Kinetic-simulating experiment combined with GC-IRMS analysis: application to identification and assessment of coal-derived methane from Zhongba Gas Field (Sichuan Basin, China)   总被引：2，自引：0，他引：2  

Yongqiang Xiong  Ansong Geng  Jingzhong Liu 《Chemical Geology》2004,213(4):325-338

The main purpose of this study is to model the δ¹³C values of methane derived from coal by combining kinetic-simulating experiment with the gas chromatography-isotope ratio mass spectrum (GC-IRMS) analysis. The stable carbon isotopic variation of methane in pyrolysates with heating temperature indicates that the assumptions for both a constant kinetic isotope effect (α) and a uniform initial isotopic composition (δ¹³C_o) are impractical for explaining the carbon isotopic fractionation during coalification. For purposes of simplification, two approaches are used in this paper to deal with the heterogeneity of terrestrial organic matter. One is that, assuming a uniform initial isotopic composition (i.e., δ¹³C_{i, o}=δ¹³C_o) for all methane-generating precursors in coal, the isotopic variation of methane is fitted by adjusting ΔE_{a, i} (E_{a¹³C, i}−E_{a¹²C, i}) for each hypothetical reaction. The other is that, assuming a constant kinetic isotope effect during the whole gas formation, that is all ΔE_{a, i} values are identical, the modeling of methane isotopic composition is achieved by changing the ¹³CH₄ generation potential of each reaction (f_{i, ¹³C}), namely, by adjusting the initial δ¹³C value (δ¹³C_{i, o}) for each methane-generating precursor. Results of the kinetic calculation shows that the two simulating methods can yield a similar result at a geological heating rate of 2 °C/My, which further demonstrates that those natural gases with methane δ¹³C value being approximately −36‰ are possibly sourced from the upper Triassic coal measure strata in the Northwestern Sichuan Basin.  相似文献   

Dislocating modernity: Identity, space and representations of street trade in Durban, South Africa     

E. Jeffrey Popke  Richard Ballard 《Geoforum》2004,35(1):99-110

South Africa’s cities have experienced dramatic changes over the past decade. Cities are now home to a multiracial population, and have been transformed by new forms of economic and social interaction. For some, these changes have become a significant source of fear and anxiety. In this paper, we examine reactions to urban spatial change in the city of Durban, as expressed in local newspapers and interviews with suburban residents. We describe how the discourses of urban change in Durban have centred on the increased presence of street traders within the city’s public spaces, and the various ways in which the activity of street trade has disrupted long-established modernist norms governing the occupation and use of the urban space. Specifically, we offer a detailed reading of three prominent narratives within the discussion of street traders in Durban--chaos, congestion and pollution. We argue that street traders have come to embody a wide range of more deeply seated cultural anxieties, which have been brought to the fore in the context of South Africa’s transition. These anxieties arise from the ways in which modern understandings of order, agency and subjectivity have been called into question by material changes in the city, and have implications for the nature of citizenship and civic engagement in post-apartheid South Africa.  相似文献   

A furrow runs through it: An example of sustainable traditional irrigation in Western Cape Province,South Africa     

H. A. P. Smit  J. A. Jacobs 《GeoJournal》2004,61(2):191-196

Water and water related matters are important issues in water scarce countries like the Republic of South Africa. This is especially true for the agricultural sector that relies heavily on the availability of water for irrigation to ensure a secure food supply. In South Africa, present day irrigation projects rely on government subsidies and are usually large undertakings beyond the reach of individuals or small communities. The sustainability of such large irrigation projects is still a matter of debate. A 100 years ago a different set of rules applied. Irrigation could only be achieved by hand-dug furrows that supplied water in relatively small quantities to small farming communities. This paper investigated such a small community, the Leeukloof farming community in the Western Cape Province of the Republic of South Africa. For the past 93 years this community has maintained a furrow that supplies water not only to farms bordering the Perdeberg River, which supplies the furrow with water, but also to farms not bordering the river. The authors try to reconstruct the changes in agricultural practices brought about by the furrow, methods of water extraction during each phase, as well as the development and role of the furrow system. The perception by the community of the necessity of this method of water extraction from the river system is also investigated. This revised version was published online in July 2006 with corrections to the Cover Date.  相似文献   

Mudstones of the Tanqua Basin, South Africa: an analysis of lateral and stratigraphic variations within mudstones, and a comparison of mudstones within and between turbidite fans     

P. O. D. Andersson  R. H. Worden† 《Sedimentology》2004,51(3):479-502

Permian deep‐water mudstones in the Tanqua Basin, South Africa, have been studied using geochemical and spectral gamma ray techniques. The mudstones occur as thick sequences between sand‐rich submarine fans, but also occur as thinner mud‐rich units within each fan. The interfan mudstones are interpreted to have accumulated during transgression and the consequent period of relatively high sea‐level, while the submarine fans and their intrafan mudstones were deposited during regression and relatively low sea‐level. Geochemical analyses revealed systematic differences between interfan and intrafan mudstones because the two types of mudstones have slightly different source lithologies. Differences between the two types of mudstone suggest that changes in relative sea‐level played a role in controlling exposure of sediment source areas. There are geochemical signals that display systematic stratigraphic trends within both interfan and intrafan mudstones. These are best explained by gradual denudation, exposure and weathering of different lithologies within a single sediment source area. Both interfan and intrafan mudstones have uniform geochemical signals along the flow direction except for the relative amount of uranium. It is most likely that the basinward increase in uranium in the mudstones is the result of reduced clastic dilution of uranium‐bearing pelagic fallout.  相似文献   

Neotectonic deformation in the transition zone between the Dead Sea Transform and the East Anatolian Fault Zone, Southern Turkey: a palaeomagnetic study of the Karasu Rift Volcanism     

O Tatar  J.D.A Piper  H Gürsoy  A Heimann  F Kobulut 《Tectonophysics》2004,385(1-4):17-43

In southern Turkey ongoing differential impingement of Arabia into the weak Anatolian collisional collage resulting from subduction of the Neotethyan Ocean has produced one of the most complex crustal interactions along the Alpine–Himalayan Orogen. Several major transforms with disputed motions, including the northward extension of the Dead Sea Fault Zone (DSFZ), meet in this region. To evaluate neotectonic motion on the Amanos and East Hatay fault zones considered to be northward extensions of the DSFZ, the palaeomagnetism of volcanic fields in the Karasu Rift between these faults has been studied. Remanence carriers are low-Ti magnetites and all except 5 of 51 basalt lavas have normal polarity. Morphological, polarity and K–Ar evidence show that rift formation occurred largely during the Brunhes chron with volcanism concentrated at 0.66–0.35 Ma and a subsidiary episode at 0.25–0.05. Forty-four units of normal polarity yield a mean of D/I=8.8°/54.7° with inclination identical to the present-day field and declination rotated clockwise by 8.8±4.0°. Within the 15-km-wide Hassa sector of the Karasu Rift, the volcanic activity is concentrated between the Amanos and East Hatay faults, both with left lateral motions, which have rotated blocks bounded by NW–SE cross faults in a clockwise sense as the Arabian Block has moved northwestwards. An average lava age of 0.5 Ma yields a minimum cumulative slip rate on the system bounding faults of 0.46 cm/year according with the rate deduced from the Africa–Arabia Euler vector and reduced rates of slip on the southern extension of the DSFZ during Plio-Quaternary times. Estimates deduced from offsets of dated lavas flows and morphological features on the Amanos Fault Zone [Tectonophysics 344 (2002) 207] are lower (0.09–0.18 cm/year) probably because they are limited to surface fault breaks and do not embrace the seismogenic crust.Results of this study suggest that most strike slip on the DSFZ is taken up by the Amanos–East Hatay–Afrin fault array in southern Turkey. Comparable estimates of Quaternary slip rate are identified on other faults meeting at an unstable FFF junction (DSFZ, East Anatolian Fault Zone, Karatas Fault Zone). A deceleration in slip rate across the DSFZ and its northward continuation during Plio-Quaternary times correlates with reorganization of the tectonic regime during the last 1–3 Ma including tectonic escape within Anatolia, establishment of the North and East Anatolian Fault Zones bounding the Anatolian collage in mid–late Pliocene times, a contemporaneous transition from transpression to transtension and concentration of all basaltic magmatism in this region within the last 1 Ma.  相似文献   

Modes of occurrence of mercury and other trace elements in coals from the warrior field, Black Warrior Basin, Northwestern Alabama   总被引：1，自引：0，他引：1  

S.F Diehl  M.B Goldhaber  J.R Hatch   《International Journal of Coal Geology》2004,59(3-4):193-208

The mineralogic residence and abundance of trace metals is an important environmental issue. Data from the USGS coal quality database show that potentially toxic elements, including Hg, As, Mo, Se, Cu, and Tl are enriched in a subset of coal samples in the Black Warrior Basin of Alabama, USA. Although the coal as-mined typically is low in these elements, localized enrichments occur in high-pyrite coals and near faults. Microscopic analyses demonstrate that the residence of these elements is dominantly in a late-stage pyrite associated with structurally disrupted coal. Further, our data suggest addition of Hg to the coal matrix as well. The source of these trace elements was hydrothermal fluids driven into the Black Warrior Basin by Alleghanian age tectonism.  相似文献   

Sedimentology and palynology of the Calafate Formation (Maastrichtian), Austral Basin, Southern Patagonia, Argentina     

S. Marenssi  V. Guler  S. Casadío  R. Guerstein  O. Papú 《Cretaceous Research》2004,25(6):907-918

The Calafate Formation crops out in south-western Santa Cruz Province, Argentina, and displays a stacking of asymmetrical coarsening–fining-upward cycles. These cycles are interpreted as the product of short-lived transgressive-regressive events in which the coarsening upward part represents sedimentary aggradation with a stable or decreasing sea level. Sedimentological and palynological analyses indicate nearshore marine conditions. Even though the existence of an estuary or incised valley cannot be determined, this is the most probable palaeogeographic model. Based on dinoflagellate cysts, the base of the section is considered to be not older than Maastrichtian. The presence of the oyster Ambigostrea clarae (Ihering) occurring together with the dinoflagellate cyst species Manumiella druggii (Stover) Bujak and Davies and Eisenackia circumtabulata Drugg in the middle part of the section indicates an age no older than late Maastrichtian. According to sedimentological data, deposits representing the Cretaceous–Palaeogene transition would have been eroded, which is confirmed by the presence of Grapnelispora loncochensis Papú. This megaspore is a consistent component of the Maastrichtian assemblages from Patagonia.  相似文献   

Geochemical Correlation Between Metasediments of the Mfongosi Group of the Natal Sector of the Namaqua-Natal Metamorphic Province, South Africa and the Ahlmannryggen Group of the Grunehogna Province, Antarctica     

Ian J. Basson  Samantha Perritt  Michael K. Watkeys  Andrew H. Menzies   《Gondwana Research》2004,7(1):57-73

The whole-rock geochemistry of metamorphosed greywackes, arenites and arkoses within the Mesoproterozoic Namaqua-Natal-Maudheim Province is interpreted with the aim of establishing geochemical correlations and defining common sediment source terrains. Metasediments of the Mfongosi Group of the Natal Sector of the Namaqua-Natal Metamorphic Province were sampled from their type area in the Mfongosi Valley. Metagreywackes from the northern limits of the Mfongosi Valley, directly adjacent to the Kaapvaal Craton, show ocean island arc signatures while metagreywackes from the southern limits of the Mfongosi Valley, near the contact with the Madidima Thrust of the Natal nappe zone, show mainly active continental margin signatures. Interleaved, geochemically distinct low-Ca+Na, high-K metamorphosed arkoses to lithic arkoses indicate a minor passive margin sediment component. Geochemical classification of low-grade Ahlmannryggen Group greywackes, arenites and arkoses of the Grunehogna Province, Antarctica, indicates both active and passive continental margin sediment sources. An oceanic island arc signature is not evident in Ahlmannryggen Group data. The active continental margin signature in both Natal Sector and Grunehogna Province metasediments potentially provides for a common link between these terranes. Discriminant Function Analysis, using three pre-defined provenance sub-sets within the Mfongosi Group and two pre-defined provenance sub-sets within the Ahlmannryggen Group, indicate that metasediments with active continental margin signatures from both groups are geochemically identical, implying that the active continental margin of the Grunehogna Province shed immature sediments westwards (African azimuths) into the developing, narrow or restricted Mesoproterozoic ‘Mfongosi Basin.’ This was accompanied by minor sediment influx from a stable continental platform, potentially the Kaapvaal Craton. Oblique and diachronous collision, initiated in the southwestern portions of the combined Natal Sector/Grunehogna Province system produced a laterally variable Mfongosi Group, which formed in the ‘Mfongosi Basin’. Coarse-grained sediments dominated in its eastern portions while basalts with thin sapropelite units dominated in its western portions.  相似文献   

Temnospondyls from the Beaufort Group (Karoo Basin) of South Africa and Their Biostratigraphy     

Ross J. Damiani   《Gondwana Research》2004,7(1):165-173

The Permo-Triassic Beaufort Group (Karoo Basin) of South Africa is biostratigraphically subdivided into eight, temporally successive assemblage zones based on therapsids (‘mammal-like reptiles’). The Temnospondyli, fossil tetrapods usually regarded as extinct amphibians, are second only to therapsids in terms of diversity and abundance in these strata, with nine higher-level taxa (‘families’) known. Temnospondyls are also playing an increasingly important role in biostratigraphy and correlation of the Beaufort strata. The lower Beaufort Group (Late Permian) contains six of the eight biozones, but only one temnospondyl ‘family’, the Rhinesuchidae, whose record in the Karoo is the richest in the world. However, rhinesuchid taxonomy remains in flux and the group is thus of limited biostratigraphic utility. The Early Triassic Lystrosaurus Assemblage Zone (middle Beaufort Group) contains the Rhinesuchidae, Amphibamidae, Lydekkerinidae, Tupilakosauridae, Rhytidosteidae, Mastodonsauridae and Trematosauridae, although the biostratigraphy of temnospondyls within this biozone is poorly constrained. The uppermost reaches of the Lystrosaurus biozone contain a paucity of fossils but includes ‘Kestrosaurus’ (Mastodonsauridae) and ?Trematosuchus (Trematosauridae), taxa previously thought to pertain to the lower part of the overlying Cynognathus biozone. The late Early to Middle Triassic Cynognathus Assemblage Zone (upper Beaufort Group) hosts the Mastodonsauridae, Trematosauridae, Brachyopidae, Laidleriidae and, possibly, the Rhytidosteidae. Based largely on the spatial and temporal distribution of mastodonsaurids, this biozone has been biostratigraphically subdivided into a lower A, middle B and upper C subzones, characterised by differing ages and faunas.  相似文献   

Late Pleistocene-Holocene Paleoclimatic History of the Southern Kerala Basin, Southwest India     

K. Jayalakshmi  K.M. Nair  Hisao Kumai  M. Santosh 《Gondwana Research》2004,7(2):585-594

The South Kerala Sedimentary Basin (SKSB) constitutes one of the most significant landward extensions of the southwest offshore sedimentary basins of India, and is situated between 8^o45^' and 10^o15^' N latitudes. With a maximum width of about 20 km and incorporating a 700 m thick sedimentary succession ranging in age from Early Miocene to Holocene, this belt lies almost entirely under water or alluvium-covered coastal plains. In this study, we use two continuously cored bore holes at Eruva (7.25m deep) and Muthukulam (3m deep) separated by a distance of about 7km to investigate the depositional environment as well as paleo ecology of the depocentre and climatic aspects during the Late Pleistocene and Holocene. Results from C¹⁴ dating of shell fragments from Eruva (depth zone: 2.10–6.64m) yielded ages in the range of 36.2 to 42.5 kyBP corresponding to the late Pleistocene. Wood fragments in the Muthukulam core sample (depth zone: 1.27–3.00m) gave C¹⁴ ages in the range of 3.7 to 7.2 kyBP indicating a Holocene history. The lower half of the Eruva bore hole indicates a marginal marine environment with an abundant supply of terrestrial carbonaceous debris probably corresponding to a period of abnormally high rainfall recorded in many parts of the globe covered by the Asian summer monsoon. The sediments in the upper part of this bore hole indicate a continuation of this environment but with much less input of terrestrial organic carbon. The lower part of the bore hole from this locality, corresponding to the Holocene transgression, is similar to the lower part of Eruva bore hole in the case of TOC. Deposition took place in water bodies with considerable marine influence but receiving high amounts of terrestrial plant debris-mostly in the form of finely divided particles mixed with mud. This transgressive sequence was also deposited during a time when the Asian summer monsoon was abnormally high in intensity as indicated by many examples in India, Africa, Madagascar and elsewhere. It is significant that during the deposition of this part, the sea level was probably the same as present or higher suggesting possible lowering of the stream velocities and resultant deposition of only muddy sediments laden with terrestrial organic material along the coast. The upper part of the section shows a progressively reduced rainfall pattern culminating in a period of very low precipitation with the development of a paleosol, which is traceable all over the SKSB where Late Holocene sediments are available. This period also witnessed aeolian activity modifying the sand ridges in the ridge-runnel systems formed by the Holocene regression.  相似文献