Genesis of the Taishanmiao Au Deposit in the Ningshan–Zhenan Ore Field, South Qinling Orogen, China: Evidence from Geochemical, Geochronological and S-Pb-H-O Isotopical Study     

GAO Zuoyu  LIU Yunhu  SUN Naiquan  LI Yuntao  LI Bo 《《地质学报》英文版》2022,96(3):993-1009

The Taishanmiao Au deposit is in the western part of the Ningshan–Zhenan ore field, in the South Qinling orogen. Based on geological and geochemical features, we propose that the Taishanmiao Au deposit is a magmatic-hydrothermal type of deposit. All samples have high SiO2, K2O + Na2O contents and differentiation index values, low CaO, MgO, P2O5, and TiO2 contents, are enriched in high field-strength elements, and depleted in large ion lithophile element. The stable isotope δ34S values of pyrite vary from 6.8%–7.8%, and the H-O isotopic compositions of quartz from quartz-pyrite veins indicate the ore-forming fluid is a mixture of a small amount of magmatic-hydrothermal solution and groundwater. Lead isotope ratios of pyrite and silicalite can show that the ore-forming materials were derived from a mixed source containing mantle and crustal materials. At the same time, the LA-ICP-MS U-Pb dating of monzogranite is 198.4 ± 4.2 Ma. Combined with the regional geological background, the intracontinental extension in the late collisional orogeny and large-scale lithospheric thinning associated with mantle uplift may lead to large-scale mineralisation in the region.  相似文献   

大庆油田古龙凹陷青山口组页岩油储层方解石脉中发现藻生物层     

何文渊  张金友  钟建华  孙宁亮 《地质论评》2023,69(6):2081-2084

<正>顺层方解石脉是页岩油储层中比较常见的一种构造,虽然它的体量不大,但是携带的地质信息很多,近年来颇受重视,取得了很多成果(何文渊等,2022,2023;杨勇等,2023)。近期大庆油田在古龙凹陷青山口组获得了页岩油的资源量可达15.1 Gt,已引起广泛关注,但还有一些地质问题没有解决,严重地影响了页岩油的勘探开发。因此,对古龙凹陷青山口组页岩的基础地质进行深入研究具有重要意义。  相似文献   

Genesis of Fibrous Calcite in the Chang 7 Member of the Yanchang Formation, Ordos Basin, China     

LIU Guanglin  LIU Xianyang  MA Xiaofeng  MA Shuang  WANG Xiaofeng  LI Shuo  SHI Zhiqiang  WANG Yanxin 《《地质学报》英文版》2023,97(5):1490-1502

To explore the genesis of the laminated calcite veins developed in the black shale of Chang 73 submember of the Ordos Basin, the petrology, microstructure and geochemistry of calcite veins are studied using thin sections, fluid inclusions, trace elements and isotopic geochemistry. The source, the time of formation, the mechanism of formation, and the dynamic background of the veins are discussed. The veins are mostly made up of calcite, mixed with lenticular or spindle-shape solid wall rock inclusions. Three structures are identified in the calcite minerals: fibrous, rhombic cleavage, and wedge-like structure. Trace elements and isotopes of carbon and oxygen confirm that the calcite veins were formed from a high density hydrothermal fluid. It is assumed that calcite veins formed prior to wall rock consolidation during the formation of the Qinling Orogenic Belt in the Middle and Late Triassic. The results show that the sedimentary sources of Chang 73 submember were influenced by hydrothermal materials besides terrigenous detritus. The fibrous calcite is different from the fibrous calcite reported in the morphology and mechanism of formation. In this way, the research complements and improves the morphology and the mechanism of formation of fibrous calcite.  相似文献   

电子背散射衍射技术(EBSD)在组构分析中的应用和相关问题     

张青  李馨 《岩石学报》2021,37(4):1000-1014

在过去的二十年里,EBSD (Electron Backscattered Diffraction),即电子背散射衍射测试技术,已广泛应用于韧性组构分析,成为变形运动学、流变学分析的常规手段。该方法主要应用于流变条件下矿物晶轴组构定向性分析,以判定流变剪切指向、对比应变强度、估算变形温度。理论上讲,EBSD法适用于所有矿物的全部晶轴定向的分析测试。然而鉴于天然变形的复杂性,笔者建议EBSD分析应以石英,特别是经历了动态重结晶的石英条带为组构分析的主要对象。长期以来,石英晶轴组构的不对称性被视作独立的剪切指向标志。然而,近年来基于天然变形和一般剪切实验的研究结果表明,塑性流变的剪切指向含义应为多重流变剪切指向标志综合判别比对的结果。尽管在提出之初,石英的轴组构开角被视作独立可靠的变形温度计(Kruhl,1998)。然而限于天然变形的复杂性,特别是对变质与变形阶段的对应、耦合的认识;尽管石英变形滑移系及石英晶轴组构开角可为动力变质温度提供重要的参考,但是石英晶轴组构开角并非独立的变形温度计。  相似文献   

Development of crystallographic preferred orientations by nucleation and growth of new grains in experimentally deformed quartz single crystals   总被引：1，自引：1，他引：0  

Martine G.C. Vernooij  Bas den Brok  Karsten Kunze 《Tectonophysics》2006,427(1-4):35

Deformation experiments have been carried out to investigate the effect of dynamic recrystallisation on crystallographic preferred orientation (CPO) development. Cylindrical samples of natural single crystals of quartz were axially deformed together with 1 vol.% of added water and 20 mg of Mn₂O₃ powder in a Griggs solid medium deformation apparatus in different crystallographic orientations with compression direction: (i) parallel to <c>, (ii) at 45° to <c> and 45° to <a> and (iii) parallel to <a>. The experiments were performed at a temperature of 800 °C, a confining pressure of 1.2 GPa, a strain rate of  10^− 6 s^− 1, to bulk finite strains of  14–36%. The deformed samples were analysed in detail using optical microscopy, electron backscatter diffraction (EBSD) and transmission electron microscopy (TEM). Two different microstructural domains were distinguished in the deformed samples: (i) domains with undulatory extinction and deformation lamellae, and (ii) domains with new recrystallised grains. Within the domains of undulatory extinction, crystal-plastic deformation caused gradual rotations of the crystal lattice up to  30° away from the host orientation. New recrystallised grains show a strong CPO with c-axis maxima at  45° to the compression direction. This is the case in all experiments, irrespective of the initial crystallographic orientation. The results show that c-axes are not continuously rotated towards the new maxima. The new grains thus developed through a mechanism different from subgrain rotation recrystallisation. New grains have a subeuhedral shape and numerous microcavities, voids, fluid channels and fluid inclusions at their grain boundaries. No host control is recorded in misorientation axes across their large angle grain boundaries. New grains might have been created by nucleation from solution in the μm-scale voids and microfractures. The CPO most likely developed due to preferred growth of the freshly precipitated grains with orientations suitable for intracrystalline deformation at the imposed experimental conditions.  相似文献   

湖北铜绿山矿床石英闪长岩的矿物学及Sr-Nd-Pb同位素特征   总被引：11，自引：8，他引：3  

赵海杰  毛景文  向君峰  周振华  魏克涛  柯于富 《岩石学报》2010,26(3):768-784

铜绿山是长江中下游鄂东南矿集区最重要的、大型夕卡岩型Cu-Fe(Au)矿床。本文对该矿区中与成矿密切的石英闪长岩进行了详细的矿物成分、地球化学及Sr-Nd-Pb同位素研究。结果表明:岩石中斜长石主要为更长石(An=21～31);角闪石贫Ti(0.2),高Mg/(Mg+Fe)(0.5),属于富镁角闪石;而黑云母为镁质黑云母。岩石的地球化学具有高硅(58.86%～67.71%),富碱(Na2O+K2O=5.67%～9.63%),富集轻稀土元素(LREE)和大离子亲石元素(LILE),并强亏损元素Nb、Ta、Ti等特征。岩石的(87Sr/86Sr)i为0.7055～0.7069,εNd(t)为-7.65～-3.44;(206Pb/204Pb)i=17.66～18.00,(207Pb/204Pb)i=15.49～15.56,(208Pb/204Pb)i=37.73～38.19。矿物成分、地球化学和同位素特征说明,铜绿山岩体与阳新岩体为同源岩浆的产物,源区为深度大于40km的富集地幔,经下地壳的混染及分离结晶作用形成。岩浆熔体形成的温度应大于889℃。角闪石和黑云母的温度计估算岩浆结晶温度分别为650～800℃和500～630℃,黑云母开始结晶温度略低于角闪石结晶结束温度,压力为1.49kbar,对应侵位深度约4.9km。岩浆具有利于Cu、Fe、Au等成矿元素进入熔体的条件,可能与板块俯冲作用相关。  相似文献   

Fluid inclusion characteristics of hematite-bearing quartz vein from the Daenam mine, Republic of Korea     

B.C. Yoo  J.W. Yin  G.J. Lee  H.K. Lee   《Journal of Asian Earth Sciences》2010,37(2):117-129

The Daenam mine, which produced over 9250 tons of iron oxide ore from 1958 to 1962, is situated in the Early Cretaceous Yeongyang subbasin of the Gyeongsang basin. It consists of two lens-shaped, hematite-bearing quartz veins that occur along faults in Cretaceous leucocratic granite. The hematite-bearing quartz veins are mainly composed of massive and euhedral quartz and hematite with minor amounts of pyrite, pyrrhotite, mica, feldspar and chlorite.Fluid inclusions in quartz can be divided into three main types: CO₂-rich, CO₂–H₂O, and H₂O-rich. Hydrothermal fluids related to the formation of hematite are composed of either H₂O–CO₂–NaCl ± CH₄ (homogenization temperature: 262–455 °C, salinity <7 eq. wt.% NaCl) or H₂O–NaCl (homogenization temperature: 182–266 °C, and salinity <5.1 eq. wt.% NaCl), both of which evolved by mixing with deeply circulating meteoric water. Hematite from the quartz veins in the Daenam mine was mainly deposited by unmixing of H₂O–CO₂–NaCl ± CH₄ fluids with loss of the CO₂ + CH₄ vapor phase and mixing with downward percolating meteoric water providing oxidizing conditions.  相似文献   

东濮凹陷桥口-白庙地区砂岩石英增生及其对流体活动的反映   总被引：2，自引：2，他引：2       下载免费PDF全文

费卫红  李忠  孙海山 《地质科学》2001,36(2):152-163

对东濮凹陷下第三系储层砂岩石英增生边及其中的流体包裹体进行了鉴定和检测,结果表明东濮凹陷桥口-白庙地区共有3期石英增生现象,代表3期流体活动。第1期与第2期发生在盆地深陷期,当时埋深1700～3000m,年代28～37Ma,第3期增生边尚不能确定其形成条件,但可确定其形成于碳酸盐大规模交代石英颗粒之后。桥口地区第1期所代表的流体活动温度主要在110～115℃,第2期所代表的流体活动温度主要在130～135℃。白庙地区第1期所代表的流体活动温度主要在105～110℃,第2期所代表的流体活动温度主要在120～125℃。这3期流体活动的性质可能是粘土矿物转化过程中释放的晶格水通过泥岩的幕式压裂作用向砂岩中释放的结果。  相似文献   

Evidence for volatile-influenced differentiation in a layered alkali basalt flow, Penghu Islands, Taiwan     

John D. Greenough  Chi-Yu Lee  Brian J. Fryer 《Bulletin of Volcanology》1999,60(6):412-424

An approximately 20-m-thick alkali basalt flow on the Penghu Islands contains ∼20 cm thick, horizontally continuous (>50 m), vesicular layers separated by ∼1.5 m of massive basalt in its upper 8.5 m. The three layers contain ocelli-like "vesicles" filled with nepheline and igneous carbonate. They are coarse grained and enriched in incompatible elements relative to the massive basalt with which they form sharp contacts. These vesicular layers (segregation veins) formed when residual liquid in the underlying crystal mush was forced (gas filter pressing) or siphoned into three thermally induced horizontal cracks that opened successively in the advancing crystal mush of the flow's upper crust. Most vesicular layer trace elements can be modelled by residual melt extraction after 25–40% fractional crystallization of massive basalt underlying each layer. Sulphur, Cl, As, Zn, Pb, K, Na, Rb, and Sr show large concentration changes between the top, middle, and bottom layers, with each vesicular and underlying massive basalt forming a chemically distinct "pair." The large changes between layers are difficult to account for by crystal fractionation alone, because other incompatible elements (e.g., La, Sm, Yb, Zr, Nb) and the major elements change little. The association of these elements (S, Cl, etc.) with "fluids" in various geologic environments suggests that volatiles influenced differentiation, perhaps by moving alkali, alkaline earth, and chalcophile elements as magma-dissolved volatile complexes. Volatiles may have also led to large grain sizes in the segregation veins by lowering melt viscosities and raising diffusion rates. The chemical variability between layers indicates that a convection and concentration mechanism acted within the flow. The specific process cannot be determined, but different rates of vesicle plume rise (through the flow) and/or accumulation in the upper crust's crystal mush might account for the chemical pairing and extreme variations in Cl, S, As, and C. This study emphasizes the importance of sampling vesicular rocks in flows. It also suggests that volatiles play important physical and chemical roles in rapidly differentiating mafic magmas in processes decoupled from crystal fractionation. Received: 11 November 1996 / Accepted: 20 September 1998  相似文献   

庐枞地区铀成矿规律探讨   总被引：9，自引：0，他引：9  

陈一峰 《铀矿地质》1994,10(4):193-202,206

庐枞地区铀与铁、铜等金属组成区域成矿系列，其成矿作用主要受区域性深大断裂及火山岩前“基底”断裂的控制，燕山期的岩浆活动及其演化是成矿的内在因素。铀矿化是岩浆演化晚阶段的产物。主要铀矿化类型为碱性岩外带型，铀矿化与石英正长岩的空间上相依、时间上相近、成因上相联。中侏罗统罗岭组是主要含矿层位、砂岩是含矿主岩、接触带构造是区内主要的控矿构造类型。富铀矿在区内占较大比例，具多来源、复成因、叠加成矿的特征。  相似文献