裂呈带状或簇集状分布;震源深度分布优势范围为5～20 km,其平均深度为11 km;地震深度分布与断裂的关系密切,地震条带与断裂构造可以较好的相对应.  相似文献   

3-D voxel-based solid modeling of a broad-leaved tree for accurate volume estimation using portable scanning lidar     

《ISPRS Journal of Photogrammetry and Remote Sensing》2013

We developed a method to produce a 3-D voxel-based solid model of a tree based on portable scanning lidar data for accurate estimation of the volume of the woody material. First, we obtained lidar measurements with a high laser pulse density from several measurement positions around the target, a Japanese zelkova tree. Next, we converted lidar-derived point-cloud data for the target into voxels. The voxel size was 0.5 cm × 0.5 cm × 0.5 cm. Then, we used differences in the spatial distribution of voxels to separate the stem and large branches (diameter > 1 cm) from small branches (diameter ⩽ 1 cm). We classified the voxels into sets corresponding to the stem and to each large branch and then interpolated voxels to fill out their surfaces and their interiors. We then merged the stem and large branches with the small branches. The resultant solid model of the entire tree was composed of consecutive voxels that filled the outer surface and the interior of the stem and large branches, and a cloud of voxels equivalent to small branches that were discretely scattered in mainly the upper part of the target. Using this model, we estimated the woody material volume by counting the number of voxels in each part and multiplying the number of voxels by the unit voxel volume (0.13 cm³). The percentage error of the volume of the stem and part of a large branch was 0.5%. The estimation error of a certain part of the small branches was 34.0%.  相似文献   

Metamorphic history of the South Tibetan Detachment System,Mt. Everest region,revealed by RSCM thermometry and phase equilibria modelling   总被引：2，自引：0，他引：2  

J. M. COTTLE  D. J. WATERS  O. BEYSSAC  M. J. JESSUP 《Journal of Metamorphic Geology》2011,29(5):561-582

This study combines microstructural observations with Raman spectroscopy on carbonaceous material (RSCM), phase equilibria modelling and U–Pb dating of titanite to delineate the metamorphic history of a well‐exposed section through the South Tibetan Detachment System (STDS) in the Dzakaa Chu valley of Southern Tibet. In the hanging wall of the STDS, undeformed Tibetan Sedimentary Series rocks consistently record peak metamorphic temperatures of ～340 °C. Temperatures increase down‐section, reaching ～650 °C at the base of the shear zone, defining an apparent metamorphic field gradient of ～310 °C km^?1 across the entire structure. U–Th–Pb geochronological data indicate that metamorphism and deformation at high temperatures occurred over a protracted period from at least 20 to 13 Ma. Deformation within this 1‐km‐thick zone of distributed top‐down‐to‐the‐northeast ductile shear included a strong component of vertical shortening and was responsible for significant condensing of palaeo‐isotherms along the upper margin of the Greater Himalayan Series (GHS). We interpret the preservation of such a high metamorphic gradient to be the result of a progressive up‐section migration in the locus of deformation within the zone. This segment of the STDS provides a detailed thermal and kinematic record of the exhumation of footwall GHS rocks from beneath the southern margin of the Tibetan plateau.  相似文献   

川东北毛坝气藏含自然硫包裹体的发现及其地质意义     

李保华  顾雪祥  李黎  付绍洪  徐仕海  赵甫峰  肖德长 《矿物学报》2011,31(3):541-549

根据流体包裹体显微观察,均一温度、盐度测定和激光拉曼分析结果,毛坝气藏储层中存在多种类型包裹体,包括气液H20包裹体、烃一H20包裹体、气相烃包裹体、沥青包裹体和含自然硫气液H20包裹体。在含自然硫气液H20包裹体中,自然硫的特征激光拉曼峰值是151．1cm^1～、217．9em^1和473．3cm^1。根据包裹体的产状、分布以及组合特征,可将本区下三叠统储层流体包裹体划分为3期。晚成岩期方解石中气液H20包裹体均一温度变化范围为104～206°c,盐度为4．03％～19．29％NaCl。温度和盐度呈一定的负相关关系,反映随着成岩环境的埋藏深度增加,地层中孔隙水的温度趋于升高,同时烃类与流体中SO42发生热化学还原反应（TSR）,生成H2s和H20,使盐度降低。在区域抬升降温、降压期,由于外来流体的不均匀混合,流体温度、盐度进一步降低（均一温度为31～108℃,盐度为0．35％～4．03％NaCl）,在低温及硫主要以H2s形式存在的条件下,02与H2s反应生成大量自然硫。在自然硫形成过程中,随着温度的降低,pH值趋向于升高,lgf（02）趋向于降低。当温度为100℃时,自然硫在pH=2．9～3．4,lgf（02）=-50．61～-49．92的环境中形成;25℃时,自然硫形成于pH=1．9～6．5,lgf（02）=-69．30～-63．11的环境中。  相似文献   

Precambrian fossils from the Hamersley range,Western Australia,and their use in stratigraphic correlation     

H. S. Edgell 《Australian Journal of Earth Sciences》2013,60(2):235-261

The palaeontology, correlation and sedimentation of the Proterozoic sequence in the Hamersley Range, Western Australia, are discussed. Fossil calcareous algal growths, such as stromatolites and onkolites are described, as well as possible medusoid impressions. These indicate shallow water accumulation of the sediments and provide evidence of the extensive existence of plant and animal life in the Late Precambrian of Western Australia.

Distinctive stromatolites are shown to characterize various levels in the Proterozoic succession. A descending sequence of stromatolite assemblages is proposed denoted by:

• Collenia frequens—Conophyton cf. inclinatum

• Collenia australasica—C. undosa

• C. cf. kona—C. brockmani

• C. sp. aff. multiflabella.

Emphasis is placed on the possible significance of these calcareous algae for correlation and age subdivision of the Proterozoic of Western Australia and its relation to other Precambrian successions.  相似文献   

具磷灰石假象绿松石的岩石矿物学及谱学特征     

申广耀  卢保奇  亓利剑 《上海国土资源》2013,(4):96-100

采用x射线粉晶衍射（XRD）、博里叶变换红外光谱（FTI码以及拉曼光谱等方法对安徽马鞍山具磷灰石假象的绿松石进行了研究。结果表明：其主要矿物组成为绿松石,保留了磷灰石六边形的形态特征。XRD~U试的特征谱线d值为36745～36748（111）、29008～29025（123）、34247～34293（2101、32709～32781（113）、61626～61781（011）3020130～20162（301）,与绿松石的标准衍射谱线基本致。红外光谱测试分析表明：3510～3465cm。间的谱带归属绿松石0（OH）的伸缩振动,3300～3070cm’间的谱带归属为绿松Nu（M-H。O）伸缩振动,1210-1012cm’间的谱带归属为绿松石U3口O。）ira缩振动,在838cm。附近的吸收谱带归属为绿松石6（OH）弯曲振动,655-480cm。间的谱带归属为绿松石u4（P04）弯曲振动。拉曼光谱测试分析表明：3466cm’附近的尖锐拉曼谱峰归属于绿松石（OH）基团的伸缩振动所致,宽缓的拉曼谱峰3281cm’~03078cm’归属于绿松石中水合络离子的伸缩振动,798cm’谱峰则是由于OH的弯曲振动所致。  相似文献   

差应力与石英组构关系的实验研究     

马瑞  田海民  张刚 《吉林大学学报(地球科学版)》2009,39(1):89

为了探讨柯石英的形成条件,利用河北省平山县西柏坡地区太古代阜平群中的黑云母片麻岩进行高温高压条件下的岩石变形实验。实验的温度为800 ℃,围压为0.2 GPa,应变量为10%,应变速率为10^-5/s。实验结果表明,变形后样品中不同部位石英颗粒的激光拉曼光谱与标准的石英光谱相比较发生了明显的变化,具体表现为：挤压带中,石英颗粒的光谱出现了9个峰,而标准石英光谱为6个峰;在剪切带中,石英颗粒的谱线只有一个清晰的峰,在拉伸带中,石英颗粒的谱线无论峰的数目还是出现的位置都与标准石英光谱有着显著的区别,说明导致岩石变形的差应力对石英晶格结构的改造具有一定的影响。  相似文献   

The orientation and vibrational states of H2O in synthetic alkali-free beryl     

B. A. Kolesov  C. A. Geiger 《Physics and Chemistry of Minerals》2000,27(8):557-564

 The polarized single-crystal Raman spectra of synthetic H₂O-containing alkali-free beryl were recorded at room and low temperatures, and the polarized single-crystal IR spectra at room temperature. The H₂O molecule in the channel cavities is characterized by a Raman-active symmetric stretching vibration (ν₁) at 3607 cm⁻¹ and an IR-active asymmetric stretch (ν₃) at 3700 cm⁻¹ at room temperature. At low temperatures this ν₃ mode is observed in the Raman. Weak ν₁ and ν₃ modes of a second type of H₂O are also observed in the Raman spectra but only at 5 K. The H⋯·H vector of the most abundant type of H₂O is parallel to the channel axis of beryl along [0 0 0 1]. The components of the polarizability tensor of the ν₁ mode of H₂O are similar to, but not exactly the same as, those of a free H₂O molecule. The Raman measurements indicate that the H₂O molecule is rotationally disordered around [0 0 0 1]. External translation and librational modes of H₂O could be observed as overtones with the internal H₂O-stretching modes. In the case of the librational motions, normal modes could also be observed directly in the Raman spectra at ∼200 cm⁻¹. The energies of the translational modes can be determined from an analysis of the overtones and are about 9 cm⁻¹ in energy (i.e., T_z). The energies of the librational modes are about 210 cm⁻¹ for R_x and 190 cm⁻¹ for R_y. Received: 8 April 1999 / Accepted: 5 April 2000  相似文献   

榴辉岩中石英出溶体的拉曼光谱学研究及其构造意义   总被引：2，自引：0，他引：2  

王璐  金振民  何谋春 《地球科学》2003,28(2):143-150

利用拉曼光谱学和费氏台方法对若干地区超高压榴辉岩中柯石英和榴辉岩中石英出溶体的超显微构造特征进行了研究.研究结果表明, 石榴石(或绿辉石) 中柯石英向石英相变是一个连续变化过程.绿辉石中石英出溶体和主晶具有一定的晶体学拓扑关系, 即石英出溶体长轴有两个展布方向: 平行于绿辉石(10 0) 裂理面和平行于绿辉石(- 10 1) 面.目前, 部分学者推断榴辉岩绿辉石中石英出溶体可作为超高压变质作用的标志.笔者认为, 棒状定向石英在绿辉石中出溶的温压条件和出溶机理尚未查明.因此, 需加强过量二氧化硅单斜辉石出溶机理的超高压实验研究, 从而为证实石英出溶体作为超高压标志提供实验定量约束.   相似文献