极谱法测定海水介质的铜络合容量     

张怀成  孙秉一  史致丽  桓新 《中国海洋大学学报(自然科学版)》1990,(4)

采用新极谱技术(1.5次微分)的阳极溶出伏安滴定方法测定天然海水的铜络合容量和条件稳定常数。对测试条件、EDTA回收率和有关问题进行了探讨。青岛近岸水样的九次平行测定表明,铜的表现络合容量为3.01×10~(-7)mol/dm~3,条件稳定常数为7.34×10~7,相对标准偏差分别为9.2％和13.8％。  相似文献   

An altered carrying capacity of the Benguela upwelling ecosystem for African penguins (Spheniscus demersus)     

Crawford  Robert J. M.; Underhill  Les G.; Upfold  Leshia; Dyer  Bruce M. 《ICES Journal of Marine Science》2007,64(3):570-576

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太平洋海域海气热通量地理分布和时间变化的研究   总被引：6，自引：1，他引：6  

钱粉兰  周明煜 《海洋学报》2001,23(1):21-28

应用美国宇航局Goddard地球观测系统四维资料同化系统计算和分析了太平洋海域感热通量和潜热通量随时间的变化规律和地理分布特征.研究结果表明,太平洋西北部海域热通量有明显的季节性变化,其余海域这种现象不明显.在太平洋海域总是存在潜热通量最高值区域,而感热通量除冬季20°N以北海域数值稍高外,其余海域数值都很小,没有出现最高值区域.纬度不同热通量随经度的变化规律不同,经度不同,热通量随纬度的分布规律也不同,同时各断面热通量随纬度的分布趋势随季节而改变.  相似文献   

Distribution of dissolved species and suspended particulate copper in an intertidal ecosystem affected by copper mine tailings in Northern Chile   总被引：1，自引：0，他引：1  

Santiago Andrade  James Moffett  Juan A. Correa   《Marine Chemistry》2006,101(3-4):203-212

The coastline near Chañaral in Northern Chile is one of the most highly Cu-contaminated zones in the world due to discharges from mining activities for more than 60 years. The speciation of Cu has been studied to determine the importance of organic complexation in highly contaminated areas, and to assess the likely physiological impacts of Cu on marine organisms. Dissolved Cu concentrations of up to 500 nM were measured, completely saturating organic ligands and leading to free Cu²⁺ concentrations in excess of 10^− 8 M. These values are higher than those reported in any other marine environment, and because they occur over an extensive area, provide a unique opportunity to study the effects of Cu on marine ecosystems and to see how Cu behaves when its speciation is predominantly inorganic. We found strong gradients in free Cu²⁺ between Chañaral and adjacent areas with lower Cu, where speciation is dominated by organic complexation. There is also a significant increase in the partitioning of Cu onto suspended particles in the contaminated areas, consistent with previous studies that showed that organic ligands stabilize Cu in the dissolved phase, whilst “excess” Cu is rapidly scavenged. Those high dissolved Cu concentrations persist in spite of solid phase partitioning and advective processes along this open-ocean coastline, suggesting that Cu inputs into the system are still very large. Measurements were made using anodic stripping voltammetry with a thin mercury film coated with Nafion, which previous workers have shown can mitigate ambiguity in the data arising from inadvertent reduction of organic complexes. Our findings suggest that this is a useful methodology for contaminated systems.  相似文献   

闽江河口区湿地生态旅游环境容量研究   总被引：3，自引：0，他引：3  

叶萍  黄义雄 《台湾海峡》2006,25(1):77-82

本文讨论了生态旅游环境容量的定义及内涵，分析了生态旅游环境容量的特征及构成，在此基础上估算了闽江河口区湿地生态旅游环境容量．结果表明：闽江河口区湿地生态旅游环境容量的限制因子是鳝鱼滩自然保护区生态旅游环境空间容量．鳝鱼滩旅游步行道可分成南路和北路，北路为水路游线，南路为陆路游线．北路游线环境空间日容量为800人次／d，南路游线环境空间日容量为1144人次／d．鳝鱼滩湿地生态旅游环境空间年容量为451202人次／a．这一环境容量可作为闽江河口区湿地生态旅游活动环境容量的最高限制量．  相似文献   

Theoretical aspects of cap-rock and fault seals for single- and two-phase hydrocarbon columns   总被引：6，自引：0，他引：6  

N.L. Watts   《Marine and Petroleum Geology》1987,4(4)

Cap-rock seals can be divided genetically into those that fail by capillary leakage (membrane seals) and those whose capillary entry pressures are so high that seal failure preferentially occurs by fracturing and/or wedging open of faults (hydraulic seals). A given membrane seal can trap a larger oil column than gas column at shallow depths, but below a critical depth (interval), gas is more easily sealed than oil. This critical depth increases with lower API gravity, lower oil GOR and overpressured conditions (for the gas phase). These observations arise from a series of modelling studies of membrane sealing and can be conveniently represented using pressure/ depth (P/D) profiles through sealed hydrocarbon columns. P/D diagrams have been applied to the more complex situation of the membrane sealing of a gas cap underlain by an oil rim; at seal capacity, such a two-phase column will be always greater than if only oil or gas occurs below the seal.These conclusions contrast with those for hydraulic seals where the seal capacity to oil always exceeds that for gas. Moreover, a trapped two-phase column, at hydraulic seal capacity will be less than the maximum-allowed oil-only column, but more than the maximum gas-only column. Unlike membrane seals, hydraulic seal capacity should be directly related to cap-rock thickness, in addition to the magnitude of the minimum effective stress in the sealing layer and the degree of overpressure development in the sequence as a whole.Fault-related seals are effectively analogous to membrane cap-rocks which have been tilted to the angle of the fault plane. Consequently, all of the above conclusions derived for membrane cap-rocks apply to both sealing faults sensu stricto (fault plane itself seals) and juxtaposition faults (hydrocarbon trapped laterally against a juxtaposed sealing unit). The maximum-allowed two-phase column trapped by a sealing fault is greater than for equivalent oil-only and gas-only columns, but less than that predicted for a horizontal membrane cap-rock under similar conditions. Where a two-phase column is present on both sides of a sealing fault (which is at two-phase seal capacity), a deeper oil/water contact (OWC) in one fault block is associated with a deeper gas/oil contact (GOC) compared with the adjacent fault block. If the fault seal is discontinuous in the gas leg, however, the deeper OWC is accompanied by a shallower GOC, whereas a break in the fault seal in the oil leg results in a common OWC in both fault blocks, even though separate GOC's exist. Schematic P/D profiles are provided for each of the above situations from which a series of fundamental equations governing single- and two-phase cap-rock and fault seal capacities can be derived. These relationships may have significant implications for exploration prospect appraisal exercises where more meaningful estimates of differential seal capacities can be made.The membrane sealing theory developed herein assumes that all reservoirs and seals are water-wet and no hydrodynamic flow exists. The conclusions on membrane seal capacity place constraints on the migration efficiency of gas along low-permeabiligy paths at depth where fracturing, wedging open of faults and/or diffusion process may be more important. Contrary to previous assertions, it is speculated that leakage of hydrocarbons through membrane seals occurs in distinct pulses such that the seal is at or near the theoretically calculated seal capacity, once this has been initially attained.Finally, the developed seal theory and P/D profile concepts are applied to a series of development geological problems including the effects of differential depletion, and degree of aquifer support, on sealing fault leakage, and the evaluation of barriers to vertical cross-flow using RFT profiles through depleted reservoirs. It is shown that imbibition processes and dynamic effects related to active cross-flow across such barriers often preclude quantitative analysis and solution of these problems for which simulation studies are usually required.  相似文献   

WATER MASS FORMATION IN THE SOUTH INDIAN OCEAN BY AIR-SEA FLUXES     

Ming Feng 《热带海洋学报》2004,23(6):16-21

1Introduction　TheIndianCentralWater (ICW) ,formedandsubductedintheSubtropicalConvergenceintheSouthIndianOcean ,occupiesasignificantportionofthethermoclineintheIndianOcean[1,2 ]　 (Fig .1 ) .TheSubantarcticModeWater(SAMW)isformedinthe 2 6.5-2 7.1σθrangenorthoftheSub antarcticFront—thesouthernboundaryofthesubtropicalgyres[3]　 .InthesoutheastIndianO cean ,theSAMWisthethickest,ventilatedasathicklayerofhighoxygenextendingtothetropicalIndianOcean[4 ,5 ]　 .　Watermasstransformation…  相似文献   

Experimental Study on Stability of Breakwaters with Penetrating Box Foundations     

别社安  李伟  李增志  任增金  及春宁 《中国海洋工程》2003,17(1)

1 .ＩｎｔｒｏｄｕｃｔｉｏｎＴｈｅｐｅｎｅｔｒａｔｉｎｇｂｕｃｋｅｔａｎｄｂｏｘｆｏｕｎｄａｔｉｏｎｉｓａｎｅｗｔｙｐｅｏｆｓｔｒｕｃｔｕｒｅ ,ｗｈｉｃｈｈａｓｂｅｅｎａｐｐｌｉｅｄｉｎｍａｎｙｅｎｇｉｎｅｅｒｉｎｇｆｉｅｌｄｓ .Ｉｎｖｉｅｗｏｆｔｈｅｈｉｇｈｃｏｎｓｔｒｕｃｔｉｏｎｃｏｓｔａｎｄｔｈｅｆｏｒｍｉｄａｂｌｅｃｏｎｓｔｒｕｃｔｉｂｉｌｉｔｙｏｆｏｆｆ ｓｈｏｒｅｐｌａｔｆｏｒｍｓｗｉｔｈｐｉｌｅｄｆｏｕｎｄａｔｉｏｎｓ ,Ｂａｅｒｈｅｉｍｅｔａｌ.(1 990 )ｐｒｏｐｏｓｅｄｔｈｅｃｏｎｃ…  相似文献   

Calculation of Environmental Capacity of Petroleum Hydrocarbon in Jiaozhou Bay     

李克强  王修林  邓宁宁  石晓勇  祝陈坚  韩秀荣  胡海燕 《海洋通报(英文版)》2004,6(1):53-59

The method has been established to calculate the environmental capacity (ECo),surplus environment capacity (SECo) of water with respect to marine petroleum hydrocarbons associated with oil (PHAOs) and the self-purification capacity (SPCo) of main self-purification process to PHAOs in the Jiaozhou Bay, China, according to the dynamic model for distribution of marine PHAOs among multiphase environments. The variation of concentration of PHAOs in the Jiaozhou Bay is well simulated by the dynamic model. Based on the model.the ECo, SECo of water with respect to PHAOs in the Jiaozhou Bay were calculated during the last 10 years under the first-class and second-class quality standard requirement, according to SPCoof main self-purification process to PHAOs. The results show that about 200 tons of PHAOs could be discharged into the Jiaozhou Bay for maintaining the first class seawater quality standard, and about 600 tons of PHAOs for the second class seawater quality standard later.  相似文献   

Bowen数和东中国海Bowen数分布     

张淮水  汪园祥  楼顺里 《中国海洋大学学报(自然科学版)》1988,(3)

本文讨论Bowen数的意义、功能和计算法。同时,依据多年水文气象实测资料作统计,计算出东中国海的Bo值。其结果绘制成1月至12月的月平均分布图,从而对本海域的Bo分布特点作详细分析介绍。  相似文献