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41.
Chantal Guillard Hervé Delprat Can Hoang-van Pierre Pichat 《Journal of Atmospheric Chemistry》1993,16(1):47-59
The photodegradation of naphthalene (NPH), chosen as a model of polynuclear aromatic pollutants, has been studied in the presence of a layer of four water-insoluble inorganic solids which can be found in the troposphere (TiO2, Fe2O3, muscovite, and a fly ash sample). Direct photolysis of NPH is negligible at >340 nm. Dark adsorption of NPH on TiO2 (mainly anatase, nonporous, 50 m2 g–1) at 293 K corresponds to a surface coverage ofca. 50% at equilibrium. Under these conditions (saturated surface), the stationary-state photocatalytic degradation reaches 0.4 molecule nm–2 h–1 (>340 nm, radiant fluxca. 22 mW cm–2). Dioxygen is required and its partial pressure in air is such that the degradation is zero order in O2. Water vapor markedly increases the rate. The other particulates have also an effect, less important than that of TiO2, however quite noticeable with respect to surface area unit for the fly ash sample which contains 3.2% Fe2O3. Apart from 1,4-naphthoquinone, which is the main intermediate product in all cases, 2-naphthol, phthalide, phthaldialdehyde, phthalic acid, acetophenone, benzaldehyde, benzoic acid are also formed on dry TiO2. Depending on their volatility, these compounds are transferred to the gas phase or remain principally adsorbed on the solid particles where they are further transformed. For instance, phthalic acid (or anhydride) and benzoic acid are generated from 1,4-naphthoquinone. Degradation mechanisms are briefly discussed. 相似文献
42.
膜分离技术的应用及发展趋势 总被引:8,自引:0,他引:8
综述世界和中国膜分离技术的发展,并对膜分离技术的基本特性、技术特点、膜材料、分类及膜分离装置进行了简单介绍;并介绍了膜分离法在化工及石油工业、食品工业、医药工业和医疗设备、生物技术和环境工程中的应用,并分析了膜分离技术将会在膜材料、新的膜过程和集成膜过程3个方面的发展趋势。同时指出如果能解决膜产品的价格、膜污染和膜分离性能的提高这3个膜的制约因素,膜分离技术将在人类社会的发展史上起到不可替代的作用。 相似文献
43.
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45.
Performance of Mortar and Chemical Grout Injection into Surrounding Soil When Slurry Pipe-jacking Method is Used 总被引:1,自引:0,他引:1
Hideki Shimada Takashi Sasaoka Saeid Khazaei Yasuhiro Yoshida Kikuo Matsui 《Geotechnical and Geological Engineering》2006,24(1):57-77
Small-diameter shallow tunnels are often being built by using the slurry pipe-jacking method. This system involves the pushing
or thrusting of a drivage machine and concrete pipes into the ground. Chemical grout injection into the surrounding soil around
the tunnel is carried out after the drivage and pushing processes are finished. The purpose of the chemical grout injection
is to maintain permanent stability of the surrounding soil. However, the behavior of the chemical grouting material in the
surrounding soil around the tunnel and the amount of optimum injection is not clearly understood. From these points of view,
this paper discusses the performance of the chemical grouting material, when it is injected into the surrounding soil around
the tunnel, by means of 2-D Eulerian–Lagrangian seepage analysis. Moreover, the effectiveness of the chemical grout injection
was evaluated by using the non-linear finite element method. This investigation show when the range of the grouted zone is
designed; it is necessary that the relationship between Young’s modulus of the soil/grouted zone and the confining stress
be taken into consideration in order to establish effective, economical and safe chemical grout injection system. Understanding
the performance of the seepage/dispersion behavior of the chemical grout and the characteristics of soil/ grouted zone is
also important. 相似文献
46.
The hydraulic behaviour of the karst aquifer in the Hubelj spring catchment area (SW Slovenia) was studied by using an indirect
research method based on natural tracers. The variations of natural tracers (in precipitation and in groundwater) during the
storm event made possible the separation of the Hubelj spring storm hydrograph by the three-component separation technique.
The results produced information on the aquifer recharge, storage and discharge processes, as well as on the mechanisms that
affected them. They verified the so-called epikarst hypothesis presuming that an important part of a karst aquifer recharge
reaches rapidly and intensively from the epikarst zone. It was demonstrated that epikarst water could occupy up to 50% of
the spring discharge during precipitation events. This phenomenon could have important consequences on protection and management
of the problems of karst aquifers, including engineering problems in karst areas. With this respect the results could give
way to new engineering ideas. 相似文献
47.
In their comment, Park & Ree have raised several points against the interpretation by Park et al. , and argued that the remagnetization in the Jeongseon area was caused by the thermal effects of a Late Cretaceous pluton and/or associated short-range hydrothermal fluids, rather than by long-range fluids advocated by us.
We disagree with most points raised by Park & Ree and we make a case that these are invalid because of what we believe is incorrect geologic evidence. Hence, our model—that the fluids causing the chemical remagnetization might migrate through the fault system within the Ogcheon Fold Belt—is the most plausible scenario. We recognize that our model needs to be tested in a future study and we welcome new interpretations for or against our model based on reliable geologic or geophysical data. 相似文献
We disagree with most points raised by Park & Ree and we make a case that these are invalid because of what we believe is incorrect geologic evidence. Hence, our model—that the fluids causing the chemical remagnetization might migrate through the fault system within the Ogcheon Fold Belt—is the most plausible scenario. We recognize that our model needs to be tested in a future study and we welcome new interpretations for or against our model based on reliable geologic or geophysical data. 相似文献
48.
蒋承菘 《中国地质灾害与防治学报》2006,17(3):96-97,102
文章提出另一类型地质灾害,即化学型地质灾害的定义及其分类。并认为化学型地质灾害不像物理型地质灾害那样发生瞬时灾害,而有一个延缓过程,但是一旦发生,难于挽救。化学型地质灾害体的主体是化学元素,开展地球化学调查,研究化学元素的赋存规律、土壤及沉积物承受各类元素的极限、各类元素活化的条件是揭示诱发化学型地质灾害机理的关键。因此要十分重视与加强化学型地质灾害的调查、研究、监测与治理工作。 相似文献
49.
p-nitrotoluene is an important organic intermediate widely used in pesticide, foamed plastics, dyestuff and medicine industries.
In this paper, Crusian carps (Carassius auratus) were exposed to dilute p-nitrotoluene solutions with different concentrations of 0, 20, 40, 80, 120, 160, 240 and 320 μg/L; the subsequent physiological
responses to the chemical were observed, and the variation characteristics of blood corpuscles, ovaries and oocytes were studied
by bio-microscopy. Results showed that even very low concentrations of p-nitrotoluene would lead to toxicosis and even the death of Carassius auratus. The bio-microscopic structures revealed that, compared with the compartment of Carassius auratus growing in the p-nitrotoluene-free water (the control group), the lower concentrations of p-nitrotoluene (for example no more than 80 μg/L) would result in the faster disintegration of erythrocytes and the significant
enlargement of oocytes, while the higher contents of p-nitrotoluene (no less than 240 μg/L in this case) would inhibit the division of cells and their further growth, even degenerate
blood corpuscles and ovaries, suggesting stronger estrogenic activities.
The study is financially supported by the Development Foundation of Science and Technology under Shandong Provincial Education
Department (No. J05D51). 相似文献
50.
1 IntroductionFracturing plays an important role in increasingthe production and injection and enhancing the final re-covery of oil and gas. At present, the use of ahydroxypropyl guar gum, borate-crosslinked, hydraulicfracturing fluid systemhas become ext… 相似文献