陕西小秦岭华阳川韧性剪切带的特征 及其区域构造意义   总被引：1，自引：0，他引：1  

郭威  周鼎武  任军锋  周小虎  桑海清 《地质通报》2008,27(6):823-828

陕西小秦岭华阳川韧性剪切带发育在新太古界太华群之中,野外调研和显微构造观察结果表明,该韧性剪切带是由构造片岩、眼球状片麻岩组成的深层次韧性剪切带,具有逆冲兼左行走滑的斜冲特征。对韧性剪切带构造片岩黑云母进行^40Ar／^39Ar同位素定年,获得坪年龄为419M±0．6Ma,反等时线年龄为417Ma±0．8Ma。认为华阳川韧性剪切带及其相应的小秦岭区域主导构造变形是发生于419Ma左右的秦岭加里东事件的结果。  相似文献   

江西省安福地区地热水化学特征研究     

余廷溪  刘凯  孙军亮  王路瑶  王书训 《地球学报》2024,45(1):99-111

为研究江西安福地区水文地球化学特征及控制因素, 本文采集了15组样品, 采用水化学、同位素分析等方法进行研究。结果表明: 研究区地热水以Na-HCO3型水为主, 地下水以HCO3-Na·Ca型为主, 地表水由西南向东北从HCO3-Na·Ca向HCO3-Ca型水演化。水化学组分演化过程主要受岩石风化作用控制, 地层封闭性较差, 水中的Na+、HCO– 3、Sr2+来源于硅酸岩风化溶解。由稳定同位素特征可知, 研究区地热水补给来源为大气降水。研究区热储温度为49.8~101.4 ℃, 地热水循环深度为1 502.6~1 513.6 m。热水在沿断裂带上升过程中与浅层冷水发生混合, 其混合比例为76.1%~87.5%。研究成果为安福地区水循环演化提供依据, 有利于地热资源的合理开采与保护。  相似文献   

Fe-Cu-Zn-Mo同位素示踪氧化还原过程     

黄思民  张贵宾 《岩石矿物学杂志》2024,43(2):469-494

非传统稳定同位素（Fe-Cu-Zn-Mo）理论与数据相结合提高了科研工作者对地质体系氧化还原过程的理解。本文对这一相对较新的领域进行了综述,包括与氧化还原过程相关的同位素分馏理论和实验约束、时空尺度下的氧逸度以及同位素示踪氧化还原过程。稳定同位素理论预测,Fe-Cu-Zn-Mo同位素应该对氧化还原状态的变化能够做出响应。结果表明,Fe同位素作为岩浆过程、表生过程、俯冲带流体性质"氧逸度计"应用前景广阔;Cu同位素在岩浆、热液、陆地系统可以很好地示踪氧化还原过程;Zn同位素由于络合过程分馏已经被用在许多不同环境中作为含硫/碳流体迁移的敏感示踪剂;Mo同位素作为古氧逸度计可有效重建古海洋-大气氧化还原状态。  相似文献   

Sulfur Isotope Fractionation in Magmatic Systems：Models of Rayleigh Distillation and Selective Flux   总被引：2，自引：0，他引：2  

郑永飞 《中国地球化学学报》1990,9(1):27-45

The effect of Rayleigh distillation by outgassing of SO2 and H2S on the isotopic composition of sulfur remaining in silicate melts is quantitatively modelled.A threshold mole fraction of sulfur in sulfide component of the melts is reckoned to be of critical importance in shifting the δ^34S of the melts mith respect to the original magmas.The partial equilibrium fractionation in a magmatic system is evaluated by assuming that a non-equilibrium flux of sulfur occurs between magmatic volatiles and the melts,while an equilibrium fractionation is approached between sulfate and sulfide within the melts.The results show that under high fo2 conditions,the sulfate/sulfide ratio in a melt entds to increase,and the δ^34S value of sulfur in a solidified rock might then be shifted in the positive direction.This may either be due to Rayleigh outgassing in case the mole fraction of sulfide is less than the threshold,or due to a unidirectional increase in δ^34S value of the sulfate with decreaing temperature,Conversely,at low fo2,the sulfate/sulfide ratio tends to decrease and the δ^34S value of total sulfur could be driven in the negative direction,either because of the Rayleigh outgassing in case the mole fraction of sulfide is greater than the threshold,or because of a unidirectional decrease inδ^34S value of the sulfide.To establish isotopic equilibrium between sulfate and sulfide,the HM,QFM or WM buffers in the magmatic system are suggested to provide the redox couple that could simultaneously reduce the sulfate and oxidize the sulfide.CaO present in the silicatte Melts is also called upon to participate in the chemical equilibrium between sulfate and sulfide,Consequently,the δ^34S value of an igneous rock could considerably deviate from that of its original magma due to the influence of oxygen fugacity and temperature at the time of magma solidification.  相似文献   

辽宁太古代红透山铜矿的稳定同位素地球化学特征及矿床成因     

侯可军  李延河  万德芳 《矿床地质》2006,25(Z2):167-170

文章分析了辽宁太古代红透山铜矿中硫化物的多硫同位素组成和石英的硅氧同位素组成。δ³⁴S在-0.7‰~+3.1‰，极差为3.8‰，平均值为0.21‰，与深部幔源硫相似。δ³³S≈0.52δ³⁴S，即δ³³S=0(δ³³S =δ³³S-1000[(1+ δ³⁴S/1000)0.515-1]，不具有硫同位素非质量分馏效应，表明该矿床中的硫没有经历大气循环过程。矿石中石英的δ30Si分布在-0.8‰~+0.4‰之间，δ¹⁸O分布在+8.5‰~+9.5‰之间，与海底黑烟囱及热水喷气成因硅质岩的硅氧同位素组成相似。提出红透山铜矿为海底热液喷气沉积变质成因。  相似文献   

芙蓉锡矿床及骑田岭A型花岗岩Pb同位素来源示踪     

李晓敏  胡瑞忠  毕献武  彭建堂 《矿床地质》2006,25(Z3):353-254

芙蓉超大型锡矿床与骑田岭A型花岗岩在成因上密切相关。研究表明，该矿床中几种矿石矿物的Pb同位素特征为正常铅，且具有同源性，与“南岭燕山期锡矿床”Pb同位素特征吻合。骑田岭岩体不同单元花岗岩的长石铅和全岩铅亦为正常铅，其特征与“南岭省含锡花岗岩”长石铅同位素特征相似。矿石铅和长石铅主要来源为上地壳，混有少量的下地壳和地幔源铅，且两者间也具有同源性。  相似文献   

同位素地球化学、岩石地球化学——密坑山锡矿同位素年代学研究的启示     

邱检生  蒋少涌胡建 McInnes B I A 凌洪飞 《云南地质》2006,25(4):436-437

密坑山锡矿田位于江西省会昌县西南约40km处。该区为一晚中生代破火山，火山岩为上侏罗统鸡笼嶂组流纹质凝灰熔岩及火山碎屑岩，火山口周围环状及放射状断裂发育，火山口中心为浅成相的密坑山似斑状钾长花岗岩中央岩株侵入体所充填。上世纪80年代以来，在该岩体与流纹质凝灰熔岩的内外接触带相继发现了岩背、淘锡坝、苦竹岽、矿背、上湾等一批大、中型锡多金属矿床或矿点，表明这一岩体对成矿具有重要的制约作用。  相似文献   

High-resolution sedimentary record of lead in the coastal mud of the East China Sea in the past one hundred and fifty years     

Yunchao HAO Zhigang GUO Dejiang FAN 《中国地球化学学报》2006,25(B08):13-13

In the East China Sea （ECS）, there are some mud areas, including the south coastal mud area, the north coastal mud area, and the mud area to the southwest of Cheju Island. X-ray fluorescence （XRF） techniques and Thermal Ionization Mass Spectrometry （TIMS） were used to study the high-resolution sedimentary record of Pb concentrations and Pb stable isotopic compositions in the past one hundred and fifty years in the coastal mud of the ECS. Pb concentrations of a ^210Pb dating S5 core in the study area have increased rapidly since 1980, and reached the maximal value with 65.08 μg/g in 2000, corresponding to the fast economic development of China since the implementation of the ＂Reform and Open Policy＂ in 1978; ^206Pb/^207Pb ratios generally had stabilized at 1.195 from 1860 to 1966, and decreased gradually from 1966 to 2000, indicating that the anthropogenic source Pb contribution to the ECS has increased gradually since 1966, especially since 1980. Pb concentrations decreased distinctly from 2000 to 2003 and ^206Pb/^207Pb ratios increased from 2001 to 2003, corresponding closely to the ban of lead gasoline from 2000 in China. From 1950 to 2003, there occurred four distinct decrease events of ^206Pb/^207Pb, possibly responding to the Changjiang River （Yangtze River） catastrophic floods in 1998, 1991, 1981 and 1954; from 1860 to 1966, there were two decrease periods of ^206Pb/^207Pb, which may respond to the catastrophic floods of Changjiang River in 1931 and 1935, and 1870. As a result of the erosion and drowning by the catastrophic floods, the anthropogenic lead accumulated in soil and water environments over a long period of time was brought into the Changjiang River, then part of them was finally transported into the ECS, which leads to changes in Pb stable isotopic composition.  相似文献   

Boron isotopic geochemistry of karst groundwater in Guiyang City, China     

Wei ZHANG Congqiang LIU Zhiqi ZHAO 《中国地球化学学报》2006,25(B08):172-172

Boron has two stable isotopes （^10B and ^11B） with relative abundances of about 20% and 80%, respectively. Boron isotopic ratios in natural materials show a huge range of variations, from -70‰ to ＋60‰, when expressed with the classical δ^11B notation. Most of these isotopic variations occur at the surface of the Earth. Hence, boron isotopic composition can be used as a sensitive tracer in geochemical study, for instance, to identify the different sources of contamination and factors controlling the salinity of groundwater. During the last decade, boron isotopes have been used to discriminate between the influences of seawater intrusion and anthropogenic discharge. But few of those researches can precisely identify the different sources of contamination. We measured the boron concentrations and boron isotopic ratios of groundwater samples collected in Guiyang City, as well as the major ions. The results indicate that the major ion composition of the groundwater in the investigated area is mainly controlled by the interactions between water and the dominant rock i.e. carbonates. All the water compositions are characterized by high concentrations of Ca^2＋, Mg^2＋, HCO3^-, SO4^2-, and NO3^-, which are the dominant contaminants. Both dissolved boron concentrations and isotopic ratios show large variations among the ground waters, from 2 μg/L to 90 μg/L and from -6‰ to ＋26‰, respectively. The boron concentrations and isotopic ratios indicate that the river across the studied city has been seriously contaminated by urban discharge. Boron concentrations of fiver water samples varied from 20 μg/L to 140 μg/L, with an average δ^11B value of ＋2.0‰. Using boron isotopic compositions and different geochemical indices allowed us to clearly identify and distinguish the two major sources of contamination, agricultural activity and urban wastewater. Both of the two sources are characterized by high boron concentrations but their boron isotopic compositions significantly differ.  相似文献   

The effect of acid deposition on base cation cycling in a karstic-forested catchment： Evidence from strontium isotopes     

Houyi ZHENG Congqiang LIU Zhongliang WANG 《中国地球化学学报》2006,25(B08):174-174

Bedrock weathering and atmospheric deposition are the two primary sources of base cations （K^＋, Na^＋, Ca^2＋ and Mg^2＋） to forest ecosystems. Therefore, the key problem is to understand the relative inputs from these two sources and the cycling in the ecosystem. This study focuses on the effects of acid deposition on cation cycling in a small-forested karstic catchment in Guizhou Province. Sr isotope ratios were used as a tracer for understanding the transport process between the different cation pools： rock, soil, surface water, atmospheric deposition and plant. The samples of wet deposition, total deposition, throughfall, surface and ground waters, vegetation, and soil were monthly collected. The exchangeable Sr^2＋ and Ca^2＋ in soil samples were extracted by using 1 M ammonium acetate. The leaf-tissue samples were ashed at 550℃, and the residue was digested in ultrapure HClO4 and HNO3. All water samples were filtrated through 0.45 μm aperture filter paper. Base cation concentrations and Sr isotopic composition were analyzed for all the samples. The results show that acid deposition （average pH 4.9） frequently occurred in the studied region. Cation abundance follows an increasing manner from rainwater, throughfall, to surface water or ground water samples, suggesting that acid deposition at first eiuviates Ca^2＋ , Mg^2＋ and Sr^2＋ from leaf, then the exchangeable cations from soil, and at last cations accumulate in surface water or ground water.  相似文献