中亚萨亚克矿田成矿岩体矿物学和地球化学:岩浆性质与成矿意义   总被引：3，自引：1，他引：2  

安芳  王居里  朱永峰  王建其  魏少妮  赖绍聪  SEITMURATOVA Eleonora 《岩石学报》2015,31(2):555-570

萨亚克大型铜矿田位于哈萨克斯坦北巴尔喀什斑岩成矿带中部,以矽卡岩型矿床为主。通过对矿区石英闪长岩的矿物化学和地球化学研究,发现石英闪长岩呈斑状结构,斑晶为斜长石和角闪石,其中的斜长石斑晶主要为中长石,角闪石斑晶为镁质普通角闪石;岩石属于高钾钙碱性系列,富集Rb、Sr、Ba等大离子亲石元素和轻稀土元素,亏损Nb、Ta和重稀土元素,高Sr/Y、La/Yb比值,与埃达克岩相似。地球化学特征指示萨亚克矿区侵入岩形成于岛弧环境,为矽卡岩-斑岩型成矿提供了有利的构造背景,岩石可能是岛弧玄武质岩浆在高压下经结晶分异而成。根据角闪石温压计及其成分与氧逸度和岩浆中水含量之间的关系,确定萨亚克石英闪长玢岩中角闪石斑晶结晶时岩浆的温度为799~843℃、处于3.6~9.6km深度范围内(P=1.2~3.2kbar)、氧逸度logfO2=-11.5~-12.0(ΔFMQ=2.0~2.8)、平均水含量为1.2%,相对较高的氧逸度和水含量有利于形成富含挥发分和Cu、Au等成矿物质的岩浆,是最终演化形成大型岩浆-热液型铜矿田(斑岩型、矽卡岩型)的有利条件。  相似文献   

西秦岭温泉斑岩钼矿床岩浆-热液演化   总被引：5，自引：3，他引：2  

邱昆峰  宋开瑞  宋耀辉 《岩石学报》2015,31(11):3391-3404

西秦岭北缘广泛出露印支期中酸性侵入岩和相关的斑岩-矽卡岩矿床。温泉矿床位于该矿带东段,是其内已探明规模最大的斑岩钼矿床。温泉矿床发育多阶段热液脉体,黄铁矿作为其中的贯通性金属硫化物,其化学组成蕴含着岩浆-热液演化及金属沉淀过程等诸多信息,对于斑岩系统模型的厘定具有重要意义。温泉矿床热液脉体时序为:钾长石-黑云母-石英脉(A脉)、石英-黄铜矿脉、石英-辉钼矿脉(B脉)和石英-绢云母-黄铁矿脉(D脉)。A脉是斑岩系统岩浆-热液演化的最早期脉体,主要矿物组合为钾长石+黑云母+石英+黄铁矿±磁铁矿±磷灰石±黄铜矿,代表了引起早期基性岩浆矿物被蚀变为黑云母的流体通道;B脉与钾长石化蚀变关系密切,围岩中斜长石斑晶大量被蚀变为钾长石;石英-辉钼矿脉切割所有早期黑云母化-钾化蚀变阶段的石英-硫化物网脉,并形成于所有斑岩侵位之后,少量黄铁矿和黄铜矿共生于辉钼矿裂隙及边部;D脉是斑岩系统岩浆-热液成矿作用的最晚期事件,其主要被黄铁矿和石英及少量黄铜矿填充,发育晚期的绢英岩化和泥化蚀变,长石多发生破坏性蚀变。四个阶段石英网脉中黄铁矿电子探针分析显示,A脉的黄铁矿中Cu、Mo和Au含量均较低,有少量的金属硫化物(黄铁矿+黄铜矿)沉淀,但通常不能形成规模矿体;石英-黄铜矿脉的黄铁矿中Cu含量明显较高,且多与高品位Cu矿体的空间产出位置相一致,可能是斑岩系统伴随钾化蚀变作用主要的铜沉淀阶段;B脉的黄铁矿中Mo含量明显较高,与高品位钼矿体空间产出关系密切,可能代表了斑岩系统钼成矿作用的主要阶段;D脉的黄铁矿中Au含量明显升高,可能代表了金在斑岩系统岩浆-热液成矿作用的最晚期事件中的沉淀。  相似文献   

A Discussion of Concavo-Convex Contacts between Oolites and Quartz Grains in Mixed Siliciclastic-Carbonate Rocks in Huanghua Basin, China     

Ma Yanping  Liu Li 《世界地质(英文版)》2002,5(2)

Concavo-convex contacrs between oolites and quartz grains are observed in mixed siliciclastic-carbonate rocks of the lower part of number 1 of Shahejie Formation, beach area, Dagang. Thin sections observation shows that oolite is convex in quartz grain, and oolite is complete. A possible explanation for it is pressure dissolution under alkaline fluid.  相似文献   

Fluid inclusion studies of the Abawso gold prospect,near the Ashanti Belt,Ghana   总被引：1，自引：0，他引：1  

Sven?E.?WilleEmail author  Reiner?Klemd 《Mineralium Deposita》2004,39(1):31-45

The major Ghanaian lode gold deposits are preferentially aligned along the western and eastern contacts of the Kumasi Basin with the Ashanti and Sefwi Belts, respectively. The investigated area of the Abawso small-scale concession, covering the workings of the old Ettadom mine, is situated 3 km west of the lithological contact of the Birimian metavolcanic rocks of the Akropong Belt in the east with the Birimian metasedimentary rocks of the Kumasi Basin in the west. The rocks of the Abawso concession represent a steeply NW-dipping limb of a SE-verging anticline with an axis plunging to the SW. Quartz veining occurs predominantly in the form of en échelon dilatational veins along NNE–SSW-striking shear zones of a few metres width and shows evidence of brittle and ductile deformation. Also stockwork-style quartz veining occurs in the vicinity of the main shaft of the old Ettadom mine. Hydrothermal alteration includes sericitisation, sulphidation and locally carbonatisation. The auriferous quartz veins mainly follow the trend of brittle to ductile deformed quartz veins; however, some occur in stockwork. Fluid inclusion studies reveal a large number of H₂O inclusions along intragranular trails in auriferous quartz vein samples, as well as an overall dominance of H₂O and H₂O-CO₂ inclusions over CO₂ inclusions. Textural observations and physico-chemical fluid inclusion properties indicate post-entrapment modifications for all quartz vein samples due to grain boundary migration recrystallisation. This process is interpreted to be responsible for the generation of the CO₂ inclusions from a H₂O-CO₂ parent fluid. In comparison with mineralisation at the Ashanti and Prestea deposits, which are characterised by CO₂±N₂ inclusions, the observed inclusion assemblage may be due to a shallower crustal level of mineralisation, or different degrees and styles of recrystallisation, or a less pronounced development of laminated quartz veins due to comparably restricted pressure fluctuations. Furthermore, the microthermometric observations allow the reconstruction of a possible retrograde P-T path, depicting near-isothermal decompression in the P-T range of the brittle/ductile transition.Editorial handling: E. Frimmel  相似文献   

Crystallographic orientations of high-angle grain boundaries in dynamically recrystallized quartz: First results   总被引：1，自引：0，他引：1  

Boriana Kuntcheva  Jrn H. Kruhl  Karsten Kunze 《Tectonophysics》2006,421(3-4):331-346

The crystallography and geometry of high-angle grain boundaries from dynamically recrystallized quartz have been studied. On the basis of combined electron backscatter diffraction and universal stage measurements, the complete crystallographic orientation of the grain boundaries could be calculated. The u-stage rotation of the grain boundaries to a vertical position reveals that they are never curved but always consist of straight segments. Our results show that these segments preferentially occupy rhombohedral, trapezohedral and bipyramidal orientations, i.e., orientations in a  25–50° girdle to the c-axis. A specific, albeit low, number of segments with special crystallographic orientation, with respect to a neighbouring quartz grain, often shows another special orientation with respect to the other neighbouring grain. Preferred combinations of grain boundary orientations related to both neighbouring grains are (i) low-index rhombohedral and high index trapezohedral, (ii) low-index bipyramidal and low-index trapezohedral or high-index rhombohedral, and (iii) low-index trapezohedral and low or high index trapezohedral. In certain cases, such as at triple junctions, the boundaries occupy specific trapezohedral orientations with a constant angle to the c-axis. This argues for energy isotropy of trapezohedral planes with the same angle to the quartz c-axis. In general, good match coincidence site lattice (CSL) orientations are not preferentially occupied so that most of the studied grain boundaries represent general boundaries. The formation of straight segments in special crystallographic orientations indicates the crystallographic control and implies an energy reduction of certain general boundaries.  相似文献   

Fractal analysis of quartz grain boundary sutures in a granite (Malanjkhand,Central India) — Implications to infer regional tectonics     

Sukhen Majumder  Manish A. Mamtani 《Journal of the Geological Society of India》2009,73(3):309-319

In the present paper the intensity of serration of quartz grain boundary sutures in the Palaeoproterozoic age Malanjkhand granite (Central India) is quantified using the ruler method of fractal analyses. The northern margin of the granite has proximity to the Central Indian Suture (CIS) that forms the southernmost part of Central Indian Tectonic Zone (CITZ) along which amalgamation of the northern and southern Indian shields took place. The fractal dimension (D) of the quartz sutures is calculated in 13 samples collected at varying distance from the CIS. D values are noted to increase in samples towards the CIS. This demonstrates the influence of the tectonic events along the CIS on fabric development in the Malanjkhand granite. Magmatic fabric defined by preferentially oriented feldspar laths and high-T solid-state deformation fabrics are observed in areas distant from the CIS. In contrast, mylonites and low-T fabrics such as bulging quartz grain boundaries occur in proximity to the CIS. It is inferred that the emplacement and high-T fabric development in the Malanjkhand granite was synchronous with regional accretionary processes that occurred in the region during the Palaeoproterozoic. Two different possibilities, one involving a single tectonic event and the other involving multiple tectonic events are discussed to explain the superimposition of low-T over high-T fabric due to which intensity of quartz grain boundary serration increases towards the CIS.  相似文献   

Luminescence-dated aeolian deposits of late Quaternary age in the southern Tibetan Plateau and their implications for landscape history   总被引：5，自引：0，他引：5  

ZhongPing Lai  Knut Kaiser  Helmut Brückner   《Quaternary Research》2009,72(3):421-430

Aeolian deposits are widely distributed in the interior of the Tibetan Plateau, and their chronology is poorly known. It is not yet clear whether they accumulated only after the last deglaciation, or over a longer time. We applied quartz OSL dating to aeolian samples from the Lhasa area with OSL ages ranging from 2.9 ± 0.2 to at least 118 ± 11 ka. The probability density frequency (PDF) distribution of 24 ages reveals age clusters at about 3, 8, 16–21, 33, and 79–83 ka, indicating enhanced sediment accumulation then. The results show that aeolian deposition occurred throughout most of the last 100 ka. This implies that: 1) an ice sheet covering the whole Tibetan Plateau during the last glacial maximum (LGM) could not have existed; and 2) erosion during the last deglaciation was not as strong as previously proposed, such that not all pre-Holocene loess was removed. The age distribution shown in the PDF indicates that aeolian accumulation is episodic. Sand-formation events revealed by age clusters at 3, 8, and 16–21 ka imply roughly synchronous environmental responses to corresponding global-scale arid events.  相似文献   

Radiation-induced defects in quartz. III. Single-crystal EPR,ENDOR and ESEEM study of a peroxy radical     

Mark J. Nilges  Yuanming Pan  Rudolf I. Mashkovtsev 《Physics and Chemistry of Minerals》2009,36(2):61-73

The X- and W-band single-crystal electron paramagnetic resonance spectra of an electron-irradiated natural quartz permit quantitative analysis of a ²⁹Si hyperfine structure (A ~12.6 MHz) and an ²⁷Al hyperfine structure (A ≤ 0.8 MHz) for a previously reported hole-like center. The ²⁹Si hyperfine structure arises from interaction with two equivalent Si atoms and is characterized by the direction of the unique A axis close to a Si–O bond direction. The ²⁷Al hyperfine structure, confirmed by pulsed electron nuclear double resonance and electron spin echo envelope modulation spectra, is characterized by the unique A axis approximately along a twofold symmetry axis. These ²⁹Si and ²⁷Al hyperfine data, together with published theoretical results on peroxy radicals in SiO₂ as well as our own density functional theory (DFT) calculations on model peroxy centers, suggest this hole-like center to have the unpaired spin on a pair of oxygen atoms linked to two symmetrically equivalent Si atoms and a substitutional Al³⁺ ion across the c-axis channel, a first peroxy radical in quartz. The nuclear quadrupole matrix P also suggests that the Al³⁺ ion corresponds closely to the diamagnetic precursor to the [AlO₄]⁰ center. Electronic supplementary material  The online version of this article (doi:) contains supplementary material, which is available to authorized users.  相似文献   

山东崔家峪玻璃用石英砂岩矿床地质特征及成因          下载免费PDF全文

司荣军  顾雪祥  杨道荣  刘金民  程晓萍  杨学生 《地质找矿论丛》2004,19(1):30-33

崔家峪石英砂岩矿床赋存于下寒武系李官组,矿体呈层状,厚度5.2～15.50 m;矿石中砂结构,分选性好;矿石ω(SiO2)高达98.77%～98.98%,ω(Fe2O3)仅0.038%～0.045%,实属少见的超纯石英砂岩矿床.该矿床形成于温暖潮湿气候下的稳定大陆壳边缘滨海环境,石英直接来源于震旦系土门群砂岩,矿床是剥蚀-沉积多个旋回不断分选富集的结果.研究该矿床地质特征和成因具有地质和找矿指导意义.  相似文献   

蚌埠五河地区金矿床成矿物质来源及其年代学研究——以河口和荣渡金矿床为例     

杨治  邓宇峰  袁峰  李跃  林涛  张顺林  张家嘉 《岩石学报》2019,35(12):3875-3893

安徽省蚌埠五河地区河口和荣渡金矿床是华北地台东南缘蚌埠台隆和五河台坳邻接区域的两个金矿床。本文通过对比研究河口和荣渡金矿床的地质特征、流体包裹体地球化学、Re-Os同位素以及H-O-S同位素特征,来厘定其形成时代、探讨其成矿物质来源和成矿过程。河口及荣渡金矿床矿体主要呈细脉浸染状、脉状和网脉状赋存于古太古代西堌堆地层中,成矿过程可划分为4个阶段:(1)石英脉阶段(早阶段);(2)石英-黄铁矿阶段(早阶段);(3)石英-多金属硫化物阶段(中阶段);(4)碳酸盐阶段(晚阶段);其中,中阶段为金的主要矿化时期。河口和荣渡金矿床早阶段(石英脉和石英-黄铁矿阶段)的石英内发育富液两相包裹体(WL型)、富气两相包裹体(WG)以及少量的含子晶的气液固三相包裹体(S型),均一温度为322～412℃,盐度介于5. 56%～15. 67%NaCleqv之间,属于高温中低盐度流体体系;中阶段(石英-多金属硫化物脉阶段)石英内发育有富液两相包裹体(WL型)、富气两相包裹体(WG),均一温度为257～357℃,盐度介于3. 06%～7. 45%NaCleqv之间,属于中高温低盐度流体体系。从成矿早阶段到主成矿阶段流体的盐度和温度都发生了较大程度的降低,推测矿化过程可能是由流体温度和盐度的降低引起的。成矿阶段石英中流体水的δ~(18)O值介于5. 01‰～7. 90‰之间,δD_(V-SMOW)值介于-89‰～-65‰之间,表明两个矿床的成矿流体为主要为岩浆水。河口金矿床矿石中的黄铁矿δ~(34)S值介于3. 89‰～9. 65‰之间,荣渡金矿床方铅矿δ~(34)S值为0. 76‰,表明河口及荣渡金矿床δ~(34)S值具有岩浆硫的特征,后期由于岩浆去气作用或地层硫的参与使矿石中的δ~(34)S值升高。因此,这两个金矿床可能是与岩浆热液有关的热液石英脉型金矿床。对荣渡金矿床矿石的黄铁矿进行Re-Os同位素定年,确定金矿床形成于134±19Ma,结合前人对该地区所做的岩浆岩定年工作,推测荣渡金矿床的成矿可能与区内130Ma左右的岩浆活动密切相关。  相似文献