IR-spektroskopische und weitere Untersuchungen an neuen Weichspüler-Wirkstoffen     

H. Hellmann 《洁净——土壤、空气、水》1996,24(5):218-225

IR Spectroscopy and Further Analyses of New Fabric Rinse Agents Distearyldimethylammoniumchloride (DSDMAC) that dominated the fabric softener market in Germany in the past is now substituted by three new types of ester-based agents, i.e. imidazoline ester, ester quats, and diester quats what poses new challenges to surface water analytics. The IR spectra and the chromatographic behaviour of these three agents are more or less similar to those of naturally occuring fatty esters. The paper reports about the use of IR spectroscopy, its benefit in the sense of fingerprinting principle, the identification of substances by functional groups, and the analytical tracing of transformation products. The latter relates to the formation of salts with anions that are easily detectable, the clean up, and the final spectroscopic determination. While in 1994 DSDMAC was still determinable in concentrations of 10…20 mg/kg in suspended solids from the Middle Rhine River, the concentration of the substitutes was below the detection limit of 2 mg/kg and 1…2 μg/L in 1995.  相似文献   

Morphological characteristics of the earthquake surface ruptures on Awaji Island, associated with the 1995 Southern Hyogo Prefecture Earthquake   总被引：1，自引：0，他引：1  

Aiming  Ian Shinichi  Uda 《Island Arc》1996,5(1):1-15

Abstract The earthquake surface ruptures on the northern side of Awaji Island accompanying the 1995 Southern Hyogo Prefecture Earthquake in Japan consist of three earthquake surface rupture zones called the Nojima, Matsuho, and Kusumoto Earthquake Surface Rupture Zones. The Nojima Earthquake Surface Rupture Zone is - 18 km long and was formed from Awaji-cho at the northern end of Awaji Island to Ichinomiya-cho. It occurred along the pre-existing Nojima geological fault in the northern segment and as a new fault in the southern segment. The northern segment of the Nojima Earthquake Surface Rupture Zone is composed of some subparallel shear faults showing a right-step en echelon form and many extensional cracks showing a left-step en echelon form. The southern segment consists of some discontinuous surface ruptures which are concentrated in a narrow zone a few tens of meters in width. This surface rupture zone shows a general trend striking north 30°-60° east, and dipping 75°-85° east. The deformational topographies and striations on the fault plane generated during the co-seismic displacement show that the Nojima Earthquake Surface Rupture Zone is a right-lateral strike-slip fault with some reverse component. Displacements measured at many of the outcrops are generally 100-200 em horizontally and 50-100 em vertically in the northern segment and a few em to 20 em both horizontally and vertically in the southern segment. The largest displacements are 180 em horizontally, 130 em vertically, and 215 em in netslip measured at the Hirabayashi fault scarp. The Matsuho Earthquake Surface Rupture Zone striking north 40°-60° west was also found along the coastline trending northwest-southeast in Awaji-cho for ～1 km at the northern end of Awaji Island. The Kusumoto Earthquake Surface Rupture Zone occurred along the pre-existing Kusumoto geological fault for ～ 1.5 km near the northeastern coastline, generally striking north 35°-60° east, dipping 60°-70° west. From the morphological and geomorphological characteristics, the Nojima Earthquake Surface Rupture Zone can be divided into four segments which form a right-step en echelon formation. The geological and geomorphological evidence and the aftershock epicenter distributions show clearly that the distributions and geometry of these four segments are controlled by the pre-existing geological structures.  相似文献   

近年来我国地面反射率的若干重要特征     

李国平  陈仲林 《地理科学》1996,16(1):46-50

本文利用１９８６－１９９０年我国１４个具有地理、气候代表性的日射观测的实测资料，分析了我国地面反射率的若干最新特征，为认识和研究我国地理和气候变化提供了某些依据。  相似文献   

用气象卫星资料推算黑河地区地表特征参数   总被引：7，自引：5，他引：7  

陈添宇  陈乾 《高原气象》1992,11(4):431-439

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气压变化引起地表垂直向位移的估计：与汪福田同志商榷     

张昭栋  张广城 《地震研究》1992,15(1):86-90

本文利用理想的弹性半空间及Guterberg水平层状地层模型,估算出10hPa气压在半径100km圆心处,引起地表垂直向位移变化,它的量级很小,只有几毫米。  相似文献   

陆地水水质全球变化研究进展   总被引：1，自引：0，他引：1  

陈静生 《地球科学进展》1992,7(4):71-76

对陆地水水质全球变化研究中的几个问题进行了讨论，包括:陆地淡水水质的全球参比值问题;水质监测的发展及全球淡水水质监测计划;全球淡水水质变化趋势分析。
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Interannual Fluctuations of Surface Air Temperature over North America and Its Relationship to the North Pacific SST Anomaly     

Wu Renguang  Chen Lieting 《大气科学进展》1995,12(1):20-28

The characteristics of interannual fluctuations of the surface air temperature over North America are investigated by using the surface air temperature data of 130 stations during 1941 through 1980. It is found that the surface air temperature bears about ten-year time scale oscillation over the southeastern and northwestern North America and along the west coast of the United States, and it has the characteristics of quasibiennial oscillation over the eastern North America. The ten-year scale oscillation of the surface air temperature is related to that of the sea surface temperature (SST) of North Pacific through the PNA pattern atmospheric circulation anomaly over North Pacific through North America. It is shown that the North Pacific SST has a closer association with the surface air temperature over North America than the central and eastern equatorial Pacific SST. The characteristics of the seasonal variations of the relationship between the North Pacific SST and the surface air temperature over No  相似文献   

Surface complexation at hydrous fluorapatite     

Willis Forsling  Liuming Wu 《Aquatic Sciences - Research Across Boundaries》1993,55(4):336-346

The adsorption of H⁺, OH^– and ARS (Alizarin Red S) onto hydrous fluorapatite surfaces and Ca²⁺—ARS complexation in solution were studied by means of combined potentiometric and spectrophotometric titrations, as well as zeta potential and FT-IR measurements. Corresponding equilibrium constants of surface and solution reactions are determined. The application in flotation processes is discussed.  相似文献   

Estimation of abl Parameters Using the Vertical Velocity Measurements of an Acoustic Sounder   总被引：2，自引：0，他引：2  

J. A. Kalogiros  C. G. Helmis  D. N. Asimakopoulos  P. G. Papageorgas 《Boundary-Layer Meteorology》1999,91(3):413-449

The friction velocity, the surface heat flux and the height of the Atmospheric Boundary Layer (ABL) are important parameters. In this work, vertical velocity variance ( _w ² ) and wind velocity structure parameter (C _v ² ) profiles estimated by acoustic sounder measurements are used, along with similarity relations, to estimate these parameters in the unstable Atmospheric Boundary Layer and the friction velocity in the stable one. The data were collected by two acoustic sounders with different height range and resolution under various atmospheric conditions (stability) and at two experimental sites in different terrain. The C _v ² profiles are estimated using gate difference of the vertical velocity measurements and the assumption of local isotropy. The vertical velocity data are corrected for the significant effects of noisy measurements and sampling volume averaging on the _w ² and C _v ² estimations using original techniques that are presented in this work. The results of the similarity method using acoustic sounder data are compared against estimates of the corresponding atmospheric parameters obtained from direct measurements. The comparison confirms the ability of the method to provide reasonably accurate estimates of these parameters especially in the middle of the day.  相似文献   

Evaluation of aluminum speciation in surface waters in China and its environmental risk assessment     

S.?P.?BiEmail author  N.?Gan  X.?C.?Lu  H.?Y.?Ni  H.?Lin  X.?L.?Wang  Z.?B.?Wei 《Environmental Geology》2003,45(1):65-71

As the ongoing global research on acid precipitation is developing in depth, more and more attention has been paid to the ecological effects of aluminum (Al) due to its toxicity to plants and animals, which is caused by acid precipitation. As a very serious problem of terrestrial and aquatic environmental acidification occurs in China, especially in southwestern China, a systematic investigation of Al speciation in these regions is very important. In this paper, the Al speciation results of surface waters in China are reported and its ecological impacts is evaluated. More than 100 water samples were collected from about twenty provinces of China. Driscoll's Al speciation scheme combined with the modified MINQEL computer model is used for speciation of Al. This study shows that the ecological impacts of acidification are quite different between China and Western countries, because of different geographical environments and geological settings. In Western countries, acidification is mainly caused by NO₂^-. Due to low concentrations of K⁺, Na⁺, Ca²⁺, Mg²⁺, the buffer capacities of soil and water are weak. Therefore, natural waters can be acidified to pH<5 very easily, resulting in a considerable mobilization of Al and worsening of the ecological environment. In China, acid precipitation is mainly in the form of sulfuric acid. In northwestern China, concentrations of K⁺, Na⁺, Ca²⁺, Mg²⁺ are high in soil and surface waters. This leads to much higher capacity and a high resistance ability to acidification. The pH values of waters in this region are high (around 7) and no serious Al toxicity is found at present. However, in northeastern and southeastern China, the soil is rich in Al (unsaturated aluminosilicates in northeastern China, saturated aluminosilicates in north and central China, aluminum-rich soil in southeastern and southwestern China). The concentrations of K⁺, Na⁺, Ca²⁺, Mg²⁺ in soil and waters are lower than those of northwestern China. Therefore the buffer capacity is limited. Numerous surface waters have already been acidified and pH values declined to 5. The impacts of Al toxicity on ecological systems in these regions are very serious, especially in Jiangxi, Hubei Provinces and Chongqing Municipality.  相似文献