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151.
Sandro Fadda 《Geostandards and Geoanalytical Research》2005,29(1):143-156
Major concentrations of Al2O3, Fe2O3, MgO, CaO, Na2O and K2O, minor levels of TiO2, P2O5 and thirty petrologically, geochemically and environmentally significant trace elements have been determined in microwave oven acid leachates of whole powdered coal samples by direct current plasma‐atomic emission spectrometry (DCP‐AES). A single sample preparation procedure was suitable for all the determinations with no additional dilution step for major elements solution. Dried samples (0.5 g) were treated in low‐pressure PFA digestion vessels with HF/HCl/HNO3/HClO4 acids to quantitatively extract the analytes from the bulk material, while leaving the major part of organic matrix as a residue. The major constituents of geological samples, in particular the easily ionised elements (EIEs) such as alkali and alkaline earths, may complicate the instrumental determinations in DCP‐AES because of differential enhancements of elemental emission intensities and stray light interferences. Taking account of these factors, the coal matrix is considered to have very low major oxide totals as compared to many other common geo‐environmental and related materials (rocks, sediments, soil, ashes etc.). The sample size employed here, while yielding a relatively concentrated solution to cover a wide range of elemental determinations, provided a sample matrix that significantly diminished interferences for DCP measurements. The need for closely matching the unknowns and calibrators was eliminated except for overall acidity and an excess quantity of caesium for EIE buffering. Calibration of the spectrometer was accomplished by simple aqueous single element solutions as high concentration calibrators in addition to a reagent blank as a low concentration calibrator. Two point working curves were established to allow for the maximum concentrations of each element expected in the unknowns. The precision of determinations under routine conditions as well as the reproducibility of the leaching and precision of instrumental measurements have been evaluated. Relative standard deviations (RSD) were of 1–2% for those elements whose concentrations in solid samples were well above the limits of quantification. Method detection limits in the buffered solutions were also evaluated. To evaluate the accuracy of the microwave oven‐DCP method a suite of eight certified coal reference materials of differing rank, were analysed with good agreement with the certified and/or available published data. Results are presented for the uncertified major oxides in the AR series reference materials. 相似文献
152.
Grayna Ceglarska-Stefaska Katarzyna Zarbska 《International Journal of Coal Geology》2005,62(4):211-222
The paper reports the results of experiments concerning the sorption/desorption processes, observed under laboratory conditions, in two types of coal extracted from operational coal-mines in Poland, using CH4 and CO2 to observe their relative inter-reaction with the coal samples when introduced in varying proportions and conditions. Numerous studies concerning the sorption/desorption phenomena have described the operational mechanisms and the relationship of mine gases to the organically-created coal-body in mines. The differences in the behaviour of certain gases is twofold: firstly the essentially different characteristics of CO2 and CH4, and secondly the structure of the coal-bed itself: its degree of metamorphism and content of macerals. From the results yielded, it was observed that the divergence of the isotherms of sorption of CH4 and other gases in comparison with the isotherms of sorption of CO2 and a CO2/CH4 mixture differed and that the curve on the sorption isotherm was more clearly distinct after the introduction of CO2 molecules to the system: coal with a higher degree of metamorphism—CH4, which is closely related to the rigidity of the structure according to the level of metamorphism. Since coals with higher carbon content exhibit lower molecular bonding than low-carbonised coals, the characteristic feature of the bonds in the first case is their mobility. Knowledge of the physical and chemical properties of hard coals, as well as their interaction with mining gases, is of great use in solving problems concerned with the extraction of methane from mines or its storage in goafs. 相似文献
153.
Analysis of rock structure stability in coal mines 总被引:1,自引:0,他引:1
In this paper, the theory of limit point instability is used to analyse the stability of rock structures in coal mines. A general method of analysing stability of rock structures is put forward and a uniform instability condition of rock structures is set up. Some instability phenomena, such as rock bursts in circular roadways, pillars and long walls, and the outburst of coal and gas from circular roadways, are discussed analytically. At a later stage, the critical point of rock structure instability is determined. The influence of relative parameters (such as the mechanical properties of rock, coal, and the geometric sizes) on the stability of the rock structures is carefully analysed. Copyright © 2005 John Wiley & Sons, Ltd. 相似文献
154.
Localization of mining-induced horizontal fractures along rock layer interfaces in overburden: field measurements and prediction 总被引:3,自引:0,他引:3
V. Palchik 《Environmental Geology》2005,48(1):68-80
The locations of mining-induced horizontal fractures along rock interfaces in the overburden of Donetsk Coal Basin were identified using an original experimental device. The device traps methane from horizontal fracture zone (100–fold coal seam thickness) over an active longwall mining excavation. Presence or absence of horizontal fractures along rock layer interfaces is correlated with physical characteristics of the overburden, such as thickness, uniaxial compressive strength of overburden rock layers, location of rock layer interfaces and thickness of extracted coal seams. As a result, a combined criterion based on these physical characteristics is proposed to predict the presence of overburden horizontal fracturing in coal mine operations. 相似文献
155.
Erodibility of low‐compaction steep‐sloped reclaimed surface mine lands in the southern Appalachian region,USA
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The use of loose spoils on steep slopes for surface coal mining reclamation sites has been promoted by the US Department of Interior, Office of Surface Mining for the establishment of native forest, as prescribed by the Forest Reclamation Approach (FRA). Although low‐compaction spoils improve tree survival and growth, erodibility on steep slopes was suspected to increase. This study quantified a combined KC factor (combining the effects of the soil erodibility K factor and cover management C) for low compaction, steep‐sloped (>20°) reclaimed mine lands in the Appalachian region, USA. The combined KC factor was used because standard Unit Plot conditions required to separate these factors, per Revised Universal Soil Loss Equation (RUSLE) experimental protocols, were not followed explicitly. Three active coal mining sites in the Appalachian region of East Tennessee, each containing four replicate field plots, were monitored for rainfall and sediment yields during a 14‐month period beginning June 2009. Average cumulative erosivity for the study sites during the monitoring period was measured as 5248.9 MJ·mm·ha?1·h?1. The KC ranged between 0.001 and 0.05 t·ha·h·ha?1·MJ?1·mm?1, with the highest values occurring immediately following reclamation site construction as rills developed (June – August 2009). The KC for two study sites with about an 18–20 mm spoil D84 were above 0.01 t·ha·h·ha?1·MJ?1·mm?1 during rill development, and below 0.003 t·ha·h·ha?1·MJ?1·mm?1 after August 2009 for the post‐rill development period. The KC values for one site with a 40 mm spoil D84 were never above 0.008 t·ha·h·ha?1·MJ?1·mm?1 and also on average were lower, being more similar to the other two sites after the rill development period. Based on an initial KC factor (Ke) measured during the first few storm events, the average C factor (Ce) was estimated as 0.58 for the rill development period and 0.13 for the post‐rill development period. It appears that larger size fractions of spoils influence KC and Ce factors on low‐compaction steep slopes reclamation sites. Copyright © 2013 John Wiley & Sons, Ltd. 相似文献
156.
Concentration–discharge relationships in the coal mined region of the New River basin and Indian Fork sub‐basin,Tennessee, USA
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For many basins, identifying changes to water quality over time and understanding current hydrologic processes are hindered by fragmented and discontinuous water‐quality and hydrology data. In the coal mined region of the New River basin and Indian Fork sub‐basin, muted and pronounced changes, respectively, to concentration–discharge (C–Q) relationships were identified using linear regression on log‐transformed historical (1970s–1980s) and recent (2000s) water‐quality and streamflow data. Changes to C–Q relationships were related to coal mining histories and shifts in land use. Hysteresis plots of individual storms from 2007 (New River) and the fall of 2009 (Indian Fork) were used to understand current hydrologic processes in the basins. In the New River, storm magnitude was found to be closely related to the reversal of loop rotation in hysteresis plots; a peak‐flow threshold of 25 cubic meters per second (m3/s) segregates hysteresis patterns into clockwise and counterclockwise rotational groups. Small storms with peak flow less than 25 m3/s often resulted in dilution of constituent concentrations in headwater tributaries like Indian Fork and concentration of constituents downstream in the mainstem of the New River. Conceptual two or three component mixing models for the basins were used to infer the influence of water derived from spoil material on water quality. Copyright © 2012 John Wiley & Sons, Ltd. 相似文献
157.
结合DIn SAR与World View-2光学遥感解译技术,对研究区进行多源数据处理,提取研究地区的煤矿塌陷区信息,然后对处理后的两种结果进行对比。二者既有区别,又可以互补,最终在研究区形成完整的塌陷区信息。 相似文献
158.
东昆仑祁漫塔格山地区夏日哈木镍矿床矿物学特征 总被引:3,自引:0,他引:3
青海夏日哈木是近年来新发现的超大型镍矿床,大地构造位置处于东昆仑造山带之东昆中花岗—变质杂岩带的隆起区,成矿与镁铁质—超镁铁质小侵入体有关,属岩浆深部熔离贯入型。矿体呈透镜状、似层状,主要产于辉石岩、橄辉岩和苏长岩中;矿石为块状、准块状、海绵陨铁状、浸染状、细脉状和斑杂状构造,粒状结构、交代结构和固溶体分离结构等。矿石金属矿物主要为磁黄铁矿、镍黄铁矿和黄铜矿,含少量和微量紫硫镍矿、马基诺矿、铬铁矿、磁铁矿、黄铁矿、闪锌矿、辉铋矿、钛铁矿和自然铋等;脉石矿物主要有斜方辉石、橄榄石、普通辉石、基性斜长石、镁铁闪石、直闪石、滑石、蛇纹石等。文中对夏日哈木和金川我国两个超大型镍矿的主要地质特征作了对比;与世界上主要同类型硫化物铜镍矿床相比较,夏日哈木镍矿具有不少独特的特征,如其成岩成矿时代相对较年轻,矿石中铜的品位较低、亏损铂族元素等。 相似文献
159.
川西义敦岛弧稻城花岗岩体和海子山花岗岩体锆石U-Pb年代学、Hf同位素特征及地质意义 总被引:2,自引:0,他引:2
义敦岛弧形成于晚三叠世大规模俯冲造山作用过程中,位于松潘-甘孜褶皱带和羌塘地体之间。稻城岩体和海子山岩体分别为义敦岛弧上出露的晚三叠世和白垩纪花岗质岩体。结合野外考察,本文对上述岩体进行岩相学、锆石U-Pb年代学和Hf同位素的研究,结果表明,1稻城岩体和海子山岩体主要矿物为斜长石、钾长石、石英和黑云母,副矿物为锆石、榍石、磁铁矿和磷灰石等;钠质斜长石颗粒,以及钾长石和石英不连续出现,表明二者均属于低熔线花岗岩,是含水条件下,在与造山事件有关的环境中形成。2稻城岩体的侵位年龄为217.4Ma,属晚三叠世花岗岩侵入体,εHf(t)为-7.1~-0.1,二阶段模式年龄(tDM2)为1.26~1.7Ga,表明在中元古代与扬子克拉通经历了共同的地壳演化历史;海子山岩体的形成时代为98.3 Ma,为白垩纪时期产物,εHf(t)变化于-12.1~+2.5,二阶段模式年龄(tDM2)变化于1.0~1.93Ga。3结合前人研究成果,本文认为稻城岩体源岩可能是与扬子克拉通有关的中元古代的下地壳物质,在甘孜-理塘洋俯冲闭合后的同碰撞造山阶段,因地幔岩浆底侵作用而发生了部分熔融,同时伴有少量的亏损地幔成分加入,之后上升侵位于中—上地壳,并且侵位后经历了快速的冷却过程。海子山岩体是与俯冲有关的造山后伸展环境下形成的A2型花岗岩,源岩主要为中元古代地壳物质,同样有少量地幔物质加入,在白垩纪时侵位于地壳较浅部位,之后亦同样经历了快速的冷却过程。 相似文献
160.
近年来输气管道工程的大规模建设,其不可避免地要通过一些煤矿采空沉陷区和地质构造复杂区域。煤矿采空沉陷区的地表移动变形必然会使上覆的输气管道发生变形、甚至破坏,因此,分析与预测煤矿采空区地埋输气管道的安全性具有重要意义。本文以西气东输一线为例,依据弹性理论分析计算,当管道下伏分别为土体和岩体时,输气管道破坏时的岩土体垮塌宽度,并统计在垮塌影响范围一定的条件下,岩土体垮塌宽度与管道变形及最小曲率半径之间的规律。结果表明,管道的弯曲变形与垮塌宽度之间呈递增关系。 相似文献