不同类型天然气水合物真空分解过程实验研究     

孟庆国  刘昌岭  业渝光  胡高伟 《现代地质》2010,24(3):607-613

在放置于恒温室内的真空装置内,对合成的冰粉-气体水合物(包括甲烷、乙烷、丙烷、正丁烷-氮气、异丁烷、混合气水合物)、冰粉-不同粒度多孔介质甲烷水合物和祁连山冻土区及南海神狐海域天然气水合物进行了分解实验研究,初步探讨了不同气体水合物分解动力学特征和分解规律。实验结果表明,合成的冰粉-气体水合物的分解过程相似,除丙烷水合物和异丁烷水合物外,分解压力基本呈单调增长,均未出现明显的自保护效应;不同粒度多孔介质中甲烷水合物分解过程,压力增长呈现“快→慢→快”的特点,主要原因可能是多孔介质中的水合物尺寸较大,分解时更易产生自保护效应;祁连山冻土区天然气水合物的分解压力曲线与不同粒度多孔介质中甲烷水合物的相似,总体呈现“快→慢→快”的特点,水合物自保护效应明显;南海神狐海域天然气水合物分解气体压力变化虽然总体与祁连山冻土区天然气水合物压力增长过程相似,但同时呈现“阶梯状”增长,这可能与两种不同水合物岩心的岩性和水合物在岩心中的分布模式和赋存状态有关。  相似文献   

Predicting iron speciation in coastal waters from the kinetics of sunlight-mediated iron redox cycling     

Andrew?L.?Rose  T.?David?WaiteEmail author 《Aquatic Sciences - Research Across Boundaries》2003,65(4):375-383

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Vertical mixing of oil droplets by breaking waves   总被引：2，自引：0，他引：2  

Tkalich P  Chan ES 《Marine pollution bulletin》2002,44(11):1219-1229

Oil spilled on a sea surface can be dispersed by a variety of natural processes, of which the influence of breaking waves is dominant. Breaking waves are able to split the slick into small droplets, facilitating oil mixing in the water column. Vertical dynamics of the droplets plays a major role in the oil mass exchange between the slick and the water column. In this paper a mathematical model of oil droplet mixing by breaking waves is developed. The model uses a kinetic approach to describe the vertical exchange of the droplets at the interface between the slick and the water column. The majority of the coefficients and parameters are conveniently combined into a single "mixing factor". The model is verified using sensitivity analysis and empirical formulae of other authors. The model permits a rapid estimation of the amount of dispersed oil under the breaking waves. The ultimate goal of the research is to parameterise influence of breaking waves on vertical mixing of oil droplets to be used in a general 3-D oil spill model.  相似文献   

Pyritization of Iron in Sediments from the Continental Slope of the Northern Gulf of Mexico     

John W. Morse  Dwight K. Gledhill  Karen S. Sell  Rolf S. Arvidson 《Aquatic Geochemistry》2002,8(1):3-13

In sediments from the continental slope of the Northern Gulf of Mexico, generally,the degree of iron pyritization (DOP) is low (<0.1) and dissolved sulfide is belowdetection limits (5 M), whereas dissolved Fe is typically about 50 to100 M. Therefore, the dissolution of kinetically reactive iron minerals generallydominates over the rate of sulfide production in sediments throughout this region.However, in sediments where hydrocarbons have been added via seepage from thesubsurface, dissolved-Fe is undetectable, DOP can approach 1, and high concentrationsof dissolved sulfide (up to 11 mM) are commonly present. Even though thesesediments have high total reduced sulfide (TRS) concentrations (typically 150 to370 mol gdw^-1), their average C/S ratio is about 4 times that of normal marine sediments reflecting the major input of hydrocarbons. DOP is significantly (20%) higher when calculated using reactive-Fe extracted by citrate dithionite than by cold 1N HCl. This difference is primarily due to the greater extraction efficiency of the cold HCl method for silicate-Fe. TRS tends to rise to a maximum, and remains close to constant even at high (mM) dissolved sulfide concentrations. These TRS concentrations, therefore, represent the size of the ``kinetically' reactive-Fe pool during early diagenesis.  相似文献   

FT-IR Study of the Kinetics and Products of the Reactions of Dimethylsulphide, Dimethylsulphoxide and Dimethylsulphone with Br and BrO   总被引：3，自引：0，他引：3  

B. Ballesteros  N. R. Jensen  J. Hjorth 《Journal of Atmospheric Chemistry》2002,43(2):135-150

Kinetics and products of the gas-phase reactions of dimethylsulphide (DMS), dimethylsulphoxide (DMSO) and dimethylsulphone (DMSO₂) with Br atoms and BrO radicals in air have beeninvestigated using on-line Fourier Transform Infrared Spectroscopy (FT-IR) as analytical technique at 740 ± 5 Torr total pressure and at 296 ± 3 K in a480 L reaction chamber. Using a relative rate method for determining the rate constants; the following values (expressed in cm³molecule^–1 s^–1) were found: k_DMS+Br = (4.9 ±1.0) ×10^–14, k_DMSO + Br < 6 × 10^–14,k_{DMSO 2} + Br 1 × 10^–15,k_DMSO + BrO = (1.0 ± 0.3) × 10^–14 andk_{DMSO 2} + BrO 3 × 10^–15 (allvalues are given with one on the experimental data). DMSO, SO₂, COS, CH₃SBr andCH₃SO₂Br were identified as the main sulphur containing products of the oxidation of DMS by Br atoms. From the reaction between DMSO and Br atoms, DMSO₂and CH₃SO₂Br were the only sulphur containing products thatwere identified. DMSO, DMSO₂ and SO₂ were identified as themain sulphur containing products of the reaction between DMS and BrO.DMSO₂ was found to be the only product of the reaction between DMSO and BrO. For the reactions of DMSO₂ with Br and BrO no products were identified because the reactions were too slow.The implications of these results for atmospheric chemistry are discussed.  相似文献   

The ultra‐high pressure coronitic and pseudomorphous reactions in a metagranodiorite from the Brossasco‐Isasca Unit,Dora‐Maira Massif,western Italian Alps: a petrographic study and equilibrium thermodynamic modelling     

M. Bruno  R. Compagnoni  M. Rubbo 《Journal of Metamorphic Geology》2001,19(1):33-43

Metagranodiorite samples from the Brossasco‐Isasca Unit, Dora‐Maira Massif, western Alps, show pseudomorphous and coronitic textures where igneous minerals were partially replaced by ultra‐high pressure (UHP) metamorphic assemblages. The original magmatic paragenesis consisted of quartz, plagioclase, K‐feldspar, biotite and minor phases. During UHP metamorphism, the plagioclase (site P) was replaced by zoisite, jadeite, quartz, K‐feldspar and kyanite, and coronitic reactions developed between biotite and adjacent minerals. At the original igneous biotite–quartz contact (site A), a single corona of poorly zoned garnet is developed, whereas at the biotite–K‐feldspar (site B) and biotite–plagioclase (site C) contacts, composite coronas are formed. Integration of results from petrographic observations, calculations of mineral stoichiometry and thermodynamic calculations of mineral stability has allowed the determination of the metamorphic reactions involved and the estimation of the metamorphic conditions, which reached as high as 24 kbar and 650 °C. Accurate microanalysis by energy‐dispersive spectroscopy (EDS) and statistical analysis of the data allowed us to identify, for the first time in a natural Na‐pyroxene of metagranitoid rocks, the end‐member Ca‐Eskola.  相似文献   

Estimation and inference in inverse methods for kinetic models of hydrocarbon generation     

David R. Fox 《Mathematical Geology》1995,27(8):923-938

Procedures based on ordinary and generalized least of squares for the estimation of kinetic parameters in laboratory pyrolysis experiments are compared. When the data consist of measurements on the degree of chemical reaction through time for a number of temperatures, a single regression procedure is preferred to the two-stage regression alternative. Methods are developed for the construction of confidence intervals for calibration curves used to infer formation temperature on the basis of the unreacted fraction of source material.  相似文献   

Inverse methods and kinetic models of hydrocarbon generation. II. Case histories for residual kerogen analysis     

Jianchang Liu  I. Lerche 《Mathematical Geology》1990,22(8):989-1009

Using the results of the first paper in this series, which dealt with an inverse procedure for hydrocarbon generation, this paper focuses on case histories and numerical implementation of the model. Experimental data on residual kerogen analysis have been used with the inverse procedure to examine the applicability of the model to hydrocarbon generation directly from the degradation of kerogen, and to derive the kinetic parameters for the construction of a prediction equation. Energy-dependent channeling probability distributions are used to exhibit the stability of the model in describing the processes of kerogen degradation. The numerical methods for the solution of the inverse procedure and a sensitivity analysis are also discussed.  相似文献   

氯化钠和硫酸钾晶体生长动力学研究     

周利民刘峙嵘  许文苑 《华东地质学院学报》2005,28(3):266-269

研究了不同添加剂对晶体生长的影响,对NaCl和K2SO4晶体在流化床中的动态生长行为及单个晶体在溶液中的静态生长行为进行了研究.实验中还考虑了晶体表面的完整程度对晶体生长的影响,并对上述晶体的生长机理进行了分析.此外,对存在添加剂及纯溶液中NaCl和K2SO4晶体的溶解过程进行了研究.结果表明,本实验所选用的添加剂在低浓度下即能有效抑制NaCl和K2SO4晶体生长.  相似文献   

The Vale de Abrutiga uranium phosphates mine, central Portugal     

Marina M.S. Cabral Pinto  Maria M.V.G. Silva 《Chemie der Erde / Geochemistry》2007,67(3):251-252

A brief summary about the composition and origins of the U deposit is present. The mineralization is composed by secondary uranium phosphates (saleeite and meta-saleeite). The precipitation was probably the main responsible factor for U retention within the quartz veins leading to the uranium phosphate mineralization of Vale de Abrutiga.  相似文献