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11.
The kinetics of the reactions of C2H radical with ethane (k1), propane (k2), and n-butane (k3) are studied over the temperature range of T = 96-296 K with a pulsed Laval nozzle apparatus that utilizes a pulsed laser photolysis-chemiluminescence technique. The C2H decay profiles in the presence of both the alkane reactant and O2 are monitored by the CH(A2Δ) chemiluminescence tracer method. The results, together with available literature data, yield the following Arrhenius expressions: k1(T) = (0.51 ± 0.06) × 10−10 exp[(−76 ± 30)K/T] cm3 molecule−1 s−1 (T = 96-800 K), k2(T) = (0.98 ± 0.32) × 10−10exp[(−71 ± 60)K/T] cm3 molecule−1 s−1 (T = 96-361 K), and k3(T) = (1.23 ± 0.26) × 10−10 cm3 molecule−1 s−1 (T = 96-297 K). At T = 296 K, k1 is measured as a function of total pressure and has little or no pressure dependence. The results from this work support a direct hydrogen abstraction mechanism for the title reactions. Implications to the atmospheric chemistry of Titan are discussed.  相似文献   
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Paul Withers  S.W Bougher 《Icarus》2003,164(1):14-32
Mars Global Surveyor accelerometer observations of the martian upper atmosphere revealed large variations in density with longitude during northern hemisphere spring at altitudes of 130-160 km, all latitudes, and mid-afternoon local solar times (LSTs). This zonal structure is due to tides from the surface. The zonal structure is stable on timescales of weeks, decays with increasing altitude above 130 km, and is dominated by wave-3 (average amplitude 22% of mean density) and wave-2 (18%) harmonics. The phases of these harmonics are constant with both altitude and latitude, though their amplitudes change significantly with latitude. Near the South Pole, the phase of the wave-2 harmonic changes by 90° with a change of half a martian solar day while the wave-3 phase stays constant, suggesting diurnal and semidiurnal behaviour, respectively. We use a simple application of classical tidal theory to identify the dominant tidal modes and obtain results consistent with those of General Circulation Models. Our method is less rigorous, but simpler, than the General Circulation Models and hence complements them. Topography has a strong influence on the zonal structure.  相似文献   
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ECOLOGICAL SERIES OF SOIL ANIMALS IN DARLIDAI MOUNTAIN   总被引:1,自引:0,他引:1  
The ecological series of soil animals under the broad-leaved and pine mixed forest in Darlidai Mountainwas studied. Seven sample plots were selected according to different altitude gradients, which belong to different vegeta-tion types. By investigating and analyzing soil animals in every sample plot it is found that there are 45 groups and 1956individuals, which axe involved in 3 phylums, 7 classes, 16 orders, respectively. The altitude is a key factor which af-fects ecological series of soil animals. Both the groups and individuals of soil animals increase with altitude increasingunder certain conditions, which contrastes with ordinary cases, resulting from special micro-climate in studied area. Thegroups and individuls of soil animals are the most under the broad-leaved and pine forest on the top of the mountain, andthe least under Picea-Abies forest in the foot of the mountain.  相似文献   
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The structure, functioning and hydrodynamic properties of aquifers can be determined from an analysis of the spatial variability of baseflow in the streams with which they are associated. Such analyses are based on simple low‐cost measurements. Through interpreting the hydrological profiles (Q = f(A)) it is possible to locate the aquifer(s) linked to the stream network and to determine the type of interrelated flow, i.e. whether the stream drains or feeds the aquifer. Using an analytical solution developed for situations with a positive linear relationship, i.e. where the baseflow increases linearly with increasing catchment size, it is also possible to estimate the permeability of the aquifer(s) concerned at catchment scale. Applied to the hard‐rock aquifers of the Oman ophiolite, this method shows that the ‘gabbro’ aquifer is more permeable than the ‘peridotite’ aquifer. As a consequence the streams drain the peridotites and ‘leak’ into the gabbro. The hydrological profiles within the peridotite are linear and positive, and indicate homogeneity in the hydrodynamic properties of these formations at the kilometre scale. The permeability of the peridotite is estimated at 5 · 10?7 to 5 · 10?8 m/s. Copyright © 2004 John Wiley & Sons, Ltd.  相似文献   
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隧道工程地质评价的内容和方法   总被引:2,自引:0,他引:2  
结合工程隧道实际,首先阐述了隧道工程的基本地质环境和工程地质条件,然后针对隧道工程可能出现的不良地质现象和可采取的工程措施,从大气降水、围岩稳定、围岩压力、洞口稳定、隧道比选等角度探讨隧道工程地质评价的主要方法和一般内容,进行隧道工程地质评价,为隧道施工、支护提供了依据.  相似文献   
19.
介绍了MATLAB语言特点和系统建模方法的基本理论.根据南海气象数据的实际建模处理过程,给出了建模的详细步骤及其MATLAB实现过程以及MATLABTM的主要实现程序.试验讨论和结果表明利用MATLAB语言可以方便地对南海气象数据用系统建模方法进行建模和处理,MATLAB在运用系统建模法处理南海气象数据方面具有明显的优越性.  相似文献   
20.
Optimal deflection of NEOs en route of collision with the Earth   总被引:1,自引:0,他引:1  
Ralph Kahle  Gerhard Hahn 《Icarus》2006,182(2):482-488
Recently, a method for the n-body analysis of the velocity change required to deflect a hazardous near-Earth object (NEO) was presented by Carusi et al. [Carusi, A., Valsecchi, G.B., D'Abramo, G., Boattini A., 2002. Icarus 159, 417-422]. We extent this method in order to optimize the velocity change vector instead of its along-track magnitude. From an application of both methods to a fictitious NEO we find Carusi's parallel approach to be reasonable for phases of unperturbed two-body motion. But, for orbit phases inhering third-body perturbations, i.e., for planetary close approaches or prior to a collision, the results obtained from the new method show the radial component of deflection impulse to play a major role. We show that a fivefold greater efficiency can be achieved by a deflection impulse being non-parallel to orbital velocity. The new method is applied to two possible 99942 Apophis impact trajectories in order to provide constraints for future Apophis deflection mission analysis.  相似文献   
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