Structure cristalline d'une ménéghinite naturelle pauvre en cuivre,Cu_0,58Pb_12,72(Sb_7,04Bi_0,24)S₂₄Crystal structure of a Cu-poor natural meneghinite,Cu_0.58Pb_12.72(Sb_7.04Bi_0.24)S₂₄     

Yves Moëlo  Pierre Palvadeau  Nicolas Meisser  Alain Meerschaut 《Comptes Rendus Geoscience》2002,334(8):529-536

Cu-poor meneghinite from La Lauzière Massif (Savoy, France) has the composition (electron microprobe) (in wt%): Pb 59.50, Sb 20.33, Bi 1.19, Cu 0.87, Ag 0.05, Fe 0.03, S 17.62, Se 0.05, Total 99.64. Its crystal structure (X-ray on a single crystal) was solved with R1=0.0506, wR2=0.1026, with an orthorhombic symmetry, space group Pnma, and a=24.080(5) Å, b=4.1276(8) Å, c=11.369(2) Å, V=1130.0(4) Å³, Z=4. Relatively to the model of Euler and Hellner (1960), this structure shows a significantly lower site occupancy factor for the tetrahedral Cu site (0.146 against 0.25). Among the five other metallic sites, Bi appears in the one with predominant Sb. Developed structural formula: Cu_0.15Pb₂(Pb_0.53Sb_0.47)(Pb_0.46Sb_0.54)(Sb_0.75Pb_0.19Bi_0.06)S₆; the reduced one: Cu_0.58Pb_12.72(Sb_7.04Bi_0.24)S₂₄. The formation of such a Cu-poor variety seems to be related to specific paragenetic conditions (absence of coexisting galena), or to crystallochemical constraints (minor Bi). To cite this article: Y. Moëlo et al., C. R. Geoscience 334 (2002) 529–536.  相似文献   

阿尔泰可可塔勒铅锌矿床围岩蚀变及成因   总被引：2，自引：3，他引：2  

姜俊 《矿产与地质》2003,17(6):679-682,734

可可塔勒铅锌矿床受火山喷发中心和沉积洼地控制，铅锌沉淀于海进阶段的局限还原卤水池中；矿下存在大型蚀变带，构成成矿流体对流循环过程中的水-岩作用带；后期造山挤压过程使地层和矿体倒转，矿床最终定位于麦兹倒转向斜之北东倒转翼的东南近转折部位。指出该矿床属海底火山喷流沉积改造型块状硫化物铅锌矿床。  相似文献   

Re-Os Age of Cu-Ni Ores from the Huangshandong Cu-Ni Sulfide Deposit in the East Tianshan Mountains and Its Implication for Geodynamic Processes   总被引：4，自引：0，他引：4  

MAO Jingwen  YANG Jianmin  QU Wenjun  DU Andao  WANG Zhiliang  HAN Chunming Faculty of Geosciences  Resources  China University of Geosciences  Beijing  E-mail: jingwenmao@.netInstitute of Mineral Resources  Chinese Academy of Geological Sciences  Beijing National Research Center of Geoanalysis  Chinese Academy of Geological Sciences  Beijing 《《地质学报》英文版》2003,77(2):220-226

An isochron age of 282±20 (95% conf. limit) Ma of the sulfide ores in the Huangshandong Cu-Ni sulfide deposit, the East Tianshan Mountains has been obtained through Re-Os isotopic measurement. The age implies that the Cu-Ni sulfide deposit and other related deposits in the same area occurred in a Permian extensional environment of post-collision instead of Devonian-Early Carboniferous ophiolite-related oceanic or island arc environments inferred before. It shares the same ages with the orogenic and epithermal gold deposit systems in the same area. An initial 187Os/188Os ratio of 0.25±0.04 (1σ) and a γos value of 99 on average display the participation of large quantities of crustal components into the rock-forming and ore-forming system during mineralization and magmatic emplacement.  相似文献   

略阳煎茶岭铜镍硫化物矿床Re—Os同位素年龄及其地质意义   总被引：12，自引：0，他引：12  

王瑞廷  赫英  王东生  刘民武 《地质论评》2003,49(2):205-211

采用矿石Re-Os同位素方法对陕西省煎茶岭硫化镍矿床矿石进行了成矿年代学研究,获得了878士27 Ma(1σ)的等时线年龄,首次厘定了该矿床成矿时代为新元古代,成岩成矿基本同时.通过对878 Ma硫化镍矿石初始Re-Os同位素体系的γOs计算和Re/Os值分析表明,其yOs和Re/Os值变化范围大,深部条带状矿石的Re/Os值仅为0.05,yOs为-6.70;块状矿石的Re/Os值范围为4.24～24.43,γOs为-15.37～+280.65,说明成矿过程中有壳源物质的混染;两件样品的γOs为负值(-15.37,-6.70),可能指示其超镁铁质岩浆来源于Re亏损地幔.煎茶岭超基性岩体年龄及其镍矿石的Re-Os等时线年龄与扬子克拉通北缘火山岩浆活动时间相对应,它们是扬子克拉通西北缘晋宁期构造岩浆成矿作用的产物.  相似文献   

中子活化分析在铼—锇法年龄测定中的应用     

屈文俊  杜安道 《岩矿测试》1997,16(4):289-292

同位素稀释中子活化分析铼与感耦等离子体质谱法测定锇相结合，应用于辉钼矿及铜＿镍硫化物矿物的铼＿锇年龄测定，取得了满意的结果，扩大了铼＿锇测年法的应用范围。  相似文献   

建德铜矿床的海底喷流沉积成因   总被引：2，自引：0，他引：2  

刘家军  李元林 《矿产与地质》1996,10(3):145-154

建德铜矿床是浙江西部多金属成矿带中一个引人瞩目的重要矿床。它产于中石炭统底部伴有火山岩、硅质岩和碧玉岩的白云岩中。整合块状矿体之下有一筒状矿化蚀变带。其成分以Ｃｕ＞Ｚｎ＞Ｐｂ为特征。根据矿床地质、地球化学特征以及近年来研究所获得资料，认为该矿床属海底喷流沉积成因  相似文献   

太白维山大型银矿床地质地球化学特征   总被引：1，自引：0，他引：1  

秦明宽  叶荣 《铀矿地质》1997,13(1):30-36

太白维山大型银矿床为典型的中低温火山－次火山隐爆角砾岩型矿床，受岩性和断裂构造控制明显，矿体的产出部位和矿石品级与隐爆角砾岩关系密切。本文通过对基岩和１：２０万水系沉积物资料的分析与处理，得出基岩中主成矿元素组合为Ａｇ－Ｃｕ－Ｐｂ－Ａｓ－Ｓｂ－Ｚｎ，水系沉积物中主成矿元素组合为Ａｇ－Ｐｂ－Ｚｎ－Ｃｄ－Ｍｎ－Ｈｇ的结论，同时指出Ｐｂ可作为此矿床最重要的间接指示元素，而主成矿元素中各单元素异常浓集中心对银矿床的产出部位有很好的指示作用，为找矿的重要指标。  相似文献   

内蒙古镁铁质-超镁铁质岩型铜镍矿床成矿条件与找矿远景分析   总被引：5，自引：2，他引：5  

刘国军  王建平 《地质与勘探》2004,40(1):17-20

按构造环境控岩控矿特点,划分区内铜镍型矿成矿(岩)带,分析成矿条件,研究了与该类矿床成矿有关的镁铁质岩、超镁铁质岩分布规律及铜镍硫化物成矿特征,提出了找矿方向和建议.  相似文献   

石岭沟-拐道沟铜-铅-锌多金属成矿带成矿地质条件分析     

常宗东  韦龙明  王设计  高卫宏  张万业 《矿产与地质》2004,18(2):122-127

成矿带位于北秦岭北部晚元古代-早古生代裂谷带南缘的变质火山岩区，受油房-皇台断裂的次级分支断裂及燕山-印支期的侵入岩体及次火山岩脉的联合控制，成矿地质条件与甘肃白银厂铜-铅-锌矿田相类似，成矿带内地表已发现多条铜-铅-锌矿(化蚀变)体，找矿潜力较大，只要进一步深入开展工作，有望找到与白银厂铜-铅-锌矿田相类似的大型一超大型铜-铅-锌多金属矿床。  相似文献   

Improved Platinum-Group Element Extraction by NiS Fire Assay from Chromitite Ore Samples Using a Flux Containing Sodium Metaphosphate   总被引：1，自引：0，他引：1  

L. Paul Bédard  Sarah-Jane Barnes 《Geostandards and Geoanalytical Research》2004,28(2):311-316

Many chromite-rich rocks contain relatively high concentrations of the platinum-group elements (PGE). In many cases, the phases carrying PGE occur as either platinum-group minerals (PGM) or as base metal sulfides in solid solution in sulfides. In some cases, such as the UG-2 unit of the Bushveld Complex, the PGM are occluded inside chromite grains. Chromites are notably difficult to dissolve in most fluxes and if the chromite contains some PGM the possibility exists that not all the PGE will be recovered during fusion. In this work, shortcomings in published methods of analysis based on the nickel sulfide fire assay procedure were investigated and a new procedure developed based on the addition of sodium metaphosphate to the fusion mixture. Optimum composition of the fusion mixture was found to be 10 g sodium metaphosphate and 9 g silica to 10 g sample, 15 g sodium carbonate, 30 g lithium tetraborate, 7.5 g nickel and 4.5 g sulfur to achieve complete dissolution of chromite grains. The new flux mixture was evaluated by the analysis of reference material CHR-Pt+ (which is known to contain PGM inside chromite grains) and no undissolved chromite grains were found in the glassy slag. Analysis of the nickel sulfide beads from this fire assay using neutron activation analysis showed similar results for Rh and Ru when compared with published conventional true (or accepted) values, while Au, Ir, Os, Pd and Pt values determined here were 10 to 30% higher than the corresponding published conventional true values. It was concluded that the addition of sodium metaphosphate improved chromite dissolution in the flux and appears to improve PGE recovery.  相似文献