新疆阿尔泰南缘乌吐布拉克铁矿成矿机制研究   总被引：4，自引：2，他引：2  

张志欣  杨富全  刘锋  柴凤梅  耿新霞  欧阳刘进  姜丽萍  吕书君 《岩石学报》2012,28(7):2043-2056

乌吐布拉克中型铁矿床赋存于上志留统-下泥盆统康布铁堡组变质火山-沉积岩系中,矿体呈似层状、透镜状,矿体及其周围发育大量矽卡岩矿物组合。早期矽卡岩阶段包裹体均一温度为256～534℃,盐度为11.90%～>73.96%NaCleqv,密度为0.56～0.96g/cm3,表明成矿流体为高-中温、高-中盐度、高-中密度的NaCl-H2O体系;退化蚀变阶段包裹体均一温度为188～313℃,盐度为12.30%～>39.76%NaCleqv,密度为0.83～1.05g/cm3,表明成矿流体为中温、中-低盐度、高-中密度的NaCl-H2O体系。石英-硫化物-碳酸盐阶段包裹体均一温度为162～320℃,盐度为2.90%～15.57%NaCleqv,密度为0.70～1.02g/cm3,成矿流体为NaCl-H2O-CO2±CH4或N2型流体。石榴子石氢氧同位素表明早期矽卡岩阶段成矿流体主要来源于岩浆水,石英及方解石的氢氧同位素暗示石英-硫化物-碳酸盐阶段存在低温、低盐度的大气降水的加入。方解石的碳、氧同位素表明流体中碳主要来自深部岩浆。硫化物硫同位素表明硫来源于岩浆硫。成矿机制可能为早三叠世岩浆热液交代上志留-下泥盆统康布铁堡组火山岩形成矽卡岩矿物,在矽卡岩退化蚀变过程中形成铁矿体。  相似文献   

塔里木盆地西北缘奥陶系碳酸盐岩中两种来源热流体的地质与地球化学证据     

潘文庆  胡秀芳  刘亚雷  高奇东  叶瑛 《岩石学报》2012,28(8):2515-2524

塔里木盆地西北缘西克尔-巴楚-柯坪地区处于巴楚-柯坪断隆带活动区,构造活动强烈.该区出露的中下奥陶统鹰山组发育大量的热液蚀变现象,既有溶蚀形成的大小孔洞、疏松灰岩层,也有各类充填的脉体,如萤石矿、硫磺石膏矿等.通过野外露头观察和采样,并对受热流体作用的样品进行了包裹体测温测盐、微量元素和硫同位素分析.结果显示研究区主要有两种流体来源:岩浆热液和地层热液.研究表明:(1)岩浆热液主要影响研究区南西段,形成萤石、重晶石、方铅矿等矿物,流体包裹体盐度低(0.5％ ～7.5％ NaCleqv)、均一化温度相对较高(142 ～ 283℃);地层热液作用范围则主要位于研究区北东段,生成白云石、方解石、石英等矿物,流体包裹体盐度高(16％ ～ 23.3％ NaCleqv)、均一化温度低(70～ 138℃);而研究区中段同时受到两种来源热液的混合作用,包裹体盐度(7.5％～18.3％ NaCleqv)和均一化温度(142 ～ 163℃)介于前两者之间;(2)热液硬石膏、硫磺的硫同位素富含32S,δ4S平均为-9.57％,说明硬石膏是H2S气体与灰岩反应的产物,硫化氢很可能来自有机物的热裂解.  相似文献   

粤北油洞岩体SHRIMP锆石U-Pb年龄、地球化学特征及其成因研究   总被引：6，自引：0，他引：6  

黄国龙  曹豪杰  凌洪飞  沈渭洲  王小冬  伏顺成 《地质学报》2012,86(4):577-586

油洞岩体位于诸广南部岩体中部,是一个重要的产铀岩体,岩性为中粒小斑状二云母花岗岩。SHRIMP锆石U-Pb年龄为232±4Ma(MSWD=3.2),属于印支早期岩浆活动产物。该岩体在主量元素方面,具有富硅(SiO2平均为72.65%)、富铝(A/CNK值平均为1.12)和高的K2O/Na2O比值(平均为1.79);在微量元素方面,大离子元素富集,Ba、Sr、P、Ti、Nb、Ta亏损明显,具有高的Rb/Sr(平均为8.08)和Rb/Nb比值(平均为20.96);在稀土元素方面,轻稀土明显富集,配分模式呈右倾型,Eu亏损明显;在同位素方面,εNd(t)值低(平均为-11.9),(87Sr/86Sr)i高(平均为0.72330),Nd模式年龄古老(平均为1954 Ma)。这些特征一致表明,油洞岩体属于典型的壳源型花岗岩范畴,是在华南地块和印支地块碰撞结束后不久形成的伸展构造环境中,位于中—下地壳部位的古—中元古代地壳组分由于在地壳缩短之后的伸展、减薄环境下产生的减压、导水和地幔上涌等因素的综合影响下,由泥质岩和砂质岩混合组成的源区发生部分熔融而形成。  相似文献   

The Qiyugou gold-bearing breccia pipes,Xiong'ershan region,central China: fluid-inclusion and stable-isotope evidence for an origin from magmatic fluids     

《International Geology Review》2012,54(1):25-45

  相似文献   

Sulphur- and lead-isotope geochemistry of the Arapuçandere lead–zinc–copper deposit,Biga Peninsula,northwest Turkey     

《International Geology Review》2012,54(1):116-129

The Arapuçandere Pb–Zn–Cu ore body is a typical vein-type lead–zinc deposit of the Biga Peninsula, and is currently being mined for lead and zinc. In the study area, Permian–Triassic metamorphic rocks, Triassic metaclastic and metabasic rocks, Oligocene–Miocene granitoids, Miocene volcanic rocks, and Quaternary terrigenous sediments crop out. The ore deposits developed as Pb–Zn–Cu-bearing veins along faults in Triassic metasandstone and metadiabase. Microscopic studies reveal that the veins contain galena, sphalerite, chalcopyrite, pyrite, marcasite, covellite, and specular hematite as ore minerals, and quartz, calcite, and barite as gangue minerals. Analysed sulphur-isotope compositions (δ³⁴S_VCDT) of galena, sphalerite, and chalcopyrite range from ? 5.9 to ? 1.9‰ (average ? 3.4‰), from ? 5.5 to ? 1.7‰ (average ? 4.2 ‰), and from ? 3.5 to ? 0.9‰ (average ? 2.6‰), respectively; that of H₂S in the hydrothermal fluid was in the calculated range of ? 5.8 to +0.1‰ (average ? 2.5‰). These isotopic values suggest that magmatic sulphur dominates in sulphides, mixed with minor, isotopically light sulphur. Because no contemporaneous magmatic activity is associated with mineralization, it may be assumed that sulphur was leached from the surrounding Triassic units, mainly from metabasic, partly from metaclastic rocks. Lead-isotope studies indicate a model age of 114–63 Ma for the lead reservoir, in accord with possible sulphur-bearing local source rocks. Thus, the sulphur and lead deposited in the studied ore veins were probably leached from Triassic metabasic and metaclastic rocks some time during the Early Cretaceous to the Palaeocene.  相似文献   

Geochronological evidence and tectonic significance of Carboniferous magmatism in the southwest Trabzon area,eastern Pontides,Turkey     

《International Geology Review》2012,54(15):1776-1800

The northern and southern zones of the eastern Pontides (northeast Turkey) contain numerous plutons of varying ages and compositions. Geochemical and isotopic results on two Hercynian granitoid bodies located in the northern zone of the eastern Pontides allow a proper reconstruction of their origin for the first time. The intrusive rocks comprise four distinct bodies, two of which we investigated in detail. Based on LA–ICP–MS U–Pb zircon dating, the Derinoba and Kayadibi granites have similar ²⁰⁶Pb/²³⁸U versus ²⁰⁷Pb/²³⁵U Concordia ages of 311.1 ± 2.0 and 317.2 ± 3.5 million years for the former and 303.8 ± 1.5 million years for the latter. Aluminium saturation index values of both granites are between 0.95 and 1.35, indicating dominant peraluminous melt compositions. Both intrusions have high SiO₂ (74–77 wt.%) contents and show high-K calc-alkaline and I- to S-type characteristics. Primitive mantle-normalized element diagrams display enrichment in K, Rb, Th, and U, and depletion in Ba, Nb, Ta, Sr, P, and Ti. Chondrite-normalized rare earth element patterns are characterized by concave-upward shapes and pronounced negative Eu anomalies with La_cn/Yb_cn?=?4.6–9.7 and Eu_cn/Eu*?=?0.11–0.59 (Derinoba), and La_cn/Yb_cn?=?2.7–5.5 and Eu_cn/Eu*?=?0.31–0.37 (Kayadibi). These features imply crystal-melt fractionation of plagioclase and K-feldspar without significant involvement of garnet. The Derinoba samples have initial ?Nd values between –6.1 and –7.1 with Nd model ages and T _DM between 1.56 and 2.15 thousand million years. The Kayadibi samples show higher initial ?Nd_(I) values, –4.5 to –6.2, with Nd model ages between 1.50 and 1.72 thousand million years. This study demonstrates that the Sr isotope ratios generally display negative correlation with Nd isotopes; Sr isotope ratios were lowered in some samples by hydrothermal interaction or alteration. Isotopic and petrological data suggest that both granites were produced by the partial melting of early Palaeozoic lower crustal rocks, with minor contribution from the mantle. Collectively, these rocks represent a late stage of Hercynian magmatism in the eastern Pontides.  相似文献   

Quaternary high-Nb basalts: existence of young oceanic crust under the Sanandaj–Sirjan Zone,NW Iran     

《International Geology Review》2012,54(2):167-186

Quaternary basaltic volcanoes are distributed in the northern part of the Sanandaj–Sirjan Zone (N-SSZ). Those in the Ghorveh area of the N-SSZ are characterized by low SiO₂, high alkalis, and LILE + LREE enrichment. They also have high Mg numbers (Mg# = 65–70) and high contents of Cr (>300 ppm), Ni (>177 ppm), and TiO₂ (>1.5 wt.%), suggesting that they crystallized directly from primary magma. The basalts are classified as high-Nb basalts (HNB), with Nb concentrations greater than 20 ppm. Their ⁸⁷Sr/⁸⁶Sr values range from 0.7049 to 0.7053 and their ?⁰_Nd values lie between –0.2 and 1.1. The small negative values of ?⁰_Nd indicate involvement of continental material in the evolution of the source magma in the area. Based on these new chemical and isotopic data and their relationship to the Plio-Quaternary volcanic adakites in northern Ghorveh, we propose that the partial fusion of metasomatized mantle associated with adakitic magma was responsible for generation of the HNB rocks following late Miocene collision of the Arabian and Iranian plates. Rollback of Neotethyan oceanic spreading and mantle plume activity caused a thinning of the northern SSZ lithosphere; furthermore, the S wave tomography model beneath the N-SSZ supports this hypothesized lithospheric thinning. The HNB rocks have close spatial proximity and temporal association with adakites, which were formed by the subduction of young (<25 Ma) oceanic crust. Our discussion clarifies the role of the oceanic slab in the post-collision generation of the HNB basalts in this area. Our data confirm the relationship of the HNB rocks to the subduction zone instead of to the oceanic island basalt (OIB) type magma in extensional zones.  相似文献   

Age of metamorphic rock masses in Laba Basin,North Caucasus     

《International Geology Review》2012,54(10):1197-1212

A Neoarchaean sanukitoid pluton that was intruded into the base of the Guyang greenstone belt in the Yinshan Block of the North China Craton hosts a number of hornblendite enclaves. Geochemically, the pluton is characterized by high MgO, Mg#, Cr, Ni, large-ion lithophile element (LILE), and heavy rare earth element (HREE) contents and low TiO₂ and high-field strength element (HFSE) contents, and has relatively low Sr/Y ratios and negative Eu anomalies. Whole-rock Sr–Nd isotopic analyses indicate that it has ε_Nd(t) values of +1.4 to +2.0. These geochemical and isotopic characteristic suggest that the sanukitoid was formed under a low-pressure and high-temperature environment by slab melting and assimilation of hornblendite enclaves. The hornblendite enclaves show high MgO, Mg#, Cr, and Ni contents, high and variable K₂O, LREE, and Th contents, enrichment in LILEs and LREEs, and depletion in HFSEs. They have high Y contents and relatively low Sr/Y values, strongly negative Eu anomalies, and whole-rock ε_Nd(t) values of +1.0 to +1.9. The geochemical and isotopic characteristics indicate that these enclaves might have been derived from a mixed source of an enriched mantle, metasomatized by melts expelled from subducted sediments in a high-temperature, low-pressure environment. To explain these characteristics, a ridge subduction model is proposed for the formation of the sanukitoid and hornblendite in the Yinshan Block in the Neoarchaean.  相似文献   

吉林南部三棵榆树组火山岩的成因:锆石U-Pb年龄和Hf同位素证据     

隋振民  陈跃军 《现代地质》2012,26(4):627-634

锆石LA-ICP-MS U-Pb测年结果显示,吉林南部地区三棵榆树组粗面岩形成于118 Ma的早白垩世晚期。岩石地球化学研究表明,三棵榆树组粗面岩的SiO2含量为65.11%～65.61%,富碱(K2O=6.29%～7.28%,Na2O=3.71%～4.21%),属于钾玄岩系列,弱过铝质(A/CNK=1.05～1.12),含镁指数Mg#=9～16;稀土元素总量较高(∑REE=317.72×10-6～371.30×10-6),轻重稀土分馏明显(LaN/YbN=19.50～22.80),Eu负异常较弱(δEu=0.75～0.81);微量元素富集Rb、Th、Zr、K,明显亏损Nb、Ta和Sr等,显示典型的大陆地壳特征。锆石的176Hf/177Hf比值介于0.282 206～0.282 309之间,εHf(t)值介于-13.32～-16.97之间,Hf模式年龄(TDM2)介于2.0～2.6 Ga之间,平均为2.2 Ga。上述特征表明,吉林南部地区早白垩世粗面岩主要来源于古元古代地壳物质的部分熔融,形成于伸展构造环境。  相似文献   

Identifying the Sources of Solutes in Karst Groundwater in Chongqing,China: a Combined Sulfate and Strontium Isotope Approach     

PU Junbing  YUAN Daoxian  ZHANG Cheng  and ZHAO Heping 《《地质学报》英文版》2012,86(4):980-992

Groundwater from karst subterranean streams is among the world’s most important sources of drinking water supplies, and the hydrochemical characteristics of karst water are impacted by both natural environment and people. Therefore, the study of hydrochemistry and its solutes’ sources is very important to ensure the normal function of life support systems. In this paper, thirty?five representative karst groundwater samples were collected from different aquifers (limestone and dolomite) and various land use types in Chongqing to trace the sources of solutes and relative hydrochemical processes. Hydrogeochemical types of karst groundwater in Chongqing were mainly of the Ca?HCO3 type or Ca (Mg)?HCO3 type. However, some hydrochemical types of karst groundwater were the K+Na+Ca?SO4 type (G25 site) or Ca?HCO3+SO4 type (G26 and G14 site), indicating that the hydrochemistry of these sites might be strongly influenced by anthropogenic activities or unique geological characteristics. The dissolved Sr concentrations of the studied groundwater ranged from 0.57 to 15.06 μmmol/L, and the 87Sr/86Sr varied from 0.70751 to 0.71627. The δ34S?SO42? fell into a range of ?6.8‰?21.5‰, with a mean value of 5.6‰. The variations of both 87Sr/86Sr and Sr values of the groundwater samples indicated that the Sr element was controlled by the weathering of limestone, dolomite and silicate rock. However, the figure of 87Sr/86Sr vs. Sr2+/[K++Na+] showed that the anthropogenic inputs also obviously contributed to the Sr contents. For tracing the detailed anthropogenic effects, we traced the sources of solutes collected karst groundwater samples in Chongqing according to the δ34S value of potential sulfate sources. The variations of both δ34S and 1/SO42? values of the groundwater samples indicated that the atmospheric acid deposition (AAD), dissolution of gypsum (GD), oxidation of sul?de mineral (OS) or anthropogenic inputs (SF: sewage or fertilizer) have contributed to solutes in karst groundwater. The influence of oxidation of sul?de mineral, atmospheric acid deposit and anthropogenic inputs to groundwater in Chongqing karst areas was much widespread.  相似文献