Experimental Studies of the Solubility of Cassiterite and the Extraction of Tin from Granitic Melts     

李统锦 《中国地球化学学报》1989,8(1):84-96

Experiments indicate that the solubility of cassiterite can be enhanced by increasing either acidity or alkalinity in hydrothermal solutions as a consequence of the duality of tin.The minimum solubility of cassiterite is found in neutral solutions.F-and CL-coordination compounds of Sn can alternate with hydroxyl coordination compounds with changing pH in the solutions.In this case,F^- and Cl^- and OH^- can be substituted with each other.The dissolution reaction of cassiterite is of reducing nature.High temperature and acidic reducing environment are favorable for the dissolution of cassiterite and the trans-port of Sn^2 compounds in fluids or solutions.High-temperature fluoride and chloride fluids can all dissolve,extract and enrich Sn to form F^- and /or Cl-coordination compounds,However,Fplays a more important role than Cl.F-coordination compounds are more stable and efficient than Cl-coordination compounds during the transport an enrichment of Sn in melts or solutions.The solubili-ty of cassiterite and the amount of Sn extracted from granitic melt depend not only on T,P,pH and Eh in the fluids or solutions,but also on the amounts of dissociated F^- and Cl^- in the fluids.  相似文献   

Oceannographic Chemistry of Calcium Carbonate in the Sea Area at the Pearl River Mouth     

韩舞鹰  王均德 《中国地球化学学报》1989,8(2):179-186

Based on the analytical results for 101 samples from 50 survey spots,this paper describes the changes in rations of various components in calcium carbonate from the sea area at the Pearl River mouth with pH.Relations of ∑CO2 with salinity,and Ca concentration with salinity in different parts of the river mouth have been established.The annual throughput of Ca from the Pearl River and the saturation degrees of calcite and aragonite have been calculated.  相似文献   

用制约消去法分段求解自由网的观测值方法     

周丽萍  翟为檀 《勘察科技》1989,(1):1-15

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全新世天然和人为界限的放射性碳所龄值及其对比     

Xotu.  HA  郭永志 《国外第四纪地质》1989,(4):1-4

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洛川黄土剖面的粉砂与粘粒比值及粒度旋回     

胡碧茹  卢演俦 《岩石学报》1989,5(1):12-20

洛川黑木沟黄土剖面发育了一套完整的黄土地层。据剖面百余块标本粒度资料阐述了Kd=(粉砂(0.05-0.01mm％))/(粘粒(<0.005mm)％)的地质及物理意义。它反映了受风化的粉尘粒组与次生粒组之间的消长关系,Kd值变化既受风尘来源区干湿状况或生物气候条件的制约,又受风化成壤作用的制约。因此,Kd值可视为黄土、古土壤生成环境的一个指标。据Mφ(平均值)由粗到细的变化划为一个粒度旋回,全剖面共分11个旋回。每个旋回反映了一定的岩性地层组合及生物气候环境的变化。  相似文献   

长江口泥沙的来源分析与数量计算的研究   总被引：3，自引：0，他引：3  

林承坤 《地理学报》1989,44(1):22-31

本文根据地学原理，建立了长江口泥沙的来源分析与数量计算的模式。定量分析了长江口泥沙来源，计算了泥沙的数量。通过验证表明沙量的计算值与验证值两者十分吻合。  相似文献   

华北地区强震前后的 h 值及“震情窗口”变化   总被引：1，自引：0，他引：1  

钱兆霞 《地震研究》1988,(3)

邢台、渤海、海城以及唐山大地震前1年内,围绕震中甚至距离震中500多公里的地区发生的某些震群,出现衰减系数异常(h≤1)。同时发生在林县、太原、长岛地区的小震群,其月频度几乎同步出现峰值。称林县、太原、长岛地区为“震情窗口”。强震前区域震情h值异常和“震情窗口”变化呼应,对判断未来强震三要素是有益的。  相似文献   

滇西澜沧变质带中白云母的研究及其地质意义   总被引：7，自引：0，他引：7       下载免费PDF全文

赵靖 《岩石矿物学杂志》1993,(3)

本文以滇西澜沧变质带中最为广泛分布的造岩矿物——白云母为对象,详细研究和分析了其成分、多型类型及b_0值等,探讨了白云母的发育规律。研究结果表明,本带中绝大多数白云母为多硅白云母,且为3T+2M_1型,与蓝闪石共生的则以3T多硅白云母为主。此外,澜沧变质带经历了蓝闪石片岩亚相的高压变质作用,与古特提斯构造演化密切相关,并可与世界著名的高压带对比。  相似文献   

Bond—Valence Sum and Distortion of Coordination Polyhedra     

章礼明 《中国地球化学学报》1993,12(1):92-96

By using the Lagrange‘s intermediate value theorem,it is derived mathematically that the structur-al distortion of a coordination polyhedron may lead to an increase in bond-valence sum of the cen-tral atom of ion .The applicabilities of the bond-valence model are discussed in the following two cases:the modeling of crystal structure ,and the indication of distortion degree of a coordination polyhedron.Also it is shown that a distorted polyhedron should be in favor of a longer average bond length or a smaller coordination number.  相似文献   

滇西澜沧变质带中白云母bo值特征及其多期变质作...   总被引：2，自引：0，他引：2  

赵靖  钟大赉 《矿物岩石》1993,13(1):1-4

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