Carbon Isotope Geochemistry of the Orinoco Basin     

F. C. Tan  J. M. Edmond 《Estuarine, Coastal and Shelf Science》1993,36(6)

Stable carbon isotope ratios have been used to study the sources of particulate organic carbon (POC) and total dissolved inorganic carbon in the Orinoco Basin. The isotopic composition of total dissolved inorganic carbon shows a range of from -8·1 to -23·0 ppt, an indication of dominance of biological processes. The isotopic composition of POC exhibits a range of from -24·1 to -34·6 ppt with little seasonal variation. The isotopic evidence indicates that the POC is predominantly of terrestrial origin rather than a result of in situ planktonic production. The similarity of isotopic composition of POC and coastal sediments suggests that riverine organic detritus has been transported 30-50 km offshore in a direction parallel to the Orinoco river channel.  相似文献   

大鹏澳海域水体磷的形态及其分布特征     

彭云辉  王肇鼎 《热带海洋学报》1996,(2)

根据１９９２年１２月（冬季）和１９９３年７月（夏季）对大鹏澳海域２４ｈ定点连续观测和夏季大面调查，统计了该海域各种形态磷的变化范围和平均含量；计算了各种形态磷分别占总磷（ＴＰ）和总溶解磷（ＴＤＰ）的百分比；讨论了各种形态磷之间的相互关系；分析了影响ＴＰ和ＴＤＰ分布的环境因素。  相似文献   

Sources and distribution of organic matter in a river-dominated estuary (Winyah Bay, SC, USA)   总被引：12，自引：0，他引：12  

Miguel A. Goi  Maria J. Teixeira  David W. Perkey 《Estuarine, Coastal and Shelf Science》2003,57(5-6):1023-1048

The sources and distribution of organic matter (OM) in surface waters and sediments from Winyah Bay (South Carolina, USA) were investigated using a variety of analytical techniques, including elemental, stable isotope and organic biomarker analyses. Several locations along the estuary salinity gradient were sampled during four different periods of contrasting river discharge and tidal range. The dissolved organic carbon (DOC) concentrations of surface waters ranged from 7 mg l⁻¹ in the lower bay stations closest to the ocean to 20 mg l⁻¹ in the river and upper bay samples. There was a general linear relationship between DOC concentrations and salinity in three of the four sampling periods. In contrast, particulate organic carbon (POC) concentrations were significantly lower (0.1–3 mg l⁻¹) and showed no relationship with salinity. The high molecular weight dissolved OM (HMW DOM) isolated from selected water samples collected along the bay displayed atomic carbon:nitrogen ratios ([C/N]a) and stable carbon isotopic compositions of organic carbon (δ¹³C_OC) that ranged from 10 to 30 and from −28 to −25‰, respectively. Combined, such compositions indicate that in most HMW DOM samples, the majority of the OM originates from terrigenous sources, with smaller contributions from riverine and estuarine phytoplankton. In contrast, the [C/N]a ratios of particulate OM (POM) samples varied significantly among the collection periods, ranging from low values of 5 to high values of >20. Overall, the trends in [C/N]a ratios indicated that algal sources of POM were most important during the early and late summer, whereas terrigenous sources dominated in the winter and early spring.In Winyah Bay bottom sediments, the concentrations of the mineral-associated OM were positively correlated with sediment surface area. The [C/N]a ratios and δ¹³C_OC compositions of the bulk sedimentary OM ranged from 5 to 45 and from −28 to −23‰, respectively. These compositions were consistent with predominant contributions of terrigenous sources and lesser (but significant) inputs of freshwater, estuarine and marine phytoplankton. The highest terrigenous contents were found in sediments from the river and upper bay sites, with smaller contributions to the lower parts of the estuary. The yields of lignin-derived CuO oxidation products from Winyah Bay sediments indicated that the terrigenous OM in these samples was composed of variable mixtures of relatively fresh vascular plant detritus and moderately altered soil OM. Based on the lignin phenol compositions, most of this material appeared to be derived from angiosperm and gymnosperm vascular plant sources similar to those found in the upland coastal forests in this region. A few samples displayed lignin compositions that suggested a more significant contribution from marsh C₃ grasses. However, there was no evidence of inputs of Spartina alterniflora (a C₄ grass) remains from the salt marshes that surround the lower sections of Winyah Bay.  相似文献   

An Ecosystem Model Coupled with Nitrogen-Silicon-Carbon Cycles Applied to Station A7 in the Northwestern Pacific   总被引：1，自引：0，他引：1  

Yasuhiro Yamanaka  Naoki Yoshie  Masahiko Fujii  Maki N. Aita  Michio J. Kishi 《Journal of Oceanography》2004,60(2):227-241

A model based on that of Kishi et al. (2001) has been extended to 15 compartments including silicon and carbon cycles. This model was applied to Station A7 off Hokkaido, Japan, in the Northwestern Pacific. The model successfully simulated the observations of: 1. a spring bloom of diatoms; 2. large seasonal variations of nitrate and silicate concentrations in the surface water; and 3. large inter-annual variations in chlorophyll-a. It also reproduced the observed features of the seasonal variations of carbon dioxide partial pressure (pCO₂)—a peak in pCO₂ in winter resulting from deep winter convection, a rapid decrease in pCO₂ as a result of the spring bloom, and an almost constant pCO₂ from summer through fall (when the effect of increasing temperature cancels the effect of biological production). A comparison of cases with and without silicate limitation shows that including silicate limitation in the model results in: 1. decreased production by diatoms during summer; and 2. a transition in the dominant phytoplankton species, from diatoms to other species that do not take up silicate. Both of these phenomena are observed at Station A7, and our results support the hypothesis that they are caused by silicate limitation of diatom growth. This revised version was published online in July 2006 with corrections to the Cover Date.  相似文献   

Quantum yield for the photochemical production of dissolved inorganic carbon in seawater   总被引：2，自引：0，他引：2  

Sophia C. Johannessen  William L. Miller 《Marine Chemistry》2001,76(4):108

The direct photooxidation of coloured dissolved organic matter (CDOM) to dissolved inorganic carbon (DIC) may provide a significant sink for organic carbon in the ocean. To calculate the rate of this reaction on a global scale, it is essential to know its quantum yield, or photochemical efficiency. We have determined quantum yield spectra, φ(λ), (moles DIC/mole photons absorbed) for 14 samples of seawater from environments ranging from a turbid, eutrophic bay to the Gulf Stream. The spectra vary among locations, but can be represented quite well by three pooled spectra for zones defined by location and salinity: inshore φ(λ)=e^{−(6.66+0.0285(λ−290))}; coastal φ(λ)=e^{−(6.36+0.0140(λ−290))}; and open ocean φ(λ)=e^{−(5.53+0.00914(λ−290))}. Production efficiency increases offshore, which suggests that the most highly absorbing and quickly faded terrestrial chromophores are not those directly responsible for DIC photoproduction.  相似文献   

Modelling nitrogen and phosphorus cycles and dissolved oxygen in the Zhujiang Estuary Ⅰ.Model results     

管卫兵  王丽娅  许东峰 《海洋学报(英文版)》2001,(4)

rmIoxThe averag annual dischaIge of the Zhujiang Xiver is 3. 32 x l0ll m3, which ranks theZhujiang River just end to the Changjiang River in China. The dischnye occutring duringthe fltal m between APril and ffepteTnber accounts for 80% of the yearly total. The Zhu-jiang hiver has a yeaIy sediment load of about 1 x l08 tons, which also concentrates in theM arn (Zhao, l990; Chen et al., 1998). The Zhujiang Xiver delta,which has l2 cities ofdifferent sizes and more than 40 towns with a po…  相似文献   

虾池的溶解氧含量及其补充量和消耗量   总被引：8，自引：0，他引：8  

林斌  黄凌风  沈国英 《台湾海峡》1995,14(1):9-14

对对虾养殖池塘溶解氧含量及其收支情况的研究结果表明，虾池DO值具有明显的季节和昼夜变化。浮游植物光合作用是虾池溶解氧补充的主要来源，夏季最高可超过5mg／（dm3·d）。养殖后期对虾的耗氧量占总耗氧量的34％，底质和池水耗氧量分别占30％和35％。根据虾池氧的收支情况讨论了池养对虾的生产容量。  相似文献   

Optical properties of low molecular weight and colloidal organic matter: Application of the ultrafiltration permeation model to DOM absorption and fluorescence   总被引：4，自引：1，他引：4  

Claude Belzile  Laodong Guo   《Marine Chemistry》2006,98(2-4):183-196

Cross-flow ultrafiltration (CFF) is often used to obtain separation and concentration of colloids from bulk natural water samples. Application of the ultrafiltration permeation model allows the quantitative determination of the low molecular weight material (LMW, < 1 kDa) and colloids in bulk dissolved organic matter (DOM) from measurements of time series permeate samples obtained from CFF. Detailed analysis of a Yukon River water sample shows that DOM absorption coefficient and fluorescence follow the permeation model and that the complex spectral optical properties of LMW DOM can be reconstructed from CFF data. A combination of measured and modeled data indicates that the LMW contribution to bulk DOM optical properties obtained from CFF can be grossly underestimated by the use of a low concentration factor (CF, the ratio of initial sample volume to retentate volume). Even at a relatively high CF of 19, optical properties of LMW DOM calculated from measurements of the retentate or integrated permeate would underestimate true values by 5–36%. In the Yukon River sample, LMW dissolved organic carbon represented 26% of the bulk concentration, but only 3–14% of the colored DOM was in the LMW fraction while 31–33% of bulk DOM florescence was due to LMW DOM. The contrasting optical properties of LMW and colloidal DOM support the concept that analysis of bulk DOM absorption and fluorescence properties reveals information about DOM molecular weight.  相似文献   

台湾海峡上升流区夏季溶解氧的特征     

陈水土  阮五崎 《热带海洋学报》1992,(3)

本文根据1983—1984年,1987—1988年台湾海峡中北部海域调查资料,着重讨论了该海域夏季溶解氧分布特征及其与上升流、生物活动的关系。该上升流区温度、盐度、溶解氧含量及其饱和度的特征值分别为24.4℃,34.3,4.49mlO_2/L和93％。溶解氧含量及其饱和度与温度呈正相关关系,与盐度呈负相关关系。  相似文献   

珠江口水域化学耗氧量、溶解氧、无机磷与有机磷的三维水质数学模拟   总被引：12，自引：0，他引：12       下载免费PDF全文

林卫强  李适宇 《海洋学报》2003,25(3):129-137

珠江沿岸城市排污量大,对污染源治理能力十分有限,大量污染物通过河流或直接排放到珠江口,河口区半封闭的地形及潮水顶托使得污染物不易输送出外海,致使珠江口水质恶化,原有海洋生态环境遭到破坏,反过来制约了经济的发展.  相似文献