We report three new localities of corundum and sapphirine-bearing hyper aluminous Mg-rich and silica-poor ultrahigh-temperature granulites formed during Late Neoproterozoic-Cambrian times within the Palghat–Cauvery Shear Zone system in southern India. From petrologic characteristics, mineral chemistry and petrogenetic grid considerations, the peak metamorphic conditions of these rocks are inferred to lie around 950–1000 °C (as suggested by Al in orthopyroxene thermometer) at pressures above 10 kbar (as indicated by the equilibrium orthopyroxene–sillimanite–gedrite ± quartz assemblage). These rocks preserve several remarkable reaction textures, the most prominent among which is the triple corona of spinel–sapphirine–cordierite on corundum, with the whole textural assembly embedded within the matrix of gedrite, suggesting the reaction: Ged + Crn = Spl + Spr + Crd. The formation of sapphirine–sillimanite assemblage/symplectite associated with relict corundum and porphyroblasitc cordierite is explained by the reaction: Crd + Crn = Spr + Sil. The association of sapphirine cordierite symplectite with gedrite–sillimanite assemblage as well as with aluminosilicate boundaries indicates the gedrite consuming reaction: Ged + Sil = Spr + Crd. Extensive growth of sapphirine–cordierite observed on the rim of gedrite porphyroblasts with spinel occurring as relict inclusions within the sapphirine indicates the reaction: Ged + Spl = Spr + Crd. The pressure–temperature (P–T) path defined from the observed mineral assemblages and reaction texture is characterized by anticlockwise trajectory, with a prograde segment of initial heating and subsequent deep burial, followed by retrograde near-isothermal decompression. Such an anticlockwise trajectory is being reported for the first time from southern India and has important tectonic implications since these rocks were developed at the leading edge of the crustal block that was involved in collisional orogeny and subsequent extension during the final phase of assembly of the Gondwana supercontinent. We propose that the rocks were subjected to deep subduction and rapid exhumation, and the extreme thermal conditions were attained either through input from underplated mantle-derived magmas, or convective thinning or detachment of the lithospheric thermal boundary layer during or after crustal thickening. 相似文献
We report here a multiphase mineral inclusion composed of quartz, plagioclase, K-feldspar, sapphirine, spinel, orthopyroxene, and biotite, in porphyroblastic garnet within a pelitic granulite from Rajapalaiyam in the Madurai Granulite Block, southern India. In this unique textural association, hitherto unreported in previous studies, sapphirine shows four occurrences: (1) as anhedral mineral between spinel and quartz (Spr-1), (2) subhedral to euhedral needles mantled by quartz (Spr-2), (3) subhedral to anhedral mineral in orthopyroxene, and (4) isolated inclusion with quartz (Spr-4). Spr-1, Spr-2, and Spr-4 show direct grain contact with quartz, providing evidence for ultrahigh-temperature (UHT) metamorphism at temperatures exceeding 1000 °C. Associated orthopyroxene shows high Mg/(Fe + Mg) ratio ( 0.75) and Al2O3 content (up to 9.6 wt.%), also suggesting T > 1050 °C and P > 10 kbar during peak metamorphism.
Coarse spinel (Spl-1) with irregular grain morphology and adjacent quartz grains are separated by thin films of Spr-1 and K-feldspar, suggesting that Spl-1 and quartz were in equilibrium before the stability of Spr-1 + quartz. This texture implies that the P–T conditions of the rock shifted from the stability field of spinel + quartz to sapphirine + quartz. Petrogenetic grid considerations based on available data from the FMAS system favour exhumation along a counterclockwise P–T trajectory. The irregular shape of the inclusion and chemistry of the inclusion minerals are markedly different from the matrix phases suggesting the possibility that the inclusion minerals could have equilibrated from cordierite-bearing silicate-melt pockets during the garnet growth at extreme UHT conditions. 相似文献
Layers of Ca-rich garnetclinopyroxene rocks enclosedin a serpentinite body at Hujialin, in the SuLu terraneof eastern China, preserve igneous textures, relict spinel ingarnet, and exsolution lamellae of Ca-rich garnet, ilmenite/magnetite,Fe-rich spinel, and also amphibole in clinopyroxene. In termsof their major and trace element compositions, the studied samplesform a trend from arc cumulates towards FeTi gabbros.Reconstructed augite compositions plot on the trend for clinopyroxenein arc cumulates. These data suggest that the rocks crystallizedfrom mantle-derived magmas differentiated to various extentsbeneath an arc. The Ca-rich garnet + diopside assemblage isinferred to have formed by compressing Ca-rich augite, whereasthe relatively Mg-rich cores of garnet porphyroblasts may haveformed at the expense of spinel. The protolith cumulates weresubducted from near the crustmantle boundary (c. 1 GPa)deep into the upper mantle (4·8 ± 0·6 GPaand 750 ± 50°C). Negatively sloped PT pathsfor the garnetclinopyroxene rocks and the corollary ofcorner flow induced subduction of mantle wedge peridotite arenot supported by the available data. Cooling with, or without,decompression of the cumulates after the igneous stage probablyoccurred prior to deep subduction. KEY WORDS: arc cumulates; Ca-rich garnet; garnetclinopyroxene rocks; SuLu terrane; UHP metamorphism相似文献
Atmospheric dimethyl sulfide (DMS) and sulfur dioxide (SO2) concentrations were measured at Baring Head, New Zealandduring February and March 2000. Anti-correlated DMS and SO2 diurnalcycles, consistent with the photochemical production of SO2 from DMS, were observed in clean southerly air off the ocean. The data is used to infer a yield of SO2 from DMS oxidation. The estimated yields are highly dependent on assumptions about the DMS oxidation rate. Fitting the measured data in a photochemical box model using model-generated OH levels and the Hynes et al. (1986) DMS + OH rate constant suggests that theSO2 yield is 50–100%, similar to current estimates for the tropical Pacific.However, the observed amplitude of the DMS diurnal cycle suggests that the oxidation rate is higher than that used by the model, and therefore, that theSO2 yield is lower in the range of 20–40%. 相似文献
The impact of Southern Oscillation on thecyclogenesis over the Bay of Bengal duringthe summer monsoon has been investigated.The analysis of correlation coefficients(CCs) between the frequency of monsoondepressions and the Southern OscillationIndex (SOI) reveals that more depressionsform during July and August of El Niñoyears. Due to this, the seasonal frequencyof monsoon depressions remains little higherduring El Niño epochs even though thecorrelations for June and September are notsignificant. The CCs for July and August aresignificant at the 99% level.The El Niño-Southern Oscillation (ENSO)is known to affect Indian MonsoonRainfall (IMR) adversely. The enhancedcyclogenesis over the Bay of Bengal duringJuly and August is an impact of ENSO whichneeds to be examined closely. Increasedcyclogenesis over the Bay of Bengal may bereducing the deficiency in IMR duringEl Niño years by producing more rainfallover the eastern parts of India duringJuly and August. Thus there is a considerablespatial variation in the impact of ENSOon the monsoon rainfall over India and El Niñoneed not necessarily imply a monsoonfailure everywhere in India.The area of formation of monsoon depressionsshifts eastward during El Niño years.Warmer sea surface temperature (SST) anomaliesprevail over northwest and adjoiningwestcentral Bay of Bengal during premonsoon andmonsoon seasons of El Niño years.May minus March SOI can provide useful predictionsof monsoon depression frequencyduring July and August. 相似文献
A swath bathymetric survey was conducted on Marsili Volcano, the biggest seamount in the Tyrrhenian Sea. It stands 3000 m above the surrounding oceanic crust of the 3500 m-deep Marsili back-arc basin and is axially located within the basin. The seamount has an elongated shape and presents distinctive morphology, with narrow (<1000 m) ridges, made up of several elongated cones, on the summit zone and extensive cone fields on its lower flanks. A dredging campaign carried out at water depths varying between 3400 and 600 m indicates that most of Marsili Seamount is composed of medium-K calc-alkaline basalts. Evolved high-K andesites were only recovered from the small cones on the summit axis zone. Petrological and geochemical characteristics of the least differentiated basalts reveal that at least two varieties of magmas have been erupted on the Marsili Volcano. Group 1 basalts have plagioclase and olivine as dominant phases and show lower Al, Ca, K, Ba, Rb and Sr, and higher Fe, Na, Ti and Zr with respect to a second type of basaltic magma. Group 2 basalts reveal the presence of clinopyroxene as an additional phenocryst phase. In addition, the two basaltic magmas have different original pre-eruptive H2O content (group 1, H2O-poor and group 2, H2O-rich). Moreover, comparison of the compositional trends and mineralogical compositions obtained from MELTS [Ghiorso, M.S., Sack, R.O., Contrib. Mineral. Petrol. 119 (1995) 197–212] fractional crystallization calculations reveal that the evolved andesites can only exclusively be derived from a low-pressure (0.3 kbar) fractionation of magmas compositionally similar to the least evolved group 2 basalts. Finally, we suggest that the high vesicularity of the basalts sampled at relatively great depths (>2400 m) on the edifice is governed by H2O and, probably, CO2 exsolution and is not a feature indicative of shallow water depth eruption. 相似文献