A worldwide data set of more than 500 humic coals from the major coal-forming geological periods has been used to analyse the evolution in the remaining (Hydrogen Index, HI) and total (Quality Index, QI) generation potentials with increasing thermal maturity and the ‘effective oil window’ (‘oil expulsion window’). All samples describe HI and QI bands that are broad at low maturities and that gradually narrow with increasing maturity. The oil generation potential is completely exhausted at a vitrinite reflectance of 2.0–2.2%Ro or Tmax of 500–510 °C. The initial large variation in the generation potential is related to the original depositional conditions, particularly the degree of marine influence and the formation of hydrogen-enriched vitrinite, as suggested by increased sulphur and hydrogen contents. During initial thermal maturation the HI increases to a maximum value, HImax. Similarly, QI increases to a maximum value, QImax. This increase in HI and QI is related to the formation of an additional generation potential in the coal structure. The decline in QI with further maturation is indicating onset of initial oil expulsion, which precedes efficient expulsion. Liquid petroleum generation from humic coals is thus a complex, three-phase process: (i) onset of petroleum generation, (ii) petroleum build-up in the coal, and (iii) initial oil expulsion followed by efficient oil expulsion (corresponding to the effective oil window). Efficient oil expulsion is indicated by a decline in the Bitumen Index (BI) when plotted against vitrinite reflectance or Tmax. This means that in humic coals the vitrinite reflectance or Tmax values at which onset of petroleum generation occurs cannot be used to establish the start of the effective oil window. The start of the effective oil window occurs within the vitrinite reflectance range 0.85–1.05%Ro or Tmax range 440–455 °C and the oil window extends to 1.5–2.0%Ro or 470–510 °C. For general use, an effective oil window is proposed to occur from 0.85 to 1.7%Ro or from 440 to 490 °C. Specific ranges for HImax and the effective oil window can be defined for Cenozoic, Jurassic, Permian, and Carboniferous coals. Cenozoic coals reach the highest HImax values (220–370 mg HC/g TOC), and for the most oil-prone Cenozoic coals the effective oil window may possibly range from 0.65 to 2.0%Ro or 430 to 510 °C. In contrast, the most oil-prone Jurassic, Permian and Carboniferous coals reach the expulsion threshold at a vitrinite reflectance of 0.85–0.9%Ro or Tmax of 440–445 °C. 相似文献
Investigation of deposits for traditional extraction activities (metals and coal) has generally been based on determining grade, or content, of the required material. In order to apply the grade concept to an ornamental rock such as slate, it is first necessary to define the variables that determine both the geotechnical recovery rate for the rock mass — which conditions the size of the extracted blocks – and the aesthetic features of the slate — which define the quality of the slabs as potential roofing material.
For this research, geotechnical and aesthetic data for a slate deposit were collected from 16 continuous core borehole samples. A fuzzy expert system was then developed using this data, defining the rock mass recovery rate and slab quality in accordance with the criteria of a slate expert, producing as a final output a zonation of the deposit in terms of top quality slate, medium quality slate or waste.
A mathematical model based on fuzzy logic was chosen due to the fact that the boundaries between different quality groups in a deposit are not clearly distinguished. Moreover, quality also depends on a company's infrastructures for transformation of the blocks, and also on its commercial strategies. 相似文献
A study has been done for analysing soil nailed cuts with circular type wedge failure by friction circle method. Various parameters
such as nail length, nail diameter, nail inclination, wall inclination and angle of internal friction of soil have been considered
to determine the factor of safety of nailed open cuts. The study shows that for cohesionless soil nailed cut, factor of safety
increase with increase of parameters like angle of internal friction of soil, length of nail (L) versus height of cut (H) ratio, cohesion of soil and nail inclination (upto 15°) with horizontal. The study revealed that nails grouted with cement
perform better than driven nails. A case study further confirms the analytical findings.
Received 7 October 相似文献