广西金牙金矿床石英的标型特征及其意义     

方耀奎 《南方国土资源》1993,(4)

本文通过对金牙金矿床石英的化学成分、包裹体、物理性质及稳定同位素等万面的矿物学特征研究,取得了有价值的成因信息和找矿标志。认为该矿床属浅成中低温地下热(卤)水渗滤型金矿床,成矿物质来源于地层围岩。还指出石英颗粒极细小,多为隐晶至微晶,自形程度低,呈白色或无色、透明;比重低,晶胞棱长a_o大而Co小、单位晶胞体积增大(与标准石英比);红外光谱有1个宽峰、4个吸收峰和2个强的特征峰的波段,具单峰或双峰发热光曲线(在50～350℃范围内);具结构铝,含Ca、Fe、Mn、Au、Ag、Co、Ni、Se、Te与∑REE等杂质元素,其中Au与Al成正相关,而Au与∑REE呈负相关;包裹体呈无色透明、个体细小且少,以液相为主.气液比低,且出现沸腾包体群,其含盐度低,无子矿物,Na、Ca较高,为富含CO_2,CH_4的Ca~(-2)-Na_a-HCO_3~1-Cl型地下热(卤-水(温度305～190℃、压力25669～16945kpa.深度小于1km);δ~(18)O、δ~(18)O_(H_2O)、δD值具大气降水特征,δ~(13)C值类似油田碳等特征,是找“金牙型”金矿的重要找矿标志。  相似文献   

电子探针在工艺矿物学研究中的应用     

张凤英  黄巧燕 《地质论评》2023,69(Z1):457-460

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Rapid screening of Zr-containing particles from Chang’e-5 lunar soil samples for isotope geochronology: Technical roadmap for future study     

《地学前缘(英文版)》2022,13(3):101367

New samples returned by China Chang’e-5 (CE-5) mission offer an opportunity for studying the lunar geologic longevity, space weathering, and regolith evolution. The age determination of the CE-5 samples was among the first scientific questions to be answered. However, the precious samples, most in the micrometer size range, challenge many traditional analyses on large single crystals of zircon developed for massive bulk samples. Here, we developed a non-destructive rapid screening of individual zirconium-containing particle for isotope geochronology based on a Micro X-ray fluorescence analysis (µXRF). The selected particles were verified via scanning electron microscopy (SEM), 3D X-ray microscopy (XRM), and focused ion beam scanning electron microscopy (FIB-SEM) techniques, which showed that zirconium-bearing minerals with several microns were precisely positioned and readily suitable for site-specific isotopic dating by second ion mass spectrometry (SIMS). Such protocol could be also applicable in non-destructively screening other types of particles for different scientific purposes. We therefore proposed a correlative workflow for comprehensively studying the CE-5 lunar samples from single particles on nanometer to atomic scales. Linking various microscopic and spectromicroscopic instruments together, this workflow consists of six steps: (1) single-particle selection with non-destructive µXRF technique, (2) 2D/3D morphological and structural characterization with a correlative submicron 3D XRM and nanoscale resolution FIB-SEM imaging methods, (3) SEM analysis of the surface morphology and chemistry of the selected particle, (4) a series of microscopic and microbeam analyses (e.g., SEM, electron probe microanalysis, and SIMS) on the cross-section of the selected particle to obtain structural, mineralogical, chemical, and isotopic features from the micron to nanometer scale, (5) advanced 2D/3D characterization and site-specific sample preparation of thin foil/tip specimens on a microregion of interest in the selected particle with FIB-SEM technique, and (6) comprehensive analyses on the FIB-milled specimens at nanometer to atomic scale with synchrotron-based scanning transmission X-ray microscopy, analytic transmission electron microscopy, and atom probe tomography. Following this technical roadmap, one can integrate multiple modalities into a uniform frame of multimodal and multiscale correlated datasets to acquire high-throughput information on the limited or precious terrestrial and extraterrestrial samples.  相似文献   

利用X射线粉晶衍射和电感耦合等离子体质谱法研究江西西华山钨矿床中黑钨矿的矿物学特征及指示意义     

鲁麟  梁婷  陈郑辉  王勇  黑欢  谢星 《岩矿测试》2015,34(1):150-160

目前针对江西大型黑钨矿石英脉型钨矿床西华山的黑钨矿矿物学特征及指示意义研究较少。本文利用X射线粉晶衍射分析和电感耦合等离子体质谱分析技术对黑钨矿晶体结构、化学成分特征及空间变化规律开展研究。获得黑钨矿晶胞参数为a0=0.477 nm,b0=0.573 nm,c0=0.498 nm,β=90°21',属于锰钨铁矿,与前人得出的黑钨矿晶胞参数略有不同,代表不同元素对铁锰的类质同象替代。主要化学成分WO3、Fe O、Mn O的含量在空间上具有一定的变化规律,反映了成矿物质的运移特征。微量元素Sc、Y、Nb、Ta在垂向含量变化大,说明矿液运移具有复杂性。稀土总量ΣREEs较高(397.16×10-6~1071.11×10-6),具有强烈的Eu负异常,具重稀土富集左倾的"躺椅式"球粒陨石标准化配分模式。将西华山、盘古山、淘锡坑、大吉山4个典型矿床的黑钨矿稀土元素特征进行对比,反映产在花岗岩内接触带的黑钨矿的稀土总量(ΣREEs)相对最高,分馏最明显;产在花岗岩内及其外接触带的黑钨矿的稀土总量(ΣREEs)相对较低,分馏程度最不明显;而产在花岗岩外接触带的黑钨矿的稀土总量(ΣREEs)有高有低,分馏程度有强有弱。因此,黑钨矿的化学成分变化特征,可以有效地指示成矿物质空间运移特征、物质来源和矿床成因。  相似文献   

雅鲁藏布缝合带巴尔蛇绿岩边部石英菱镁岩成因          下载免费PDF全文

张岚  杨经绥熊发挥刘 飞周文达 《中国地质》2015,(5):1443-1456

石英(滑石)菱镁岩是基性岩、超基性岩与富CO2流体反应形成的一套硅化-碳酸盐化蚀变岩,常伴生金、汞、菱镁矿、碱金属矿化而在国外备受关注,但国内相关研究较薄弱。巴尔蛇绿岩位于西藏阿里地区,石英菱镁岩主要出露在蛇绿岩体东北边界,出露厚度约20 m,近北西西向延伸数千米。本文系统研究了雅鲁藏布缝合带西段巴尔蛇绿岩边部石英菱镁岩矿物学及地球化学特征。根据尖晶石镜下特征,划分为两个阶段:一阶段石英菱镁岩中尖晶石稳定存在,二阶段石英菱镁岩中尖晶石几乎全部蚀变(代表更强程度蚀变作用)。石英菱镁岩主要地球化学组成为Si O2、Mg O及CO2,8件样品主量元素含量变化较大,Si O2/Mg O比值波动较大,反映石英菱镁岩形成为非等化学过程。蛇纹石化橄榄岩与石英菱镁岩有着相似微量元素分布规律,表明同源性,但两者仍有较明显差异:两阶段石英菱镁岩LREE都较地幔橄榄岩略富集,从地幔橄榄岩到两阶段石英菱镁岩,HREE先亏损再略富集。微量元素标准化图解中,Sr在橄榄岩与石英菱镁岩中都为正异常,其含量随蚀变强度增强而增加。此外,两阶段石英菱镁岩均无Au、Hg矿化。  相似文献   

角闪石族和辉石族矿物的系统矿物学分类命名   总被引：1，自引：0，他引：1  

刘显凡  汪灵  李慧  刘菁  赵甫峰  卢秋霞  胡琳 《矿物学报》2015,35(1):19-28

角闪石族和辉石族矿物是链状硅酸盐矿物的重要组成部分,它们中的许多矿物种属于造岩矿物和/或工业矿物,具有重要的成因矿物研究意义和工业应用开发价值。国内学者对它们的分类命名和基本系统认识主要源自于王璞等(1984)编著的《系统矿物学》。随着科学技术发展和矿物学研究的不断深入,原有的矿物基础资料和分类命名都在不断更新与完善,迄今已有专业学术机构和学者在不同年代陆续发表了不同版本对该两类矿物的修订或修改意见,但一直没有统一整合,导致在涉及该两类矿物的应用研究中,在分类命名上与国际标准不统一。根据本课题组在国家公益性行业科研专项项目(新编《系统矿物学》)所承担的研究任务和当前国内外研究进展,本文系统归纳、梳理并综述了角闪石族和辉石族矿物的分类方案和命名原则,使分类命名统一标准、原则和认识并与国际接轨,这有利于该两类矿物的理论研究与开发应用,更好地支撑地质学及相关学科的研究与发展。  相似文献   

Origin of Listwanite in the Luobusa Ophiolite, Tibet, Implications for Chromite Stability in Hydrothermal Systems   总被引：1，自引：0，他引：1  

ZHANG Lan  YANG Jingsui  Paul T. ROBINSON  XIONG Fahui  CHEN Yanhong  LAI Shengmin  CHEN Mei 《《地质学报》英文版》2015,89(2):402-417

Listwanite from the Luobusa ophiolite,Tibet,forms a narrow,discontinuous band along the eastern part of the southern boundary fault. We undertook a detailed petrographic and geochemical study to understand the mineral transformation processes and the behaviour of major and trace elements during listwanite formation. Three alteration zones characterized by distinct mineral components and texture are recognized and,in order of increasing degree of alteration,these are: zoneIII is rich in serpentine minerals; zoneII is rich in talc and carbonates; and zoneI is mainly composed of carbonates and quartz. Geochemical data for the three alteration zones show significant modification of some major and trace elements in the protolith,although some oxides show linear correlations with Mg O. Gold mineralization is recognized in the Luobusa listwanite and may signify an important target for future mineral exploration. Gold enrichment occurs in both zoneI and zoneIIand is up to 0.91 g/t in one sample from zoneI. We show that CO2-rich hydrothermal fluids can modify both the occurrence and composition of chromite grains,indicating some degree of chromite mobility. Low-Cr anhedral grains are more easily altered than high-Cr varieties. The compositions of chromite and olivine grains in the listwanite suggest a dunite protolith.  相似文献   

华北陆块南缘郁山铝土矿矿物组成研究          下载免费PDF全文

焦赞超  梁会娟  张筝  刘百顺  李中明  王庆飞  董卫东 《地质找矿论丛》2015,30(4):480-491

郁山铝土矿床是2006年河南省地质调查院在豫西新安县发现的一个大型隐伏铝土矿矿床。文章通过利用显微镜、X衍射、扫描电镜、电子探针、红外光谱、热重等手段分析发现,郁山铝土矿中的矿物组成有:铝矿物,黏土矿物,铁矿物,钛矿物,非晶质,其它微量矿物(锆石、电气石、硫磷铝锶矿、明矾石、斜长石、钾长石、石英、方解石)六大类。非晶质组分的存在是华北陆块南缘铝土矿研究中物质组分方面的一个突破,为华北陆块南缘铝土矿的物质来源,成矿过程以及物质成分变化研究提供了线索和证据。  相似文献   

技术要素按贡献参与分配的探讨     

湛波 《广东海洋大学学报》2003,23(2):88-93

分析了技术要素按贡献参与分配的基本依据和存在问题 ,提出了技术要素按贡献参与分配的建议 :1.在企业分配领域 ,鼓励技术要素以多种形式参与收益分配 ,鼓励体制创新 ,推进技术股份化。 2 .在政府分配领域 ,政府财政科技投入比例与其科技发展对经济贡献增长率挂钩 ,科技财税政策与产业政策、税源经济吻合 ,营造科技奖励的软环境。 3.在社会分配领域 ,充分发挥技术评估部门和行业管理部门的作用 ,对进入技术市场的技术的成熟度和科技含量进行有效的测试和监管 ,保证技术商品的品质 ;技术交易当事人应具诚信态度和法制观念 ;重视中介的作用 ,把技术市场搞活。  相似文献   

Nouvelles données sur le téphra de Sarliève et le téphra CF7, marqueurs chrono-stratigraphiques de Grande Limagne (Massif central,France)     

Didier Miallier  Serge Sanzelle  Thierry Pilleyre  Gérard Vernet  Sarah Brugière  Tohru Danhara 《Comptes Rendus Geoscience》2004,336(1):1-8

A trachytic tephra, discovered in the ancient lake of Sarliève, ‘Grande Limagne’, has been dated using the thermoluminescence technique. The obtained age, 16±4 ka ($\text{2}\text{σ}$), is older than that of the trachytic volcanoes of the Cha??ne des Puys, the ashes of which have already been locally recognised in the region. Its analysis confirms its originality. In the course of the comparisons made to search for its spring, it appears that the wide-dispersion tephra CF7, beforehand correlated by hypothesis to the Puy de Clierzou, probably originates from the Kilian crater or the Puy de Vasset. To cite this article: D. Miallier et al., C. R. Geoscience 336 (2004).  相似文献