Phosphorus oxynitride PON, a silica analogue: structure and compression of the cristobalite-like phase; P –T phase diagram     

J. M. Léger  J. Haines  C. Chateau  G. Bocquillon  M. W. Schmidt  S. Hull  F. Gorelli  A. Lesauze  R. Marchand 《Physics and Chemistry of Minerals》2001,28(6):388-398

 The structure of the cristobalite-like polymorph of phosphorus oxynitride PON has been refined using neutron powder diffraction data. It is tetragonal, space group I&4macr;2d, Z=4. The four P–(O,N) distances are equal but the tetrahedron is compressed along c. In AX₂ or ABX₄ compounds, the tetragonal I&4macr;2d or I&4macr; structure is obtained when the average ratio of the cation to anion radius is below 1.186, whereas the tetragonal P4₁2₁2 or orthorhombic C222₁ structure is obtained at low temperatures for larger ratios. The cell parameters of this PON polymorph have been determined as a function of hydrostatic pressure by in situ angle dispersive X-ray powder diffraction in a diamond-anvil cell. Under truly hydrostatic pressure, a strong anisotropic behavior is observed with the c parameter being nearly incompressible. Very slight anisotropic stress strongly modifies the high-pressure behavior. According to the pressure-temperature conditions of treatment, three phases, cristobalite-, moganite-, and quartz-like, have been obtained by quenching experiments, and the P–T phase diagram of PON was derived. The high-pressure behavior of the α-quartz, moganite, and cristobalite-like polymorphs of PON and SiO₂ is discussed. Received: 7 August 2000 / Accepted: 21 January 2001  相似文献   

Characterisation of tobelite (NH4)Al2[AlSi3O10](OH)2 and ND4-tobelite (ND4)Al2[AlSi3O10](OD)2 using IR spectroscopy and Rietveld refinement of XRD spectra     

D. E. Harlov  M. Andrut  B. Pöter 《Physics and Chemistry of Minerals》2001,28(4):268-276

Tobelite (NH₄) Al₂ [AlSi₃O₁₀] (OH)₂, the ammonium analogue of muscovite, and its deuterated form ND₄-tobelite (ND₄) Al₂ [AlSi₃O₁₀] (OD)₂ have been synthesised at 600?°C and 200 and 500 Mpa using a well homogenised, stoichiometric SiO₂-Al₂O₃ oxide mix with Al₂O₃ in excess of 5 mol% and a 25% NH₃ solution whose relative abundance was such that the amount of NH₄ ⁺ stoichiometrically available was in excess of 50%. Characterisation of both tobelite and ND₄-tobelite using IR-spectroscopy, Rietveld refinement of X-ray powder diffraction data, and electron microprobe analysis indicate that, similar to K⁺ in muscovite, the NH₄ ⁺ or ND₄ ⁺ molecule occupies the interlayer site. IR absorption bands caused by NH₄ ⁺ and ND₄ ⁺ can be explained, to a very good approximation, on the basis of T_d symmetry. Nevertheless, substantial line broadening and the occurrence of shoulders indicate a deviation from ideal T_d symmetry. However, even at 77?K, no discrete splitting of the degenerate states could be confirmed. The OH stretching frequencies observed for synthetic tobelite are quite similar to those for muscovite, indicating that the replacement of K⁺ by NH₄ ⁺ has no effect. The low FWHH of the OH bands indicate that the hydroxyl groups are well ordered within the structure. Rietveld refinement of tobelite and ND₄-tobelite indicates that all samples synthesised consist of the 3 different mica polytypes which are typical of muscovite – namely 1M (C2/m), 2M ₁ (C2/c) and 2M ₂ (C2/c). Tobelite and ND₄-tobelite synthesised at 500 Mpa principally contain the 1M polytype, whereas the principle polytype for ND₄-tobelite synthesised at 200 Mpa, is 2M ₂. Rietveld refinement of X-ray diffraction spectra for tobelite synthesised at 200 Mpa was problematic due to the very broad FWHH of the X-ray peaks indicating poor crystallinity. In comparision to synthetic muscovite, the cell dimensions observed for tobelite and its deuterated analogue are quite similar except for the lattice constant c. Due to the larger radius of NH₄ ⁺ or ND₄ ⁺ compared to K⁺ cation, the c-direction is expanded form 10.275 Å in muscovite to approximately 10.540 Å in tobelite and ND₄-tobelite.  相似文献   

巴士系构造的地震危险性   总被引：11，自引：6，他引：11  

丁原章  梁劳 《华南地震》1992,12(2):1-14

在北东东向分布的华南地震带内,从巴士海峡到闽粤赣三省交界有呈北西向分布的地震密集带。它与北西向分布的巴士系断裂构造相一致。此组构造与华南地区其他北西向构造的重要区别在于,它起自菲律宾海板块的边缘,其动力主要来自该板块向欧亚板块不均匀的推挤作用。巴士系构造是华南地区新构造活动性最强的构造,沿着此组断裂曾有过大量强烈的地震活(?),包括6级、7级和8级地震。在未来10年内,此带的强震活动有逼近粤东、闽南沿海地区的趋势。  相似文献   

ENCORE钻孔导斜系统     

谈耀麟 《矿产与地质》1992,6(6):487-491

ENCORE钻孔导斜系统由设计先进的MOLE型固定楔、MULE型活楔、RATTY型扩孔导向矛和DOLPHIN型定向仪组成。可在40－96mm钻孔中进行定向钻进，解决钻孔纠斜或分支孔钻进问题。在分析研究其、工作原理和操作方法基础上进行对比分析，指出优点并介绍了使用效果。  相似文献   

The Sudbury Structure (Ontario,Canada): a tectonically deformed multi-ring impact basin     

A. Deutsch  R. A. F. Grieve  M. Avermann  L. Bischoff  P. Brockmeyer  D. Buhl  R. Lakomy  V. Müller-Mohr  M. Ostermann  D. Stöffler 《International Journal of Earth Sciences》1995,84(4):697-709

The occurrence of shock metamorphic features substantiates an impact origin for the 1.85 Ga old Sudbury Structure, but this has not been universally accepted. Recent improvements in knowledge of large-scale impact processes, combined with new petrographic, geochemical, geophysical (LITHOPROBE) and structural data, allow the Sudbury Structure to be interpreted as a multi-ring impact structure. The structure consists of the following lithologies: Sudbury Breccia —dike breccias occurring up to 80 km from the Sudbury Igneous Complex (SIC); Footwall rocks and Footwall Breccia — brecciated, shocked crater floor materials, in part thermally metamorphosed by the overlying SIC; Sublayer and Offset Dikes, Main Mass of the SIC and Basal Member of the Onaping Formation (OF) — geochemically heterogeneous coherent impact melt complex ranging from inclusion-rich basal unit through a dominantly inclusion-free to a capping inclusion-rich impact melt rock; Grey Member of OF — melt-rich impact breccia (suevite); Green Member of OF — thin layer of fall back ejecta; Black Member of OF — reworked and redeposited breccia material; Onwatin and Chelmsford Formations — post-impact sediments. Observational and analytical data support an integrated step-by-step impact model for the genesis of these units. Analysis of the present spatial distribution of various impact-related lithologies and shock metamorphic effects result in an estimated original rim-to-rim diameter of the final crater of 200 or even 280 km for the Sudbury Structure, prior to tectonic thrusting and deformation during the Penokean orogeny.  相似文献   

平衡剖面的正演计算及其应用   总被引：5，自引：0，他引：5       下载免费PDF全文

陈伟  曾庆 《地质科学》1993,28(2):117-126

正演运动模型近来已广泛运用于地质剖面的构造演化模拟。作者以Suppe的断层转折褶皱的几何模型为基础,详细阐述了挤压构造区域上盘地层的几何形态变化对应的速度场分布规律及地层长度变化;编制出相应的平衡剖面正演程序,并扩充了正演程序的应用范围。以川东大池干构造为实例,制作出该构造的平衡构造演化剖面。  相似文献   

兰州—天水地区三维重力反演及其地质解释          下载免费PDF全文

李渭娟  梁桂培  姚政生 《地震工程学报》1993,(4)

本文利用重力资料对兰州—天水地区的深部构造进行了研究。在计算中,采用Parker-Oldenbarg三维位场反演方法,反演前对重力资料进行了地形改正和中新生代沉积层校正。根据反演结果,综合分析了有关资料,认为该区为青藏块体过渡带,并且提出了陇中盆地为断块型构造盆地的新认识。  相似文献   

Crystal chemistry of tremolite–tschermakite solid solutions     

J. Najorka  M. Gottschalk 《Physics and Chemistry of Minerals》2003,30(2):108-124

Tremolite–tschermakite solid solutions have been synthesized between 700 and 850 °C and 200 and 2000 MPa. The starting materials were oxide–hydroxide mixtures and an additional 0.1–1.8 molal CaBr₂ solution. The run products were characterized using SEM, HRTEM, EMP, XRD and FTIR. The synthesized Al tremolites formed needles and lath-shaped crystals of up to 300 × 20 μm. HRTEM investigations showed that the majority of the amphiboles were well ordered. The EMP analysis revealed that the Al tremolites were solid solutions in the ternary tremolite–tschermakite–cummingtonite. The highest observed Al content was close to the composition of magnesiohornblende (X_ts=0.54). Different cummingtonite concentrations (X_cum=0.00–0.18) were observed, which generally increased with Al content. Rietveld refinements of the lattice constants showed a linear decrease of the cell parameters a and b with increasing Al content, whereas c and β increased. Small deviations from the linear behaviour were caused by variable amounts of the cummingtonite component. For pure tschermakite lattice parameters of a=9.7438(11) Å, b=17.936(14) Å, c=5.2995(3) Å, β=105.68(9)° and V=891.7 ± 1.4 ų were extrapolated by least-squares regression. Using the a and β lattice parameters for tremolite, tschermakite and cummingtonite, it was possible to derive amphibole compositions using powder XRD. IR spectra of the Al tremolites showed a total of 12 individual bands. The FWHMs of all bands increased with increasing Al content. According to their FWHMs, these bands were grouped into three band systems at 3664–3676 cm^?1 (I), 3633–3664 cm^?1 (II) and 3526–3633 cm^?1 (III). Assuming ^[6]Al substitution at M2 and/or M3 and ^[4]Al at T1, three principal different configurational groups could be assigned as local environments for the proton. I: only Si⁴⁺ at T1 and one or two Al³⁺ at M2 and/or M3_far, II: one Al³⁺ at T1 and one to three Al³⁺ at M2 and/or at M3_far, III: either Al³⁺ on M3_near and/or two Al³⁺ on T1 and additional one to four Al³⁺ at M2. It is assumed that these three configurational groups correspond to the three groups of observed bands. This was quantitativly supported by Monte-Carlo simulations. A model with random distribution at M2 and M3 including Al avoidance at tetrahedral and octahedral sites yielded the best agreement with the spectroscopical results.  相似文献   

Improving the efficiency of ant algorithms using adaptive refinement: Application to storm water network design     

M.H. Afshar 《Advances in water resources》2006

The ant algorithm is a new evolutionary optimization method proposed for the solution of discrete combinatorial optimization problems. Many engineering optimization problems involve decision variables of continuous nature. Application of the ant algorithm to the optimization of these continuous problems requires discretization of the continuous search space, thereby reducing the underlying continuous problem to a discrete optimization problem. The level of discretization of the continuous search space, however, could present some problems. Generally, coarse discretization of the continuous design variables could adversely affect the quality of the final solution while finer discretization would enlarge the scale of the problem leading to higher computation cost and, occasionally, to low quality solutions. An adaptive refinement procedure is introduced in this paper as a remedy for the problem just outlined. The method is based on the idea of limiting the originally wide search space to a smaller one once a locally converged solution is obtained. The smaller search space is designed to contain the locally optimum solution at its center. The resulting search space is discretized and a completely new search is conducted to find a better solution. The procedure is continued until no improvement can be made by further refinement. The method is applied to a benchmark problem in storm water network design discipline and the results are compared with those of existing methods. The method is shown to be very effective and efficient regarding the optimality of the solution, and the convergence characteristics of the resulting ant algorithm. Furthermore, the method proves itself capable of finding an optimal, or near-optimal solution, independent of the discretization level and the size of the colony used.  相似文献   

河南省气象服务短信平台     

赵战友张九营  罗传明郭庆 马建国 《河南气象》2006,(2):72-74

介绍了河南省气象短信运营平台的特点、结构和各模块的功能。  相似文献