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11.
 Canonical discriminant function analysis was employed to discriminate between electron microprobe-determined titanomagnetite and hornblende analyses from Egmont volcano and Tongariro Volcanic Centre. Data sets of 436 titanomagnetite and 206 hornblende analyses from the two sources were used for the study. Titanomagnetite chemistry provided the best discrimination between these two sources with classification efficiencies of 99% for sample averages and 95% for individual analyses. The difference between sources for hornblende chemistry was less marked, but classification efficiencies of 100% for sample averages and 87% for individual analyses were achieved. Using the same methods a preliminary discrimination of individual Egmont volcano-sourced tephras was attempted. Titanomagnetite chemistry enabled the discrimination of several individual tephras or at least pairs of tephra units, but hornblende chemistry provided little discrimination. This technique provides an improvement on previous methods for chemically distinguishing distal tephra from the two sources as well as potentially identifying individual tephras from a particular source. A major advantage over previous discrimination techniques is that individual analyses can be classified with a known probability of group membership (with groups such as volcano source or an individual tephra unit). Tephras in a depositional environment where mixing is common such as within soil, loess and marine sequences, can be sourced or identified more easily with classification of individual grains. Received: 19 July 1995 / Accepted: 13 February 1996  相似文献   
12.
Single-grain geochemical composition of volcaniclastic sandstones can be a potential tool to improve correlations of mixed pyroclastic/epiclastic deposits. To test this, trachytic tuffs of the paleoanthropologically important FLK, FLK N, and FLK NN sites of Pleistocene Olduvai Gorge Bed I (Tanzania) are used as an established tephrostratigraphic framework against which to test volcaniclastic sandstone correlations. Fluvio-lacustrine sandstones and tuff samples were collected from eight archeological trenches between Tuffs IB and ID across a 500-m transect, including Leakey's famous Zinjanthropus (FLK) and OH 7/OH 8 (FLK NN) sites. A previously unknown, thin, fine, mineralogically unique, black trachyandesitic fallout ash was discovered below Tuff IC. Compositions of individual augite, feldspar and titanomagnetite grains from sandstones between Tuffs IB and IC reveal some IB-equivalent material, and a new compositional assemblage distinct from the sandwiching marker tuffs. Mineral compositions of the “tripartite” volcaniclastic sandstone between Tuffs IC and ID are similar to ID. Volcaniclastic sandstone grain fingerprints further refine correlations between fluvio-lacustrine sections within the area, providing support for proposed high-resolution stratigraphic reconstruction of the Zinjanthropus and OH 7/OH 8 land surfaces. This method might be applied to other sections where pyroclastic particles are admixed but distinct tuffs are not preserved.  相似文献   
13.
The discovery of a cryptotephra (nonvisible volcanic horizon) in a windblown sand archaeological site in Poland highlights how luminescence and tephrostratigraphy may combine to better refine the chronology of such sites. In this study we identify a cryptotephra horizon which on the basis of major and minor element geochemistry and an OSL age of 2.3 ± 0.1 ka is correlated to the Glen Garry tephra. The different methodological strengths of OSL and tephrostratigraphy may be harnessed to counter the limitations of a single approach to produce a more secure chronology. Although in this study the tephra deposition event is shown to post-date the archaeological activity, the methodological approach is clearly demonstrated. Further investigations will reveal if cryptotephra layers are commonly preserved in such environmental settings. If this is so then future applications of this approach may prove to be more widely applicable.  相似文献   
14.
火山灰年代学:原理与应用   总被引:1,自引:0,他引:1  
火山灰(2mm)等时标志层是火山灰年代学研究的基础。火山灰地层的直接或间接测年依赖于火山灰中存在合适的原生矿物(如:透长石、锆石、磷灰石)或外来物质(如:炭化木)。然而大多数火山灰沉积层,尤其是远源火山灰,其主要由岩浆源碎屑构成,开展测年显得十分困难。利用火山玻璃(岩浆)的地球化学,是一种被广泛应用的替代性方法。火山玻璃作为岩浆源物质普遍出现在各类近源、远源可见火山灰层和显微火山灰中,其主量、微量元素含量和特定的同位素组成能被电子、激光和离子探针技术准确测定。近源-远源玻璃化学成分的相互匹配,使得火山灰等时标志层得以在时间和空间上相互关联,构成有力的地层学工具,用以同步各类环境、考古和火山活动记录。近源火山沉积和远源火山灰层中的年龄信息得以实现交叉验证和整合。远源海洋、湖泊沉积中的相对年龄信息(氧同位素地层学,年纹层年代学)也为揭示火山活动、古环境变化和考古学事件的时间顺序提供了可能。火山灰年代学在地球科学中应用广泛,尤其是对于第四纪研究,其在同步各类记录从而评估火山活动、气候/环境变化和人类演化/迁移的因果关系中具有至关重要的作用。  相似文献   
15.
Only Ulleung and Baegdusan volcanoes have produced alkaline tephras in the Japan Sea/East Sea during the Quaternary. Little is known about their detailed tephrostratigraphy, except for the U–Oki and B–Tm tephras. Trace element analysis of bulk sediments can be used to identify alkaline cryptotephra because of the large compositional contrast. Five sediment cores spanning the interval between the rhyolitic AT (29.4 ka) and Aso-4 (87 ka) tephras were analyzed using an INAA scanning method. Source volcanoes for the five detected alkaline cryptotephra were identified from major element analyses of hand-picked glass shards: Ulleung (U–Ym, and the newly identified U–Sado), and Baegdusan (B–J, and the newly identified B–Sado and B-Ym). The eruption ages of the U–Ym, U–Sado, B–J, B–Sado, and B–Ym tephras are estimated to be 38 ka, 61 ka, 26 ka, 51 ka, 68–69 ka, and 86 ka, respectively, based on correlations with regional-scale TL (thinly laminated) layer stratigraphy (produced by basin-wide changes in bottom-water oxygen levels in response to millennium-scale paleoclimate variations). This study has allowed construction of an alkaline tephrostratigraphical framework for the late Quaternary linked to global environmental changes in the Japan Sea/East Sea, and improves our knowledge of the eruptive histories of Ulleung and Baegdusan volcanoes.  相似文献   
16.
Stratigraphically important Quaternary rhyolitic tephra deposits that erupted from the Okataina and Taupo volcanic centers in New Zealand can be geochemically identified using the FeO and MgO contents of their biotite phenocrysts. The FeO/MgO ratio in biotite does not correlate with FeO/MgO in the coexisting glass phase so that tephra beds with similar glass compositions can be discriminated by their different biotite compositions. Some individual tephra deposits display sequential changes in biotite composition that allow separate phases of the eruption to be identified, greatly increasing the potential precision for correlation. In addition, devitrified lavas that are unsuitable for glass analysis can be correlated to coeval tephra deposits by their biotite compositions. Biotite is common in high-K2O (>4 wt%) tephra beds and is widely dispersed in ash plumes because of its platy form, thus making it important in correlation studies.  相似文献   
17.
Detailed tephrochronologies are built to underpin probabilistic volcanic hazard forecasting, and to understand the dynamics and history of diverse geomorphic, climatic, soil-forming and environmental processes. Complicating factors include highly variable tephra distribution over time; difficulty in correlating tephras from site to site based on physical and chemical properties; and uncertain age determinations. Multiple sites permit construction of more accurate composite tephra records, but correctly merging individual site records by recognizing common events and site-specific gaps is complex. We present an automated procedure for matching tephra sequences between multiple deposition sites using stochastic local optimization techniques. If individual tephra age determinations are not significantly different between sites, they are matched and a more precise age is assigned. Known stratigraphy and mineralogical or geochemical compositions are used to constrain tephra matches. We apply this method to match tephra records from five long sediment cores (≤ 75 cal ka BP) in Auckland, New Zealand. Sediments at these sites preserve basaltic tephras from local eruptions of the Auckland Volcanic Field as well as distal rhyolitic and andesitic tephras from Okataina, Taupo, Egmont, Tongariro, and Tuhua (Mayor Island) volcanic centers. The new correlated record compiled is statistically more likely than previously published arrangements from this area.  相似文献   
18.
Correlation of volcaniclastic deposits of the Bedded Tuff Member (K4) of the Kapthurin Formation (Kenya) provides the means to assess the nature of archaeological change during the later middle Pleistocene, a time period critical to human evolution but poorly represented at other African localities. Field stratigraphic evidence, and petrographic and electron microprobe geochemical analyses of volcanic glass and phenocrysts, define eight subdivisions of K4 tephra. These include a succession of deposits from a local volcanic source that erupted intermittently, as well as other tuffs likely from different sources outside the Baringo basin. Upper portions of the Bedded Tuff Member date to 235,000 yr. The Bedded Tuff Member is underlain by sediments that include the Grey Tuff, dated to 509,000 ± 9000 yr. The tephrostratigraphic framework defined here is used to place Acheulian and Middle Stone Age (MSA) archaeological sites in chronological order. Results show the persistence of Acheulian large cutting tool manufacture after the advent of points, considered an MSA artifact type. Two assemblages from the site of Koimilot record the appearance at 200,000–250,000 yr of a variety of Levallois flake production methods, an integral if incompletely understood feature of the MSA, here likely derived from local technological antecedents. Combined evidence from the tools and flake production methods suggest an incremental and mosaic pattern of change in hominin adaptive strategies during the Acheulian–MSA transition.  相似文献   
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