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141.
新疆冰达坂含金剪切带内高品位金矿体更倾向定位于低应变带.选取典型剖面,对比蚀变围岩、矿石、未蚀变花岗质初糜棱岩及花岗质原岩组分特征,结果表明花岗质岩石容矿的金矿床剪切变形过程中组分发生分异,动力分异与流体分异对金矿化所起作用及相对程度不同,研究区金成矿主要与流体分异作用有关.流体分异作用过程中,相对于高应变带,低应变带内强分异形成的高Fe环境及扩容空间为金矿化、沉淀提供更有利条件,且碱(Na)交代排出的Si为浅层次硅化蚀变糜棱岩型及石英脉型矿化提供物源基础,K、 Ca、 Mg形成绢云母化、碳酸盐化、绿泥石化等蚀变,从而为区内金矿化定位及共生蚀变提供了合理解释.结合已有研究成果,认为钠长石化带下部应发育钾长石化带,且作为矿根相存在,矿带东、西段深部均有较好金矿化前景  相似文献   
142.
西南天山东德沟橄榄岩的地球化学特征及其地质意义   总被引:2,自引:0,他引:2  
孔凡梅  吴苏  李旭平  李守军 《地质论评》2012,58(6):1161-1174
东德沟橄榄岩出露于中国新疆伊犁—中天山板块和塔里木板块之间西南天山造山带的北缘,含大量角闪石、金云母等含水矿物,显示全部遭受了不同程度的交代变质作用.岩石主量元素含量变化较大,其后期蚀变基本向富铝和富钙两个方向变化,其Nb/Ta和Zr/Hf值显示难熔地幔残余的特征.该区橄榄岩轻重稀土分馏较明显,稀土元素配分曲线总体为LREE富集的右倾型,且富集大离子亲石元素Rb、Ba、Sr和放射性元素Th,但岩石呈现不一致的解耦现象,即主量元素表现难熔而稀土元素、不相容微量元素体现富集,说明主量元素和微量元素具有各自的演化特点.研究认为东德沟橄榄岩是经历部分熔融的楔形地幔残余,微量元素呈现的特征是俯冲板块析出熔体或流体交代的结果.与其岩石矿物学研究结果一致,对东德沟橄榄岩地球化学特征的深入研究证明,它们来源于SSZ环境俯冲上板片地幔楔橄榄岩残片.  相似文献   
143.
铌钽矿研究进展和攀西地区铌钽矿成因初探   总被引:12,自引:3,他引:9  
王汾连  赵太平  陈伟 《矿床地质》2012,31(2):293-308
铌钽矿主要产出类型包括伟晶岩型、富Li-F花岗岩型、碱性侵入岩型、碳酸岩型及冲积砂矿型。前2种类型以钽为主,后3种则以铌占主导。铌和钽大多以铌钽独立矿物(铌铁矿、钽铁矿、细晶石、烧绿石等)呈浸染状分布于含矿岩石中,也有部分以类质同象的形式分布于云母、榍石、霓石、钛铁矿等矿物中。关于铌钽矿的富集机制,一些学者认为可由富F-Na和稀有金属(铌、钽等)的花岗质熔体经结晶分异作用形成;另一些学者则根据铌钽矿化与岩石的钠长石化、锂云母化等紧密共生的特点,认为铌钽的富集是岩浆期后流体交代早期形成的花岗岩所致。攀西(攀枝花-西昌)地区的铌钽矿床(化)基本上都是沿着断裂带分布,矿体赋存于印支期碱性岩脉(碱性正长伟晶岩)中,有少数存在于碱性花岗岩中,与区域上邻近的正长岩体及花岗岩体关系密切。其矿石矿物主要为烧绿石、褐钇铌矿等。初步推断,攀西地区的铌钽矿与二叠纪地幔柱活动有关。碱性的正长岩体及花岗岩体与广泛分布的峨眉山玄武岩、辉长岩均是地幔柱岩浆活动的产物,长英质岩体(包括正长岩体和花岗岩体)是富铌钽岩石的母岩体。碱性伟晶岩脉(如炉库和白草地区)是碱性岩浆逐步演化的产物,含矿的碱性花岗岩是花岗质岩浆分异演化的结果。此外,在该地区的铌钽矿床中,铌钽矿物几乎都富集在钠长石化发育的地段,说明后期的热液交代对铌钽的富集也起到了一定作用。因此,攀西地区铌钽的富集是岩浆结晶分异和岩浆期后热液交代共同作用的结果。  相似文献   
144.
Jadeitite is a rare constituent of serpentinite-matrix mélange bodies from certain subduction complexes. Most jadeitite crystallizes from Na-, Al-, and Si-bearing fluids that are apparently derived from multiple subduction-zone sources. Even though jadeitite is near-end-member NaAlSi2O6 in major element composition and is volumetrically minor in subduction complexes, its trace elements and stable isotopes appear to record fluid compositions not directly seen in other subduction zone metasomatic systems.

Prior to our work, how jadeitite-forming fluids interact with serpentinite host rocks and serpentinizing fluids were largely unknown, because serpentinite-to-jadeitite contacts are generally not exposed. In the Sierra de las Minas, Guatemala, we have studied a 3 m-wide pit transecting the contact between a mined-out jadeitite body and its host serpentinite. An apparent transition zone between the former jadeitite and nearby serpentinite exposed in the mine pit contains four texturally distinct rock types of differing outcrop colours, composed of albitites and meta-ultramafic rocks. (The jadeitite body is now represented only by a large spoil pile.) Seven samples from the contact zone, jadeitite from the spoil pile, a serpentinite outcrop approximately 1 m outside the pit, and a jadeitite nodule within the contact zone albitite were analysed for major, minor, and trace elements.

Abundances of Al2O3, Na2O, MgO, FeO, Cr, Ni, and Sc track the contact between sheared albitite and foliated meta-ultramafic rocks. These elements change from values typical of Guatemalan jadeitites in the jadeitite block and albitites in the contact zone to values for Guatemalan meta-ultramafic rocks and serpentinites across the contact zone. In addition, the abundances of SiO2, CaO, Fe2O3, K2O, Rb, Cs, and Y show important features. Of greatest interest, perhaps, approximately 15 cm from the contact with meta-ultramafic rock, Zr, U, Hf, Pb, Ba, Sr, Y, and Cs in albitite are greatly enriched compared to elsewhere in the contact zone. Element enrichments spatially coincide with the appearance, increase in modal abundance, and/or increase in grain sizes of zircon, rare earth element (REE) rich epidote, titantite, and celsian within albitite. All of these ‘trace-element-rich’ accessory minerals show poikiloblastic inclusions of albite, which suggests that they grew concomitantly in the metasomatic zone.

Graphical and computational methods of evaluating mass changes of metasomatites relative to likely protoliths show that, near the contact, fewer minor and trace elements in albitite show 1:1 coordination with presumed protoliths. Most metasomatitites are enriched in large-ion lithophile elements (LILE) and heat-producing elements (HPE) relative to likely protoliths. Albitite near the contact with meta-ultramafic rocks also shows ultramafic components. Except for a Ca-rich actinolite schist zone, the meta-ultramafic rocks are depleted in LILE and HPE relative to serpentinite; host serpentinite is itself under-abundant in these elements relative to average upper mantle or chondrite.

In summary, the metasomatic zone shows more evidence for the introduction of components to albitite and actinolitic meta-ultramafic rock than it does for exchange of protolith components between jadeitite and serpentinite. The fluid that presumably formed the metasomatites was sufficiently rich in LILE and high-field-strength elements (HFSE) to both saturate and grow minerals in which Zr, Ba, and Ti are essential structural constituents and/or HFSE, LILE, and HPE minor to moderate substituents. These geochemically diverse element groups were fixed in albitite via the crystallization and growth of new accessory minerals within these rocks during albititization. The amount of LILE and HPE-depleted meta-ultramafic rock appears to be too small to call upon a local source for the LILE and HPE-enrichment seen in albitites. Therefore, LILE and HPE must be of exotic origin, carried and deposited by fluids within the albitites at the jadeitite-serpentinite contact. This contact clearly testifies to an alteration style that involved crystallization of ‘trace-element’-rich minerals during fluid flow; this process appears to be essential to mass transfer within subduction zones.  相似文献   
145.
Mafic dikes, which transect the Mesoarchaean Singhbhum Granitoid Complex, are the most abundant members of the Newer Dolerite dikes of the Singhbhum Orissa craton. These dikes are subalkaline and exhibit a tholeiitic differentiation trend. Studied dikes underwent fractional crystallization of clinopyroxene and plagioclase. They show enriched patterns for the light rare earth elements (LREE) and large ion lithophile elements (LILE). On primitive mantle-normalized multi-element patterns, they possess Ba, Nb, Sr, P, and Ti depletions similar to subduction-related basaltic rocks. The high (La/Yb) n and (Gd/Yb) n ratios suggest that the studied mafic dikes were derived by low degrees of partial melting of a garnet-bearing source. Judging by trace elemental ratios (e.g. Ba/Y, Nb/Y, Ba/Th and Th/Nb), the studied dikes were derived from a mantle source metasomatized by a subduction component (e.g. fluids derived by dehydration of the subducting slab). We conclude that interaction between these fluids and the overlying mantle was the main cause of (LREE and LILE) enrichment and Nb (high field strength elements) depletion in the mafic dikes.  相似文献   
146.
提要:东波超镁铁岩体位于雅鲁藏布江缝合带的西段,在中国是一个不多见的面积超过400 km2的大型超镁铁岩体。已有的岩石学和矿物学特征表明,该岩体与同一带中含有大型铬铁矿的罗布莎岩体可以对比,是一个寻找铬铁矿床的远景区。本文开展了东波超镁铁岩的主要组成岩石类型——方辉橄榄岩的铂族元素(PGE)研究,并结合主量和稀土元素(REE)组成,探讨岩体的成因。东波超镁铁岩中方辉橄榄岩具有相当高的Os含量(3.52×10-9~4.36×10-9),亏损的主量元素组成和低于原始地幔的稀土元素含量(0.89×10-6~1.37×10-6),指示东波超镁铁岩为经历过部分熔融和熔体抽取的亏损残余地幔岩石。东波超镁铁岩的PGE总含量为23.97×10-9~31.98×10-9,高于原始地幔的含量;PGE配分型式为左倾的正斜率型,相对Ir亚组铂族元素(IPGE)亏损钯亚组铂族元素(PPGE),Pd/Ir=1.49~2.65;REE配分型式为中稀土亏损的“V”型或“U”型,原始地幔标准化元素比值(La/Sm)m 为 1.05~3.37,(Gd/Yb)m=0.28~0.64;这些数据揭示东波超镁铁岩经历过交代作用,交代物质应富集不相容元素,高PGE含量,相对IPGE富集PPGE;较低的Cu/Pd比值(1226~3448)要求交代物质还应富含硫化物;推测交代物质可能来源于俯冲带构造环境下所产生岩浆熔离出的富硫化物熔体/流体。  相似文献   
147.
148.
异剥钙榴岩及其岩石成因意义   总被引:1,自引:0,他引:1  
异剥钙榴岩作为一种特殊的交代变质岩,绝大多数与超镁铁岩的蛇纹石化有关,是超镁铁岩蛇纹石化过程中所产生的富钙流体对与其伴生的相关岩石进行钙交代的结果。蛇纹石化的超镁铁岩或为蛇绿岩的端员组分,或为太古代绿岩带、阿拉斯加型和阿尔卑斯型等其它成因类型的超镁铁岩。它们多为纯橄榄岩、方辉橄榄岩和辉石岩等。异剥钙榴岩的形成主要取决于超镁铁岩的蛇纹石化作用和钙交代程度,而与超镁铁岩的成因类型、构造属性和时代归属没有多大的关系。那种将异剥钙榴岩片面地看成蛇绿岩的组成部分或者作为鉴别蛇绿岩辅助标志的观点需要改正。  相似文献   
149.
王勇  张洋  包峻帆 《江苏地质》2019,43(2):208-221
河南固始地区矽卡岩型铅锌矿为小型层控矽卡岩型铅锌矿,矿体赋存于下石炭统花园墙组地层中,主要受地层控制,区内龟(山)—梅(山)断裂带、杨山背斜及北西西向断裂为主要控矿构造。燕山期中酸性小岩体在有利的构造部位多次侵入,与围岩下石炭统花园墙组的石英砂岩、钙硅质石英砂岩、钙硅质粉砂岩的“硅钙面”发生交代作用,从而富集成矿,燕山期中酸性小岩体是矿区主要的物质来源和热源,矿体形成受构造影响显著,矿体规模与构造附近的侵入体规模成正比。矿区内物化探对矿体均有良好的指示。研究成果对于该区进一步扩大找矿远景具有一定的借鉴意义。  相似文献   
150.
张艳飞 《地质与勘探》2009,45(5):549-557
辽东硼矿区层状混合岩为含硼岩系的一个重要组成部分,与各种变粒岩和浅粒岩呈整合接触而呈层状展布,在岩性上有过度现象。岩石中交代结构发育;与变质围岩相比,混合岩的SiO2、K2O、Na2O等组分均明显增加,而Fe2O3+FeO、CaO、MgO、MnO等组分明显减少,K2O/Na2O变化较复杂,岩石化学成分的变化与交代作用有关;微量元素具有与围岩相似的特征,稀土元素含量高于围岩,稀土元素配分模式与变粒岩一致,具有典型的重熔特征。这些特征表明层状混合岩是变质围岩经选择重熔交代而形成的。  相似文献   
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