化学动力学在地球化学中的某些应用   总被引：2，自引：0，他引：2  

Shi Pingfang Yu Chongwen 《地球科学》1986,(4)

化学动力学在地球化学（特别是成矿作用地球化学）研究中有极其重要的作用,其主要应用包括七个方面。本文重点介绍了地球化学中化学动力学的实验研究方法以及碳酸盐、硅酸盐、氧化物和硫化物等矿物的反应动力学实验成果;介绍了Helgeson的质量迁移理论及其研究热液在围岩中的运移方面的应用,并在热力学性质和动力学行为两方面研究了围岩的离解作用、蚀变作用与矿化作用及其相互关系。  相似文献   

The effect of ductile deformation on the kinetics and mechanisms of the aragonite-calcite transformation   总被引：2，自引：0，他引：2  

ELEANOUR SNOW  RICHARD A. YUND 《Journal of Metamorphic Geology》1987,5(2):141-153

Abstract The effect of ductile deformation (dislocation creep) on the kinetics of the aragonite-calcite transformation has been studied at 1 atm (330° C and 360° C) and 900-1500 MPa (500° C) using undeformed and either previously or simultaneously deformed samples (500° C and a strain rate of 10^-6 s). Deformation enhances the rate of the transformation of calcite to aragonite, but decreases the rate of transformation of aragonite to calcite. The difference results from a dependence of transformation rate on grain size, coupled with a difference in the accommodation mechanisms, climb versus recry-stallization, of these minerals during dislocation creep. Dislocation climb is relatively easy in calcite and thus plastic strain results in high dislocation densities without significant grain size reduction. The rate of transformation to aragonite is enhanced primarily because of the increase in nucleation sites at dislocations and subgrain boundaries. In aragonite, on the other hand, dislocation climb is difficult and thus plastic strain produces extensive dynamic recry-stallization resulting in a substantial grain size reduction. The transformation of aragonite is inhibited because the increase in calcite nucleation sites at dislocations and/or new grain boundaries is more than offset by the inability of calcite to grow across high angle grain boundaries. Thus the net effect of ductile deformation by dislocation creep on the kinetics of polymorphic phase transformations depends on the details of the accommodation mechanism.  相似文献   

Glaucophane and pyroxene breakdown reactions in the Pennine units of the Eastern Alps   总被引：1，自引：0，他引：1  

T. J. B. HOLLAND  N. J. RAY 《Journal of Metamorphic Geology》1985,3(4):417-438

Abstract New occurrences of crossite and jadeitic pyroxene are described from a thick metabasite unit within the upper levels of the Peripheral Schieferhülle in the Tauern Window, Austria. Unusual textures are preserved which provide evidence for the reactions and mechanisms involved in the breakdown of crossite and jadeitic pyroxene. Zones of albite and chlorite, produced by reaction between crossite and paragonite, have been preserved due to sluggish reaction kinetics during decompression from the blueschist to the greenschist facies. The zonal sequence is interpreted in terms of chemical potential gradients in Na, Mg and Al, which have been established by overstepping the equilibrium boundary. Breakdown textures of jadeite-acmite pyroxene to a symplectite of albite + hematite + actinolite, and of crossite to talc and actinolite are also described.
The occurrence of crossite and jadeitic pyroxene at high levels within the Peripheral Schieferhülle implies that even upper levels of the structural sequence have undergone blueschist facies metamorphism with pressures in excess of 8 kbar during the Alpine collisional event.  相似文献   

ABR反应器基质降解动力学有关参数的试验研究   总被引：1，自引：0，他引：1  

王存政  李建萍  黄继国  李辉  陆要斌 《吉林大学学报(地球科学版)》2004,(Z1)

通过静态模拟实验探讨了厌氧折流板反应器各级基质降解动力学。试验结果表明在25℃条件下,各级有机底物最大比降解速率Vmax和饱和常数Ks分别依次为3.06/d-1、1.52/d-1、0.97/d-1和20157.89mg/L、2947.38mg/L、7007.40mg/L。通过各级Vmax的比较可知,级中微生物活性最大,微生物处于对数增殖期,而、级中微生物处于减速增殖期或内源呼吸期。  相似文献   

Arsenic — a Review. Part I: Occurrence,Toxicity, Speciation,Mobility     

Monique Bissen  Fritz H. Frimmel 《洁净——土壤、空气、水》2003,31(1):9-18

In natural waters arsenic concentrations up to a few milligrams per litre were measured. The natural content of arsenic found in soils varies between 0.01 mg/kg and a few hundred milligrams per kilogram. Anthropogenic sources of arsenic in the environment are the smelting of ores, the burning of coal, and the use of arsenic compounds in many products and production processes in the past. A lot of arsenic compounds are toxic and cause acute and chronic poisoning. In aqueous environment the inorganic arsenic species arsenite (As(III)) and arsenate (As(V)) are the most abundant species. The mobility of these species is influenced by the pH value, the redox potential, and the presence of adsorbents such as oxides and hydroxides of Fe(III), Al(III), Mn(III/IV), humic substances, and clay minerals.  相似文献   

热成因甲烷碳同位素分布的形成机制   总被引：3，自引：1，他引：3  

关平  伍天洪 《沉积学报》2003,21(1):175-182

很多学者从不同的角度用不同的方法模拟了从有机母质 (包括煤和干酪根等气源 )形成天然气 (甲烷 )时的碳同位素分馏效应 ,建立了碳同位素分馏效应的很多模型 ,同时也讨论了催化作用和成烃后作用对天然气碳同位素的影响。但这些理论模型和模拟实验结果都还不能完全地拟合自然界中热成因甲烷碳同位素的分布 ,也未能从本质上完全阐明其碳同位素的分馏机制。其原因是各种模型的前提假设都未能完全满足复杂的自然界条件。今后工作的重点应放在用化学动力学的方法建立更完善的模型上 ,同时也应当重点考虑催化作用和成烃后作用对天然气同位素的影响。  相似文献   

磷灰石裂变径迹退火动力学模型研究进展综述   总被引：4，自引：2，他引：4  

付明希 《地球物理学进展》2003,18(4):650-655

裂变径迹退火过程是非线性动力学过程，在一系列磷灰石裂变径迹室内退火实验基础上，研究者提出许多经验退火模型，其中扇型模型与实验数据拟合最好，多组分退火模型将扇型模型的应用扩展到复杂物源成分的磷灰石，理论物理退火模型建立在原子尺度动力机制上，并经由实验数据确定具物理意义的未知参数，目前还不如经验模型成功，室内退火实验表明除了温度、受热时间，退火行为与磷灰石的化学成分，径迹与结晶c轴的方位关系、由Dpar定量表征的颗粒溶蚀度等因素有密切关系。  相似文献   

Effects of reaction kinetics and fluid drainage on the development of pore pressure excess in a dehydrating system   总被引：1，自引：0，他引：1  

Wei-Hau Wang  Teng-fong Wong 《Tectonophysics》2003,370(1-4):227-239

Fluid is released by dehydration reactions during prograde metamorphism. If the Claperyron slope for the dehydrating reaction is positive, then there is a net decrease in the total solid volume, which implies an irreversible increase in porosity. If the dilation of the pore space is insufficient to provide storage for all the released fluid, then pore pressure excess is generated, and if it becomes sufficiently high, it may lead to brittle fracturing. The time scale for pressure generation and the pore pressure excess can be maintained over long duration hinge on the interplay of reaction kinetics and fluid drainage. Motivated by experimental and microstructural observations, a hydrological model is developed that incorporates dehydration kinetics and its pressure dependence. Analytic solutions were derived for the undrained development of pore pressure. Whether lithostatic pressure may be exceeded hinges on magnitude of the overstep in temperature and corresponding equilibrium pressure. The time scale for development of pore pressure depends on the trade-off between poroelasticity and the pressure sensitivity of reaction rate. A finite difference model was also developed to simulate the progressive development of pore pressure excess, dehydration and porosity development. The model captures the experimental observation in gypsum of a reaction front that progressively propagates from the drained end toward the undrained end of a laboratory sample. It is also in reasonable agreement with experimental data on fluid drainage and porosity production.  相似文献   

An investigation on dewatering kinetics of ultrafine coal     

D. Tao  B. K. Parekh  J. T. Liu  S. Chen 《International Journal of Mineral Processing》2003,70(1-4):235-249

Ultrafine coal dewatering is of great importance to the coal industry due to its impacts on the handling and utilization characteristics of coal products. Commercially available filtration techniques are either ineffective or costly for dewatering of ultrafine coal to the desired moisture level of about 20%. Considerable efforts have been devoted to understanding the dewatering process and developing new technologies for applications in the coal industry. Most of the previous work on ultrafine coal filtration was focused on the final filter cake moisture and few studies have been conducted to investigate the filtration kinetics. The present investigation was undertaken to better understand the kinetics of vacuum filtration of ultrafine coal under various conditions. The filtrate weight was continuously monitored using a precise load cell during the entire filtration process. Operating parameters such as vacuum pressure and reagent conditioning time were examined for their impacts on filtration kinetics. Use of cationic and anionic flocculants showed significant improvement in filtration kinetics. Kinetic data obtained from the study were used to determine the fundamental parameters of filtration such as cake permeability, specific cake resistance, and filter medium resistance using the integrated form of the Darcy's law.  相似文献   

利用干酪根热解动力学模拟实验研究塔里木盆地下古生界古地温   总被引：9，自引：0，他引：9  

解启求  周中毅 《地球科学》2002,27(6):767-769

通过热解动力学模拟实验，对塔里木盆地塔参1井奥陶系干酪根的热演化过程进行了模拟，以此基础上利用KINETICS软件求取干酪根镜质体反射率（R0）的生成动力学参数，并结合塔参1井的沉积埋藏史，计算塔参1井寒武－奥陶系的古地温，这对于研究塔里木盆地下古生界高过成熟烃源岩的古地温是一种新方法。  相似文献