Geochemical evidence for coal-derived hydrocarbons and their charge history in the Dabei Gas Field, Kuqa Thrust Belt, Tarim Basin, NW China   总被引：3，自引：0，他引：3  

Shuichang Zhang  Bin Zhang  Guangyou Zhu  Huitong Wang  Zhenxi Li 《Marine and Petroleum Geology》2011,28(7):1364-1375

Large to middle-scale thrust structures are important reservoir plays for coal-derived hydrocarbons in the foreland basins of NW China, with both gas and some accompanying oil. In the Dabei Gas Field of the Kuqa Thrust, however, the oil and gas pools are vertically distributed in a quite unique way: (1) liquid oil and some dissolved gas are present in the Dawanqi Anticline with the reservoir at 300-700 m depth, forming the only oil field in the Kuqa Thrust; (2) gas and minor accompanying oil are found in the deep reservoir of the Dabei-1 and Dabei-2 thrust traps around 5000-6000 m depth; (3) an extremely dry gas pool is found in the Dabei-3 thrust trap where the depth of the reservoir is over 7000 m. Geochemical data suggest that the hydrocarbons in the Dawanqi Anticline and the Dabei thrust traps originated from a similar source, i.e. the underlying Jurassic coal measures, with some contribution from Jurassic lacustrine shales. The Jurassic source rocks did not start to generate oil until the Miocene (around the Kangcun Stage), and extended into the Pliocene (the Kuche Stage) with the main gas generation period in the Pliocene (the Kuche Stage) and the Quaternary. Because the traps formed relatively early, the Dabei-1 and Dabei-2 thrusts could trap some of the early generated oils, but most of the early charged oil was redistributed to the shallower Dawanqi Anticline during the Kuche Stage. The Dabei-3 thrust trap formed concurrently with major gas generation and thus could not trap liquid hydrocarbons. The difference in the vertical distribution of the hydrocarbon accumulations in the Dabei Gas Field resulted from a complex interplay of source variability, structural evolution of the basin and thermal maturation.  相似文献   

Gas geochemistry of the Mount Elbert Gas Hydrate Stratigraphic Test Well, Alaska North Slope: Implications for gas hydrate exploration in the Arctic   总被引：2，自引：0，他引：2  

Thomas D. Lorenson  Timothy S. CollettRobert B. Hunter 《Marine and Petroleum Geology》2011,28(2):343-360

Gases were analyzed from well cuttings, core, gas hydrate, and formation tests at the BPXA-DOE-USGS Mount Elbert Gas Hydrate Stratigraphic Test Well, drilled within the Milne Point Unit, Alaska North Slope. The well penetrated a portion of the Eileen gas hydrate deposit, which overlies the more deeply buried Prudhoe Bay, Milne Point, West Sak, and Kuparuk River oil fields. Gas sources in the upper 200 m are predominantly from microbial sources (C₁ isotopic compositions ranging from −86.4 to −80.6‰). The C₁ isotopic composition becomes progressively enriched from 200 m to the top of the gas hydrate-bearing sands at 600 m. The tested gas hydrates occur in two primary intervals, units D and C, between 614.0 m and 664.7 m, containing a total of 29.3 m of gas hydrate-bearing sands. The hydrocarbon gases in cuttings and core samples from 604 to 914 m are composed of methane with very little ethane. The isotopic composition of the methane carbon ranges from −50.1 to −43.9‰ with several outliers, generally decreasing with depth. Gas samples collected by the Modular Formation Dynamics Testing (MDT) tool in the hydrate-bearing units were similarly composed mainly of methane, with up to 284 ppm ethane. The methane isotopic composition ranged from −48.2 to −48.0‰ in the C sand and from −48.4 to −46.6‰ in the D sand. Methane hydrogen isotopic composition ranged from −238 to −230‰, with slightly more depleted values in the deeper C sand. These results are consistent with the concept that the Eileen gas hydrates contain a mixture of deep-sourced, microbially biodegraded thermogenic gas, with lesser amounts of thermogenic oil-associated gas, and coal gas. Thermal gases are likely sourced from existing oil and gas accumulations that have migrated up-dip and/or up-fault and formed gas hydrate in response to climate cooling with permafrost formation.  相似文献   

Active mud volcanism in the West Alboran Basin: Geochemical evidence of hydrocarbon seepage     

V.N. Blinova  M.C. ComasM.K. Ivanov  E.N. PoludetkinaT.V. Matveeva 《Marine and Petroleum Geology》2011,28(8):1483-1504

The West Alboran Basin was previously classified as a mud volcanic province consisting of two mud volcano (MV) fields that are inactive at the present day: the Northern (Spanish) and the Southern (Moroccan) fields. The discovery of the first active mud volcano (Carmen; cruise TTR-17) in 2008, along with several pockmarks at the central part of the basin, motivates more careful geological and geochemical analysis of previous data and comparison to new observations.Gas bubbling from the crater of Carmen MV was observed and recorded using an underwater TV-system and a large TV-grab sample. The gas mainly consisted of methane with less than 1% wetness. However, all sets of homologues up to pentane were detected in the mud breccia of Carmen MV. Both molecular and stable carbon isotopic compositions, and their distribution along the core length, suggest a deep thermogenic source of hydrocarbons (HCs). Composition of the pore water from Carmen MV also points to a deep source of mud volcanic water. The isotopic results indicate that the source of mud volcanic water is the dehydration of clay minerals in the thermal zone of the smectite-to-illite transformation. Our observations allow us to infer the presence of structure II gas hydrates in mud breccia on the top of Carmen MV.High HC gas saturation in sediments in some pockmarks accompanied with live chemosynthetic fauna directly indicates the strong seepage activity of these structures. For the first time, authigenic carbonate crusts and chimneys with associated living chemosynthetic bivalves and tubeworms were sampled from a seep site in the West Alboran Sea. Authigenic carbonates consist of aragonite and calcite, and are characterized by a light carbon isotopic signature, up to −37.2‰ PDB, which points to their methane-derived origin.  相似文献   

The structure and formation of diapirs in the Yinggehai-Song Hong Basin, South China Sea   总被引：3，自引：0，他引：3  

Chao Lei  Jianye RenPeter D. Clift  Zhenfeng WangXusheng Li  Chuanxin Tong 《Marine and Petroleum Geology》2011,28(5):980-991

The occurrence of shale diapirs in the Yinggehai-Song Hong (YGH-SH) Basin is well documented, as is their association with big petroleum fields. In order to better understand how and why the diapirs form we performed a detailed geophysical analysis using a new regional compilation of high-resolution two- and three-dimensional seismic reflection data, as well as drilling data that cover the diapirs in YGH-SH Basin. As many as 18 diapirs were identified and are arranged in six N-S-striking vertical en échelon zones. On seismic reflection sections gas chimney structures, diapiric faults and palaeo-craters are genetically linked with the process of diapirism. Here we use geophysical and geological observations to propose a three-stage model for diapirism: initiation, emplacement, and collapse. During these three stages, different diapiric structure styles are formed, which we describe in detail. These include buried diapirs, piercing diapirs and collapsed diapirs. We link the diapirism to activity on the offshore continuation of the Red River Fault, as shown on our high-resolution seismic reflection data, which is also related to a high paleogeothermal gradient caused by crustal thinning. We also recognize the role of loading by the very large volume of sediment eroded from the edges of the Tibetan Plateau and delivered by the Red River to the basin.  相似文献   

Pore fluid geochemistry from the Mount Elbert Gas Hydrate Stratigraphic Test Well, Alaska North Slope     

M.E. Torres  T.S. CollettK.K. Rose  J.C. SampleW.F. Agena  E.J. Rosenbaum 《Marine and Petroleum Geology》2011,28(2):332-342

The BPXA-DOE-USGS Mount Elbert Gas Hydrate Stratigraphic Test Well was drilled and cored from 606.5 to 760.1 m on the North Slope of Alaska, to evaluate the occurrence, distribution and formation of gas hydrate in sediments below the base of the ice-bearing permafrost. Both the dissolved chloride and the isotopic composition of the water co-vary in the gas hydrate-bearing zones, consistent with gas hydrate dissociation during core recovery, and they provide independent indicators to constrain the zone of gas hydrate occurrence. Analyses of chloride and water isotope data indicate that an observed increase in salinity towards the top of the cored section reflects the presence of residual fluids from ion exclusion during ice formation at the base of the permafrost layer. These salinity changes are the main factor controlling major and minor ion distributions in the Mount Elbert Well. The resulting background chloride can be simulated with a one-dimensional diffusion model, and the results suggest that the ion exclusion at the top of the cored section reflects deepening of the permafrost layer following the last glaciation (∼100 kyr), consistent with published thermal models. Gas hydrate saturation values estimated from dissolved chloride agree with estimates based on logging data when the gas hydrate occupies more than 20% of the pore space; the correlation is less robust at lower saturation values. The highest gas hydrate concentrations at the Mount Elbert Well are clearly associated with coarse-grained sedimentary sections, as expected from theoretical calculations and field observations in marine and other arctic sediment cores.  相似文献   

Variations of methane induced pyrite formation in the accretionary wedge sediments offshore southwestern Taiwan   总被引：4，自引：0，他引：4  

Yee Cheng Lim  Saulwood Lin  Tsanyao Frank Yang  Yue-Gau Chen  Char-Shine Liu 《Marine and Petroleum Geology》2011,28(10):1829-1837

The accretionary wedge of offshore southwestern Taiwan contains abundant deposits of gas hydrate beneath the sea floor. High concentrations of methane in pore waters are observed at several locations with little data concerning historical methane venting available. To understand temporal variation of methane venting in sediments over geologic time, a 23-m-long Calypso piston core (MD05-2911) was collected on the flank of the Yung-An Ridge. Pore water sulfate, dissolved sulfide, dissolved iron, methane, sedimentary pyrite, acid volatile sulfide, reactive iron, organic carbon and nitrogen as well as carbonate δ¹³C were analyzed.Three zones with markedly different pyrite concentration were found at the study site. Unit I sediments (>20 mbsf) were characterized with a high amount of pyrite (251–380 μmol/g) and a δ¹³C-depleted carbonate, Unit II sediments (15–20 mbsf) with a low pyrite (15–43 μmol/g) and a high content of iron oxide mineral and Unit III sediments (<10 mbsf) by a present-day sulfate–methane interface (SMI) at 5 m with a high amount of pyrite (84–221 μmol/g) and a high concentration of dissolved sulfide.The oscillation records of pyrite concentrations are controlled by temporal variations of methane flux. With an abundant supply of methane to Unit I and III, anaerobic methane oxidation and associated sulfate reduction favor diagenetic conditions conducive for significant pyrite formation. No AOM signal was found in Unit II, characterized by typical organically-limited normal marine sediments with little pyrite formation. The AOM induced pyrite formation near the SMI generates a marked pyrite signature, rendering such formation of pyrite as a useful proxy in identifying methane flux oscillation in a methane flux fluctuate environment.  相似文献   

Geological controls on focused fluid flow through the gas hydrate stability zone on the southern Hikurangi Margin of New Zealand, evidenced from multi-channel seismic data     

G.J. Crutchley  A.R. Gorman  I.A. Pecher  S. Toulmin  S.A. Henrys 《Marine and Petroleum Geology》2011,28(10):1915-1931

Highly concentrated gas hydrate deposits are likely to be associated with geological features that promote increased fluid flux through the gas hydrate stability zone (GHSZ). We conduct conventional seismic processing techniques and full-waveform inversion methods on a multi-channel seismic line that was acquired over a 125 km transect of the southern Hikurangi Margin off the eastern coast of New Zealand’s North Island. Initial processing, employed with an emphasis on preservation of true amplitude information, was used to identify three sites where structures and stratal fabrics likely encourage focused fluid flow into and through the GHSZ. At two of the sites, Western Porangahau Trough and Eastern Porangahau Ridge, sub-vertical blanking zones occur in regions of intensely deformed sedimentary layering. It is interpreted that increased fluid flow occurs in these regions and that fluids may dissipate upwards and away from the deformed zone along layers that trend towards the seafloor. At Eastern Porangahau Ridge we also observe a coherent bottom simulating reflection (BSR) that increases markedly in intensity with proximity to the centre of the anticlinal ridge. 1D full-waveform inversions conducted at eight points along the BSR reveal much more pronounced low-velocity zones near the centre of the ridge, indicating a local increase in the flux of gas-charged fluids into the anticline. At another anticline, Western Porangahau Ridge, a dipping high-amplitude feature extends from the BSR upwards towards the seafloor within the regional GHSZ. 1D full-waveform inversions at this site reveal that the dipping feature is characterised by a high-velocity zone overlying a low-velocity zone, which we interpret as gas hydrates overlying free gas. These results support a previous interpretation that this high-amplitude feature represents a local “up-warping” of the base of hydrate stability in response to advective heat flow from upward migrating fluids. These three sites provide examples of geological frameworks that encourage prolific localised fluid flow into the hydrate system where it is likely that gas-charged fluids are converting to highly concentrated hydrate deposits.  相似文献   

Seismic quality factors across a bottom simulating reflector in the Makran Accretionary Prism, Arabian Sea     

Kalachand Sain  Anoop Kumar Singh 《Marine and Petroleum Geology》2011,28(10):1838-1843

The hydrate-bearing sediments above the bottom simulating reflector (BSR) are associated with low attenuation or high quality factor (Q), whereas underlying gas-bearing sediments exhibit high attenuation. Hence, estimation of Q can be important for qualifying whether a BSR is related to gas hydrates and free-gas. This property is also useful for identifying gas hydrates where detection of BSR is dubious. Here, we calculate the interval Q for three submarine sedimentary layers bounded by seafloor, BSR, one reflector above and another reflector below the BSR at three locations with moderate, strong and no BSR along a seismic line in the Makran accretionary prism, Arabian Sea for studying attenuation (Q⁻¹) characteristics of sediments. Interval Q for hydrate-bearing sediments (layer B) above the BSR are estimated as 191 ± 11, 223 ± 12, and 117 ± 5, whereas interval Q for the underlying gas-bearing sediments (layer C) are calculated as 112 ± 7, 107 ± 8 and 124 ± 11 at moderate, strong and no BSR locations, respectively. The large variation in Q is observed at strong BSR. Thus Q can be used for ascertaining whether the observed BSR is due to gas hydrates, and for identifying gas hydrates at places where detection of BSR is rather doubtful. Interval Q of 98 ± 4, 108 ± 5, and 102 ± 5, respectively, at moderate, strong and no BSR locations for the layer immediately beneath the seafloor (layer A) show almost uniform attenuation.  相似文献   

Prediction and assimilation of surf-zone processes using a Bayesian network: Part I: Forward models     

Nathaniel G. Plant  K. Todd Holland 《Coastal Engineering》2011

Prediction of coastal processes, including waves, currents, and sediment transport, can be obtained from a variety of detailed geophysical-process models with many simulations showing significant skill. This capability supports a wide range of research and applied efforts that can benefit from accurate numerical predictions. However, the predictions are only as accurate as the data used to drive the models and, given the large temporal and spatial variability of the surf zone, inaccuracies in data are unavoidable such that useful predictions require corresponding estimates of uncertainty. We demonstrate how a Bayesian-network model can be used to provide accurate predictions of wave-height evolution in the surf zone given very sparse and/or inaccurate boundary-condition data. The approach is based on a formal treatment of a data-assimilation problem that takes advantage of significant reduction of the dimensionality of the model system. We demonstrate that predictions of a detailed geophysical model of the wave evolution are reproduced accurately using a Bayesian approach. In this surf-zone application, forward prediction skill was 83%, and uncertainties in the model inputs were accurately transferred to uncertainty in output variables. We also demonstrate that if modeling uncertainties were not conveyed to the Bayesian network (i.e., perfect data or model were assumed), then overly optimistic prediction uncertainties were computed. More consistent predictions and uncertainties were obtained by including model-parameter errors as a source of input uncertainty. Improved predictions (skill of 90%) were achieved because the Bayesian network simultaneously estimated optimal parameters while predicting wave heights.  相似文献   

东方气田海管悬跨段安全评估分析          下载免费PDF全文

姚平  范奉鑫  李中阳  李磊  曹玉龙  刘洋 《海洋科学》2011,35(8):58-62

从工程实际问题出发,利用实际测量资料,通过建立近底床悬跨海管的有限元模型,计算了不同底床形状下海管最大静挠度随海流流速变化的规律,对东方1-1气田某标段海管进行了安全评估．筛选出了危险悬跨段。这一计算结果对海管的防护维护工程实践具有切实的指导意义。  相似文献