1.8 Ga magmatism in southern Finland: strongly enriched mantle and juvenile crustal sources in a post-collisional setting     

《International Geology Review》2012,54(14):1622-1683

Whole-rock and isotope geochemistry of six ～1.8 Ga post-kinematic intrusions, emplaced along the ～1.9 Ga Southern Svecofennian Arc Complex (SSAC) and in the SW part of the Karelian Domain in Finland, was studied. The intrusive age [U–Pb secondary ion mass spectrometer (SIMS)] of one of these, the Petravaara Pluton, was determined as 1811 ± 6 Ma.

Basic-intermediate rocks are alkali-rich (K₂O?+?Na₂O > 4 wt.%) and typically shoshonitic, strongly enriched in large ion lithophile elements and light rare earth elements, but relatively depleted in high field strength elements and heavy rare earth elements. The enrichment is much higher than can be accounted for by crustal contamination and requires previously melt-depleted mantle sources, subjected to variable metasomatism by carbonate-rich fluids and sediment-derived melts. These sources are inferred to consist of phlogopite ± amphibole-bearing peridotites from depths below the spinel–garnet transition, as shown by the high Ce/Yb ratios. ⁸⁷Sr/⁸⁶Sr(1.8 Ga) ratios in the range 0.7027–0.7031 and ‘mildly depleted’ ?_Nd(1.8 Ga) values (+0.1 to?+1.4), with T _DM values <2.1 Ga, suggest that mantle enrichment was associated with the previous Svecofennian subduction–accretion process, when enriched sub-Svecofennian mantle sections developed, dominantly characterized by ¹⁴⁷Sm/¹⁴⁴Nd ratios of 0.14–0.17.

The associated granitoids are diversified. One group is marginally peraluminous, transitional between I (volcanic-arc) and S (syn-collisional) types, and was derived from mixed igneous and sedimentary, but juvenile Svecofennian source rocks, as supported by near-chondritic ?_Nd(1.8 Ga) and somewhat elevated ⁸⁷Sr/⁸⁶Sr(1.8 Ga). The other group is transitional between I and A (within-plate) types in character and had dominantly igneous protoliths. The whole-rock geochemistry and isotopes suggest that the compositional variation between ～50 and 70 wt.% SiO₂ may be explained by hybridization between strongly enriched mantle-derived magmas and anatectic granitic magmas from the juvenile Svecofennian crust. One intrusion in the east contains a significant portion of Archaean, mostly igneous protolithic material (?_Nd(1.8 Ga)?=?–2.8 and ?_Hf(t) for zircons between?+2.8 and??11.9, with an average of??4.9).

The ～1.8 Ga post-kinematic intrusions were emplaced within the SSAC subsequent to the continental collision with the Volgo-Sarmatia craton from the SE, during a shift from contraction to extension, that is, in a post-collisional setting.  相似文献   

Review of melting experiments on carbonated eclogite and peridotite: insights into mantle metasomatism     

《International Geology Review》2012,54(12):1443-1455

Experimental studies on the partial melting of eclogite and peridotite provide important clues on mantle metasomatism. Here, we review results from some of the recent experiments and show that melting of carbonated eclogite and peridotite can produce carbonatitic to carbonated silicate melt, in which carbonates melt preferentially before Ti oxides and silicates. Low-degree melting results in carbonatitic melt coexisting with Ti oxides and silicates. This process also leads to the fractionation between some high-field strength elements (Nb, Ta, Zr, Hf, and HREE) and highly incompatible elements (U and Th) in the melt. When Ti oxides are nearly exhausted in eclogite, extremely high TiO₂ contents (e.g. 19 wt.%) are present in the melt with marked concentration of Nb and Ta. These results help to explain the features of carbonatitic metasomatism and the Nb–Ta spike in oceanic island basalts as identified in experimental studies. These studies also explain the reducing conditions that stabilize diamond in the deep mantle (>150 km) as well as the occurrence of diamond at different depths reported in various studies. Melting in such a reduced mantle can happen through redox reaction between diamond, pyroxene, and olivine, in which the initial liquid is a carbonated silicate melt. However, the theoretical oxygen fugacity (fO₂) in the asthenosphere is much lower than that predicted by the reaction and requires elevated fO₂, which can be caused by the addition of relatively oxidized materials from the lower mantle, deep asthenospheric material, and various recycled components. A combination of these processes generates locally oxidized domains in the deep mantle.  相似文献   

相山矿田邹家山铀矿床碱交代矿化蚀变岩地球化学   总被引：4，自引：0，他引：4  

胡宝群  王倩  邱林飞  孙占学  王运  吕古贤  胡荣泉 《大地构造与成矿学》2016,(2):377-385

相山矿田邹家山铀矿床成矿作用与碱交代关系密切。钠、钾的带入和带出极大地影响铀成矿作用过程,钠交代和钾交代对铀成矿的影响差异明显。本文以邹家山铀矿床中典型的钠化和钾化矿体为研究对象,通过比较两矿体剖面的地球化学特征,研究其异同,探讨钠交代、钾交代与铀成矿作用关系,得出以下认识:(1)与矿体两侧的围岩相比,钠交代和钾交代矿石中都富U和Mo,而Ba含量明显降低;(2)钠交代对原岩化学成分的改变不强。除了钠含量明显增高、钾含量明显降低、钠钾摩尔比M(Na2O/K2O)明显增大外,矿石与原(或围)岩的化学成分相差不大,总碱摩尔数M(Na2O+K2O)几乎不变;(3)钾交代对原岩的矿物及化学成分改变很大。除钾高、钠低等含量变化外,强烈去Si和Na,M(Na2O+K2O)有20%~30%的减少,而且许多微量(成矿)元素含量明显增加,特别是稀土元素明显增高,且重稀土增加更快;(4)两类碱交代中行为反差最大的组分是Na2O、K2O、Si O2和REE。钠交代过程中,Na2O和Si O2增加,K2O和REE减少,M(Na2O/K2O)明显增大;而钾交代过程正相反;(5)在相山铀成矿过程中,仅有钠交代时铀的含量较低,强钾交代是形成富铀矿的必要条件。  相似文献   

接触交代型铜矿床硫同位素地球化学研究     

李蘅  徐文炘  陈民扬  丁汝福 《矿产与地质》2016,(6):940-943

我国接触交代型铜矿床主要集中在长江中下游和燕辽等成矿带;主要矿体产于浅成或超浅成中酸性侵入岩与碳酸盐岩接触带.主要矿物组合为黄铜矿、黄铁矿、磁铁矿、赤铁矿(少数矿床可见)、磁黄铁矿(少数矿床未见)、斑铜矿、钙铁榴石、透闪石、石英和方解石.矿床硫化物的硫同位素组成主要显示出两种特征,一种是单个矿床硫同位素组成变化范围大,变化范围在5‰~10‰,又有较大正值出现(如马鞍山、铜录山、铁山、个旧卡房和冬瓜山等矿床);另一种单个矿床硫同位素组成变化范围小,一般不超过5‰,具有小的正值特点(如索尔库都克、武山、铜官山、城门山、赛什塘、七宝山等矿床).根据硫同位素组成特征可以获得索尔库都克、武山、铜官山、城门山、赛什塘、七宝山等矿床的硫来自单一岩浆来源;马鞍山、铜录山、铁山、卡房和冬瓜山等矿床的硫来自于岩浆与围岩膏盐层混合来源.  相似文献   

Research Progress about the Mixing Brine Method to Produce Low- Sodium Carnallite from Saline Lake Brine     

TAN Qi  ZENG Ying  GUO Shanshan 《《地质学报》英文版》2014,88(Z1):372-372

正Mixing brine method,which founded on the commonion effect,is widely used for low-sodium carnallite production.Compared with traditional carnallite preparation techniques,the mixing brine method possess a  相似文献   

福建宁德下洋伊利石矿矿床地质特征及成因探讨     

林国珍  林志鹏 《福建地质》2014,(3):192-196

宁德下洋伊利石矿呈脉状产出,贮存于晚侏罗世南园组火山碎屑岩石中,共发现有3个矿体。矿石可分为石英一伊利石型及叶蜡石伊利石型。矿体受北东向断裂控制,由火山碎屑岩经过热液交代形成。  相似文献   

马里亚纳南部前弧橄榄岩的岩石及矿物学:对弧下地幔楔交代作用的指示   总被引：1，自引：0，他引：1  

陈俊兵  曾志刚 《海洋地质与第四纪地质》2007,27(1):53-59

描述了来自马里亚纳南部前弧的橄榄岩,并对其中的组成矿物进行了电子探针分析,结果显示来自马里亚纳南部前弧橄榄岩中普遍含角闪石,这些角闪石主要为镁角闪石—透闪石系列,其中Al2O3含量变化范围大约为0-10%。橄榄岩中尖晶石的化学组成变化规律与角闪石的出现及其成分有着较好的耦合关系:出现富Al2O3角闪石的橄榄岩中的尖晶石富Al贫Cr;贫Al2O3角闪石大量出现的橄榄岩中尖晶石相对贫Al富Fe3 。这暗示马里亚纳弧下地幔楔橄榄岩经历了两期比较明显的交代作用:①早期较高温压条件下富Al和Ca的含水流体(熔体)的交代作用,消耗斜方辉石,形成富Al2O3角闪石,并引起尖晶石的富Al贫Cr的成分演化;②晚期较低温压条件下富Ca的含水流体(熔体)的交代作用,继续交代残余的斜方辉石,形成贫Al2O3角闪石,并使尖晶石发生富Fe3 贫Al。  相似文献   

国外芒硝资源及其开发利用          下载免费PDF全文

曹兆汉 《盐湖研究》1993,1(2):53-66

在整个化学工业历史中,硫酸钠曾占有重要的地位。由于它是一种天然盐资源和作为许多化学加工副产品的来源丰富,使其价格低廉。在一定的条件下,它曾作为碱(Na_2O)和硫的来源,但这些用途都需消耗高的能源。在二十世纪初期,由于硫酸盐纸浆法的开发和商业化,使硫酸钠出现新的用途。二次世界大战以来,利用它的化学惰性和低价,导致它作为家用洗涤剂的填料。自80年代以来,由于以上工业中采用了先进的工艺以及经济和环保上的诸因素,使硫酸钠用量逐年降低。这种下降趋势将持续到90年代,除非开发耗量大的新用途。其中最具有远景的是利用电渗析法使硫酸钠转化为硫酸和苛性碱。该法已进入中试阶段,并预期具有商业化的潜力。无论天然的或副产品的加工工艺,都采用同样的基本原理以获得畅销的硫酸钠。几乎所有的生产者,都将这种原料结晶成芒硝,使其纯化,然后用熔融或完全脱水将芒硝转化成无水物,后者即可在有关工业中应用或进行再加工。本文综述芒硝和硫酸钠资源的开发历程、地球化学、储量、脱水、再加工、用途和展望等方面,并着重于脱水和电渗析技术以及其他再加工。  相似文献   

盐田兑卤法提高光卤石矿质量的方法探讨   总被引：1，自引：1，他引：0       下载免费PDF全文

李建国  王成玲 《盐湖研究》2007,15(3):33-36,47

通过相图分析及计算,介绍了一种"由盐湖卤水兑卤除氯化钠后,首先获得成矿卤水,然后对其蒸发制取质量较好光卤石矿"的生产方法。  相似文献