Negative Ce Anomaly in the Indian Banded Iron Formations: Evidence for the Emergence of Oxygenated Deep-Sea at 2.9-2.7 Ga     

Yasuhiro KATO  Takashi KANO  Keitaro KUNUGIZA 《Resource Geology》2002,52(2):101-110

Abstract: Major and rare earth element contents are reported for Late Archean banded iron formations (BIFs) in the Bababudan Group of the Dharwar Craton, South India. The BIFs are mostly composed of SiO₂ (average1ρ = 54.88.1 wt%) and Fe₂O₃* (44.38.2 wt%). The Al₂O₃ and TiO₂ contents are remarkably low, suggesting that detrital components were starved during the BIF deposition. The BIFs have a LREE-enriched pattern with a relatively high (La/Yb)_N (6.644.07). Total REE concentrations (RE) vary from 5.2 to 65.3 ppm. The REE patterns are characterized by the presence of a very large negative Ce anomaly (Ce/Ce*: 0.13-0.83) and a positive Eu anomaly (Eu/Eu*: 0.96-2.45). The Eu/Eu* decreases and (La/Yb)_N increases with a increase of RE. These correlations of REE indices are similar to those of modern hydrothermal iron-rich sediments near a mid-ocean ridge (MOR). Greenstones associated with the BIFs have MORB-like geochemical features. These geochemical and geological lines of evidence indicate that the depositional site of the BIFs was remote from a continent and/or island arc and that the BIFs were in situ hydrothermal sediments near a MOR. A striking negative Ce anomaly in the BIFs indicates that oxygenated deep-sea environments emerged at 2.9-2.7 Ga. The existence of contemporaneous Mn deposits in the Dharwar Craton supports this assertion. Our scenario of oxygen in the Earth's surface of the Late Archean is different from long-held notion that the atmosphere and ocean were persistently anoxic throughout the Archean.  相似文献   

圆弧状沉积盆地与软土单覆盖层出平面地表运动对比   总被引：2，自引：0，他引：2  

袁晓铭  李雨润  孙锐 《地震工程与工程振动》2002,22(4):16-21

采用解析方法，通过圆弧状沉积盆地与同样参数的软土均匀单覆盖层的对比，研究沉积盆地对平面SH波二维散射效应和其出平面地表运动。数值对比结果表明：（1）波垂直入射时盆地中央地表位移幅值反应，其随频率变化形式与软土单覆盖层的地表运动有较强的对应性，且此时单覆盖层地表位移幅值为其下降；（2）盆地的二维散射效应特点显著波的汇聚作用使盆地中的地表运动显著放大，总体上较软土单覆盖层的地表位移幅值要大，其频域内的最大反应则明显大于单覆盖层情况，但最大反应在盆地表面出现的位置依赖于入射波角度、盆地深宽比和盆地的软硬程度；（3）沉积盆地中地表位移运动有强烈扭转效应，且随盆地变软和入射波频率增高而增强。  相似文献   

Transient foundation solution of saturated soil to impulsive concentrated loading     

X. L. Zhou  J. H. Wang  J. F. Lu 《Soil Dynamics and Earthquake Engineering》2002,22(4)

The transient dynamic response of saturated soil under suddenly applied normal and horizontal concentrated loading is studied in this paper. The behavior of saturated soil is governed by Biot's consolidation theory. The general solutions for Biot equations of equilibrium are derived in terms of displacements and variations of fluid volume, using Laplace–Hankel integral transforms. The solutions in the time domain can be evaluated by numerical inverse Laplace–Hankel transforms. Selected numerical results for displacements, stresses, and pore pressures are presented. Comparisons with existing closed-form solutions for the elastic half-space are made to confirm the accuracy of the present solutions. The solutions can be used to study a variety of transient wave propagation problems and dynamical interactions between saturated soil and structures.  相似文献   

Genesis of chlorine and sulphur in fumarolic emissions at Vulcano Island (Italy): assessment of pH and redox conditions in the hydrothermal system     

V. Di Liberto  P. M. Nuccio  A. Paonita   《Journal of Volcanology and Geothermal Research》2002,116(1-2)

Chlorine- and sulphur-bearing compounds in fumarole discharges of the La Fossa crater at Vulcano Island (Italy) can be modelled by a mixing process between magmatic gases and vapour from a boiling hydrothermal system. This allows estimating the compounds in both endmembers. Magma degassing cannot explain the time variation of sulphur and HCl concentrations in the deep endmember, which are more probably linked to reactions of solid phases at depth, before mixing with the hydrothermal vapours. Based on the P–T conditions and speciation of the boiling hydrothermal system below La Fossa, the HCl and S_tot contents in the hydrothermal vapours were used to compute the redox conditions and pH of the aqueous solution. The results suggest that the haematite–magnetite buffer controls the hydrothermal fO₂ values, while the pH has increased since the end of the 1970s. The main processes affecting pH values may be linked to Na–Ca exchanges between evolved seawater, feeding the boiling hydrothermal system, and local rocks. While Na is removed from water, calcium enters the solution, undergoes hydrolysis and produces HCl, lowering the pH of the water. The increasing water–rock ratio within the hydrothermal system lowers the Ca availability, so the aqueous solution becomes less acidic. Seawater flowing towards the boiling hydrothermal brine dissolves a large quantity of pyrite along its path. In the boiling hydrothermal system, dissolved sulphur precipitates as pyrite and anhydrite, and becomes partitioned in vapour phase as H₂S and SO₂. These results are in agreement with the paragenesis of hydrothermal alteration minerals recovered in drilled wells at Vulcano and are also in agreement with the isotopic composition of sulphur emitted by the crater fumaroles.  相似文献   

LiCl-NiCl2熔盐体系相图          下载免费PDF全文

张宏力  方建慧  阎立诚  陈念贻 《盐湖研究》2003,11(1):7-10

用原子参数 模式识别方法研究AX BX2 型卤化物熔盐体系形成固溶体的规律性 ,同时预报了LiCl NiCl2 熔盐体系能形成以LiCl为基的广泛固溶体。采用热分析法和X 射线衍射分析等实验测定了LiCl NiCl2熔盐体系相图 ;结果与计算预报相符。  相似文献   

不同浓度Li2SO4水溶液结构的X射线衍射研究          下载免费PDF全文

房艳  房春晖  高世扬 《盐湖研究》2003,11(2)

用θ～ 2θ型粉末衍射仪反射法精确测量了不同浓度的Li2 SO4水溶液的衍射数据 ,通过数据处理给出了溶液的结构函数和径向分布函数 ,由几何结构模型的最小二乘法精修 ,得到了溶液中阳离子和阴离子第一、二水合层的结构参数。  相似文献   

内蒙古孟恩陶勒盖银铅锌矿床白云母Ar-Ar年龄及其意义   总被引：10，自引：1，他引：10       下载免费PDF全文

张炯飞  庞庆邦  朱群  金成洙 《矿床地质》2003,22(3):253-256

文章采用Ar_Ar同位素测年法对孟恩陶勒盖银铅锌矿云英岩化阶段形成的白云母进行了测试 ,获得白云母坪年龄为 (179.0± 1.5 )Ma ,等时线年龄为 (182 .3± 3.8)Ma。这组数据近似地代表了该矿床的形成年龄 ,同时也显示该地区除已知的晚侏罗_早白垩世构造_岩浆_成矿作用外 ,还有一期重要的早侏罗_中侏罗世构造_岩浆_热液成矿事件 ,这也是到目前为止所获得的大兴安岭中南段热液矿床最老的成矿年龄  相似文献   

锡铁山铅锌矿地质特征、矿床成因及找矿标志   总被引：4，自引：1，他引：4  

李如满  汪树栋 《矿产与地质》2003,17(3):218-221

通过找矿工作的实践，认为锡铁山铅锌矿床是由火山喷流沉积—后期热液叠加改造富集的块状硫化物多金属矿床。区域上NW—SE向早古生代形成的裂谷带，三级盆地内沉积的晚奥陶世滩间山群的大理岩与绿片岩系是表区找矿的最佳区段。而绢云绿泥斜长片岩、含碳质绢云绿泥片岩、白色大理岩、条带状大理岩是铅锌矿的最重要的找矿标志。  相似文献   

华南热水成因硅质岩建造的稀土元素地球化学特征   总被引：11，自引：2，他引：11  

杨海生  周永章  杨志军  张澄博  付伟 《矿物岩石地球化学通报》2003,22(1):61-64

本文在华南地区若干个重要层位热水成因硅质岩建造的稀土元素地球化学数据的基础上,讨论了热水成因硅质岩的REE特征及其与形成环境的关系。指出典型热水沉积建造的δCe为负异常,而δEu为正异常,且LREE>HREE;这种热水成因的硅质岩REE总量普遍较低,且有从热水喷口向外REE总量增高的趋势。热水成因硅质泥岩与正常沉积成因硅质泥的混合存在使稀土元素分布状况变得更复杂。  相似文献   

青海锡铁山热水沉积型铅锌矿床的地球化学特征   总被引：15，自引：0，他引：15  

邓达文  孔华  奚小双 《矿物岩石地球化学通报》2003,22(4):310-313

通过对锡铁山铅锌矿床的围岩(矿石)化学成分、稀土及微量元素特征的研究，发现矿区地层普遍具有铈负异常(δCe=0．47～0．90)，为海相沉积岩，近矿围岩中Ag、Hg、As、Sb、Ba等热水沉积指示元素偏高，显示成矿流体性质为热卤水，矿区火山岩不发育，矿床类型可以划为Sedex型。  相似文献