内蒙古查干敖包地区上石炭—下二叠统宝力高庙组特征及时代   总被引：1，自引：1，他引：0       下载免费PDF全文

武跃勇鞠文信  邵永旭姜海蛟 《中国地质》2015,(4):937-947

提要：笔者在查干敖包地区开展1∶5万区域地质调查工作时,发现本区出露的宝力高庙组层序齐全、植物化石丰富、划分标志明显,通过路线调查、剖面测量对其进行了重新划分,即据岩性组合、生物面貌等特征划分为4个岩性段,一段为河湖相灰色、灰绿色碎屑岩夹少量中性火山岩,在粉砂岩中采到了大量安格拉植物化石;二段为中偏碱性-酸性砖红色、紫色火山岩夹砂（砾）岩,其中粗面岩获得锆石U-Pb同位素年龄为(297.0±1.2) Ma;三段为灰色、灰紫色安山质火山岩夹碎屑;四段以灰白色流纹质火山岩为特征,夹砂岩、泥灰岩等,在砂岩中采到了大量安格拉植物群化石。据植物化石鉴定结果、同位素年龄资料将其形成时代确定为晚石炭—早二叠世。  相似文献   

Geochemistry,zircon U–Pb and molybdenite Re–Os dating of the Taolaituo porphyry Mo deposit in the Central Great Hinggan Range: implications for the geodynamic evolution of northeastern China     

Chen Wu  Tian Jiang  Chu Wu  Hanshi Li  Zheng Li  Wencan Liu 《Geological Journal》2016,51(6):949-964

The Taolaituo porphyry‐type molybdenum deposit is located in the eastern Inner Mongolia Autonomous Region in China. The mineralization occurs mainly as veins, lenses and layers within the host porphyry. To better understand the link between the mineralization and the host igneous rocks, we studied samples from the underground workings and report new SHRIMP II zircon U–Pb and Re–Os molybdenite ages, and geochemical data from both the molybdenites and the porphyry granites. Five molybdenite samples yield a Re–Os isochron weighted mean age of 133.0 ± 0.82 Ma, whereas the porphyry granitoids samples yield crystallization ages of 133 ± 1 Ma and 130.4 ± 1.3 Ma. The U–Pb and Re–Os ages are similar, suggesting that the mineralization is genetically related to the Early Cretaceous porphyry emplacement. Re contents of the molybdenites range from 21.74 to 42.45 ppm, with an average of 32.69 ppm, whereas δ³⁴S values vary between 3.7‰ and 4.2‰, which is typical of mantle sulphur. The ²⁰⁶Pb/²⁰⁴Pb, ²⁰⁷Pb/ ²⁰⁴Pb and ²⁰⁸Pb/²⁰⁴Pb vary in the ranges of 18.276–18.385, 15.566–15.580 and 38.321–38.382, respectively. The Taolaituo Early Cretaceous granitoids are A‐type granites. These observations indicate that the molybdenites and the porphyry granites were derived from a mixed source involving young accretionary materials and enriched subcontinental lithospheric mantle. A synthesis of geochronological and geological data reveals that porphyry emplacement and Mo mineralization in the Taolaituo deposit occurred contemporaneously with the Early Cretaceous tectonothermal events associated with lithospheric thinning, which was caused by delamination and subsequent upwelling of the asthenosphere associated with intra‐continental extension in northeast China. Copyright © 2015 John Wiley & Sons, Ltd.  相似文献   

Isotopic Geochemistry of Cadmium: A Review     

ZHU Chuanwei  WEN Hanjie  ZHANG Yuxu  LIU Yizhang  WEI Rongfei 《《地质学报》英文版》2015,89(6):2048-2057

Cadmium (Cd) is a scarce, but not an extremely rare element in the Earth’s crust (crustal average: 0.2 ppm Cd). Geochemically, Cd exhibits thiophile, lithophile, and volatile behavior in different geologic processes. Biologically, it is a nutrient-like element that is closely related to P and Zn and is toxic element to organisms. Presently, Cd isotopes have been successfully utilized to trace Cd sources and nutrient cycling in marine systems in addition to unearthing other geochemical processes. Using published studies and our recent work, this survey summarizes the chemical preparation and mass spectrometry of Cd isotopes. It also reviews Cd isotopic compositions and fractionation mechanisms in nature as well as experiments.  相似文献   

Isotopic composition of dissolved boron and its geochemical behavior in a freshwater-seawater mixture at the estuary of the Changjiang （Yangtze） River     

肖应凯  廖步勇  王中良  魏海珍  赵志琦 《中国地球化学学报》2007,26(2):105-113

The isotopic composition of dissolved boron, in combination with the elemental concentrations of B, Cl and salinities in freshwater-seawater mixed samples taken from the estuary of the Changjiang River, the largest one in China, was investigated in detail in this study. Brackish water and seawater samples from the estuary of the Changjiang River were collected during low water season in November, 1998. Boron isotopic compositions were determined by the Cs2BO^＋2-graphite technique with a analytical uncertainty of 0.2‰ for NIST SRM 951 and an average analytical uncertainty of 0.8‰ for the samples. The isotopic compositions of boron, expressed in δ^11B, and boron concentrations in the Changjiang River at Nanjing and seawater from the open marine East Sea, China, are characterized by δ^11B values of -5.4‰ and 40.0‰, as well as 0.0272 and 4.43 mg B/L, respectively. Well-defined correlations between δ^11B values, B concentrations and Cl concentrations are interpreted in terms of binary mixing between fiver input water and East Sea seawater by a process of straightforward dilution. The offsets of δ^11B values are not related to the contents of clastic sediment and to the addition of boron. These relationships favor a conservative behavior of boron at the estuarine of the Changjiang River.  相似文献   

Mineralization episode of porphyry copper deposits in the Jinshajiang-Red River mineralization belt: Re-Os dating   总被引：10，自引：0，他引：10  

WANG Denghong  QU Wenjun  LI Zhiwei  YIN Hanlong & CHEN Yuchuan Institute of Mineral Resources  Chinese Academy of Geological Sciences  Beijing  China  National Center of Rock  Mineral Analysis  Chinese Academy of Geological Sciences  Beijing  China  Resource Assessment Center of Yunnan  Kunming  China  Institute of Geology  Geophysics  Chinese Academy of Sciences  Beijing  China  Chinese Academy of Geological Sciences  Beijing  China 《中国科学D辑(英文版)》2005,48(2):192-198

Re-Os isotopic dating for the molybdenites from the porphyry copper deposits of the Jinshajiang-Red River mineralization belt in Yunnan Province yields isochron ages of 33.9±1.1 Ma for the Machangqing deposit and 34.4±0.5 Ma for the Tongchang deposit. This result shows that both the Machangqing and the Tongchang porphyry Cu-Mo deposits from two different ore-fields formed simultaneously. This new data and the published Re-Os model ages of molybdenite (35.4 Ma, 35.9 Ma, 36.2 Ma) of the Yulong porphyry copper deposit in Tibet, which is located in the same Jinshajiang-Red River mineralization belt as the Machangqing deposit and the Tongchang deposit, suggest that these three Cenozoic porphyry copper deposits in the Jinshajiang-Red River mineralization belt were contemporary for their mineralization episode. That is to say, even their present locality is far away and nearly iso-distantly distributed, these three porphyry Cu(Mo) deposits belong to the same mineralization episode at the end of Eocene.  相似文献   

Carbon isotopic characteristics and their genetic relationships for individual lipids in plants and sediments from a marsh sedimentary environment   总被引：2，自引：0，他引：2  

DUAN Yi  ZHANG Hui  ZHENG Chaoyang  WU Baoxiang & ZHENG Guodong . Lanzhou Institute of Geology  Chinese Academy of Sciences  Lanzhou  China  . Department of Earth & Planetary System Science  Graduate School of Science  Hiroshima University  Higashi-Hiroshima -Japan 《中国科学D辑(英文版)》2005,48(8):1203-1210

The carbon isotopic compositions of individual lip-ids can provide the genetic information about sedi-mentary lipids so that it has extensively applied pros-pects in geochemically studied field[1―8]. However, this applied research relies heavily on the accumula-tion of studied data in the genetic relationships between carbon isotopic compositions of individual lipids and their biological precursors in different sedi-mentary environments. Recently, the useful δ 13C data of individual lipids f…  相似文献   

Contribution to the study of Greek thermal springs: hydrogeological and hydrochemical characteristics and origin of thermal waters   总被引：1，自引：0，他引：1  

Nicolaos Lambrakis  George Kallergis 《Hydrogeology Journal》2005,13(3):506-521

A large number of chemical analyses of Greek thermal waters were evaluated in order to investigate spring water origin, water–rock interaction mechanisms, and estimate the thermal potential of the geothermal areas. Four water types were distinguished from geochemical diagrams. The relatively fresher waters include samples of Ca–HCO₃ and Mg–HCO₃ type waters originating from the schistose Rhodope Massif and the Quaternary basin of Aridea, respectively. Samples of the Na–HCO3 water type are typical of springs located in the post-orogenic basins of northern Greece. These hot, deep-rising Na–HCO₃ waters circulate in a CO₂-rich environment that favours the solubility of alkaline ions such as Na from siliceous rocks. Most of the samples belong to the Na–Cl water type and originate from Greek islands and coastal springs. These are characterized by the mixing of deep thermal solutions with seawater and fresh water. The presence of CO₂ in thermal and mineral springs is due to the metamorphism of buried marine carbonate horizons while H₂S is due to both local pyrite oxidation and the reduction of sulphates. The use of geothermometers suggested that the investigated geothermal areas have low enthalpy fluids at depth, while higher temperatures are likely present in Milos, Lesvos, Nisyros islands and Xanthi Basin.

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Resumen Se ha evaluado un gran número de análisis químicos de aguas termales griegas con objeto de investigar el origen del agua en los manantiales, los mecanismos de interacción agua-roca, y estimar el potencial termal de las áreas geotérmicas. Se distinguieron cuatro tipos de aguas a partir de diagramas geoquímicos. Las aguas relativamente frescas incluyen muestras de agua tipo Ca–HCO₃ y Mg–HCO₃ que se originan en los esquistos del Macizo Rhodope y la cuenca Cuaternaria de Aridea, respectivamente. Las muestras de agua tipo Na–HCO₃ son típicas de manantiales localizados en las cuencas post-orogénicas del norte de Grecia. Estas aguas calientes y profundas, de tipo Na–HCO₃, circulan en un ambiente rico en CO₂ que favorece la solubilidad de iones alcalinos, tal como Na proveniente de rocas silícicas. La mayoría de las muestras pertenecen al tipo de agua Na–Cl y se originan en islas y manantiales costeros griegos. Estas aguas se caracterizan por la mezcla de soluciones termales profundas con agua de mar y agua dulce. La presencia de CO₂ en manantiales termales y minerales se debe a el metamorfismo de horizontes carbonatados marinos enterrados mientras que el H₂S se debe a oxidación local de pirita y reducción de sulfatos. El uso de geotermómetros sugiere que las áreas termales investigadas tienen fluidos de baja entalpía a profundidad, mientras que las temperaturas más elevadas es probable que se presenten en Milos, Lesvos, islas de Nisyros y la cuenca Xanthi.

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Résumé Un grand nombre danalyses chimiques des eaux thermales grecques ont été menées de manière à investiguer lorigine des eaux des sources thermales, les mécanismes dinteraction avec les roches traversées, et destimer le potentiel des zones géothermiques. Quatre types deau ont été distinguées sur base des diagrammes géochimiques. Les eaux les plus fraîches correspondent respectivement aux échantillons des eaux calco et magnéso carbonatées du massif schisteux de Rhodope et du bassin quaternaire dAridea. Les échantillons deaux sodi carbonatées proviennent typiquement des sources localisées dans les bassins posts-orogéniques du Nord de la Grèce. Ces chaudes et très profondes eaux sodi carbonatées circulent dans des environnements riches en CO₂ qui favorisent la solubilité des ions alcalins, tel que le sodium, des roches siliceuses. La plus part des échantillons ont un facies chloruré sodique et proviennent des îles grecques ou des environnement côtier. Ces eaux sont caractérisées par des mélanges entre eaux profondes avec des eaux de mer et des eaux de surface. La présence de CO₂ dans les eaux de sources thermales et minérales est due au métamorphisme des horizons de calcaires marins et couverts, tandis que la présence de H₂S est due à loxydation locale de la pyrite et à la réduction des sulfates. Lutilisation de géothermomètres suggère que les zones géothermiques étudiées contiennent des eaux à faible enthalpie en profondeur, bien que des températures assez élevées soient rencontrées à Milos, Lesvos, sur les îles Nisyros et dans le bassin de Xanthi.

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Elemental and Sr–Nd isotopic systematics of the early Mesozoic volcanic sequence in southern Jiangxi Province, South China: petrogenesis and tectonic implications     

Yuejun Wang  Weiming Fan  Touping Peng  Feng Guo 《International Journal of Earth Sciences》2005,94(1):53-65

Elemental and Sr–Nd isotopic results are presented for the early Mesozoic volcanic sequence (~172 Ma) in southern Jiangxi Province, South China. The sequence is voluminously composed of ~45% subalkaline basaltic rocks (group 1), <5% high-mg andesite–dacites (group 2) and ~50% rhyolites (group 3). The group 1 rocks are characterized by (La/Yb)_cn = 3.8–7.2, Eu/Eu* = 0.65–1.15, Nb/La = 0.64–0.99, ⁸⁷Sr/⁸⁶Sr(t) = 0.70602~0.70822 and _Nd(t) = –1.63 to +0.11, similar to those of an EMII-like source. The group 2 rocks have mg=0.42~0.60, SiO₂=60.24~66.71%, MgO=2.65~ 5.54%, Ni=24~102 ppm and Cr=84~266 ppm, classified as high-mg andesitic rocks. These rocks are more enriched in LILEs and LREE with more significant negative Eu anomaly (0.63~0.79), are more depleted in HFSEs with Nb/La ratios of 0.40–0.56 and have lower _Nd(t) (–9.44 to –7.78) and higher ⁸⁷Sr/⁸⁶Sr(t) (0.70985~0.71016), in comparison with the group 1 rocks. They most likely originated from metasomatised veins in the lithospheric mantle. The origination of the group 1 and group 2 magma suggests the development of a peridotite-plus-vein lithospheric mantle during early Mesozoic era beneath the interior of the Cathaysian block. The group 3 rhyolites are characterized by high SiO₂ (72.75~77.97%), Zr (99~290 ppm), Hf (3.9~9.7 ppm) and Ga/Al (2.76~3.87) and significant Nb–Ta, Ba–Sr and P–Ti depletions. These rhyolites exhibit Sr–Nd isotopic compositions (⁸⁷Sr/⁸⁶Sr(t) = 0.70962~0.71104, _Nd(t) = –4.63 to –5.80) similar to the contemporaneous Zhaibei and Pitou A-type granites in the area. Such characteristics suggest that they might be derived from the underplating basaltic magma contaminated by crustal materials. Therefore, an early Mesozoic rifting model in response to intracontinental lithospheric extension is proposed to account for the early Mesozoic volcanism in southern Jiangxi Province, South China.  相似文献   

大别山北部卢镇关杂岩的Pb同位素特征及大地构造属性   总被引：3，自引：0，他引：3  

刘贻灿  江来利  储东如  吴维平 《矿物岩石》2004,24(4):53-58

Pb同位素组成研究表明,卢镇关杂岩中花岗片麻岩的^204Pb为1．366％～1．392％(平均为1．381％)、^206Pb／^204Pb为17．083～17．874(平均为17．463)和^204Pb／^204Pb为38．161～38．794(平均为38．438);斜长角闪岩的^204Pb为1．386％～1．412％(平均1．400％),其^206Pb／^204Pb为17．001～17．492(平均17．227)和^208Pb／^204Pb37．390～38．151(平均37．713)。二者的总平均为：^204Pb1．389％,^204Pb／^204Pb17．362,^208Pb／^204Pb38．127。与北部杂岩带和南部超高压变质带比较,卢镇关杂岩明显类似于南部超高压变质带的Ph同位素组成即表现为贫非放射成因铅和富集放射成因铅,表明它们应属于扬子大陆板块的一部分。考虑到北部杂岩带在地壳结构上应位于南部超高压带之下,以及北大别正片麻岩具有中、下地壳性质而南大别花岗片麻岩则具有上地壳特征。因此,卢镇关杂岩也应属于扬子大陆的上地壳,华北与扬子两个陆块之间的缝合线应在卢镇关杂岩以北。但是,由于在北淮阳带中一直未发现榴辉岩或榴辉岩相岩石等高压一超高压岩石以及有关印支期变质作用记录,说明至少卢镇关杂岩在印支期未卷入深俯冲,大别山的印支期俯冲带应位于卢镇关杂岩的南侧即磨子潭晓天断裂附近,大别山印支期深俯冲应属于扬子板块的陆内俯冲。  相似文献   

Characteristic　analysis　on　oxygen　isotopic　tracer　in　the　East　China　Sea　and　waters　to　east　of　the　Ryukyu－gunto     

Hong Ashi  Yuan Yaochu 《海洋学报(英文版)》1995,(3)

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