Structural properties of (Mn1-x Fe x )Nb2O6 columbites from X-ray diffraction and IR spectroscopy     

S. C. Tarantino  M. Zema  F. Maglia  M. C. Domeneghetti  M. A. Carpenter 《Physics and Chemistry of Minerals》2005,32(8-9):568-577

A suite of (Mn_1-x Fe _x )Nb₂O₆ (x=0, 0.05, 0.25, 0.50, 0.75, 1) columbite samples has been prepared by solid-state reaction from oxides. X-ray diffraction and spectroscopic investigations have been carried out in order to gain different perspectives on how the solid solution adapts at different length scales to cation mixing. X-ray powder diffraction and powder absorption IR spectroscopy data are presented. The powder diffraction data show that there is no significant excess volume of mixing on the Fe–Mn columbite join. All the unit-cell parameters decrease linearly as a function of increasing Fe content. Substitution of Fe²⁺ for the larger Mn²⁺ cation causes a decrease in the volume of the A polyhedron, which also becomes more regular with respect to both bond-length and edge-length distortion parameters. No significant variation of the B site has been observed. Wavenumber shifts of the IR peaks nearly all vary linearly with composition, consistent with linear variations of the lattice parameters. Line broadening has been quantified by autocorrelation analysis of the IR spectra. This is interpreted as suggesting that there is some element of local strain or positional disorder at the length scale of second or third nearest neighbours around sites occupied by Fe.  相似文献   

固体潮观测数据预处理中的一些常用方法及其计算机实现     

熊先保 《福建地震》2005,(Z1)

试图从台站产出的原始地形变前兆数据出发,提出一些实际操作性较强的预处理方法,从已编制好的软件中给出处理实例,从而达到提高台站观测人员的科研能力,填补资料预处理方面的某些空白的目的,这对于台站人员集观测、科研于一体有着十分重要的意义。从95-01-02项目厦门地震台前兆数据预处理的实践表明:这些方法取得了明显的实效,直到今天仍然具有很大的使用价值。  相似文献   

Preservation of coal-waste geochemical markers in vegetation and soil on self-heating coal-waste dumps in Silesia,Poland     

《Chemie der Erde / Geochemistry》2016,76(2):211-226

Occurrence and distributions of geochemical markers on vegetation and in soils covering two self-heating coal waste dumps were investigated with gas chromatography-mass spectrometry (GC–MS) and compared with those of bitumen expelled on the coal waste dump surface. Presence of biomarkers, alkyl aromatic hydrocarbons, polycyclic aromatic hydrocarbons (PAHs), and such polar compounds as phenols indicate that components of self-heating coal wastes indeed migrate to soils and plants surface and their characteristic fingerprints can be applied in passive monitoring to investigate migration of contaminants from self-heating coal wastes. Moreover, results allow to discriminate between the Upper- and Lower Silesian coal basins, notwithstanding value shifts caused by heating. Mechanisms enabling the migration of geochemical compounds into soils include mixing with weathered coal-waste material, transport in gases emitted due to self-heating and, indirectly, by deposition of biomass containing geochemical substances. Transport in gases involves mostly lighter compounds such as phenols, methylnaphthalenes, methylbiphenyls, etc. Distributions and values of geochemical ratios are related to differences in their boiling temperatures in the case of lighter compounds but preserve geochemical features in the case of heavier compounds such as pentacyclic trierpanes.  相似文献   

Evidence of technetium and iodine release from a sodalite-bearing ceramic waste form     

《Applied Geochemistry》2016

Sodalites have been proposed as a possible host of certain radioactive species, specifically ⁹⁹Tc and ¹²⁹I, which may be encapsulated into the cage structure of the mineral. To demonstrate the ability of this framework silicate mineral to encapsulate and immobilize ⁹⁹Tc and ¹²⁹I, single-pass flow-through (SPFT) tests were conducted on a sodalite-bearing multi-phase ceramic waste form produced through a steam reforming process. Two samples made using a steam reformer samples were produced using non-radioactive I and Re (as a surrogate for Tc), while a third sample was produced using actual radioactive tank waste containing Tc and added Re. One of the non-radioactive samples was produced with an engineering-scale steam reformer while the other non-radioactive sample and the radioactive sample were produced using a bench-scale steam reformer. For all three steam reformer products, the similar steady-state dilute-solution release rates for Re, I, and Tc at pH (25 °C) = 9 and 40 °C were measured. However, it was found that the Re, I, and Tc releases were equal or up to 4.5x higher compared to the release rates of the network-forming elements, Na, Al, and Si. The similar releases of Re and Tc in the SPFT test, and the similar time-dependent shapes of the release curves for samples containing I, suggest that Re, Tc, and I partition to the sodalite minerals during the steam reforming process.  相似文献   

高放废物处置库新疆阿奇山预选地段区域水文地质特征   总被引：1，自引：0，他引：1  

郭永海  何建国  周志超  董建楠  季瑞利  张明  李杰彪 《铀矿地质》2016,(4):251-256

新疆阿奇山地区是我国高放废物处置库预选地段之一。在野外调查、样品采集和测试的基础上,讨论了该地段区域水文地质特征,结果表明,阿奇山地段地下水可划分为松散岩类孔隙水、碎屑岩类裂隙孔隙水和基岩裂隙水3种类型,其单井涌水量一般10m~3/d,属于典型的低含水介质;区域地下水流向为自南东流向北西;位于吐鲁番盆地的艾丁湖一带为阿奇山地段地下水的最终排泄区。  相似文献   

Profit,reputation and ‘doing the right thing’: Convention theory and the problem of food waste in the UK retail sector     

《Geoforum》2018

In 2014, Tesco – one of the world’s largest food retailers – revealed that it had generated almost 57,000 tonnes of food waste in its UK operations over the previous twelve-month period. This shocking statistic added to existing evidence of a significant environmental and social problem in the UK and across the world. This paper utilises convention theory to examine the role of major retailers in the context of this global problem and assesses their motivations for acting on food waste. Drawing on interviews with key stakeholders (including major retailers), the analysis investigates their main justifications for action on food waste. It finds that retailers mostly appealed to three conventions or ‘orders of worth’ (civic, market and opinion) and used these as a basis for their commitment to food waste reduction. We argue that the combination of these different justifications is feasible and necessary in the context of the retail sector but that they may also lead to some unintended consequences (in the retail sector and beyond). Crucially, we demonstrate how the dilution of civic justifications (by their financial and reputational counterparts) might produce negative outcomes and inaction as retailers attempt to adhere to the so-called ‘food waste hierarchy’. The paper highlights the continuing significance of convention theory as a framework for analysing possible responses to the social and environmental challenges confronting global agro-food systems.  相似文献   

处置单元核素¹³⁵Cs迁移数值模拟研究     

彭志娟  李寻  陈经明  周泽超 《地下水》2018,(6):113-116

根据高放废物地质处置库概念设计,以北山花岗岩为参考岩性,内蒙古高庙子膨润土为参考缓冲材料,使用数值模拟软件tough2对放射性核素¹³⁵Cs在处置单元及其围岩中的迁移行为进行了数值模拟研究,考虑放射性核素衰变释热对核素迁移的影响。研究表明:膨润土对核素具有较强的滞留作用,模拟200000年后核素在花岗岩中迁移了1 m左右,且峰值为10-6个数量级;前10 a模型的温度变化最剧烈且温差最大,10 a后模型整体温度开始降低,2 000 a后整体温度接近于初始温度;温度的变化会引起核素迁移速率的改变,但总体温度对核素迁移的影响不大。  相似文献   

花岗岩风化料弃土快速堆填过程中不排水抗剪强度评估     

詹良通  孙倩倩  郭晓刚  陈锐  陈云敏 《岩土力学》2021,(1):50-58

沿海沿江城市地下开挖产生的工程渣土含泥量大、含水率高且较松散,主要运往渣土场进行堆填处置。由于产量巨大而处置场地有限,许多渣土场在运营过程中存在堆填速度快、缺乏排水设施、超高超库容堆填等问题,容易引发堆填体失稳事故。目前对于非饱和工程渣土堆体在快速堆填过程中的失稳机制认识尚不清晰,尤其是对这一过程中的高饱和度工程渣土强度增长规律缺乏足够的认识。以深圳红坳渣土场填料——花岗岩风化料(CDG)填土为研究对象,对不同初始饱和度土样进行三轴不排水不排气等向压缩和剪切试验,结果表明:非饱和CDG填土不排水抗剪强度随围压增大呈非线性增长,增长速率与试样初始饱和度密切相关;当土样压缩后的饱和度超过0.7,不排水强度随围压的增长速率显著降低。基于有效固结应力法的原理,结合Hilf孔压公式和修正剑桥模型,提出了一种工程渣土不排水抗剪强度估算方法,并通过与试验结果对比验证了该方法对初始饱和度高于0.6的CDG填土的适用性。利用该方法确定的不排水强度cu与正应力σn的关系可应用于高饱和度工程渣土快速堆填中的稳定性分析。  相似文献   

Household dependence on solid cooking fuels in Peru: An analysis of environmental and socioeconomic conditions     

《Global Environmental Change》2019

Solid fuel use is linked with adverse effects on the environment and human health. Yet, solid fuels remain an important energy source for households in developing countries. Even when country-level dependence on solid fuels is modest, there is often significant variation in within-country patterns of solid fuel use. This study examines a range of environmental and socioeconomic conditions to understand the relationship between them and household energy use within a country. While our results are derived from a study of regional patterns of solid fuel dependence in Peru, the contribution of this study is broad: variables that we include in our models of households’ fuel choice decisions are likely to shape such decisions in most developing countries. Our findings indicate that environmental conditions, such as elevation and forest cover, are associated with solid fuel use. Socioeconomic factors, including urbanization, poverty and female literacy, are similarly important. In addition, we identify nuanced links between types of female employment and indigenous population, on the one hand, and solid fuel use, on the other.  相似文献   

Transforming agricultural land use through marginal gains in the food system     

《Global Environmental Change》2019

There is an increasing need for transformational changes in the global food system to deliver healthy nutritional outcomes for a growing population while simultaneously ensuring environmental sustainability. However, such changes are subject to political and public constraints that usually allow only gradual, incremental changes to occur. Drawing inspiration from the British cycling team’s concept of marginal gains, we show how transformation might be reconciled with incremental changes. We demonstrate that a set of marginal food system changes acting to increase production efficiency, to reduce losses or to adjust diets could collectively reduce the agricultural land required globally for food production by 21%, or over a third given higher adoption rates. The results show that while all categories of action are important, changes in consumer choices in Europe, North America and Oceania and in the supply-chain in Africa and West and Central Asia have the greatest potential to reduce the land footprint of the food system.  相似文献